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The e.m.f. equtions for the three observed (solid+solid) domains, (Sb) +
E/mV = 59.58 0.0464T/K. + E/mV = 61.63 0.0527T/K. +
E/mV = 67.26 0.0695 T/K, have been established with an experimental
uncertainty of 0.5 mV. Two equations of the liquidus line, above and below
the T = 696.5 K peritectic equilibrium were also established. We have adjusted
a subregular Redlich-Kister development for the Gibbs excess function of the
liquid phase; the integral mixing enthalpy at 800 K is Hmmim (liquid) = x(1x)|
5272 1431)12x)| and the integral excess entropy Smss/J mol1K = x(1x)
[1.779 2.314(12x)]. The thermodynamic formation functions of the (Sb)
primary solution and of the , , , and compounds have been evaluated.