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12
15
1170
2140
1950
3280
3240
5840
4540
5200
The composition of the adsorbed phase is 96.8 mol % CH4, the balance being H2.
The carbon has a bulk density of 0.30 g/cm3.
The gas velocity in the adsorbers should not exceed 1 ft/s based on the cross-sectional
area of the empty vessel. This applies to all the cycles including the adsorption and the
regeneration and purge.
The feed gases enter the adsorbers at 400 psia and 80F. The product gases leave the
adsorbers at almost 400 psia and a temperature of 140F. Regeneration includes 30 ft3 (SC) of
flue gas per pound of carbon and 80 standard cubic feet of purging air per pound of carbon. The
flue gas is at 600F (its maximum temperature) and 5 psig, and the air is at 90F and 5 psig. The
air may reach a maximum temperature of 600F at the start of the purging.
For each head (either top or bottom), add equivalent cost of 5 ft additionallength per vessel. Cost
data are given above.
SOLUTION:
Given data:
10 million ft3 (measured at SC) per day
Gas contains72.5 vol % H2, and 27.5 vol % CH4
Product gas must contain 95 vol % H2
Regeneration and Purging time of one bed = 8 hrs.
Alternatively,
Time for adsorption of second bed = 1 hr
Time for desorption of second bed = 1 hr
Pressure maintained for adsorption = 400 psig
Pressure maintained for desorption = 20 psig
V=
10 10 0.275 (0.3)
24
= 3093.75m3
(PV/RT)= (101325 3093.75) / (8314273)
= 136.3052 Kmoles
Number of Kmoles of H2 in = PV/RT
X Kmoles
Y Kmoles
(5/95) X Kmoles
0.0526 X Kmoles
10 10 6 0.275
24 3600
10 10 6 0.725
24 3600
= 31.828 ft3/sec
= 83.912 ft3/sec
Therefore, volumetric flow rate of product gas is = (Volumetric flow rate of CH4 +
Volumetric flow rate of H2)
= (31.828 + 83.912) = 115.74ft3/sec
=>
115.74
62
n
4
=>
n = 4.09 = 4
Given that, for each head (either top or bottom), add equivalent cost of 5 ft additionallength per
vessel
Height of the column along with head = 1304.645 + 5 = 1309.645ft
Column cost per feet = 1170 $
Entire column cost = 1170 1309.645
= 1532284.65 $
Cost per tower for skirt or support = 1950 $
Total Cost = Column cost + Cost per tower for skirt or support
= 1532284.65 +1950
= 1534234.65 $
Case (ii):
For diameter of column = 9 ft
Volume of column = D2H/4 = 36869.26 ft3
Height of Column = (4 35154.6559) / ( 92)
= 579.8421ft
Given, gas velocity in the adsorbers should not exceed 1ft/s
10 10 6 0.275
24 3600
10 10 6 0.725
24 3600
= 31.828 ft3/sec
= 83.912 ft3/sec
Therefore, volumetric flow rate of product gas is = (Volumetric flow rate of CH4 +
Volumetric flow rate of H2)
= (31.828 + 83.912) = 115.74ft3/sec
=>
=>
115.74
92
n
4
n 1.819 = 2
Given that, for each head (either top or bottom), add equivalent cost of 5 ft additionallength per
vessel
Height of the column along with head = 579.8421+ 5 = 584.8421ft
Column cost per feet = 2140 $
Entire column cost = 2140 584.8421
= 1251562.094 $
Cost per tower for skirt or support = 3240 $
Total Cost = Column cost + Cost per tower for skirt or support
= 1251562.094 + 3240
= 1254802.094 $
Case (iii):
For diameter of column = 12 ft
Volume of column = D2H/4 = 36869.26 ft3
Height of Column = (4 * 36869.26) / ( * 122)
= 326.1612 ft
Given, gas velocity in the adsorbers should not exceed 1ft/s
Volumetric flow rate = Gas velocity Area of the tower
Volumetric flow rate
D2
i.e.,
1
n
4
10 10 6 0.275
24 3600
10 10 6 0.725
24 3600
= 31.828 ft3/sec
= 83.912 ft3/sec
Therefore, volumetric flow rate of product gas is = (Volumetric flow rate of CH4 +
Volumetric flow rate of H2)
= (31.828 + 83.912) = 115.74ft3/sec
=>
115.74
122
n
4
=>
n 1.02 = 1
Given that, for each head (either top or bottom), add equivalent cost of 5 ft additional length per
vessel
Height of the column along with head = 326.1612 + 5 = 331.1612ft
Column cost per feet = 3280 $
Entire column cost = 3280 331.1612
= 1086208.736 $
Cost per tower for skirt or support = 4540 $
Total Cost = Column cost + Cost per tower for skirt or support
= 1086208.736 + 4540
= 1090748.736 $
Case (iv):
For diameter of column = 15 ft
Volume of column = D2H/4 = 36869.26 ft3
Height of Column = (4 * 36869.26) / ( * 152)
= 208.7432 ft
Given, gas velocity in the adsorbers should not exceed 1ft/s
Volumetric flow rate = Gas velocity Area of the tower
Volumetric flow rate
D2
i.e.,
1
n
4
10 10 0.275
24 3600
10 10 6 0.725
24 3600
= 31.828 ft3/sec
= 83.912 ft3/sec
Therefore, volumetric flow rate of product gas is = (Volumetric flow rate of CH4 +
Volumetric flow rate of H2)
= (31.828 + 83.912) = 115.74ft3/sec
=>
115.74
152
n
4
=>
n 0.65 = 1
Given that, for each head (either top or bottom), add equivalent cost of 5 ft additionallength per
vessel
Height of the column along with head = 208.7432 + 5 = 213.7432ft
Column cost per feet = 5840 $
Entire column cost = 5840 213.7432
= 1248260.288 $
Cost per tower for skirt or support = 5200 $
Total Cost = Column cost + Cost per tower for skirt or support
= 1248260.288 +5200
= 1253460.288 $
Diameter
Volume
Height of
Column
Entire column
Cost
Total Cost
No of
of
of
column
cost per
cost ($)
per
($)
individual
column
column
(ft)
feet ($)
(ft)
(ft3)
tower
towers in
for skirt
each bed
or
support
($)
36869.2
1304.64
6
36869.2
5
579.842
12
6
36869.2
15
1170
1532284.65
1950
15344234.6
3240
5
1254802.09
2
1
1
2140
1251562.09
1
326.161
3280
4
1086208.73
4540
4
1090748.73
6
36869.2
2
208.743
5840
6
1248260.28
5200
6
1253460.28
Therefore,
1. The number of individual units (or towers) in each bed to give the minimum total cost for
the towers is n = 1
2. The height and diameter of the towers for the conditions in part I are
Height = 326.1612ft
Diameter = 12ft
Minimum