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Fita Candra
4301413046
Nurul Latifiyah
4301413083
heat
N2(g) + 2H2O(l)
Ammonia (NH3) is a nitrogen compound that is very important because it is the raw
material for making other important nitrogen compounds such as urea and nitrogen
oxides.
H2(g) + 3H2(g)
2NH3(g)
H = -92kJ mol-1
Nitric acid can not be isolated in pure liquid form because it is easily decomposed by
disproportionation reaction.
3HNO2 HNO3 + H2O + 2NO
HNO2 is oxidizing with iodine ions ( I- ) and as reducing the permanganate ion
(MnO4-)
2HNO2 + 2H+ + 2I- I2 + 2NO + 2H2O
5HNO2 + H+ + 2MnO4- Mn2+ + 5NO3- + 3H2O
Compounds
-3
-2
-1
0
+1
+2
+3
+4
+5
(Inorganic Chemistry Lecturer Team, 2015)
NH3
N2H4 (hidrazin)
NH2OH (hydroxylamine)
N2
N2O
NO
N2O3
NO2
HNO3
The electronic configuration of nitrogen atom in its ground state is 1s 2 2s2 2p3, with the
three 2p electrons distributed among the p x, py, and pz orbitals with spins parallel. Nitrogen
forms an exceedingly large number of compounds. Most of which are to be considered
organic rather than inorganic. It is one of the most electronegayive elements, only oxygen and
fluorine exceeding in this respect. The nitrogen atom may complete its octet in several ways :
Electron gain to form the nitride ion, N3 Formation of electron-pair bonds
Formation of electron-pair bonds with electron gain
Formation of electron-pair bonds with electron loss
(Cotton and Wilkinson. 1989)
C. Methode
Equipments
Test tube
250 ml beaker glass
100 ml erlenmeyar
Stirring bar
Spiritus burner
Tripod
Gauze
Clamp
Spatula
Materials
Litmus indicator
0,05 M NaOH
0,05 M sulfuric acid
2 M HNO3
Potassium nitrate solid
Copper nitrate solid
Concentrated nitric acid
KI
KMnO4
7 M HNO3
Aluminium metal
Copper metal
Work instructions
1. a. The reaction of HNO3 and Cu
Insert Cu metal into test tube. Add few drops of concentrated
HNO3. Observe the reaction
Dilute 2 ml of HNO3 to obtain solution of HNO3 7 M. Add
three pieces of Cu and note the gas that is formed
b. Heating of Nitrate salts
Heat a solid KNO3 in a test tube
Note the color of solution and the compounds that are formed
Divide the solution into 3 parts. Heat the first tube and observe
the gas formed
D. Observation Data
N
o
Experiment
Observed
2 Copper metals +
few drops of
concentrated
HNO3
Reaction Occured
Observation Result
+ 2NO2(g) + 2H2O(l)
3 copper metals +
HNO3 7M
NO(g) + H2O(l)
Heating a solid
KNO3
Heating a solid
Cu(NO3)2
Cu(NO3)2.3H2O(s) Cu(NO2)2(aq) +
3H2O(l) + O2(g)
2 ml HNO3 2M +
5ml NaOH
Adding of 1 piece
of Al metal
Heating
Blue solution
The color of gas is
brown
There are bubbles
The copper metal
is completely
dissolved
Colorless solution
There are bubbles
The copper metals
are dissolved
After some
minutes, the color
of solution
changed to light
blue
A solid KNO3 is
melted
There are bubbles
gas
pH of gas is acid
After some
minutes, crystal
KNO3 is formed
again
A solid Cu(NO3)2
is melted
There are bubbles
gas
pH of gas is acid
Yellow solution
Al metal is sink
Colorless solution
Diluted H2SO4
(cooled) + NaNO3
Dividing the
solution into 3
parts
Heating tube I
4
H2SO4(aq) + NaNO3(s)
NaHSO4(aq) + HNO2(aq) + 1/2O2(g)
Tube II + KI
Tube III +
KMnO4
5NO2-(aq)+2MnO4-(aq)+6H+(aq)
5NO3-(aq)+2Mn2+(aq) +3H2O(l)
Colorless solution
There are many
bubbles
pH of gas is acid
Pale yellow
solution
There are bubbles
pH of gas is acid
Purple solution
No bubbles and
gas formed
E. Discussion
Redox reaction of nitric acid with nitrate salt
Experiment 1 : The reaction of nitric acid with copper
The goal of this experiment is to identify the redox reactions that occur
between concentrated nitric acid and dilute nitric acid when reacted with metallic
copper. The first experiments were conducted was reacting concentrated nitric acid
solution with two pieces of copper metal. This experiment is carried out in a fume
because the solution used is a concentrated nitric acid.
Once we drop the concentrated nitric acid into test tube contained two pieces
of copper metal, the solution initially colorless turns to blue. There are also the
formation of bubbles. In the test tubes wall appears brownish yellow gas. Two pieces
of copper are completely dissolved. Reactions that occur :
4HNO3(l) + Cu (s) 2NO2(s) + Cu(NO3)2(aq) + 2H2O(l)
+
5
+
4
+
2
(reduction)
(oxidation)
Copper (Cu) undergoes oxidation becomes Cu2+ (Cu as a reducing agent) with
an increase in oxidation number from 0 to +2. While nitrogen (N) undergoes reduction
(nitrogen as an oxidizing agent) with a decrease in oxidation number from +5 to +4.
While the blue color is produced by the solution due to the Cu 2+ ions. In this reaction
produced NO2 because the solution thas used is a solution of concentrated nitric acid.
This is fit with the theory that if a metal reacted with concentrated nitric acid it will
produce NO2 gas.
Next, three pieces of copper metal is reacted with a solution of HNO 3 7M. This
reaction produced blue solution. There are bubbles. Copper metal is dissolved in
HNO3 solution. The reaction occured:
HNO3 (aq) + Cu (s) Cu(NO3)2 (aq) + 2NO (g) + 2H2O (l)
+
5
+
2
(oxidation)
+
2
(reduction)
The reaction produces NO gas. This different from the first reaction because
we used nitric acid solution 7M. This is fit with theory that if a metal reacted with
dilute nitric acid it will produced NO gas. In the reaction above, Cu as a reductant
because undergoes oxidation with the increase in oxidation number from 0 to +2.
While nitrogen as an oxidant because undergoes reduction with a decrease in the
oxidation number from +5 to +2.
The second reaction is slower than the first. It because we used the different
HNO3. The higher the concentration of HNO3, the ability to oxidize copper will be
greater. The gas produced is also different. The first experiment produces NO 2 gas,
while in second experiment produces NO gas.
Experiment 2 : Heating of nitrate salt
The purpose of this experiment is to identify the redox
reactions that occur in the heating of nitrate salts. First reaction is
heating spatula of white solid KNO 3 in a test tube. After heating,
KNO3 is melted and produces gas bubbles. When we test with red
litmus paper, the color of litmus does not changes. It means that the
pH of gas produced is acid. The reaction occured :
2KNO3 (s) KNO2 (l) + 1/2 O2 (g)
Second reaction is heating spatula of blue solid Cu(NO3)2 in a
test tube. After heating, Cu(NO3)2 is
bubbles. When we test with red litmus paper, the color of litmus
paper does not changes. It means that the pH of gas produced is
acid. The reaction occurs:
Cu(NO3)2.3H2O(s) Cu(NO2)2(aq) + 3H2O(l) + O2(g)
that the heating can quicken the reaction. This reaction produced ammonia gas. When
we test with red litmus paper, the color turns to blue. It means that the pH of gas that
produced is base. The reaction occured :
3NO3- (aq) + 8Al (s) + 5OH-(aq) + 18H2O (aq) NH
3 (aq) + 8[Al(OH)4]
+
-3
5
(reduction)
+
4
(oxidation)
+
3
(oxidation)
+
2
(reduction)
The reaction above is a disproportionation reaction (derived from the same species).
Nitrogen undergoes oxidation and reduction at the same time
2NO2 (aq) + 4H+ (aq) + 2I- (aq) 2NO (g) + 2H2O (aq) + I2 (aq)
+
4
-1
+
2
(reduction)
(oxidation)
+
7
+
5
+
2
(oxidation)
(reduction)