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CHEMICAL PRINCIPLE
THE OUTLINES
1. Matter
2. Atoms and Ions
3. Atomic and Molecular Mass
4. Mole Concept
5. Chemical Formula
6. Chemical Equation and Stoichiometry
MATTER
It is anything that has mass and occupies
space
Examples
Classification of MATTER
Physical state
Compositions
Physical state
Depending on its temperature, matter can
be solid, liquid or gas
Compositions
Pure substances
Elements
Atoms
Molecules
Compounds
Ions
Molecules
Mixtures
Homogeneous
Heterogeneous
Pure substances
Pure substances are defined as substances that are
made of only one type of atom or molecule, and the
purity of a substance is the measure of the extent to
which a given substance is pure
all substances are either elements or
compounds
Pure water a compound
Elements
Examples of elements
METALS
NON-METAL
Iron (Fe)
Carbon (C)
Gold (Au)
Silver (Ag)
Cuprum (Cu)
GAS
Oxygen (O2)
Nitrogen (N2)
Clorin (Cl2)
Helium (He)
periodic properties
Metals
Malleable, ductile, have
luster
oxidize to form +ve ions
Excellent conductors of
heat and electricity
can be broken down into
several groups
Transition
metals
Also called transition
elements
Able to refract light (have
unpaired electron)
Ionic solutions usually
coloured (often used as
pigments)
Lanthanides and actinides
(rarely found)
Nonmetal
Do not conduct electricity
well because they do not
have free e * Hydrogen is placed with
the metals because it has
only one valence
electron, but it is a
nonmetal
periodic properties
Some specific families within the three main groups metals, nonmetals, and
metalloids (have properties between metal and non metal)
HALOGENS (7A)
Known as salt formers
Exist as diatomic molecules
Used in modern lightning
Compounds
Substances that composed of two or
more elements; they contain two or more
kinds of atoms
Mixtures
Combinations
of
two
or
more
substances in which each substance
remain its chemical identity
Heterogeneous mixture
The mixtures do not have the same
composition, properties and appearance;
two or more substances are mixed
together but are not chemically combined
Sand in water
Homogeneous mixture
The
mixtures
that
are
uniform
throughout; has uniform composition and
appearance
Mixture of air
Metal solution
Orange juice
Interaction of Atoms
It's the electrons in orbit around the nucleus that allow
one atom to interact with other atoms so they can be
linked together.
Ions
Ions
The following image shows Na losing an electron and Cl gaining an
electron
Thus the Na becomes Na+
The Cl becomes Cl-
Ions
Here are some examples of common ions:
Na+
Sodium
K+
Potassium
ClChloride
Ca+
Calcium
Fe+
Iron
PPhosphorous
Ions
Mass
Abundance (%)
6Li
6.015
7.59
7Li
7.016
92.41
16O
15.995
99.757
17O
16.999
0.038
18O
17.999
0.205
Molecular Mass
The molecular mass of a substance
(less accurately called molecular
weight and abbreviated as MW) is
the mass of one molecule of that
substance, relative to the unified
atomic mass unit (u)
Molecular Mass
The molecular mass can be
calculated as the sum of the
atomic masses of all the atoms of
any one molecule.
The molar mass of a substance is
numerically equal to the molecular
mass, but expressed in mass units
per mole (e.g. grams per mole)
Molecular Mass
For example: the atomic mass of hydrogen is
1.00784 u and that of oxygen is 15.9994 u;
therefore:
the molecular mass of water
with formula H2O is
= (2 1.00784 u) + 15.9994 u
= 18.01508 u.
Therefore, one molecule of water weighs 18.01508 u,
and one mole of water weighs 18.01508 grams.
Molecular Mass
Molecular mass or molar mass are
used in stoichiometry calculations.
Stoichiometry is the part of chemistry that studies amounts of substances that are
involved in reactions.
1. You might be looking at the amounts of substances before the reaction.
2. You might be looking at the amount of material that is produced by the
reaction.
Stoichiometry is all about the numbers
When you're doing problems in stoichiometry, you might look at..
1.
2.
3.
4.
5.
Mole Concept
The mole (symbol: mol) is one of the
seven SI base units and is commonly
used in chemistry.
Mole is a unit of measurement used in chemistry to
express amounts of a chemical substance, defined as the amount
of any substance that contains as many elementary entities
(e.g., atoms, molecules, ions, electrons) as there are atoms in
12 grams of pure carbon-12 (12C)
SI base units
SI BASE UNITS
QUANTITY
Length
UNIT
SYMBOL
meter
kilogram
kg
Temperature
kelvin
Time
second
mole
mol
Electric current
ampere
Luminous intensity
candela
cd
Mass
Amount of substances
Mole Concept
Avogadro's number
Avogadro's number is the number of particles found in
one mole of a substance.
It is the number of atoms in exactly 12 grams
of carbon-12.
This experimentally determined value is approximately
6.022 x 1023 particles per mole.
Chemical Formula
There are two types of chemical
formulas:
(a) Empirical Formula,
(b) Molecular Formula .
Empirical formula and molecular
formula are used for different purposes.
Empirical Formula
Example:
Acetylene (C2H2) and benzene (C6H6)
the simplest ratio C : H = 1 : 1
Empirical Formula = CH
Molecular Formula
Chemical Equation
aA + bB
cC
2 HCl + 2 Na 2 NaCl + H2
Chemical Equation
3 ways of representing the reaction of H2 with O2 to form H2O
reactants
products
2 MgO
C2H6 + O2
CO2 + H2O
2C2H6
NOT
C4H12
2 carbon
on left
C2H6 + O2
6 hydrogen
on left
C2H6 + O2
CO2 + H2O
1 carbon
on right
multiply CO2 by 2
2CO2 + H2O
2 hydrogen
on right
2CO2 + 3H2O
multiply H2O by 3
2CO2 + 3H2O
4 oxygen + 3 oxygen
(3x1)
(2x2)
7O
2 2
2CO2 + 3H2O
2C2H6 + 7O2
4CO2 + 6H2O
C2H6 +
multiply O2 by
7
2
= 7 oxygen
on right
remove fraction
multiply both sides by 2
2C2H6 + 7O2
12
4 CH
14
O(2(2
(7xx2)6)
2)
4CO2 + 6H2O
1412
OH
(44(6
xC 2x +2)6)
Reactants
Products
4C
4C
12 H
12 H
14 O
14 O
EXERCISE:
Write a balanced chemical equation for:
1.
2.
3.
4.
moles CH3OH
molar mass
CH3OH
209 g CH3OH
moles H2O
molar mass
H2O
coefficients
chemical equation
1 mol CH3OH
32.0 g CH3OH
4 mol H2O
2 mol CH3OH
235 g H2O
grams H2O
18.0 g H2O
1 mol H2O
Excess Reactant - The reactant in a chemical reaction that remains when a reaction
stops when the limiting reactant is completely consumed. The excess reactant remains
because there is nothing with which it can react.
No matter how many tires there are, if there are only 8 car bodies, then only 8 cars can
be made. Likewise with chemistry, if there is only a certain amount of one reactant
available for a reaction, the reaction must stop when that reactant is consumed
whether or not the other reactant has been used up.
6 green used up
Al2O3 + 2Fe
mol Al
g Fe2O3 needed
OR
g Fe2O3
124 g Al x
mol Fe2O3
1 mol Al
27.0 g Al
mol Al needed
1 mol Fe2O3
2 mol Al
160. g Fe2O3
1 mol Fe2O3
g Al needed
=
367 g Fe2O3
mol Al
2Al + Fe2O3
124 g Al x
mol Al2O3
g Al2O3
Al2O3 + 2Fe
1 mol Al2O3
102. g Al2O3
1 mol Al
= 234 g Al2O3
x
x
27.0 g Al
2 mol Al
1 mol Al2O3
3.9
Actual Yield
Theoretical Yield
x 100
Chemical Equation
and Stoichiometry
When a stream of chlorine gas, Cl2, is
directed onto solid phosphorus, P4, the
mixture bursts into flame, and a chemical
reaction produces liquid phosphorus
trichloride, PCl3.
This reaction can be represented by using
a balanced chemical equation:
P4(s) + 6Cl2(g) 4PCl3(l)
Chemical Equation
and Stoichiometry
The problem is:
How we get the chemical equation?
Look at the data given:
1. chlorine gas, Cl2
2. solid phosphorus, P4
3. liquid phosphorus trichloride, PCl3.
Chemical Equation
and Stoichiometry
So, the chemical equation should be:
Cl2 + P4 PCl3
Consider the chemical phase:
Cl2(g) + P4 (s) PCl3 (l)
Chemical Equation
and Stoichiometry
Balance the chemical equation:
66Cl2(g) + P4 (s) 4 PCl3 (l)
or
P4 (s) + 6Cl2(g) 4PCl3 (l)
Answer
UNITS OF CONCENTRATION
There are a number of different ways of expressing solute concentration that are
commonly used
Molarity, M = moles solute/liter of solution
Normality, N = equivalents of solute/liter of solution
Concentrations of Solutions
Molarity (M)
The most widely used to quantify
the concentration of solutions.
Concentrations of Solutions
Molarity (M)
The molarity of a solution is
defined as
molessolutes
Molarity
volume of solution(L)
n
or M
V
Molarity Exercise 1
Calculate the molarity of a
solution made by dissolving
23.4 g of sodium sulphate in
enough water to form 125 mL of
solution.
Answer
1.32 M
Molarity Exercise 2
How many grams of sodium
sulphate, Na2SO4 are required to
make 0.350 L of 0.500 M Na2SO4?
Answer
24.8 grams
Normality (N)
The normality of a solution is the gram equivalent weight of a solute per liter of solution. A
gram equivalent weight or equivalent is a measure of the reactive capacity of a given chemical
species (ion, molecule, etc.). Normality is the only concentration unit that is reaction
dependent.
Here's an example of how to calculate the normality of a solution.
Normality Example #1
1 M sulfuric acid (H2SO4) is 2 N for acid-base reactions because each mole of sulfuric acid
provides 2 moles of H+ ions.
1 M sulfuric acid is 1 N for sulfate precipitation, since 1 mole of sulfuric acid provides 1
mole of sulfate ions.
Molality (m @ b)
As is clear from its name, molality involves moles!!!
A molality is the number of moles of solute dissolved in one kilogram of solvent.
Question:
A 4 g sugar cube (Sucrose: C12H22O11) is dissolved in a 350 ml teacup of 80 C water. What is
the molality of the sugar solution?
Given: Density of water at 80 = 0.975 g/ml
Definition
Answer:
The molality of the sugar solution is 0.034 mol/kg.