Professional Documents
Culture Documents
[11]
[45]
Mercado et a1.
[54]
4,423,031 12/1983
4,673,571 6/1987
4,996,044
Feb. 26, 1991
Patent Number:
Date of Patent:
OTHER PUBLICATIONS
64542k.
[63]
[56]
References Cited
8/1981
[57]
ABSTRACT
An improved lipstick formulation is provided which is
creamy, shiny and soft, which includes relatively small
amounts of organic high staining dyes and yet maintains
ingredients.
424/64
8 Claims, No Drawings
4,996,044
, 1
oring to the lips and thus lessen the need for frequent
55
4,996,044
eral formula
or carnauba wax.
mixtures thereof.
35
being preferred.
>
4,996,044
% Present
Glycine
20.0-30.5
Alanine
Serine
Threonine
Proline
8.0-1 1.0
2.9-4.1
1.8-2.6
13.7-18.0
Hydroxyproline
12.1-14.5
Valine
Isoleucine
Leucine
Phenylalanine
2.1-3.4
1.3-1.8
2.8-3.5
1. l-2.6
Tyrsine
Cystine/Cysteine
0.2-1.0
0.0-0.9
Methionine
0.7-0.9
Aspartic Acid
5.7-9.0
Glutarnic Acid
10.0-11.7
Arginine
7.8-9.0
Histidine
0.7-1.0
Lysine
Hydroxylysine
3.9-5.2
0.7-1.2
The term wheat germ glycerides as employed 45 the lipstick formulation by incorporation into the anhy
drous base or even into the color intermediate, in
herein is as de?ned in the CTFA Cosmetic Ingredient
amounts of less than about 1% by weight of the lipstick
Dictionary, Second Edition, 1977, namely, a mixture of
formulation and preferably from about 0.1 to about
mono-, di- and triglycerides produced by the transester
0.3% by weight.
i?cation of wheat germ oil. It is a known material and is
The lipstick when applied coats the lips with the
available commercially as Wickenol 535 from Wickhen 50
acrylate copolymer causing the color or pigment to
Products, Inc., Huguenot, N.Y. 12746.
easily laydown in a creamy uniform manner with the
The color intermediate will contain from about 25 to
colors penetrating every pore and crevice on the lip
about 40% by weight and preferably from about 30 to
surface.
about 36% by weight (based on the weight of the color
Preferred lipstick formulations in accordance with
intermediate) of one or more color pigments which 55
the present invention are set out below.
include one or more organic high staining dyes, option
ally one or more other organic dyes (including medium
Preferred Formulations
% w/w of Total
Ingredient
Base lnterrnediate
Candelilla wax (stick
strengthener)
Lipstick Formulation
50 to 70
10 to 14
2 to 6
1.5 to 10
enhancer)
strengthener)
7 to 20
4,996,044
. 7
-continued
-continued
Preferred Formulations
_
Ingredient
Beeswax (strengthener)
Hydrogenated vegetable oil
Ingredient
_% w/w f To!
Lipstick Formulation
0.5 to 5
3 to 6
Petrolatum white
Lanolin oil
Ole)1 a1chl
pmpyl Paraben
Butylated hydroxyanisole
0.02
1.5 to 12
SOfICHCI-CQSIOI 011
7-46
(fed cnhancef-cfcam)
Petrolatum white (lip
moisten")
6.4
6A
11-6
Q09
4 to 8
4 to 8
7 to l5
Amloxidlm
CPIOI' Imcrmedilm
10
Red 7
Russet
Red 6
4
2.5
l
2
20
(1005
0.025
Tioz
Castor oil
propyl paraben
0 to 0.1
0 0 Q02
10 I0 35
15
Butylated hydroxyanisole
Acrylates Cowlmer Intermediate
20 to 30
1.5
polymer powder)
Castor oil
1.5
Q5
Fragm
3239i
Parts by Weight
2o
ems
(o tfzoqzggm
0 0'01
50mm (cum 0)
6 to 20
a e were a
1 to 3
Preservative
0 to 0.05
dd d
e
an
.tat.
agi
t.
Fragrance
OJ m as
lipstick.
It was found that the lipstick formulation of the in
to 80 minutes.
45
EXAMPLE 2
heating at 70' to 75 C.
The mixture is then molded to form the lipstick for
sition.
Ingredient
55
Parts by Weight
Base intermediate
60
Candelilla wax
l2
Cetyl alcohol
Ozokerite
4
2.3
Lanolin alcohol
Beeswax
9.2
5
2.5
Candelilla wax
9.2
Ozokerite
Lanolin alcohol
4.5
9.2
0.25
Petrolatum white
Wheat germ glycerides
9.2
0.45
0.03
8
Propyl paraben
65
Pans by Weight
warm
Softener-castor oil
Color intermediate
Red 7
Russet
Red 6
0.2
19.14
4
2.5
l
4,996,044
Ingredient
Parts by Weight
TiO;
0.(X)5
0.025
1.5
utes.
20
Propyl paraben
Butylated hydroxyanisole
Ac lates Co
Castor oil
er Intermediate
1.5
Fragrance
0.3
10
lipstick.
It was found that the lipstick formulation of the in
was soft but had good structure, was creamy, shiny and
was soft but had good structure, was creamy, shiny and
EXAMPLE 4
EXAMPLE 3
Parts by Weight
of lipstick
"Base intermediate
Softener
Castor oil
Lanolin oil
Color intermediate
ormse 5,3655
0.07
organic dyes
0.07
Red 21'1403Z
Red 6,C19-028
Pink 3571
Red 7,7044
Ingredient
25
6.31
.
' " pglen's
] and mm
Yellow 6,5270
dyes
Castor oil
Propyl paraben
Butylated hydroxyanisole
'
0.4
0.9
0.4
35
0.1!)5
0.025
. h
Rd 7,70
pigments
1.3
DC Red 6,C19-O12
3nd "5"
11
(barium lake)
ycs
'
1'7
Red 27,704
Castor oil
1.8
0.3
% by Weight of
Red
Russett
33,1(7192
C33-2527
TiOg
16.5
Fragrance
Lanolin alcohol
Beeswax
0.17
staining dye
0.9
Candelilla wax
5.2
32
2
Castor oil
Cetyl alcohol
Ozolterite
65
polymer powder)
Base Intermediate
Castor oil
Lanolin oil
Parts by Weight
65
7.4
2.0
5.4
24.6
} high staining
as described below.
Ingredient
10
-continued
'
3.9
13
Propyl paraben
Butylated hydroxyanisole
Acrylates Copolymer Intermediate
0.005
0.025
2.7
1.8
polymer powder)
Castor oil
0.9
Fragrance
0.3
Base Intermediate
20
6.7
3.8
45
15.3
1.4
Petrolatum white
Lanolin oil
Mineral oil
4
10.7
9.2
Oleyl alcohol
Propyl paraben
19.4
0.2
0.5
0.05
50
55
properties.
What is claimed is:
l. A lipstick formulation comprising 50-70% of a
the temperature at from 75 to 80 C. After the waxes 60 20-30% pigments and castor oil dispersant in a range of
1:4 to 1:1 wherein the pigments are 0.2-0.9% based
4,996,044
_11
12
_cominued
softener
74
Castor on
L0
'
Lanolin oil
5.4
8 ingegggdim
range
2:87
Red 21,14032
merits.
Red 6,Cl9-028
6-3
Pink 3571
14
10
Pans by Weight,
Base intermediate
60
Candelilla wax
12
Cetyl alcohol
Ozokerite
2.3
Lanolin alcohol
Beeswax
g:
Castor 0i]
16:5
Propyl paraben
Butylated hydroxyanisole
0.005
0.025
1 mer Intermediate
Acrylates. copolymer
1.8
195w 0
8'2
"gram:
9.2
Base Intermediate
Candelilla wax
6.4
6-4
11.6
'
% by Weight of
2.5
Petrolatum white
Lawn" 0
Oleyl alcohol
?zgoyzlgzm
Ac lates Co
15
Q07
Base Intermediate
20
Cay] alcohol
20
6'7
ozoken-te
Lanolin alcohol
Becswax
33
15.3
1,4
PYOPYI Parlbc?
0~09
Butylated hydroxyanisole
0.02
Petrolatum white
Softener-Castor oil
Color intermediate
Red 7
7.46
4
Lanolin oil
Mineral oil
Oleyl alcohol
25
'
10.7
9.2
19.4
Russet
Z5
Propyl paraben
Red 6
Tioz
Pmpyl paraben
2
0005
0.5
0.05
Butylated hydroxyanisole
0.025
30
1.5
Castor oil
1.5
Fragrance
05
Ingredient
35
Parts by Weight
0.2
Parts by Weight
Base intermediate
65
Softener
5-2
Castor oil
Lanolin oil
3.2
2
Meg-lg:
Red 21,14032
0.17
9-2
45
40
Russett css-zszv
Red 33.x7192
Lanolin alcohol
Acetylated lanolin alcohol
9.2
7
Red 7,7044
D&C Rd 6,c19-012
0.6
0.3
1_3
0.25
(barium lake)
Candell-lla wax
0101mm
Petrolatum white
9.2
0.45
0.03
8
Propyl paraben
Red 27,704
4'5
0,2
19,14
Color intermediate
Red 7
Russet
Red 6
TiO;
2 5
l
2
Castor oil
Propyl paraberl
5O
Butylated hydroxyanlsole
0.005
_
Butylated hydroxyanisole
0.025
2.7
Acrylates copolymer
1.8
Castor oil
0.9
Fragrance
0.3
% by Weight of
Base Intermediate
55
20
Cay] alcohol
6]
0.025
Ozokcme
1.5
1.5
0.3
Lanolin alcohol
Beeswax
Hydrogenated vegetable oil
Petrolatum white
Lanolin oil
60
35
153
1.4
8
4
10.7
Mineral oil
Base intermediate
3.9
18
0.005
Candelllla Wait
Ingredient
1.7
TiOz
Castor oil
Propyl paraben
Base Intermediate
20
1,1
9.2
Oleyl alcohol
19.4
Propyl paraben
0.2
Parts by Weight
65
65
"