Concentration

Absorbance

( mg/l)
5
10
15
20
25

0.19
0.383
0.563
0.727
0.948

Calibration Curve
1

f(x) = 0.0374290909x
R = 0.9996352674

0.8
0.6

Absorbance 0.4
0.2
0
0

10

15

20

25

Concentration mg/l

Time in min

when H2O2 200ppm when H2O2 500ppm

when H2O2 800ppm

0
10
20
30
40
60

0
19.73
30
40
49
64

0
34.08
51.92
67.49
82.32
95.14

0
23.24
42.97
59.46
72.97
88.65

% degra

10

% degradation

200

0
10
20
30
40
60

0
0.22
0.36
0.51
0.67
1.02

500

0
0.3
0.65
1
1.45
2

800

0
0.45
0.85
1.32
1.73
2.8

Effec
3

2.5 f(x) = 0.0

R = 0.99
2
f(x) = 0.0
1.5 R = 0.99
Ln(C0/Ct)
1

f(x) = 0.0
0.5 R = 0.99
0
0

10

f(x) = 0.0
0.5 R = 0.99
0
0

150

0
10
20
30
40

0
17.12
35.14
51.35
60

100

0
10
20
30
40

0
34.08
51.92
67.49
82.32

20

0
10
20
30
40

0
10
20
30
40
60

0
34.08
51.92
67.49
82.32
95.14

0
27.03
43.24
55.41
68.38
80.54

0
25.405
39.189
48.108
59.459
71.622

0
10
20
30
40
60

0
0.45
0.85
1.32
1.73
2.8

0
0.32
0.57
0.81
1.15
1.64

0
0.29
0.5
0.66
0.9
1.26

10

0
45.95
72.97
86.49
94.59

% degr

Ln(Co/Ct

For H2O2

200 ppm

For 20 g/l mineral hematite

Time
in Absor
Remainin
min
bance g
concentra
tion
0
10
20
30
40
60

0.37
0.30
0..23
0.16
0.12
0.10

100
80.3
70.0
60.0

51.0
36.0

%
degradat
ion

Ln(C 0 /
Ct)

0
19.73
30
40
49
64

0
0.22
0.36
0.51
0.67

For 15g/l mineral hematite

Absor
Remain %
bance
ing
degrada
concent tion
ration

Ln(C 0 /
Ct)

For 10g/l mineral hematite

Absorb Remain
ance
ing
concent
ration

.37
.33
.29
.24
.21
.17

0.00
0.114
0.243
0.433
0.567
0.77

.37
0.35
0..3
0.26
0.24
0.19

100
89.18
78.37
64.8
56.7
45.94

0.00
10.82
21.63
35.2
43.3
54.06

0
10
20
30
40
60

0
19.73
30
40
49
64

0
10.82
21.63
35.2
43.3
54.06

0
5.41
18.92
29.73
35.14
48.65

0
10
20
30
40
60

0
0.22
0.36
0.51
0.67
1.02

0
0.114
0.243
0.433
0.567
0.77

0
0.05
0.209
0.352
0.432
0.666

100
94.5
81.08
70.27
64.86
51.37

1.2
1
0.8

Ln(Co/Ct) 0.6
0.4
0.2

f(x) = 0.0170757
R = 0.998463151
f(x) = 0.0133136
R
f(x)==0.996546815
0.0109818

R = 0.994623258

1
0.8
Ln(Co/Ct) 0.6
0.4

f(x) = 0.0170757
R = 0.998463151
f(x) = 0.0133136
R
f(x)==0.996546815
0.0109818

R = 0.994623258

0.2
0
0

10

20

30

Time

ve

90909x
2674

20

25

30

on mg/l

% degradation curve of orange-g

100

Hyrogen
peroxide: 200
mg/l

80
60

degradation

Hyrogen
peroxide: 500
mg/l

40
20
0
0

10

20

30

40

50

60

Hyrogen
peroxide: 800
mg/l

70

Time in min

Effect of varying H2O2

Hydrog
en per
oxide:
200
mg/l

2.5 f(x) = 0.0451969697x

R = 0.9986634416
2
f(x) = 0.0339393939x
1.5 R = 0.9983485545
C0/Ct)
1

f(x) = 0.0170757576x
0.5 R = 0.9984631518
0
0

10

20

30

40

Time in min

50

60

70

Linear
(Hydro
gen
per
oxide:
200
mg/l)

f(x) = 0.0170757576x
0.5 R = 0.9984631518
0
0

10

20

30

40

50

60

70

gen
per
oxide:
200
mg/l)

Time in min

100
80
Hematite: 20g/l

60
% degradation

Hematite: 15g/l
40

Hematite: 10g/l

20
0
0 10 20 30 40 50 60 70
Time in min

3
2.5 f(x) = 0.0451969697x
R = 0.9986634416

2
Ln(Co/Ct) 1.5 f(x) = 0.0277727273x
1

R
f(x)==0.9990660208
0.0218636364x
R = 0.9960921691

0.5
0
0

10 20 30 40 50 60 70
Time in min

or 10g/l mineral hematite

Remain %
degrad
concent ation
0
5.41
18.92
29.73
35.14
48.65

Ln(C 0 /
Ct)

0.00
0.05
0.209
0.352
0.432
0.666

f(x) = 0.0170757576x
R = 0.9984631518
f(x) = 0.0133136364x
R
f(x)==0.9965468155
0.0109818182x
R = 0.9946232583

Hematite:
20g/l
Linear
(Hematite:
20g/l)
Hematite:
15g/l

Hematite:
20g/l
Linear
(Hematite:
20g/l)
Hematite:
15g/l
Linear
(Hematite:
15g/l)
Hematite:
10g/l

Hematite:
20g/l

f(x) = 0.0170757576x
R = 0.9984631518
f(x) = 0.0133136364x
R
f(x)==0.9965468155
0.0109818182x

Linear
(Hematite:
20g/l)

R = 0.9946232583

10

20

30

Hematite:
15g/l
40

Time in min

50

60

70

Linear
(Hematite:
15g/l)

70
60
50
40
% degradation 30

Hematite: 20g/l
Hematite: 15g/l
Hematite: 10g/l

20
10
0
0 10 20 30 40 50 60 70
Time in min

Hematite: 20g/l
Hematite: 15g/l
Hematite: 10g/l