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Vapour Pressure
Sampling
Sealed container (D3700 FPC) or
D1265 cylinder required
API/ASTM also working on MPC
Vapour Pressure
Direct analysis of TVP via field method ASTM D7975 and
ASTM D6377 lab method vs RVP ASTM D323
Standard Test Method for Determination of Vapor Pressure of
Crude Oil: VPCRx-F(TmC) (Manual Expansion Field
Method)
Sampling
pressurized samples - cylinders
ASTM D3700 Floating Piston Cylinder
or ASTM D1265 LPG type with ullage
tube
Component
Molecular
Weight of
Component
(g/mol)
C1
C2
C3
iC4
n-C4
iC5
n-C5
n-C6
Benzene
n-C7
n-C8
n-C9
n-C10
n-C11
n-C12
n-C13
n-C14
n-C15
n-C16
n-C17
n-C18
n-C19
n-C20
n-C21
n-C22
n-C23
n-C24
16.04
30.08
44.01
58.12
58.12
72.15
72.15
86.18
78.12
100.21
114.23
128.76
142.29
156.32
170.34
184.37
198.4
212.42
226.45
240.48
254.51
268.53
282.56
296.59
310.61
324.67
338.67
Density of
Generalized Generalized
Component
Boiling
Molecular
@ 20 C
Point of Weight of
(g/mL)
Cut Point Cut Point
Fraction Fraction
Interval C Interval
(g/mol)
0.36
0.45
0.52
0.549
0.5788
0.6201
0.6262
0.6603
0.8765
0.6837
0.7025
0.7176
0.73
0.7402
0.7487
0.7564
0.7628
0.7685
0.7733
0.778
0.782
0.7855
0.7886
0.7919
0.7944
0.7969
0.7991
63.9
84
0.685
91.9
116.7
142.2
165.8
187.2
208.3
227.2
246.4
266
283
300
313
325
338
351
363
375
386
96
107
121
134
147
161
175
190
206
222
237
251
263
275
291
305
318
331
0.722
0.745
0.764
0.778
0.789
0.800
0.811
0.822
0.832
0.839
0.847
0.852
0.857
0.862
0.867
0.872
0.877
0.881
1.00
0.937
0.916
0.906
0.906
0.899
0.899
0.895
0.812
0.892
0.890
0.888
0.887
0.886
0.885
0.884
0.883
0.883
0.882
0.882
0.881
0.881
0.881
0.880
0.880
0.880
0.880
Instrument Set-up
Hydrogen Carrier GC
HPLIS heated stem injection (200C)
Split/splitless injector
MXT1 15m x 0.280mm, 3um film column.
FID detector
HPLIS valve on GC
Component Wt%
nC1
2000
nC6
nC5
nc2
500
iC4
1000
iC5
1500
0.35
0.14
10.06
0.84
2.40
0.56
0.71
nC1
nC2
nC3
iC4
nC4
iC5
nC5
nC4
2500
nC34
nC33
nC32
nC31
nC30
nC29
nC28
nC10
nC27
nC26
nC25
nC21
nC20
nC22
nC23
nC18
nC24
nC19
nC17
nC8
nC16
nC9
nc14
nC11
nC12
nC13
nC15
3000
nC7
pA
C6 fraction
-5 0 0
0 .5
1 .5
2 .5
C7 fraction
3 .5
4 . 5 m in
pA
4000
nC4
3000
10
15
nC31
nC30
nC28
nC29
nC26
nC27
nC24
nC23
nC25
nC21
nC22
nC19
nC20
nC17
nC18
nC15
nC16
nC13
nc14
nC11
nC12
nC9
nC10
nC8
nC7
nC6
iC5
nC5
nc2
1000
iC4
nC1
2000
20
2 5m i n
Calibration Standards
Gasoline/Jet A1mix spiked with methane,
ethane, and n-paraffin's betweenC16 and
C24.
Seven D1265 cylinders were made and run
multiple times on the HPLIS to get precision
data, and verify the ability to make
homogeneous samples in cylinders of this
type.
Methane
Ethane
Propane
Isobutane
Butane
C4+ to C17c17
c18
c19
c20
c22
c24
TOTAL AREA
Average,
mass%
0.156
0.546
0.002
0.448
2.769
95.759
0.063
0.050
0.058
0.055
0.052
0.041
210094
StdDev
0.0075
0.0179
0.0001
0.0103
0.0588
0.0893
0.0006
0.0005
0.0006
0.0007
0.0010
0.0019
5286
Max
0.175
0.585
0.002
0.458
2.829
96.134
0.064
0.051
0.059
0.057
0.055
0.047
222713
Min
0.137
0.478
0.002
0.404
2.515
95.633
0.062
0.049
0.057
0.054
0.051
0.038
203066
r estimate
0.0208
0.0496
0.0003
0.0285
0.1629
0.2474
0.0017
0.0014
0.0017
0.0019
0.0028
0.0053
%RSD
4.8
3.3
4.6
2.3
2.1
0.1
1.0
1.0
1.0
1.2
2.0
4.7
2.5
Calibration Standard
10
C24
C22
C20
C19
C16
C17
C14
C15
C9
C8
C7
hexane
pentane
iso butane
Propane
500
C10
1500
1000
C12
C13
Methane
2500
2000
C11
Iso pentane
3000
Ethane
Norm.
butane
15
20
25 min
C2
C3
0.75 0.5
0.25 1.5
0.25 1.5
iC4
nC4
iC
nC5 nC6
5
0
0
0
0
3.7
3.7
1
1
1
5
2.9
2.9
8
4
4
Sample VP (kPa)
at 4:1 Vapour-toliquid volume
ratio at 37.8C
174
128.7
128.7
0.5
2.9
183.7
0.05 0.075
15
Not calculated
Sample 1
Component/Cut
METHANE
ETHANE
PROPANE
IC4
NC4
IC5
C5
C6
C7 (includes C6 isomers)
C6s + C7
C8
C9
C10
NC10+
Total
Actual, mass%
0.29
0.87
0.59
0.00
0.00
1.02
4.99
7.98
0.12
8.10
0.99
2.44
3.92
76.80
100
Sample 2 & 3
Components
METHANE
ETHANE
PROPANE
IC4
NC4
IC5
NC5
C6
C7 (includes C6 isomers)
C6 + C7
C8
C9
C10
C10+
Total
HPLIS GC
0.05
0.18
1.46
0.01
3.63
0.92
2.68
3.10
0.80
3.90
1.10
2.57
4.14
79.37
100
Actual
0.06
0.29
1.47
0.00
3.88
1.01
2.92
4.01
0.12
4.13
1.02
2.50
4.02
78.71
100
HPLIS GC
0.05
0.10
1.34
0.01
3.41
0.92
2.72
3.30
0.83
4.13
1.06
2.54
4.05
79.66
100
Actual
0.06
0.29
1.51
0.00
3.87
1.00
3.00
3.98
0.12
4.10
1.02
2.50
4.01
78.65
100
Sample 4
Component/Cut
METHANE
ETHANE
PROPANE
IC4
NC4
IC5
NC5
C6
C7 (includes C6 isomers)
C6 + C7
C8
C9
C10
C10+
Total
Actual, mass%
0.11
0.58
3.04
0.00
0.00
1.00
2.91
3.98
0.12
4.10
1.04
2.56
4.11
80.55
100
Sample 5
Component/Cut
METHANE
ETHANE
PROPANE
IC4
NC4
IC5
NC5
C6
C7 (includes C6 isomers)
C8
C9
C10
C10+
Total
Actual, mass%
0.06
0.09
0.00
0.00
15.05
0.00
0.00
0.00
0.12
1.00
2.45
3.94
77.29
100.0
Pressure, kPa
70
60
50
40
30
AIR
20
Methane
Ethane
10
0
Propane
Butane
0
0.5
1.5
2.5
3.5
4.5
Experimental Values
Binary Mixtures
Air has profound effect on VPCR at low
VL ratios
Air and methane have similar
effect/curves
Sample #
HPLIS
GOR
0.007
0.005
0.000
0.006
0.017
0.016
0.005
0.004
0.012
0.010
0.004
0.005
0.012
0.008
0.014
0.007
0.039
0.025
10
0.023
0.022
11
0.006
0.005
12
0.011
0.007
13
0.014
0.010
14
0.006
0.006
15
0.024
0.023
16
0.033
0.045
HPLIS vs GOR
Methane
on 16 Various Crude samples
Thank you
AITF Chris Goss, Trevor Lockyer, Deepyaman
Seth
CCQTA, ASTM
Bob Falkiner Imperial Oil Engineering Services
bob.j.falkiner@esso.ca
Dan Wispinski Alberta Innovates
dan.wispinski@albertainnovates.ca