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Article history:
Received 20 October 2015
Received in revised form
7 May 2016
Accepted 7 May 2016
Available online 24 May 2016
Effective promotion of GPC is required in order to minimize the environment threat due to y ash waste
disposal and reduce cement consumption. To achieve this, specic mix design procedure for development of GPC is essential. Therefore, efforts have been made in this paper to develop a mix design
methodology for GPC with the main focus on achieving better compressive strength in an economical
way for different alkaline solutions to binder proportions. Low calcium y ash brought from local sources
as the binder material, sodium hydroxide and sodium silicate as alkaline activator solutions, and
aggregate grading based on DIN standards, have been employed for conducting experimental investigation. Correlation between the alkaline activator solution to binder ratios and 28 day compressive
strength has been investigated to propose conceptual mix design method for GPC in a rational way. Mix
design is proposed for various AAS/FA ratios ranging from 0.4 to 0.8, and the 28 day compressive strength
as high as 54 MPa has been noticed. The design methodology proposed has been given step-wise and the
same has been veried with the help of an example in this paper.
2016 Elsevier Ltd. All rights reserved.
Keywords:
Activator solution
Compressive strength
Fly ash
Geopolymer concrete
Mix design
1. Introduction
Nowadays, the increase in the people's attention on the conservation of natural resources and minimization of environment
depletion has led to look at the alternatives to accustomed construction materials. Currently, ordinary Portland cement based
concrete is the leading construction material all across the world,
with the cement usage being 4.0 billion tons per annum and growth
rate being 4% per annum (Mineral Commodities Summary, 2014).
The major problems associated with the Portland cement are its
production, which is energy consuming and more signicantly it
releases very high volume of carbon dioxide in to the atmosphere.
At the same time the disposal of industrial wastes such as y ash,
ground granulated blast furnace slag, mine waste, red mud etc, has
become a big problem, it requires large areas of useful land and also
has huge impact on the environment. Therefore, the need is
emanated from further investigation into safe waste disposal and
118
119
Table 1
Maximum water content per cubic metre of concrete (IS 10262: 2009).
Nominal maximum size of aggregate (mm)
10
20
40
208
186
165
Let;
Then;
Mass of AAS
120
80
The ne and coarse aggregate content was determined according to combined aggregate grading as recommended by DIN 1045
standards (1988). Let the percentage of ne aggregate in the total
aggregate be x% and that of the coarse aggregate be y%. Various
sizes of coarse aggregates are used and are categorized as CA1, CA2
and CA3. Let percentage of CA1 mm size of aggregate be y1%,
CA2 mm size of aggregate be y2% and CA3 mm size of aggregate be
y3%. Then,
60
40
20
0
0.3
0.4
0.5
0.6
0.7
0.8
0.9
w/c ratio
Fig. 2. Strength versus water to cement ratio curve.
121
Table 2
Mix proportion used in the study.
Mix
1
2
3
4
5
AAS/FA
0.4
0.5
0.6
0.7
0.8
500
400
333
286
250
NaOH Kg/m3
80
80
80
80
80
Na2SiO3 Kg/m3
120
120
120
120
120
Aggregates (kg/m3)
20 mm
12.5 mm
6.3 mm
Fine Aggregate
465
500
523
540
552
538
578
605
624
638
318
341
357
369
377
320
344
360
371
380
Water/Geopolymer Solid
SP kg/m3
0.21
0.26
0.30
0.34
0.37
6
4
3.2
e
e
Table 3
Chemical composition of y ash.
Oxide
SiO2
Al2O3
Fe2O3
CaO
Na2O
K2O
MgO
SO3
LOI
Wt (%)
61.89
28.05
4.11
0.87
0.40
0.82
0.38
1.32
0.49
better strength, workability and economy. Moreover, at AAS content of 200 kg/m3, the water content present in the AAS found to be
within the maximum water content limits given in Table 1 for
20 mm maximum aggregate size case.
STEP 2: Determination of Strength
From Fig. 2, for AAS/FA ratio of 0.5, the minimum 28 day
compressive strength that has to be obtained is 38 MPa.
STEP 3: Calculation of Binder Content
122
% passing
60
40
20
0
0.1
1
Particle size (log scale) (mm)
10
Bc =GB MNaOH =GNaOH
MNa2 SiO3 MNa2 SiO3 f1=1000g
VTA 0:98
Slump (mm)
0.4
0.5
0.6
0.7
0.8
35
60
80
110
Collapse
53.56
45.95
37.12
33.41
23.45
55.33
47.49
39.96
36.85
28.26
60
R2 = 0.934
28 day compressive strength = 20.352 (AAS/FA) -1.119
50
40
30
Normal concrete
(ACI relationship)
GPC relationship
20
10
0.3
0.4
0.5
0.6
0.7
0.8
0.9
123
Fig. 6. SEM images of y ash based GPC for different AAS/FA (a) 0.4 (b) 0.5 (c) 0.6 (d) 0.7 (e) 0.8.
124
6. Conclusions
A rational mix design approach for y ash based GPC has been
introduced. A review on the earlier proposed mix designs shows
that they all depend mainly on the AAS content. As AAS is the
costliest ingredient of all, providing exibility in xing the AAS
content is very advantageous from the economy point of view. The
ndings of this study suggest that, using the proposed method GPC
can be produced for a specic strength by employing the corresponding AAS/FA ratio obtained from the modied ACI strength vs.
w/c ratio curve. GPC can also be produced for a specic AAS/FA ratio
to achieve the corresponding strength. Using the proposed
125
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