Professional Documents
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1|Page
C2H4O
44.05 gmol1
Colourless liquid
Etherial odor
Density
Melting point
Boiling point
Solubility
0.79040.7928 gcm3(10 C)
123.37 C (190.07 F; 149.78 K)
20.2 C (68.4 F; 293.3 K)
Miscible with ethanol, ether,
benzene, toluene, xylene, acetone
slightly soluble in chloroform
Vapor pressure
740 Hg (20 C)
2|Page
basic dyes. Acetaldehyde is also used as a solvent in the rubber, tanning, and paper
industries, as a fruit and fish preservative, as a flavouring agent, for hardening gelatin, as
a denaturant for alcohol and in fuel compositions.
3|Page
The conversion of ethanol is assumed to be 60.8%. The yields for each reaction are as
follows:
(1) Acetaldehyde 91.7%
(2) Ethyl acetate 3.8%
(3) Butanol 2.4%
(4) Acetic acid 2.1%
4|Page
References are not available for these values. Since reaction kinetics were not
available, the above conversions were assumed in the design of the process. NRTL
thermodynamics was used for K-values, as suggested by the Chemcad.
5|Page
Ethyl Acetate
Even though it is not the main product in the manufacturing process it is a
valuable chemical and thus if recovered properly may also be sold as a by-product to
industries that require ethyl acetate as their raw materials or anywhere else in their
manufacturing process.
Ethyl acetate (systematically Ethyl Ethanoate, commonly abbreviated EtOAc or
EA) is the organic compound with the formula CH3-COO-CH2-CH3, simplified to
C4H8O2. This colourless liquid has a characteristic sweet smell (similar to pear drops) and
is used in glues, nail polish removers, decaffeinating tea and coffee, and cigarettes). Ethyl
acetate is the ester of ethanol and acetic acid; it is manufactured on a large scale for use
as a solvent.
Butanol
Butanol (also butyl alcohol) refers to a four-carbon alcohol with a formula of
C4H9OH. There are four possible isomeric structures for butanol, from a straight-chain
primary alcohol to a branched-chain tertiary alcohol. It is primarily used as a solvent, as
an intermediate in chemical synthesis, and as a fuel. It is sometimes also
called biobutanol when produced biologically.
Butanol sees use as a solvent for a wide variety of chemical and textile processes,
in organic synthesis and as a chemical intermediate. It is also used as paint thinner and a
solvent in other coating applications where it is used as a relatively slow evaporating
latent solvent in lacquers and ambient-cured enamels. It finds other uses such as a
component of hydraulic and brake fluids.
Butanol is considered as a potential biofuel (butanol fuel). Butanol at 85 percent
strength can be used in cars designed for gasoline (petrol) without any change to the
engine (unlike 85% ethanol), and it contains more energy for a given volume than ethanol
and almost as much as gasoline, so a vehicle using butanol would return fuel
consumption more comparable to gasoline than ethanol. Butanol can also be used as a
blended additive to diesel fuel to reduce soot emissions.
6|Page
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Vaporizer:
1000 C, superheated stream of ethanol Steam
(Heating fluid)
Condensed steam
300 C, ethanol
Ethanol liquid inlet temperature = Ti =30 C. Ethanol leaves as superheated steam at 100 C =
To
Heating fluid is assumed to be saturated steam here and to provide sufficient temperature
2|Page
= 4718.30 kg.
Reactor:
3|Page
Heat exchanger:
1000 C, ethanol
T=3100 C.
A= 6500 kg.
H = 295.45 kg.
2000C
E = 433.75 kg.
This is used only for heat recovery. Since it is assumed vapour is heated
upto 200 C by the product stream of the reactor at 300 C.
Let outlet temperature = T C.
= 1017.06*0.549*(310-T) + 397.78*2.485*(310-T)+10165.54*0.528
Therefore, T = 282.48 C
Condenser 1
In condenser 1 it is decided to use cooling water at 3000 C. the outlet temperature
of cooling water is not allowed to go above 500C, because above this temperature, there
is a problem of vaporization. Normally the approach temp difference is about 100C.
Since the product can at best be cooled to 400C, at this temperature the product stream
would be a two-phase mixture and the mixture composition can be found out from VLE
data.
We make an approximate that; the information given at 699 mmHg is taken. At 4000C,
Ethanol in vapour phase = 4.1 mole %.
4|Page
Vapours at 400C.
H = 295.45 kg.
H = 295.45 kg.
E =433.75 kg.
A = 6500 kg.
E = 433.75 kg
A =295.45 kg
T= 50 0C
Liquid at 40 0C
E= 148.46 kg
A= 116.186 kg
3
10 kcal.
Heat given out by acetaldehyde = 8750.7* 0.417 * (282.48 40) + 525.8 * 139.5
= 958.17 * 103 kcal.
Heat given out by ethanol = 1017.06* 0.5415 * (282.48 40) + 671.6 * 200.6
= 268.27 * 103 kcal
5|Page
Condenser 2
In condenser 2, it is desired to condense all ethanol and acetaldehyde. If the
working pressure is 1atm from the equilibrium data it is seen that for temperatures
below 30 C, there is going to be no ethanol in vapour phase and acetaldehyde would exert
its vapour pressure at that temperature. If it is desired to achieve about 97% recovery of
acetaldehyde, the outlet temperature of the product stream should be about 25 C. This is
because at 22.6 C, its vapour pressure is 100 mmHg and the vapour phase will consists of
13.15mole%. In view of this, the cooling fluid chosen is saturated NH3 at 1 atm. At which it
boils at 33.6 C.
Liquid ammonia at 33.860C.
Vapours at 400C
295.45 kg = H
E = 285.32 kg
A = 6383.52 kg.
H = 295.45 kg
6|Page
Vapors at 250
191.5 kg =A
Heat balance, At 40 C,
Preheater:
The preheater to the distillation column is necessary because the feed plate will be
completely chilled if the feed is not heated. The water stream from condenser c1 is
available at 50 C and is used in the preheater. If the maximum approach temperature
7|Page
Heat balance,
At 400C,
Cp, acetaldehyde = 0.347 kcal/kg 0C. Cp, ethanol = 0.616 kcal / kg 0C.
Distillation column
In distillation column acetaldehyde condenses at 400C. Since vapour pressure
datas of pure gas is not available, it is estimated using Antoines equation.
ln P = A + B/T
Where, A and B are constants, they can be determined from boiling point data at Pressures
760 mmHg and 400 mmHg.
At 760 mmHg T = 20.2 C= 293.2K
400 mmHg T = 4.9 C = 277.9K
Therefore, ln 760 = A + B/293.2
ln 760 = A + B/277.9
On solving above two equations we get,
A = 18.29 and B = -3418.2
Therefore, ln P = 18.29 3418.2/T
Therefore at 400C, P = 1586.41mmHg.
Assume 99% acetaldehyde recovery in overhead product.
Assume xd = 0.99
In overhead:
Acetaldehyde = 8153.22kg.
Ethanol = 82.36 kg.
Total D = 8235.58 kg.
8|Page
In bottom:
Acetaldehyde = 28.65 kg. Ethanol = 448.77 kg. Total W = 477.42 kg.
F=D+W
F * xf = D * xd + W * xw
Therefore, xw = 0.06
Assume reflux ratio = 0.3
Therefore L / D = 0.3
L = 0.3 * 8235.58 = 2470.67 kg.
Vapour going to the condenser = L + D = 10706.25kg
Of this 99% is acetaldehyde.
Therefore, vapour composition going to the condenser:
Acetaldehyde =10492.13 kg.
Ethanol = 214.117 kg.
Heat load to the condenser
=Methanol * Aethanol + Macetaldehyde * Aacetaldehyde
= 214.117 * 200.6 + 10492.13 * 139.5
= 1506.604 * 103 kcal.
Reboiler load
Let m be the amount of liquid vaporized. Let L be liquid going into
the reboiler.
Let L/ W = 10
Therefore, L = 477.42 * 10 = 4774.2 kg.
Therefore, m = L W
= 4774.2 - 477.42 = 4296.78 kg.
Of which about 10% is acetaldehyde.
9|Page
10 | P a g e
Serial no
Activities
Duration (months)
1.
2.
3.
4.
5.
0.5
0.5
2.5
5
2.5
6.
7.
8.
9
3
3
9.
10.
11.
12.
13.
4
3
4
4
3
11 | P a g e
Sl. No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
12 | P a g e
Description
Main Plant
Raw material storage
Water Storage tank
Pump house
Pond
Power Substation
Final Product inventory
Fire Fighting
R&D
Garden
Administrative Building
Medical Room
Guard room
Worker's room
Cycle Stand
Canteen
Toilet Block
Gate
Internal Road(6 m wide)
Surface Drain(500 mm wide)
Future expansion and others
Total
Area (m2)
1000
350
120
30
80
120
400
50
150
80
250
80
60
30
20
60
20
50
400
100
2500
5950
1.47028
2
m
Acres
Sl. No.
Description
1 Main Factory Buinding
2 Buildings for auxiliary services
a.
b.
c.
d.
Pump House
Laboratory
Fire Fighting
Power Substation
35
50
50
120
80
60
30
20
60
20
Administrative building
4 Stores/Godowns/Warehouses etc
5 a. Raw materials storage
b. Final product storage
3200
3200
3200
3200
Sub Total(2)
1.12
1.6
1.6
3.84
8.16
3500
3000
3000
2500
3500
3000
Sub Total(3)
250
4000
2.8
1.8
0.9
0.5
2.1
0.6
8.7
10
350
400
3000
3000
Sub Total(5)
10.5
12
22.5
80 Rs. 150/m2
80
1500
Sub Total (6)
200 Rs. 10000/m3
Total (1 to 7)
0.12
1.2
1.32
35
169.36
13 | P a g e
Sl no.
1
2
3
4
5
6
7
8
9
10
11
Description
No of Required equipments
Reator
Preheater
Heat Exchanger
Absorber
Distillation Column
Alcohol storage Tank
Acetaldehyde Storage Tank
Reboiler
Condenser
Vaporiser (Flash)
Pumps
Sub Total (10)
1
3
3
1
4
1
1
1
4
1
5
1.
Raw Materials:
a. Ethyl alcohol
b. Copper- cobultchromium catalyst
2.
Power
3.
4.
Water
Packing (10kg/bottle)
14 | P a g e
Specific
consumption
per kg of
product
1.16 kg
0.012
Annual
Delivered Price
Requirement
(Rs/Ton)
s
( Tons)
19140
198
4000
6.60E+07
KWH/ton
10 kg
5.54E +04
5000/day
1650000 No.
Total Price
(Rs in lakhs)
35000
90500
6699.0
179.2
Subtotal
4.0 /KWH
6878.2
2.64E+03
6.5/ton
20/Bottle
Total (1-4)
1.07E+01
21.6
16428.7
Description
1 Land and site development
a. Land @ 13.5 lakh/acre
b. Cost Of levelling,land filling etc. (filling depth 0.8m); @ Rs. 35/m3
c. Gate
d. Surface Drains @Rs.300/m
e. Internal Roads @Rs.800/m
Sub Total (1)
Buildings/ Civil Works
2 a. Main Factory Buildings
b. Factory Building for auxiliary services
c. Adminstrative building
d. Non-factory Buildings
e. Stores, Godowns and Warehouses etc.
f. Water Reservoir
e. Miscellaneous Buildings/ Civil works
Sub Total (2)
43
8
10
4
18
30
0.52
113.52
355.34
88.84
17.76
56.85
14.21
14.21
17.76
53.3
35.53
653.8
15 | P a g e
0.544
0.8
8
40
69.214
5
3.5
1.5
1.6
1.6
13.2
1076.774
2.5
86.08
8.13
9.41
43.04
2
4
152.66
115.18
270.34
1347.114
237.72
1584.834
5.7. DEPRECIATION
A. DECLINING BALANCE METHOD
SL.NO.
ITEM
1 BUILDING
a. Factory
b. Non-factory
2 PLANT EQUIPMENT
3 MISC. FIXED ASSET
4 FURNITURE AND OFFICE
5 VEHICLES
TOTAL
2nd
3rd
4th
5th
6th
7th
8th
10
5
4.3
2.03
3.87
1.73
3.48
1.65
3.13
1.56
2.12
1.49
2.54
1.41
2.28
1.34
2.05
1.28
1.85
1.21
1.65
1.15
355.34
3.2
8.5
1.5
452.06
25
25
10
20
95
88.84
0.89
0.85
0.3
97.21
66.63
0.66
0.77
0.24
73.9
49.97
0.49
0.7
0.19
56.48
37.48
0.37
0.62
0.15
43.31
28.1
0.28
0.56
0.12
32.67
21.08
0.21
0.51
0.1
25.85
15.81
0.16
0.45
0.08
20.12
11.85
0.12
0.41
0.06
15.77
8.89
0.09
0.37
0.05
12.46
6.67
0.07
0.33
0.04
9.91
ITEM
DEPRECIABLE COST RATE AS PER DBM (%) DEPRECIATION PER YEAR ( Rs. In lakhs)
1 BUILDING
a. Factory
43
3.34
1.4362
40.52
1.63
0.66
2 PLANT EQUIPMENT
355.34
8.48
30.13
3.2
8.48
0.27
8.5
3.34
0.28
b. Non-factory
5 VEHICLES
TOTAL
16 | P a g e
10th
43
40.52
9th
1.5
6.78
0.1
452.06
32.05
32.8762
Particulars
Sl.no
.
1.
Profit Before Tax
2.
Add Depreciation (SLM)
3.
Less Depreciation (DBM)
4.
Taxable Income (1+2-3)
1
5.
Cumulative Taxable Income
6.
Income Tax
(@30% cumulative taxable
income )
17 | P a g e
st
1370.92
32.87623
97.21
306.59
1306.59
391.98
nd
rd
1307.85 1760.58
2.8762 32.8762
73.9
56.48
1266.83 1736.97
1266.83 1736.97
380.05 521.09
th
Operating Years
5
6th
th
7th
2895.27
32.8762
20.12
2908.03
2908.03
872.41
8th
3419.88
32.8762
15.77
3436.99
3436.99
1031.10
9th
10th
4004.78
32.8762
12.46
4025.19
4025.19
1207.56
4660.90
32.8762
9.91
4683.87
4683.87
1405.16
18 | P a g e
Designation
No.
Salary(Rs./month)
Annual
Expenses(Rs. In
Lakhs)
1.Administration
a.
General Manager
50000
6.0
b.
Personal Manager
26000
3.12
c.
PA of GM
12000
1.44
d.
Typist/PC Operator
10
5000
6.0
e.
Peon
12
4400
6.34
f.
Security officer
20000
9.6
g.
Production
manager
40000
4.8
SUB TOTAL(1)
37.30
2. Production
a.
Work Manager
30000
3.6
b.
Skilled Operator
20
10000
24
c.
Shift Engineer
14
15000
25.2
d.
Security Staff
15
5000
e.
Purchase Officer
20000
2.4
f.
20000
4.8
g.
Maintenance
Manager
Electrician
8000
4.8
h.
Mechanic
5000
SUB TOTAL(2)
76.8
3. Sales
a.
b.
Sales Officer
Sales Assistant
2
4
50000
13500
SUB TOTAL(3)
12
6.5
18.5
a.
Chief Accountant
20000
2.4
b.
Accountant
15000
3.6
c.
Cashier
12000
4.32
SUB TOTAL(4)
10.32
4. Accounts
19 | P a g e
a.
Chief Chemist
12000
1.44
b.
Chemist
8000
2.88
c.
Lab Assistant
5000
1.2
d.
Sweeper
2000
1.44
e.
Gardener
2000
0.48
f.
Driver
3000
1.8
SUB TOTAL(5)
9.24
15000
8000
SUB TOTAL(6)
1.80
2.88
4.68
6.Material Handling
And Development
Material Manager
Material Executive
1
3
SUB TOTAL(1 to 6)
20 | P a g e
156.6
R.
C.
D.
E.
F.
H.
I.
J.
K.
L.
M.
N.
O.
P.
Q.
Description
COST OF PRODUCTION
ADMINISTRATIVE EXPENSES
1. Administrative salary with 5%
increase per year
2. Light postage etc. [15% of 1]
3. Insurance, taxes on office
property [1% of Furniture+
car/van + office mach. cost]
4. Travelling and conveyance
[10% of administrative salary]
TOTAL ADMINIST. EXPENSES
SALES EXPENSES
1. Sales salary with 5% increase
per year
2. Publicity commission travel
etc. [0.1% of sales realisation]
3. Packing cost
2nd (80%)
7845.10
3rd (80%)
7852.489
4th (80%)
7860.246
37.30
39.17
41.13
43.17
45.33
5.595
0.1
5.876
0.1
6.169
0.1
6.48
0.1
3.73
3.917
4.113
46.725
49.063
18.5
8.856
21.6
TOTAL SALES EXPENSES
48.956
7452.405
TOTAL COST OF PRODUCTION
(A+B+C)
8856
SALES REALISATION
1403.595
GROSS PROFIT BEFORE INT &
DEP.
(E-D)
32.8762
DEPRECIATION (SLM)
1370.72
OPERATING PROFIT (F-H)
0
OTHER INCOME (IF ANY)
0.2
Preliminary Expenses Written Off
1370.92
PROFIT/LOSS BEFORE TAX (I+J+K)
391.98
PROVISION FOR TAXATION
0
TURNOVER TAX
978.94
PROFIT AFTER TAX (L-M-N)
Add depreciation (SLM)
32.8762
Less preliminary expenses
0.2
1012.01
GROSS CASH ACCURAL
Less instalment
0
012.01
NET CASH ACCURAL
21 | P a g e
Operating Years
5th (80%)
6th (85%)
8347.59
8356.165
1st (75%)
7356.724
7th (85%)
8854.252
8th (90%)
8863.684
9th (90%)
8873.587
10th (90%)
8883.984
47.59
49.97
52.47
55.09
57.84
6.79
0.1
7.138
0.1
7.496
0.1
7.871
0.1
8.264
0.1
8.676
0.1
4.317
4.533
4.759
4.997
5.247
5.509
5.784
51.512
54.067
56.753
59.587
62.563
65.688
68.963
72.4
19.425
20.396
21.416
22.487
23.611
24.791
26.03
27.33
28.69
9.285
9.749
10.24
10.748
11.286
11.85
12.442
13.064
13.714
21.6
50.31
7944.47
21.6
51.745
7955.746
21.6
53.256
7967.572
21.6
54.835
8459.18
21.6
56.497
8472.249
21.6
58.241
8922.056
21.6
60.072
8989.444
21.6
61.994
9024.544
21.6
64.004
9020.424
9585
1640.53
9749
1793.254
10240
2272.428
10748
2288.82
11286
2813.751
11850
2927.944
12442
3452.556
13062
4037.456
13714
4693.576
32.8762
1607.65
0
0.2
1607.85
380.05
0
1227.6
32.8762
0.2
1260.68
683.62
77.06
32.8762
1760.38
0
0.2
1760.58
521.09
0
1239.49
32.8762
0.2
1272.57
683.62
88.95
32.8762
2234.55
0
0.2
2234.75
667.29
0
1567.46
32.8762
0.2
1600.53
683.62
16.91
32.8762
2255.94
0
0.2
2256.14
676.91
0
1579.23
32.8762
0.2
1612.3
683.62
28.68
32.8762
2780.87
0
0.2
2781.07
836.45
0
1944.62
32.8762
0.2
1977.69
683.62
294.07
32.8762
2895.07
0
0.2
2895.27
872.41
0
2022.86
32.8762
0.2
2055.93
683.62
372.31
32.8762
3419.68
0
0.2
3419.88
1031.10
0
2388.88
32.8762
0.2
2421.95
0
421.95
32.8762
4004.58
0
0.2
4004.78
1207.56
0
2797.22
32.8762
0.2
2830.29
0
830.29
32.8762
4660.70
0
0.2
4660.90
1405.16
0
3254.84
32.8762
0.2
3287.91
0
287.91
1.
2.
nd
Opening
Balance
0
1011.816
Profit After
Depreciation
Tax
(SLM)
978.94
32.8762
1227.6 32 32.8762
Closing Balance
1011.816
2272.29
BREAK-EVEN CAPACITY
Basis: 2nd year operation at 80% capacity
Sl.No.
A.
B.
Particulars
SALES REALISATION
VARIABLE COST
1. Raw Materials
2. Utilities
3. Packing (10 kg/bottle)
4. Interest on working capital
C.
22 | P a g e
Value
9585
5502.56
2.12E+03
17.3
221.35
7.62E+03
164.43
29.42096
9.893
32.8762
236.62
5.13Executive Summary:
Pay Back Period: Within the 2nd year of operation.
Break-Even Capacity: 175.928
From this thorough analysis we can conclude that this project is feasible.
23 | P a g e