CHEMISTRY

CLASS XII
Time allowed : 3 hours

Maximum Marks : 100

General Instructions:
(a)
All questions are compulsory.
(b)
The questions paper consists of 26 questions divided into three section A, B and C, Section A comprises of 6
questions of one mark each, Section B comprises of 13 questions of four marks each and Section C
comprises of 7 questions of six marks each.
(c)
All questions in Section A are to be answered in one word, one sentence or as per the exact requirement of
the question.
(d)
Use of Calculators is not permited.

1.

SECTION A
Give the structure of propane 1, 2, 3 tricarbaldehyde

2.

Give that IUPAC name of

3.

Identify all the possible monochloro structural isomers expected to be formed on free radical monochlorination of
CH3CH2CH3

4.

What is prosthetic group? Give its functions

5.

Why the hydrolysis of ester is slow in the beginning and becomes faster after sometime?

6.

How is cast iron different from pig iron?

C6H5 CH2 CH2 COOH

SECTION B
7.

Give reason :
I
Aldehydes do not form stable hydrates but chloral exists as alcohol hydrate
II
Acetic acid can be halogenated in presence of red phosphorus and chlorine but formic acid cannot be
halogenated

8.

Give the application of Henrys law on scuba drivers

9.

Explain Frenkel defect

OR
Silver forms ccp lattice and X-ray studies of its crystals show that the edge length of its unit cell is 408.6 pm. Calculate
the density of silver. (Atomic mass = 107.9 u)

10.

Write a note on order of a reaction.

11.

(A) Identify all the possible monochloro structural isomers expected to be formed on the radical monochlorination of
CH3 2 CHCH2CH3
(B) During the reaction of alcohols with KI, sulphuric acid is not used. Give reason
(C) Alkyl halides though polar, are immiscible with water. Why ?

12.

How the presence of sulphur dioxide is detected?

13.

Vapour pressure of chloroform

respectively.

CHCI3 and dichloromethane CH2CI2 at 298 K are 200mm Hg and 415 mm Hg

(A) Calculate the vapour pressure of the solution prepared by mixing 25.5g of
(B) The mole fractions of each component in vapour phase
14.

CHCI3

and 40 g of

CH2CI 2

Complete the following reactions:

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at 295 K

 A HgCI2 PH3
B NaCIO3 I2
C SCI2 NaF
15.

Define the term:

(A) Monosaccharides
(B) Oligosaccharides
(C) Polysaccharides

16.

Calculate the mole fraction of ethylene glycol

17.

Give the formulas of the following complexes:

(A) Tetraaminedichloridocobalt (IIII ) ion
(B) Amminechloridobis (ethane 1, 2 diamine) cobalt (III) ion
(C) Potassium trioxalatoaluminate (III)

C2H6O2 in a solution containing 20% of

C2H6O2

by mass.

OR
Give some limitations of valence bond theory
18.
19.

Calculate the value of Ea and A

Differentiate globular proteins and fibrous proteins
SECTION C

20.

What are the different types of polymers based on the structure ? Give an example each

21.

How are drugs classified?

22.

Differentiate ideal and non-ideal solution.

23.

If we apply pressure greater than the equilibrium osmotic pressure to the solution compartment show below, pure
solvent will flow from the solution to the solvent compartment.
(A) What is the name of this process
(B) Write an important application associated with this process. Explain.

24.

Give the name of the reagents to bring the following conversions:

(A) Allyl alcohol to propenal
(B) But-2-ene to ethanol
(C) Cyclohexanol to cryclohexanone
(D) Hexan-1-ol hexanal
(E) Hexan-1-ol to hexanal
Complete the reactions:

O
+

HO

NH2

(A)

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O
R

CH

CH

CHO

+ NH 2

NH

NH2

(B)

O
C
CH3

+ CH 3CH 2 NH 2

(C)

25.

(A) Give the important advantage of fuel cells over ordinary batteries.
(B) Define molar conductivity and equivalent conductivity
OR
(A) Represent the cell in which the following reactions takes place
Mg S 2Ag 0.0001M Mg2 0.130M 2Ag s .
E cell Ecell 3.17 V
Calculate its
Cu s 2 Ag aq Cu2 aq 2 Ag s . Ecell 0.46 V
(B) The reaction the equilibrium constant of the reaction:
If

26.

(A) The standard electrode potential for Daniell cell is 1.1V. Calculate the standard Gibbs energy for the reaction :
Zn s Cu2 aq Zn2 aq Cu s
2
(B) If the limiting molar conductivities for NaCI, HCI and NaAc are 126.4, 425.9 and 91.05 cm mol respectively,
0
then calculate for HAC

OR
5
(A) The conductivity of 0.001028 mol/L acetic acid is 4.95 x 10 s / cm . Calculate the dissociation constant if the
2
limiting molar conductivity for acetic acid is 390.5 S cm / mol
(B) Give a short note on nickel cadmium cell. Give its overall reaction during discharge.

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