UCI GENERAL CHEMISTRY DEPARTMENT PEER TUTORING

REVIEW SESSION FEEDBACK EVALUATION

Quarter

Spring 2015

Date

Class: Chem 1C- Prof. Prescher

Circle One

Midterm Review

Final Review

Tutors Names Kiro- Sina

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General Chemistry Peer Tutoring Midterm 1 Review

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Professor Prescher Chem 1C

Kiros Section:
1. Predict the effect of the following changes on the reaction in which SO3 decomposes to form
SO2 and O2.
2 SO3(g)

2 SO2 (g) + O2 (g)

Ho = 197.78 kJ

(a) Increasing the temperature of the reaction.

(b) Increasing the pressure on the reaction.

(c) Adding more O2 when the reaction is at equilibrium.

(d) Removing O2 from the system when the reaction is at equilibrium.

2. Write the Kp for the reaction and state where the reaction is Homogeneous or Heterogeneous.
a) 2C2H4 (g) + 2H2O (g) 2C2H6 (g) + O2 (g)

b) Ti (s) + 2Cl2 (g) TiCl4 (g)

3. The two common chlorides of Phosphorus, PCl3 and PCl5, both important in the production of
other phosphorous compounds, coexist in equilibrium through: (number 17 from p. 655 in the
textbook)
PCl3 (g) + Cl2 (g) PCl5 (g)
At 250 C, an equilibrium mixture in a 2.50 L flask contains 0.105 g PCl5, 0.220 g PCl3, and
2.12 g Cl2. What are the values of (a) Kc and (b) Kp for this reaction?

4. Determine the percent H2O2 that decomposes in the time using k=6.40105s1 if the time
for the concentration to decompose is 600.0 s after the reaction begins.

5. How much time will be required for a sample of H-3 to lose 75% of its
radioactivity? The half-life of tritium is 12.26 years.

Sinas Portion:

1. When CS2 (g) (0.006226 M) and 10.96 mol of H2 in a 440.0 L reaction vessel at 679.0
degrees Celsius are allowed to come to equilibrium, the mixture contains 1.823 mol of CH4
(g). What is the concentration of H2?
CS2 (g) + 4H2 CH4 (g) + 2H2S (g)

2. Consider the reaction below:

2SO2 (g) + O2 (g) 2SO3 (g)
At equilibrium at a certain temperature, the concentrations of SO3 (g), SO2 (g), O2 (g) are
0.24 M, 0.82 M, and 0.33 M, respectively. Calculate the value of Kc for this reaction.

3. Consider the following reaction. The initial concentrations are [HSO4 ] = 0.50 M, [H3O+] =
0.020 M, [SO42-]= 0.060 M.
HSO4 (aq) + H2O (l) H3O+ (aq) + SO42-(aq)
K = 0.012

(a) Which way would the reaction shift to reach equilibrium?

(b) What are the equilibrium concentrations of the products and reactants.

4. Consider the following reaction:

2NO(g)+2H2 (g) N2 (g)+2H2O(g)
Determine the value of the equilibrium constant, Kc, for the reaction. Initially, a mixture of
0.100 M NO, 0.050 M H2, 0.100 M H2O was allowed to reach equilibrium (initially there
was no N2). At equilibrium the concentration of NO was found to be 0.062 M.