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MichaelDoyle
HonorsChemistry
Mr.Sabur
Lab2.4
Hour2
12/4/15
Design
ResearchQuestions
1.) Whatscientificconceptsisthislababout?
ThislabusestheLawofDulongandPetit.
2.) Whataretheobjectivesforthislab?
Theobjectivesaretofindthespecificheatandthentousethattofindtheatomic
mass.
3.) Whatistheoverallpurposeofthelab
ItistoshowanexampleofhowtousetheLawofDulongandPetit
4.) Whatreasoningdidyouusetoarriveatyourhypothesis?
UsingtheLawofDulongandPetitiskeyandhelpful,but,systematicerroris
almostalwaystobeexpected,therefore,therewillbesomewhatofapercenterror.
Hypothesis
Ithinkthatwewillbeabletofindthespecificheatandatomicmassofcopperwithin
15%errororless.
Variables
ManipulativeVariables:
Choiceofmetal
Amountofwater
Massofmetal
Timespentheatingthemetal
ResponsiveVariables
Changeintemperature
ControlledVariables
Amountofwater
Initialtemperatureofwater
Massofmetal
Typeofmetal
Equipment/Materials
samplesofmetals
largetesttube
400mLbeaker
hotplate
balance
foamcoffeecups
thermometer
Safety
Anapronandgogglesmustbeworninthelaboratory
Avoidcontactwiththehotplate
Procedure
Placeabout200mLoftapwaterina400mLbeakerandplaceitonthehotplate.Heat
thewateruntilitboils
Selectametaltouseforthisexperiment.Weighoutapproximately20gramsofthe
metal.Recordthemassinthedatatable.
Copperwaspreselectedasthetypeofmetaltobeusedinthislab.
Transferthemetaltoalargetesttube.Placethetesttubeinthehotwaterbath,andletit
sitfor10minutes.
Whilethemetalisheatinginthehotwaterbath,obtainafoamcoffeecup.Weighit,and
recordthemass.Placeabout100mLofdistilledwaterinthecup,andweighagainto
determinethemassofthewater.Youmaywishtoplacethecupina250mLbeakerto
giveitgreaterstability.
Measureandrecordthetemperatureofthewaterinthefoamcup.Itisimportantinthis
experimentthatalltemperaturereadingsbemadeasaccuratelyaspossible.Afewtenths
ofadegreecangreatlyaffecttheresults.
Whenthemetalhasbeenheatedlongenoughinthehotwaterbath,measureandrecord
thetemperatureoftheboilingwater.Transferthemetaltothefoamcup.Stirthewater,
andrecordthemaximumtemperatureofthewaterinthefoamcup.
Placetheusedmetalinthecontainerdesignatedforthatpurpose.Repeattheprocedure
usingfreshwaterinthefoamcupeachtime.
Datacollection
Trial1
Trial2
Trial3
MetalUsed
Copper
Copper
Copper
MassofMetal
20.226g
20.533g
20.125g
MassofFoamCup
1.756g
1.756g
1.676g
MassofFoamCup&Water
102.070g
102.072g
98.427g
MassofWaterinFoamCup
100.314g
100.314g
96.751g
InitialTemperatureCup
21.41C
21.79C
21.30C
FinalTemperatureCup
22.73C
23.24C
23.24C
TemperatureChangeCup
1.32C
1.449C
1.94C
TemperatureHotWaterBath
99.69C
100.6C
101.30C
InitialTemperatureofMetal
99.69C
100.6C
101.30C
FinalTemperatureofMetal
22.73C
23.24C
23.24C
TemperatureChangeofMetal
76.96C
77.36C
78.06C
HeatGainedbyWater
554.0J
608.17J
785.3J
HeatlostbyMetal
554.0J
608.17J
785.3J
SpecificHeatofMetal
0.356J/gC
0.383J/gC
0.500J/gC
AtomicMass
74.18amu
68.97amu
52.81amu
Q(Heat)=TwaterXmasswaterX4.184J/gC
Trial1:1.32Cx100.314gx4.184J/gC=554.0J
Trial2:1.45Cx100.314gx4.184J/gC=608.17J
Trial3:1.94Cx96.751gx4.184J/gC=785.3J
C(SpecificHeat)=Q/(TmetalXmassmetal)
Trial1:554.0J/(76.96Cx20.226g)=0.356J/gC
Trial2:608.2J/(77.36Cx20.533g)=0.383J/gC
Trial3:785.3J/(76.06Cx20.125g)=0.500J/gC
Average:0.413J/gC
AtomicMass=26.4/C
Trial1:26.4/.3559J/gC=74.18amu
Trial2:26.4/.3828J/gC=68.97amu
Trial3:26.4/.4999J/gC=52.81amu
Average:65.32amu
PercentErrors
PercentError=((acceptedexperimental)/accepted)x100
AtomicMass:
Accepted:63.55amu
((63.5565.32)/63.55)x100=2.79%
SpecificHeat:
Accepted:0.385J/gC
((0.3850.413)/0.385)x100=7.27%
EndingQuestions
1.Howwouldacalculationfortheatomicmassbeaffectedifthehotmetalsamplecooled
offwhilebeingtransferredtothecalorimeter?
Thecalculationwouldbeinaccurate.Itwouldbeinaccuratebecauseyouarenotgetting
theentiretemperaturechangebecausethemetalwouldgiveoffheatwithoutbeinginthebeaker
thatmeasuresthetemperaturechange.
2.Whatarepossiblesourcesoferrorinthisexperiment?
Systematicerrorisoneofthemainerrorsinflictedinthisexperiment.Onesystematic
errorwasthemetallosingheatasitwastransferredtothebeakerwithroomtemperaturewater
fromthehotwaterbath.Itlostheatwithoutbeingmeasuredbecausethereisashortamountof
timewherethepieceofmetalisoutofwaterandnotbeingrecorded.
Conclusion
Ithoughtthatwewouldbeabletocalculatethespecificheatandatomicmassofcopper
within15%errororless.Myhypothesiswasprovencorrectwhenweusedtheprocedurewe
weregiven.Theresultsweconcludedprovedmyhypothesiswhenwegot7.27%errorfor
specificheatand2.79%errorfortheatomicmasswhicharebothlessthan15%error.
Therewaslittleerrorinthelab.Theerrorthatdidoccurwasallsystematicerror.The
onlyerrorthatIdetectedwaswhenthecopperwastransferredfromthehotwaterbathtothe
roomtemperaturewatertherewasasmallamountofheatlosswhenitwasoutofwater.Other
thanthat,therewasnomorenoticeableerror.ThepercenterrorsIcalculatedshowhowthaterror
affectedtheanswerbecauseiftherewasnoheatlossoutofwaterthepercenterrorswouldhave
beenextremelysmallornonexistent.
Itisveryhardtocomeupwiththeexactlycorrectmeasuremeasurementsforspecific
heatandatomicmassinthislabbecausetherewillalwaysbeheatloss.EvensotheanswersI
calculatedweremoderatelyclose.ThroughthislabIlearnedabouttheLawofDulongandPetit
andhowitisusedtocalculatespecificheatwhichthencanbeusedtocalculateatomicmass.I
thinkawaythatcouldgomoreindepthwiththislabiswecouldusemultipledifferentmetals
andcalculatetheirspecificheatandatomicmassthatwaywecouldfigureoutifweareprecise
withourcalculationsandpercenterrors.