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COMBUSTION TABLE FOR HYDROCARBONS FUELS

Molar mass
species
C
H2

g/mol

Dry basis analysis


g/kgf
%-mass
12.01
30.2%

Wet basis analysis


mol/kgf

302.00

%-mass
25.15
11.5%

2.02

3.5%

35.00

17.33

1.3%

O2

32.00

24.3%

243.00

7.59

9.3%

N2

28.01
32.06
--18.02

2.3%
2.7%
37.0%
0.0%

23.00
27.00
370.00
0.00

0.82
0.84

0.9%
1.0%
14.1%
61.8%

100.0%

1000.00

S
Ash
Water
Sum

0.00

100.0%

Nitrogen in stoch. air = 3,76 * O2


Stoichiometric air need ao

ao

Stoichiometric gas amount go

go

Stoich. dry flue gas go dry


Excess air factor
Oxygen due to air in excess
Nitrogen due to air in excess

Total air need

Total flue gas amount

g
gdry

Total dry flue gas

Fractions in REAL (TOT) gas or volume ratio (same as mole r


Fractions in DRY gas or volume ratio (same as mole ratio):
Normal conditions
T
273.15 K
p
1.013 bar
Occupied volume at normal conditions
3
V
0.0224 m n/mol
Result summary
Stoichiometric air

ao

49.219 moldry air/kgf

Normal total air

63.985 moldry air (tot)/kgf

HHVdry
HHVwet

12.19 MJ/kgdry fuel


4.66 MJ/kgwet fuel

LHVdry
LHVwet

Air pre-heating temperature


Air enthalpy (from tables)
Air density (at normal condition)

10.39 MJ/kgdry fuel


2.86 MJ/kgwet fuel
300 C
305.6 KJ/kg
3
1.28 kg/m n

Hp: Flue gas density = Air density (normal)

1.28 kg/m

Total air for combustion (a or I)

1.83 kgair/kgfuel

3.00 kgflue gas/kgfuel

Total flue gases (g)


Adiabatic enthalpy of the flue gas (hgas)
Gas content of the flue gas (x)
ADIABATIC TEMPERATURE
hair (KJ/kg)
T (C)
Dh (KJ/kg)
1000
900
910
920
930
940
950
960
970
980

1089.5
972
983.7
995.4
1007.1
1018.9
1030.6
1042.4
1054.1
1065.9

102.5
89
90.3
91.6
93
94.3
95.6
97
98.4
99.7

1137.56 KJ/kg
0.769 -

hgas (KJ/kg)
1168.35
1040.46
1053.16
1065.86
1078.64
1091.44
1104.14
1117.02
1129.79
1142.59

Adiabatic temperature wi

ARBONS FUELS

Fuel type:
Needed
oxygen

Wet basis analysis


g/kgf

mol/kgf

mol/kgf

H 2O

115.36

9.606

9.606

13.37

6.619

3.309

92.83

2.901

-2.901

8.79
10.31
141.34
618.00

0.314
0.322

34.295
1000.00 Sum O2

CO2

N2

SO2

O2

9.606
6.619
0.314

0.322

0.322
34.295

10.336

molN2/kgf

38.883

moldry air/kgf

49.219

molflue gas/kgf

90.038

molflue gas (dry)/kgf

49.124

stoichiometric mols
38.883
40.914

9.606

39.197

0.322

1.3
3.101
11.665
moldry air (tot)/kgf

63.985

molflue gas (tot)/kgf


molflue gas (dry tot)/kgf

104.804

40.914

63.890

total mols

or volume ratio (same as mole ratio):


me ratio (same as mole ratio):

ry air (tot)

Flue gas composition (mol/kgfuel)

/kgf

39.04%

9.606
9.17%
15.03%

50.861

0.322

3.101

48.53% 0.31%
79.61% 0.50%

2.96%
4.85%

3
1.103 m n/kgfuel

Stoichiometric gas

go

3
1.433 m n/kgfuel

Normal total gas

90.038
104.804

abatic temperature will be between 970 and 980 C

molflue gas/kgf

3
2.017 m n/kgfuel

molflue gas (tot)/kgf

3
2.348 m n/kgfuel

COMBUSTION TABLE FOR HYDROCARBONS FUELS


Molar mass
species
C
H2

Dry basis analysis

g/kgf
g/mol
%-mass
12.01
56.0%

Wet basis analysis


mol/kgf

560.00

g/kgf
%-mass
46.63
50.4%

504.00

2.02

3.5%

35.00

17.33

3.2%

31.50

O2

32.00

16.2%

162.00

5.06

14.6%

145.80

N2

28.01
32.06
--18.02

2.3%
2.0%
20.0%
0.0%

23.00
20.00
200.00
0.00

0.82
0.62

2.1%
1.8%
18.0%
10.0%

20.70
18.00
180.00
100.00

100.0%

1000.00

100.0%

1000.00

S
Ash
Water

Sum

0.00

Nitrogen in stoch. air = 3,76 * O2

molN2/kgf

Stoichiometric air need ao

ao

moldry air/kgf

Stoichiometric gas amount go

go

molflue gas/kgf

Stoich. dry flue gas go dry

molflue gas (dry)/kgf

Excess air factor


Oxygen due to air in excess
Nitrogen due to air in excess

Total air need

moldry air (tot)/kgf

Total flue gas amount

g
gdry

molflue gas (tot)/kgf

Total dry flue gas

molflue gas (dry tot)/kgf

Fractions in REAL (TOT) gas or volume ratio (same as mole ratio


Fractions in DRY gas or volume ratio (same as mole ratio):
Normal conditions
T
273.15 K
p
1.013 bar
Occupied volume at normal conditions
3
V
0.0224 m n/mol
Result summary
Stoichiometric air

ao

217.939 moldry air/kgf

Normal total air

272.424 moldry air (tot)/kgf

HHVdry

LHVdry

HHVwet

0 MJ/kgdry fuel
0.00 MJ/kgwet fuel

LHVwet

Flue gas temperature


Power plant operation hours per year
Fuel flow
Density of SO2 at normal conditions
Density of CO2at normal conditions

-0.93 MJ/kgdry fuel


-0.93 MJ/kgwet fuel
155 C
8000 h/y
5 kg/s
3
2.87 kg/m n
1.978 kg/m

at flue gas T
at flue gas T

Flue gas flow (at flue gas temperature)


The fraction of SO2 in total flue gas

51.098 m3/s
1928.94 ppm

SO2mass flow per minute

10.828 kg/min
Carbon dioxide CO2emission (in thousand tons per year)

267.75

LS

Fuel type:
Needed
oxygen

s analysis
mol/kgf

H 2O

41.965

41.965

15.594

7.797

4.556

-4.556

0.739
0.561
5.549
Sum O2

CO2

N2

SO2

O2

41.965
15.594
0.739

0.561

0.561
5.549

45.767

stoichiometric mols

172.172

172.172

217.939
236.581

e gas (dry)

e gas (tot)

mol/kgf

Flue gas composition (mol/kgfuel)

/kgf

21.143

41.965

172.911

0.561

215.438
1.25
11.442
43.043
272.424

/kgf

e gas (dry tot)

/kgf

291.066

21.143

269.922

total mols

(same as mole ratio):


as mole ratio):

41.965

7.26% 14.42%
15.55%

215.954

0.561

11.442

74.19% 0.19%
80.01% 0.21%

3.93%
4.24%

3
4.882 m n/kgfuel

Stoichiometric gas

go

236.581

3
6.102 m n/kgfuel

Normal total gas

291.066

1.83 kg/m3
1.26 kg/m3

103t/a

molflue gas/kgf

3
5.299 m n/kgfuel

molflue gas (tot)/kgf

3
6.520 m n/kgfuel

COMBUSTION TABLE FOR HYDROCARBONS FUELS


Molar mass
species
C
H2

Dry basis analysis

g/mol
%-mass g/kgf
12.01
49.4%

Wet basis analysis

mol/kgf

g/kgf
%-mass
41.14
42.0%

494.12

420.00

2.02

5.9%

58.82

29.12

5.0%

50.00

O2

32.00

38.8%

388.24

12.13

33.0%

330.00

N2

28.01
32.06
--18.02

0.0%
0.0%
5.9%
0.0%

0.00
0.00
58.82
0.00

0.00
0.00

0.0%
0.0%
5.0%
15.0%

0.00
0.00
50.00
150.00

100.0%

1000.00

100.0%

1000.00

S
Ash
Water

Sum

0.00

Nitrogen in stoch. air = 3,76 * O2

molN2/kgf

Stoichiometric air need ao

ao

moldry air/kgf

Stoichiometric gas amount go

go

molflue gas/kgf

Stoich. dry flue gas go dry

molflue gas (dry)/kgf

Excess air factor


Oxygen due to air in excess
Nitrogen due to air in excess

Total air need

moldry air (tot)/kgf

Total flue gas amount

g
gdry

molflue gas (tot)/kgf

Total dry flue gas

molflue gas (dry tot)/kgf


Fractions in real gas:
Fractions in dry gas:

Normal conditions
T
273.15 K
p
1.013 bar
Occupied volume at normal conditions
3
V
0.0224 m n/mol
Result summary
Stoichiometric air

ao

176.355 moldry air/kgf

Normal total air

229.262 moldry air (tot)/kgf

HHVdry
HHVwet

18 MJ/kgdry fuel
15.30 MJ/kgwet fuel

Combusion residue
ER, lambda
Gasification residue
Pyrolysis residue

LHVdry
LHVwet

16.55 MJ/kgdry fuel


13.85 MJ/kgwet fuel

50 kg
0.2
92 kg
260 kg

Oxygen neededto combust 1 ton of wood chips


Oxygen needed to gasify 1 ton of wood chips

1185.107 kg
237.02141 kg

CC - Combustion
CC - Gasification
CC - Pyrolysis

100%
90%
50%

UELS

Fuel type:
Needed
oxygen

is analysis
mol/kgf

H 2O

34.971

34.971

24.752

12.376

10.313

-10.313

0.000
0.000
8.324
Sum O2

CO2

N2

SO2

O2

34.971
24.752

% wt wet / (1 - M
0.000

0.000

0.000
8.324

37.035

stoichiometric mols

139.321

139.321

176.355
207.368

e gas (dry)

e gas (tot)

mol/kgf

Flue gas composition (mol/kgfuel)

/kgf

33.077

34.971

139.321 0.000

174.291
1.3
11.110
41.796
229.262

/kgf

e gas (dry tot)

/kgf

260.275

33.077

227.198

total mols

ons in real gas:


ons in dry gas:

12.71

34.971
13.44
15.39

181.117 0.000
69.59
79.72

0.00
0.00

11.110
4.27
4.89

100.000
100.000

3
3.950 m n/kgfuel

Stoichiometric gas

go

207.368 molflue gas/kgf

3
5.135 m n/kgfuel

Normal total gas

260.275 molflue gas (tot)/kgf

wt wet / (1 - M)

3
4.645 m n/kgfuel
3
5.830 m n/kgfuel

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