Professional Documents
Culture Documents
Formulae
*not all these are given in the exam
RH
1
1
1
= RH 2 2
2
n
nf
ni
f
2
ni
E
h
E = hf
f
c
c = f
f
h
h
=
m
mv
v
p
h
px
x
2
h
A
A4
4
Z X Z 2Y + 2 He
Wavelength
Rydbergs Constant
Energy of photon
Plancks Constant
Frequency
Speed of Light
Frequency
Wavelength
Wavelength
Plancks Constant
Mass
Velocity
Uncertainty in position
Plancks Constant
Alpha Decay
X ZA 1 Y + 0+1 e + v
+ Beta Decay
X ZA Y +
Gamma Decay
A
Z
A
Z
Joules
6.626 x 10-34
Hertz
3 x 108
Hertz
Metres
Metres
6.626 x 10-34
Kilograms
J
Js-1
Hz
m s-1
Hz
m
m
Js-1
Kg
m s-1
6.626 x 10-34
Js-1
Uncertainty in momentum
Beta Decay
X ZA +1 Y + 01 e + v
m
m -1
Series number
A
Z
Metres
1.097 x 107
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1.
Cathode
Anode
Canal rays
+ +
+
+
+
+
+
+
+
+ +
+
Rutherfords Experiment
! Alpha particles were fired at a thin gold foil and were observed how they were scattered.
Most of the alpha particles passed through with only small deflections.
! Rutherford proposed that the only way that the alpha particles could be deflected through
large angles was if all the atoms positive charge and nearly all its mass was
concentrated in a small dense nucleus with the electrons some distance away.
! Rutherford showed that the atom is mostly empty space, with almost all of its mass
contained in a small, positively charged nucleus.
! Rutherford estimated the atom was 10-10m in diameter, and the nucleus of 10-19m. Most of
the atom is empty space.
! Rutherford proposed a solar system model of the atom, where orbiting electrons were
held to the positive nucleus by electrostatic attraction.
! Rutherfords model was criticised because an orbiting electron would emit
electromagnetic radiation and spiral into the nucleus.
Inadequacies of Rutherfords Atom:
! What is the nucleus made up of?
! What keeps the negative electrons from being attracted into the positive nucleus?
! How are the electrons arranged around the nucleus?
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Wavelength
Metres
7
Rydbergs
Constant
1.097
x
10
m -1
RH
1
1
1
= RH 2 2
2
n
nf
Series number
ni
f
2
ni
Planck
Max Planck found that he could only get agreement between theory and experiment for Black
Body Radiation by making a fundamental change to the laws of physics.
Planck proposed that Energy is not emitted by a hot object continuously as classical physics
said it should but rather it is emitted in little bursts or packets of energy. QUANTA of energy.
E
Energy of photon
Joules
J
Plancks Constant
6.626 x 10-34
Js-1
h
E = hf
Frequency
Hertz
Hz
f
8
c
Speed of Light
3 x 10
m s-1
Frequency
Hertz
f
c = f
Hz
Wavelength
Metres
m
Bohrs Postulates
1. Electrons can revolve in certain allowed orbits without radiating energy. This postulate
accounts for the observed stability of atom. Why these stationary states existed was
unknown.
2.
When an electron falls from a higher energy level to a lower energy level, it emits
energy that is quantised by Plancks relationship E2 E1 = E = hf
The 2nd postulate explains the line emission spectra. Emissions of energy is
discontinuous and corresponds to a transition between two stationary states. Since the
energy is quantised, the frequency of the emitted radiation is predetermined. A
transition between different states will lead to different frequencies.
3.
nh
where n is the
2
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The Bohr model was able to provide a physical basis for the Balmer series formula.
hf = E f Ei
=
hc
1
1
E 2 E1
2 1
nf
ni
1
1
= E1 2 2
n
ni
f
1
1
= E1 2 2
n
ni
f
E 1
1
= 1 2 2
hc n f
ni
1
1
= RH 2 2
n
ni
f
RH
nf
ni
1906-14
1885
1908
1
E
2 1
ni
Ef =
1
E
2 1
nf
Wavelength
Rydbergs Constant
c = f
Ei =
f =
Metres
1.097 x 107
m
m -1
Series number
Spectral
Region
Energy Level
nf
UV
UV & Visible
Infrared
1
2
3
ni
2, 3, 4
3, 4, 5
4, 5, 6,
It could not explain the relative intensities of the spectral lines. Some lines were more
intense than others were. The reason this occurred was unknown.
Carbon spectral lines were found to consist of a number of very fine and close lines.
The cause of these hyperfine spectral lines could not be explained.
The splitting of spectral lines when the sample was placed in a magnetic field the
Zeeman effect could not be explained.
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2.
h
mv
Using Einsteins mass-energy equation and Plancks formulae, we equate and get:
E = hf
E = mc 2
c = f
hc
mc 2 =
c=v
h
mc =
h
mv =
Wavelength
Metres
Plancks Constant
Js-1
6.626 x 10-34
h
Mass
Kilograms
Kg
m
Velocity
v
m s-1
De Broglie referred to these as matter waves. This wavelength is comparable to atomic
dimensions. It should be possible to prove the wave nature of matter by observing some
characteristic wave property such as interference or diffraction.
h
mv
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Detector
Nickel Crystal
nh
2
Now that it is a standing wave, no energy is lost and the wave would not collapse, explaining
the stability of the electron orbits in the Bohr atom.
Heisenbergs Uncertainty Principle
Uncertainty of position of a particle is related to the uncertainty of the momentum.
Uncertainty in momentum
p
h
px
Uncertainty in position
x
2
Plancks Constant
6.626 x 10-34
Js-1
h
The more precisely the position is determined, the less precisely the momentum is known in
the instant. The converse is true.
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3.
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4.
Chadwick
In 1930, Bothe and Becker fired alpha particles at beryllium which resulted in the emission of
a penetrating type of radiation. The radiation proved not to be gamma rays event though these
were the expected penetrating radiation.
Protons
?
Be
Paraffin
In 1932, Chadwick measured the momentum of energy of the protons and used the laws of
conservation of momentum to prove that the unknown rays were neutral particles slightly
heavier than the protons.
1. Since ionisation is the principal method of detecting radiation, the uncharged neutrons
would be hard to detect, as they would cause little or no ionisation.
2. The addition of the proton-rich paraffin enhances the detection. The neutrons eject
protons as a result of elastic collisions and as these cause ionisation they are readily
detected. (Juliot and Curie)
3. By applying the laws of conservations of momentum and energy, Chadwick was able to
prove the existence of the neutron.
As a result of the work of Rutherford and Chadwick, the nucleus was shown to consist of
protons and neutrons.
Nucleons
Protons and Neutrons are collectively called Nucleons.
Protons are the positive subatomic particles found in the nucleus of an atom.
Neutrons are the subatomic particles with no electric charge and a mass almost equal to that
of a proton.
Property
Proton
Neutron
-27
Mass
1.672 x 10 kg
1.675 x 10-27 kg
Charge
+1.6 x 10-19 C
Neutral
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Transmutation
Transmutation occurs when one element changes into another element. Natural
transmutations occur in radioactive decay such as alpha and beta decay. Gamma decay is not
an example of transmutation.
In all transmutations, the mass number and atomic number are conserved.
A
Mass number = number of nucleons
A
Z
Atomic number = number of protons/ electrons
Z X
X
Element
Isotopes
Same atomic number = same chemical properties
Different mass number = different nuclear properties.
Helium nucleus
Charge
Mass
DECAY
Electrons
+2
4
Range in Air
Stopped by:
EM waves
Short wavelength,
High frequency
High energy
0
0
1
1
1860
Short
Paper
Medium
Aluminium
Long
Lead
Alpha Decay
ZA X ZA 42Y + 42 He
Alpha particles have a definite range, therefore a definite energy is needed for a particular
reaction with the excess energy being carried off by a gamma ray of specific energy.
Beta Decay
+ Beta Decay
_
ZA X ZA +1 Y + 01 e + v
ZA X ZA 1 Y + 0+1 e + v
Beta particles have a varying range, therefore have a variable energy. Since a particular
nuclear charge should have specific energy, it was predicted that the excess energy was
carried off by a tiny neural particle, the neutrino, so that the laws of conservation of mass/
energy and momentum were still obeyed.
Gamma Decay
ZA X ZA Y +
Radioactivity
Radioactivity is the spontaneous breakdown of an element into a new element by the
emission of , and rays.
Natural radioactivity is exhibited by all of the natural occurring isotopes above Bismuth (Bi)
in the periodic table.
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Fermi
Enrico Fermi was the first to realise the neutrons potential. He bombarded as many of the
known elements as possible with neutrons. In the majority of cases new isotopes were
formed.
When Fermi reached Uranium, the heaviest known element, the results were confusing. He
failed to discover nuclear fission in their experiments with Uranium. The breakdown of the
nucleus into two nuclei of roughly equal size a process the called nuclear fission.
Pauli & The Neutrino
! In 1930, Pauli suggested that an undiscovered particle might also be emitted in beta decay
which accounted for the missing energy and momentum.
! In 1932, the Italian physicist Fermi, constructed a mathematical theory of beta decay that
incorporated Paulis hypothesised particle.
! Fermi believed that this particle would have no electric charge, no mass, and no magnetic
properties, spin like electrons, travels at the speed of light and would have almost no
interaction with matter. It would, have energy, linear momentum and angular momentum.
! He named this particle the Neutrino
! He also hypothesised that a fourth force of nature, called the weak nuclear force is
involved in beta decay.
! Neutrinos are very small fundamental particles with no charge or rest mass.
! When the masses before and after were measured, a discrepancy arose. The electron was
found to have less energy then expected from the mass-defect (on average one third of the
energy that should be associated with the electron disappeared) and nothing could be
found to make up the deficit.
Forces between Nucleons and the Strong Nuclear Force
! Electrostatic attraction holds the electrons in the atom.
! The force of gravitational attraction is a million times weaker than the electrostatic force,
and is consequently negligible within the atomic nucleus.
! Nuclear particles (nucleons) are held together by a force that operates only within the
atomic nucleus. This strong nuclear force operates between protons and protons, neutrons
and neutrons, and protons and neutrons.
! While the strong nuclear force is much stronger than the electrostatic force, it operates
only over very short distances of about 2.3 x 10-15m.
! If the nucleons are brought closer together than 0.7 x 10-15m, the nuclear force pushes
them apart, and if they are pulled further apart, the force draws them back together, just as
if they were joined by a spring.
! If the nucleons are moved large distances apart, the nuclear force rapidly declines to zero.
Mass Defect/ Binding Energy
The mass of the atom is less than the sum of the masses of its components. This difference is
called the Mass Defect.
To separate the particles of a nucleus, we must overcome the forces holding the nucleus
together. This requires work to be done and energy to be put into the system. Conversely, if
the separate particles were to come together to form a nucleus, then energy would be
released. This energy is called Binding Energy. The energy appears as a difference in mass
between the actual mass of the nucleus and the mass calculation from the sum of the
theoretical particles.
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12
6
12
6
kg
12 6.022 1023
= 1.6 x 10-27
mass of 1 atom
mass of 1 unit
) (
= 1.6 10 27 3 108
= 1.5 x 10-10 J
Energy in Reactions
1amu
12
6
C+
1
0
Total LHS
12.0000
1.0087 +
13.00087
Mass Defect
12
6
C
Total RHS
13.0034
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5.
Fission Reactor
! The purpose of a nuclear reactor is to release nuclear energy at a controlled rate.
! Nuclear fission reactors can be classified as either:
1. Thermal reactors where the neutrons producing the fissions have energy comparable
to gas particles at normal temperatures. Most commercial reactors are of this type.
2. Fast reactors where the neutrons producing the fissions have large energies.
Thermal Reactors
! Fuel
The nuclear fuel must contain fissionable material. Most reactor fuel is a mixture of
fissionable and fertile material. The smallest possible amount of fissionable material that will
sustain a chain reaction is the critical mass.
! Moderator
Since the neutrons liberated by a chain reaction have high initial speeds (energies) they need
to be slowed down to thermal energies. This can be achieved by collisions with atoms that
wont readily absorb neutrons in moderators. Moderators include:
1. Ordinary water
2. Heavy water
3. Graphite
4. Beryllium
! Control Rods
To control the rate at which fission occurs in a reactor, a means of absorbing excess neutrons
is required. Most reactors use water or heavy water or moveable control rods made of steel
that contains a high proportion of neuron-absorbing cadmium or boron. Most reactors have
two sets:
1. Regulating rods for routine control
2. Safety rods for emergency shutdown
If the reaction is proceeding too fast, the control rods are pushed further into the reactor core
and absorb additional neutrons so causing the reaction to slow down. Conversely, pulling the
control rods further out of the reactor core allows more neutrons to initiate a fission.
! Coolant
To cool the reactor core to prevent it from melting down and to extract useful heat, reactors
use a coolant. The most common coolant is light water, but heavy water, liquid sodium and
helium are also used.
! Radiation Shield
Concrete shielding is used to protect workers from radiation emitted by the reactor, and the
core and cooling system are enclosed in a large cylindrical building designed to withstand
pressure in the event of a cooling system failure. Types of shields:
1. A shield designed to protect the walls of the reactor from radiation damage and at the
same time reflect neutrons back into the core
2. A biological shield that is used to protect the reactor personnel. This consists of many
centimetres of high-density concrete
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! Power Supply
The heat produced by the radioisotope plutonium-238 can be converted into electricity to
power a cardiac pacemaker.
! Radiocarbon dating
Radiocarbon dating is a method for estimating the age of ancient artefacts. It relies upon the
fact that there is a fixed proportion of radioactive Carbon-14 in the atmosphere together with
the stable Carbon-12.
The proportion of Carbon-14 in the sample under test can be determined to give an estimate
of the age of the sample. However, Carbon dating is of use for only relatively recent material
up to about 70 000 years.
! Half-life
The half-life of an element is defined as the time it takes for half a given mass of an element
to decay into a new element. It may vary from microseconds to millions of years.
Neutron Scattering
Neutron scattering is a powerful method of analysing the internal structure and properties of
matter using neutrons.
A neutron is an uncharged particle with a mass slightly greater than that of the proton. Free
neutrons interact with matter in a number of ways depending upon their velocity and the
nature of the target. They include:
1. Scattering
2. Absorption
3. Capture
! Neutrons, because of their neutral charge, penetrate matter more easily than do charged
particles.
! Neutrons with energies of < 1eV18 are termed slow neutrons. Those with energies > 1keV
are referred to as fast electrons.
! In neutron scattering, an energetic recoil nucleus is produced. The energy of the recoil
nucleus varies depending on the type of collision.
! If the neutron collides with a hydrogen nucleus it can transfer almost all its energy in a
single collision.
! The neutron scattering technique has been used to look inside bulk matter to determine its
structure and properties. It has been used in the development of magnetic materials for
computer data storage and in the determination of the structure of superconductors and
even in identifying the structure of viruses.
Neutron Activation Analysis
Certain elements can be made radioactive by bombarding them with a flux of neutrons. These
radioactive elements then decay and the emitted particles have energies that allow them to be
readily measured. Neutron activation analysis is also used to identify specific trace elements
in hair in forensic investigations.
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6.
Betatron
Synchrotron
Linear
Accelerators
A series of drift tubes connected to an oscillator in such a way that each tube
has the opposite polarity to the preceding tube.
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Leptons
(Weak
Interactions)
Muon-Neutrino
Tau
Tau-Neutrino
Gluon
Bosons
(force carriers)
Photon
Weakon
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Quarks
Quarks are fundamental particles with charges 13 e and 23 e . They are considered point-like
in that they have no measurable size and are fundamental since they have no known
components. There are six varieties of quarks.
! Each quack has a quantum property called colour.
! Quarks can be red, blue or green.
! Quarks of different colour charge attract each other.
! Quarks of similar colour charge repel each other.
! When quarks combine to form hadrons, they do so in certain colour combinations. The
net colour charge is zero.
! Quarks do no exist in isolation. They are always combined with one or two quarks to
form composite particles called hadrons.
Hadrons
Hadrons always have an integral charge and although individual quarks have colour-charge,
hadrons are colour-neutral.
Hadrons are classified as either:
! Bargons (3 quark combinations). Bargons interact through the strong force.
! Mesons (2 quark combinations). Mesons are unstable and decay in millionth of seconds.
Leptons
Leptons are particles with little or no mass. They do no experience they strong force, but
rather they interact through the weak force.
! Like quarks, each lepton has an antilepton.
! Unlike quarks, leptons exist independently.
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Generations
Generation
!
!
!
!
Quark
Charge
Lepton
Charge
2
+
Up
Electron
-1
3
First
1
Electron
0
Down
neutrino
3
2
+
Charm
Muon
-1
3
Second
1
Muon-neutrino
0
Strange
3
2
+
Top
Tau
-1
3
Third
1
Tau-neutrino
0
bottom
3
Each generation consists of a set composing each charge type of quark and lepton.
The 1st generation particles constitute everyday matter.
The 2nd and 3rd generation particles are unstable and decay into 1st generation particles.
Each generation is more massive than the previous one.
Force-Carrier Particles
The four fundamental forces are carried by force-carrier particles bosons. They are:
1. Gravity Graviton
2. Electromagnetic Photon
3. Strong Nuclear Gluon
4. Weak Nuclear - Weakon
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