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in combustion processes
DEFINITION OF NOX
NOX means the sum of NO and NO2 contents
in flue gas recalculated on NO2
NOx = NO + NO2
(expressed in NO2)
UNITS OF NOX
NOX FORMATION
IN
COMBUSTION PROCESSES
Thermal
Prompt
Fuel
COMBUSTION AND FUELS
O + N2 NO + N, (4)
the N atoms liberated in this reaction quickly react with O2
N + O2 NO + O
(5)
50000
1,0E+05
40000
1,0E+03
30000
1,0E+01
20000
1,0E-01
10000
1,0E-03
1,0E-05
1000
1500
2000
2500
[NO]r, ppm
Equilibrium concentration of
NO, [NO]r, and time to reach
0,5[NO]r versus the temperature
3000
T, K
It shows that the Zeldovich mechanism becomes important when the temperature reaches the
COMBUSTION AND FUELS
range of 1600-1800 K.
CH2 + N2 HCN + NH
CH + N2 HCN + N
C + N2 CN + N
general
CHx + N2 HCN and other radicals (CN, NH, N...)
As a result: HCN, NH i CN are easily oxidized to NO in flame.
Wd
MJ/kg
Va, min
m3/kg
Tcomb
C
Gas
85
15
47
11,57
2263
Heating oil
1
86,4
12,5
0,05
0.05
45,2
11,18
2258
Heating oil
2
85,5
13
0,4
0.3
0,8
43,6
11,96
2210
Heating oil
3
87
11,4
0,5
0.6
0,3
43,1
10,74
2262
NF in different coals:
Bituminous coal:
Anthracite
<1% N
Lignite:
0.6 - 2% N.
CONVERSION OF
FUEL NITROGEN
DURING COAL COMBUSTION
Rapid
combustion
of v.m.
Slow burning
of char
Coal
particle
Products:
HCN, NH3, tar,
aromatic compounds
nitrogen in
volatile matter
nitrogen in
char residue
N, czci lotne
HCN
N paliwowy
nitrogen in
char residue
N poz. koks.
O2
NO
N koks.
OH, O, O2
nitrogen in fuel
C(s)
N koks.
NO
nitrogen in
char residue
NO
2
N2
C(s)
T < 800 C
NO2 undergoes destruction on tat higher temperatures:
T > 1200 C
COMBUSTION AND FUELS
NO + HO2 NO2 + OH
(where from HO2: H + O2 + M HO2 + M)
T < 1000 K
COMBUSTION AND FUELS
NO + RO2 NO2 + RO
(where from RO2:
R + O2 + M ROO + M)
NO + O + M NO2 +M
NO2 also is generated, but the contribution of this
reaction is not important.
The temperature range: T < 800 K.
[NO2]/[NOx]100% 5%
More important contribution to the total production of
NOx NO2 introduces during combustion in gas turbines:
[NO2]/[NOx]100% 10-15%
COMBUSTION AND FUELS
O + N 2 + M N 2O + M
The temperature range of the chemical reaction:
T < 1500 C
N2O + O NO + NO
COMBUSTION AND FUELS
DOMINATING MECHANISMS
OF NOx IN FLAMES
O
al N
m
r
the
volatile matter NO
Tangencial
Tangencial
Tangencial
Wall fired
FBB
FBB
FBB
Power
MWe
Coal type
NOx
mg/m3
650750
465490
200360
425460
110
160
230
bituminous
bituminous
bituminous
bituminous
bituminous
bituminous
lignite
71060
7501000
500900
1360110
40080
52080
280 50
OIL FLAMES
Heavy heating oil has much of fuel nitrogen NF > 0,5%.
NOx emission from oil burners operating on heating oils nr 2 and 3 is in
the range:
300-700 mg/m3
(mainly fuel NOx).
Fuel nitrogen NF is a dominating factor.
180-220 mg/m3
(mainly thermal NOx).
GAS FLAMES
No fuel nitrogen NF in gas.
Industrial gas burners (flames).
Range of NOx emission:
100-300 mg/m3
10-100 mg/m3