CUESTIONARIO 11

1.- Calclate the solubility-product constant for each of the following substances, given that the formal concentrations of their saturated solutions are as
indicated. A1P04 (7.62 * l0-1 0).
2.- What is the lead ion concentration in a saturated aqueous solution of: (a) Pb(OH)2? y (b) PbCl2?
3.- What is the iodide ion concentration in a saturated aqueous solution of AgI?
4.- What hydroxide ion concentration must be achieved in order to diminish that of lead ionto 1.0 * 10-5M?
5.- What lead ion concentration is needed to (a) initiate precipitation of PbS0 4 from a solution that is 0.05 F with respect to sulfate ion?
(b) lower the sulfate ion concentration to 1.0 * 10.6 M?
6.- Treatment of a 0.400-g sample- of impure potassium chloride with an excess of AgN03 resulted in the formation of 0.733 g of AgCl. Calclate the percentage
of KC1 in the sample.
7.- A 5.00-g sample of a pesticide, was decomposed with metallic sodium in alcohol, and the liberated chloride ion was precipitated as AgCl. Express the
results of this analysis in terms of percent DDT, C14H9C15 , based upon the recovery of 0.160 g of AgCl.
8.- The mercury in a 0.715-g sample was precipitated with an excess of paraperiodic acid, H5I06 : 5 Hg2+ + 2 H5IO6 == -Hg5(I06)2 + 10 H+
The precipitate was filtered, washed free of precipitating agent, dried, and weighed as such, 0.340 g being recovered. What was the percentage of mercury in
the sample?
9.- A 6.88-g sample containing magnesium chloride and sodium chloride was dissolved in sufficient water to give 500 ml of solution. Analysis for the chloride
content of a 50.0-ml aliquot resulted in formation of 0.592 g of AgCl. The magnesium in a second 50.0 ml aliquot was precipitated as MgNH4P04 ; upon ignition,
0.1796 g of Mg2P207 was found. Calclate the percentages of MgCl2*6H20 and of NaCl in the sample.
10.- Write the solubility-product expression for ZnHg(SCN)4 == Zn2 + + Hg(SCN)2
11.- An EDTA solution has a titer of 1.200 mg CaCO3 per milliliter. Express the total hardness of a water sample in parts per million CaC03 , based upon the
accompanying data.
'r Buret Gontaining Buret Containing :
sample Volume (ml)
Final 44.62
Initial 0.07
EDTA
Volume (ml)
Final 27.36
Initial 0.06
12.- Instead of using the disappearance of turbidity due to Ag as an indicator for titration of the excess cyanide, the analysis in Problem 12 was completed by
introducing the standard zinc solution until the first turbidity due to Zn(CN)2 was observed. Reaction: Zn(CN)2- + Zn2+ == 2Zn(CN)2-. What volume of zinc
solution was needed for this titration?
13.- A 1.728-g sample of a lead-cadmium alloy was dissolved in acid and diluted to exactly 500 ml in a volumetric flask. Titration of a 25.00-ml aliquot at a pH of
10 in an NH4+- NH3 buffer required 43.60 ml of standard 0.01080 F EDTA and involved both cations. The cadmium ion was masked by using an HCN - NaCN
buffer to bring the pH of a second 25.00-ml aliquot to 10; 32.70 ml of the standard EDTA solution were used in this titration. Calclate the respective
percentages of lead and cadmium in the sample.
14.- Evalate conditional constants for the process Cd(CN)42- + H2Y2- == CdY2- + 4CN- + 2H+ in solutions buffered to pH 10 when the formal cyanide
concentration is 5.00 * 10-1. Log K vales for cadmium-cyanide species are: pK1=5.48; pK2=5.14; pK3=4.56; pK4=3.58
15.- Derive a curve for the titration of 25.0 ml of 0.020 F Cu2+ with 0.010 F H2Y2- in a solution buffered to a pH of 9.00. Consider that the concentration of NH3
rmains essentially constant at 5.0 * 10-1 F throughout the titration. Constants for the formation of successive ammine complexes of copper(II) are: K 1= 1.35 *
104; K2=3.02 * 103; K3=7.40 * 102; K4=1.29 * 102. Evalate pCu after the addition of 0, 10, 25, 40, 45, 49, 50, 51, 55, and 60 ml of titran.
16.- What is the pH of a solution that is 0.10 F in disodium hydrogen phosphate?
17.- Calclate the pH of a solution that is 0.01 F with respect to Na2HP04 and .025 F with respect to NaH2P04.
18.- What is the ratio of acid to conjgate base in a carbonate and hydrogen carbonate buffer that has a pH of 10.7 ?
19.- A homogeneous mixture is prepared by grinding and blending 47.0 g of NaH2 P04*H2 0 with 73.0 g of Na2 HP04 *2 H20 . What will be the p H of the solution
that results when 6.5 g of this mixture are dissolved in 160 ml of water?
20.- For integer p H vales between 1 and 12, calclate a for each species derived from sulfurous acid.
21.- What mnimum volume of 0.1130 AgN03 will assure an excess of silver ion in the titration of a sample of impure NaCl weighing 0.310 g?
22.- The Fajans method is to be used in the routine analysis of solids for their chloride content. It is desired that the volume of standard silver nitrate used in
these titrations be numerically equal to the percentage of chloride when 0.400-g samples are taken for analysis. What will be the normality of the AgN0 3
solution?
23.- Calclate the silver ion concentration after the addition of 5.00, 15.0, 25.0, 30.0, 35.0, 39.0, 40.0, 41.0, 45.0, and 50.0 ml of 0.10 F AgN03 to 50.0 ml of 0.08
F KSCN. Construct a titration curve from these data, plotting pAg as a function of titrant volume.
24.- Calclate the pH of a solution that is 0.050 F in salicylic acid and 5.00 * 10-3 F in HC1.
25.- Calclate the pH of a solution that is 1.00 * 10-2 F with respect to NaOH and 1.00 * 10-1 F with respect to sodium cyanide.
26.- A series of solutions containing NaOH, Na2CO3, and NaHC03 , alone or in combination, were titrated with standard 0.10 N HCl . This solution required are
the acid volumes needed to titrate 25.0-ml portions of solution to (1) a phenolphthalein end point 21.67 ml, and (2) a methyl orange end point 21.70 ml. Use this
information to deduce the composition of the solutions. In addition, calclate the number of milligrams of each solute per milliliter of solution.
27.- Exactly 34.40 m of 0.1070 N NaOH were needed to titrate a 0.7050-g sample containing NaHC20 4*H20 , H2C204*2H20, and inert materials. After
evaporation to dryness, the titrated sample was strongly ignited to convert the product, Na2C204, to Na2CO3 : Na2C204 == Na2CO3 + CO
The ignited residue was cooled, dissolved in water, and treated with 50.0 ml of 0.125 N HC1. Calclate the percentages of NaHC204*H20 and H2C204*2H20 in the
sample if a 2.34-ml back-titration with the NaOH solution was needed to neutralize the excess acid.

28.- A 0.282-g sample of an impure aluminum salt was dissolved in dilute acid, treated with an excess of ammonium oxalate, and slowly made alkaline through
the addition of aqueous ammonia. The precipitated aluminum oxalate was filtered, washed, redissolved in dilute acid, and titrated with 36.0 ml of 0.110 N KMn04
. Calclate the percentage of aluminum in the sample.
29.- The KSCN content of a 0.321-g sample was determined by titration of the SCN- with a 0.0672 N solution of KI03 in the presence of a high concentration of
HCl . The titration required 36.4 mi of the reagent. Calclate the percent KSCN presen
30.- A 0.722 g sample of alkali metal sulfates was dissolved and diluted to exactly 100 ml. The sodium in a 25.0-ml aliquot was precipitated as
NaZn(U02)3(OAc)9*6H20. After filtration and washing, the preciptate was dissolved in acid and the uranium reduced to U 4+ in a Jones reductor; then the U4+ was
titrated with 37.7 ml of 0.108 N Ce4+ . Calclate the percent Na2SO4, in the sample.
31.- Derive a curve for the titration of 40.0 ml of 0.10 F malonic acid with 0.20 F NaOH . Calclate the pH of the solution after the addition of 0.0, 5.0, 10.0, 19.0,
20.0, 21.0, 30.0, 39.0, 40.0, 41.0, and 45.0 ml of base.
32.- A 20.0-ml portion of a solution that is 0.15 F with respect to HCl and 0.30 F with respect to acetic acid is titrated with 0.20 F NaOH. Calclate the pH of the
solution after the addition of 0.0, 10.0, 14.0, 15.0, 16.0, 20.0, 30.0, 40.0, 45.0, and 50.0 ml of base. Prepare a titration curve from these data.
33.- A 50.0-ml sample of vinegar (density = 1.060 g/ml) was diluted to 250 ml in a volumetric flask. A 25.0-ml aliquot of this solution required 28.1 ml of 0.136 N
NaOH to achieve a phelphthalein end point. Express the acid content of the vinegar in terms of percent acetic acid.
34.- A Kjeldahl analysis was performed upon a 0.110-g sample of impure biguanidine,C2H7N5 . The liberated ammonia, collected in 40 ml of 5 percent boric
acid, was titrated with 42.5 ml of 0.106 N HCl. Calclate the percentage of biguanidine in the sample.
35.- A 0.850-g sample of impure sodium carbonate was titrated with 0.134 N HCl to a bromcresol green end point, 28.8 ml of the acid being required. What was
the percentage of Na2CO3 in the sample?