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ANSWERS BAHAN PELAJAR BINTANG

CARBON COMPOUND

QUIZ 1
1(a)

C1

(i)
(ii)

A : Hexane
B : Hex-1-ene

1
1

C2

(i)
(ii)

A : C6H14
B : C6H12

1
1

C3

(i)
(ii)

A : C6H14 + 19/2 O2 6CO2 + 7H2O


B : C6H12 + 9 O2 6CO2 + 6H2O

1
1

C4

(i)
(ii)

A : Alkane + oxygen
B : Alkene + oxygen

1
1

C5

(i)
(ii)

A : Alkane melecule
B : Alkene molecule

carbon dioxide +water


carbon dioxide +water

Total
1

(a)

(b)

1. Hydrocarbon Y is an unsaturated hydrocarbon / contain double


bond.
2. Additional / bromination reaction occur.
3. Butane is a saturated hydrocarbon / contain single bond.
4. No additional reaction.
Isomer Compound A :

*either one

Isomer Compound B :

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1
10
1
1
1
1
1

hex-2-ene

(c)

(d)

(e)

4-methylpent-2-ene
*accept any correct isomer
1) Addition of bromine / Halogenation / Bromination
2) Reacts with excess oxygen to form carbon dioxide and water
3) Reacts with water to form alcohol
4) Reacts with hydrogen to form alkane
1. % C in hexane, C6H14 = 6(12) x 100% = 83.7 %
[ 6(12) + 14(1) ]
2. % C in hexene, C6H12 = 6(12) x 100% = 85.7 %
[ 6(12) + 12(1) ]
3. % of carbon in one molecule of hexene is higher than in hexane
4. Hexene produced more soot
Physical property K :
1) Exist as liquid at room condition
2) Soluble in water
Chemical test to differentiate J and K :
3) Pour 5 cm3 of compound J and compound K solution into two different
boiling tubes
4) Add 10 cm3 of acidified potassium dichromate (VI) solution into both
boiling tubes
5) Heat gently both boiling tubes and observe the colour change.
6) The orange solution in boiling tube containing compound K changes to
green
7)The orange solution in boiling tube containing compound J remains
unchanged.
Total

QUIZ 2

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
21

1(a)

C1

(i)
(ii)
(iii)

X : Methanol
Y : Propanoic Acid
Ester : Methyl propanoate

1
1
1

C2

(i)

X:

Y:
1

C3

(i)

2CH3OH + 3O2 2CO2 + 4H2O

C4

(i)

Alcohol + oxygen

C5

(i)

Alcohol melecule

(ii)

Oxygen molecule

(a)

(b
)

(c)

(i)
(ii)

carbon dioxide +water

Total

Ester
Sweet/pleasant/fragrance/fruity smell
X : Methanol
Colourless liquid at room
temperature
Has a low boiling point
Very soluble in water
Y : Propanoic acid
Colourless liquid at room
temperature
Has a low boiling point
Soluble in water
The colour of potassium dichromate(VI) solution changes from orange to
green and the product that formed is methanoic acid
Total

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1
1
1
1

QUIZ 3

1
1
1
1
1
10

1(a)

C1

(i)

X : Ethene

C2

(i)

X : C2H4

C3

(i)

C4

(i)

Alkene Polyalkene

C5

(i)

Ethene molecule

Total
1

(a)

(b
)

(i)

(i)

Natural polymer

Monomer

Natural rubber

Isoprene

Starch

Glucose

Cellulose

Glucose

Protein

Amino acid

1
1
1

Vulcanization

(ii)

(iii
)
(c)

1) Can withstand higher temperature


2) Harder and stronger
1) Ammonia solution contains hydroxide ions, OH- that
2) neutralize the acid produced by the bacteria.
3) the rubber particles remain negatively charged
4) and the coagulation is prevented.

1
1
1
1
1
1
Total

12

QUIZ 4
1(a)

C1

(i)

Y : Propyl propanoate

(ii)

J : Propanol

C2

(i)

C3H6

C3

(i)

C3H7OH + 2[O]

(ii)

C3H7OH C3H6 + H2O

(i)

Alcohol + Oxidising agent

(ii)

Alcohol Alkene + Water

(i)
&
(ii)

Alcohol molecule

C4

C5

CH3CH2COOH + H2O

1
1

Carboxylic acid + Water

Total
1

(a)

(i)
(ii)

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Oxidation
1) Add alcohol J with oxidising agent such as potassium dichromate (VI)
solution

1
1

2) Add few drops of concentrated sulphuric acid and heat gently the
mixture

1
1

(iii
)

(b)
(c)

Sweet/pleasant/fragrance/fruity smell
1) Add 2cm3 of propene and propane into two different test tube.
2) Add 3 drops of bromine in 1,1,1-trichloroethane and shake
3) Propene decolorize the brown solution of bromine.

1
1
Total

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