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AITS-CRT-III-PCM(S)-JEE(Main)/14

JEE (Main), 2014

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ANSWERS, HINTS & SOLUTIONS


CRT III
(Main)

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Q. No.
1.

PHYSICS
A

CHEMISTRY
B

MATHEMATICS
A

2.

3.

4.

5.

6.

7.

8.

9.

10.

11.

12.

13.

14.

15.

16.

17.

18.

19.

20.

21.

22.

23.

24.

25.

26.

27.

28.

29.

30.

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AITS-CRT-III-PCM(S)-JEE(Main)/14

Physics
1.

V = Es ;
2sm
E=
qt 2
V

.2

PART I

2s2m
= 11.375 Volt
qt 2

'

sin30 sin60

' 3

' ' cos 30 v cos30


cos60(v ' ') cos 60(2v) v

= v/ =

3.

40 3
0.1 3

120

400 rad/s

30

for x<0
It will oscillate like SHM
m
Time period T1
k
For x>0
It will perform periodic motion under constant force
T2 2

2E
mg2

Hence time period T T1 T2


T

m
2E
2
k
mg2

mv 02
R
mv 0
B
eR

ev 0B

a2 R2 b R
b2 a2
R
2b
2bmv 0
B 2
(b a2 )e

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5.

AITS-CRT-III-PCM(S)-JEE(Main)/14

Here the total time is given T


Time spent m the region is ( 2)
Hence total time spent
2
T

2
v

2
v

6.

Torque of Internal force is always zero. All other quantities will vary.

8.

Static friction depends on tendency.

9.

ML2
3ML2
sin2 60 2
12
24

10.

When impulse of external force is zero.

11.

Balance forces.
R

( )

m L cos

N
mg

12.

13.

t x 2
y(x, t) = e b v = b

15.

2L = m (1/2) =
L = n (2/2) =

m T
2f 9

n
2f

T
4

m = 3n = 3 1 = 3
16.
17.

cos = 1 = 0 L = 1/C
v v 0 sin 30
fB = f f0 =
f0 f0
v v 0 sin 30
2v 0 f0
=
2v v 0

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AITS-CRT-III-PCM(S)-JEE(Main)/14

18.

1
mv 2 h
2

19.

= D/d, is minimum for violet.

20.

VPG VPC VCG 2xj 2i


Hence, for the paritcle,
Vx = 2m/s and Vy = 2x = 4t
ax = 0 ay = 4m/s2
x = 2t, y = 2t2
aTotal = 4m/s2
(a) (along Y-axis)
x2 x2
and trajectory y 2.

4
2

when a aN , a cos = a sin = 45


So, Vx = Vy = 2 V = 2 2
4
V2
42
RC

2 2m=
m
o
aN 4.cos 45
2

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AITS-CRT-III-PCM(S)-JEE(Main)/14

Chemistry
2.

PART II
OH

O
O

O
H

OH

OH
O

H
OH

OH

Tautomerise

3.

D
D

D
D3 O

D
D

4.

2n

Talc has empirical formula Mg2(Si2O5)2Mg(OH)2 which Si2 O5 n units of two dimensional sheet
silicates.

5.

H
O
It has half open book like structure having dihedral angle 97o

97o O

6.

H
r Ho

2 46.1 187.8 2 285.8 H N H kJ / mol


o

-1

= - 241.0 kJ/mol
Hro N2H4 50.6 kJ / mol
9.

Decomposition enthalpy = - 50.6 kJ/mol.


Radius ratio for MgO is = 0.464 which reflect the coordination number 6 and radius ratio for MgS
is 0.353. Which reflect the coordination number 4.

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AITS-CRT-III-PCM(S)-JEE(Main)/14

10.

H2 O ClO3 aq
ClO4 aq 2H aq 2e
2H aq ClO3 aq 2e ClO2 aq H2O
2ClO3 aq
ClO2 aq ClO4 aq
Eocell 0.33 0.36 0.03

RT
lnK (at equilibrium)
nF
0.059
0.03
logK
2
logK = - 1
K = 0.1

2ClO3
ClO4 ClO2
Eocell

Initially
equilibrium

.1
.1 2x

0
x

0
x

x2

.1 2x

1
x2

x 0.019 M
10 .1 2x 2

12.

Probability of finding an electron is zero, i.e. 2 0 .


2

1 1 3 /2

2
/ 2

1 8 12 e 0
16 4 a0

1 2 8 12 0
On solving for we get
2r
= 1, 6, 2 and
a0
For = 1; 1
2; 2

a0
2

r a0

2r
r 3a0
a0
n-factor of H3PO2 is 4/3 for the reaction.
Tb K b m i
2.08 = 0.52 1 i
i=4
This implies that the salt on dissociation gives 4 ions. Thus, the salt that gives four ions is
K3[Fe(CN)6].
6;

13.
14.

2r
a0

2r
a0

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15.

AITS-CRT-III-PCM(S)-JEE(Main)/14

OH

H
H

CH3

CH3

CH3
-D shift

OH

OH
D

D
H

CH3
16.

CH3
O

SeO2

B
18.
19.
20.
21.
22.
25.

OH
OH
Bezilic acid rearrangement

COO

It is a non-degradable pollutant.
Colloidal silver bromide solution is used in photography.
Stability of carbonates increases down the group. Carbonates of alkali metals are more stable
than those of alkali metals.
2px and 2py have one nodal plane each. In 1s there is no nodal plane and in case of *2px there
are two nodal planes.
Le-Chatelliers principle.
COOH

COCl

SOCl2

AlCl3 /

Zn/Hg

HCl

26.

NH4 Cl Nesseler 's reagent


Brown colour of iodide million's base.

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AITS-CRT-III-PCM(S)-JEE(Main)/14

Mathematics

PART III

1.

Using T = S1 take midpoint (h, k) then equation of PQ is


xh + yk (h2 + k2) = 0
.. (1)
mx y + 2m = 0
.. (2)
Compare (1) and (2) eliminate m

2.

As f(x) is continuous decreasing function on (0, ), so 0 < f(8x) < f(6x) < f(4x)
f 6x
f 4x
So lim 1 lim
lim

x
x f 8x
x f 8x
f 6x
By squeeze play theorem lim
1
x f 8x

3.

The given lines will be parallel to lines ax2 6xy + y2 = 0


2

y
y
So, 6 a 0
x
x
m + m2 = 6
Which gives m = 3 or 2
and mm2 = a
From (2) a = 27 or 8
Hence sum of all possible value of a = 19
lim

4.

.. (1)
.. (2)

x x 2

e ln g 2 x2 ln g 2 form
0

g' 2 x 2
2x
g' 2
1

x 0 g 2 x 2

1
g 2
2
e
e
e
2x
e
lim

1/ n

f t dt
5.

I lim

form
0

n2
Using : L Hospital and using Leibnitz rule
1 1
n3 f 2
n 1
n n
I lim
lim f
n
n 2 n
2
1
Put n hence
h
1
f 0 h f 0 1
I lim
f' 0
2 h 0
h
2

6.

dy
1
2
dx
x
2
Slope of normal to xy = 1 for x > 0 (x 0)

For xy = 1

Slope of line (given) =

log2 1 5a a 2
0
5

So 1 + 5a a > 1
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AITS-CRT-III-PCM(S)-JEE(Main)/14

a2 5a < 0 hence a (0, 5)


7.

2
3

1
1 2
2
ah

2
2
3
3
abc 2 1 1 3
R

4
3 4 2 2

8.

2
3

1
1

Area of the parallelogram outside the circle


= Area of parallelogram Area of sector OPQ
1

= sin 2 sin f
2

2
2

n 1

n n 1

r r 1

9.

Using n Cr

10.

We have |(A1) adj(B1) adj(2A1)| =

Cr 1

Area of triangle =

13.

r=1

Cr 2 is equal to

64
1 1 64
2 2 =
8
A B
2 1 4
A

This distance between the given parallel lines (h) is


length of the side of triangle is =

12.

n2

M
a

1
and |adj B| = |B|n1 where n is order of square matrix)
A

(By using |A1| =

11.

1
2
3 1
3

1
5

2h
3

3 4h
h
1

4
3
3 5 3

1 0 0
1 1
1
The volume of tetrahedron = OA OB OC 1 1 0
6
6
6
0 1 1

Area of base =

1
i j i j k i 1 i k = 1 2 1
2
2
2
2

Hence height =

3 volume
3 2
1

Area of base
6
2

C = 20
1
ab
2
Sa=7
S b = 13
ab=6
a2 + b2 = 400

C
b

.. (1)
A

13

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10

AITS-CRT-III-PCM(S)-JEE(Main)/14

(a b)2 + 2ab = 400


ab = 182
1
ab 91
2
14.

16.

17.

18.

Let r xi yj zk
Comparing x = t2 + t 2 y = t + 2 z = t2 + 6t + 9
Hence z x = 5t + 11 z x = 5(y 2) + 11 x + 5y z + 1 = 0

a b a b 8
2
ab 8
2 2
a b sin2 8
8
2
b
16
1
2
1
2

b 4

If

x2

(x2y2)
(x1y1)
y1

y2

f(x) = sec x cosec x

f(x) = 0 at x
4

Also f " 0 so f(x) is minimum at x


4
4

f
4
a

19.

y2

1, a > b
a2 b2
So x1x2 = y1y2 = b2
3d = 49
3d 7

/4

/2

/4
a

cos a x
ln cot a tan x dx ln
dx
sina cos x

2 1
= 2ln 2 1
2 1

sec d cosec d = ln

lncos a x dx lnsinadx lncos xdx

I(a) = ln (sin a) a
I(1) = ln (sin a) = ln |cosec 1|
1/ x

20.

Let A lim 2x 1
x 0
2

= e

lim

x0 x

1
2x 1 1
2

(1 form)

2x 1
lim

2x
e
x 0

= e2

ln 2

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11

21.

Un

n 2 n 1
1
1
1

n 1 n 2
n 1 n 2
n 1 n 2
n

Sn

AITS-CRT-III-PCM(S)-JEE(Main)/14

n 1 n 2 2 n 2
n 1

Hence lim Sn
n

22.

1
2

100

z 1 i 3

100

= 2100 cos isin


3
3

100
100
100
= 2 cos
isin
3
3

= 2100 cos isin


3
3

1
3
= 2100 i

2
2
1

Re z
1
2

Im z
3
3

23.

|wz 1 w2| = a
|z + 1| = a
|a 1 + 2| = a
|z 1| + 2 a
0a4

24.

Since RHS is even. So LHS is also even integer so either both x and y should even or both
should odd integer. Now
x4 y4 = (x y)(x + y)(x 2 + y2)
(x y), (x + y), (x 2 + y2) must be an even integer
Therefore (x y)(x + y)(x 2 + y2) must be divisible by 8
But RHS is not divisible by 8
So given equation has no solution

25.

Given numbers can be rearranged as


1, 4, 7 .. 3n 2 (3 2) type
2, 5, 8 .. 3n 1 (3 1) type
3, 6, 9 .. 3n
3 type
This means either both the numbers should from (3 type) or one number each from (3 2) type
and (3 1) type
n n 1
3n2 n
So total number of ways n C2 nC1 nC1
n2
2
2

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12

AITS-CRT-III-PCM(S)-JEE(Main)/14

26.

(1 + x + x2 + x3)5 = a0 + a1x + a2x2 + a3x3 + a4x4 + .. + a15x15


Put x = 1 and x = 1 and add
45 a0 a1 a2 a3 a4 ..... a15
0 a0 a1 a2 a3 a4 ..... a15
_____________________________
45 2 a0 a2 a4 ............... a14

a0 + a2 + a4 + .. + a14 = 512
27.

28.

29.

f(x) = 3x + 2ax + b
y = f(x) is increasing x R
f(x) 0 x R
2
So (2a) 4 3 b 0
2
a 3b 0
This is true for exactly 16 ordered pairs (a, b) 1 a, b 6
16 4
So required probability =

36 9
ab2 ac 2 bc 2 ba2 ca2 cb2 6 6 6 1/ 6
a b c
6
So a(b2 + c2) + b(c2 + a2) + c(a2 + b2) 6abc

2r 2r 1
tan1

1 2r 2r 1
n

tan

2r tan1 2r 1

r 1

= tan1 (2n) tan1 (1)

= tan1 (2n)
4
30.

cot A cot C
sin A C sinB

cotB
sin A sinC cosB

=
=
=
=

sin2 B
sin A sinC cosB
4R 2b2
4R 2ac cosB

b2
ac cosB
2b2
2002b2 b2

2
2001

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