Professional Documents
Culture Documents
TECHNICAL PAPER
INTRODUCTION
Anti-washout admixtures (AWAs) are used to enhance the
stability of fresh cement-based systems, including underwater concrete. Several researchers have reported improvement
in washout resistance and in-place properties of underwatercast concrete when the concrete incorporates AWAs.1-3
Such admixtures are also used in self-consolidating concrete
to enhance resistance to bleeding, segregation, and surface
settlement.
Commonly used AWAs include cellulose derivatives and
polysaccharides of microbial sources.4-6 The mode of action
of AWA depends on the type and concentration of the polymer. For example, welan gum is believed to increase the viscosity of mixing water as long-chain polymer molecules
adhere to the periphery of water molecules, thus imbibing
and fixing part of the mixing water and enhancing the paste
viscosity.7 This can improve the capacity of the paste to suspend solid particles and retain free water. Concrete modified
with AWA exhibits higher yield value and plastic viscosity
compared with non-AWA concrete. 6 High-range waterreducing admixture (HRWR) is added to reduce the yield
value of AWA concrete. The increase in HRWR and AWA
dosages could secure flowable concrete of relatively low
yield value and moderate-to-high plastic viscosity of high
washout resistance. Mixtures containing AWA can exhibit
shear-thinning behavior, whereby the apparent viscosity
ACI Materials Journal/July-August 2001
289
The objective of the study presented herein is to investigate the coupled effect of AWA concentration, w/cm, and
supplementary cementitious materials on the variations of
washout resistance with the fluidity of underwater concrete.
Such high-performance concrete is targeted for use in underwater construction and repair.
RESEARCH SIGNIFICANCE
Ensuring high washout resistance is essential to secure
proper in-place performance of underwater cast concrete.
The results presented in this paper deal with the effects of
AWA type and concentration, w/cm, and binder composition
on slump flow consistency and washout resistance of highperformance concrete. Such data are critical given the increasing
demand to secure quality repairs underwater and the higher
environmental constraints to limit water pollution resulting
from such operations.
MATERIALS
This study used a Type 10 Canadian cement (CSA3-A5M83) similar to ASTM Type I cement, a nondensified silica
fume, a Class F fly ash (ASTM C 618-84), and a granulated
blast-furnace slag. The specific gravity values of the silica
fume, fly ash, and granulated blast-furnace slag were 2.22,
2.53, and 2.88, respectively. The Blaine fineness of the cement,
fly ash, and ground blast-furnace slag were 380, 360, and
450 m2/kg, respectively.
A continuously graded crushed limestone aggregate with
nominal particle size of 14 mm and a well-graded siliceous
sand with fineness modulus of 2.5 were used. The values of
bulk specific gravity of the coarse aggregate and sand were
2.72 and 2.66, respectively, with absorption levels of 0.3 and
1.2%, respectively.
Powdered welan gum and a liquid-based cellulosic material
with 1.20 specific gravity were used for the AWA. A naphthalene-based HRWR conforming to CSA3-A266-2-M85
with solid content of 42% and specific gravity of 1.21 was
used in AWA mixtures containing welan gum and those
without any AWA. A melamine-based HRWR was used in
mixtures made with the cellulose-based AWA. The solid
content and specific gravity of this HRWR are 40% and 1.20,
respectively. A carboxylic hydroxide acid conforming to
CSA3-A266-2-M78 was incorporated to enhance fluidity retention of the AWA concrete.
MIXTURE PROPORTIONS
As summarized in Table 1, the investigated mixtures were
prepared with w/cm of 0.41 and 0.47, corresponding to highperformance concrete used for underwater construction and
repair. As indicated in Table 1, the concentrations of welan
gum were varied between 0.07 and 0.15% (by mass of binder), which represent low to moderate dosages for underwater
concrete application. The dosages of the cellulosic AWA
ranged between 1 and 1.65 L/100 kg of cementitious materials, representing moderate to high values.
The sand-to-aggregate mass ratio was fixed at 0.46. All
mixtures incorporated high binder contents to limit aggregate volume to approximately 300 L/m3 to enhance flow
characteristics in restricted areas. High binder content can
reduce the HRWR and AWA demand necessary to secure
given levels of fluidity and stability, with direct impact on
100% C
Cement, kg/m3
592
530
473
58
kg/m3
w/cm = 0.47
6% SF +
10% SF 20% FA 50% SL
6% SF +
20% FA 50% SL
100% C
10% SF
296
557
497
439
278
55
119
109
Granulated blast-furnace
slag, kg/m3
296
278
water, kg/m3
243
241
243
243
262
261
261
258
816
810
817
819
830
822
838
827
693
690
694
698
707
700
698
706
85
85
85
85
85
85
85
85
Fly ash,
Sand,
kg/m3
1.6 to 8.2 4.2 to 9.8 5.9 to 9.4 2.1 to 5.9 0.0 to 3.1 3.2 to 5.6 4.0 to 7.0 0.7 to 2.8
0.07*
0.07
0.07
0.07
0.07
0.07
0.07
0.07
0.15
0.15
0.15
0.15
0.15
0.15
Melamine-based HRWR,
1.4 to 2.0 2.5 to 4.1 1.9 to 3.9 0.0 to 2.6 0.0 to 1.5 3.1 to 4.5 1.0 to 3.0 0.0 to 1.7
L/m3
Cellulose AWA,
L/100 kg of CM
*0.07%
0.15%
290
1.0
1.0
1.0
1.0
1.0 to 1.65
1.0
1.0
1.65
binder = 0.17% of water for w/cm = 0.41 and 0.15% of water for w/cm = 0.47.
binder = 0.37% of water for w/cm = 0.41 and 0.32% of water for w/cm = 0.47.
w/cm
0.41
0.47
Type of CM
0.7
205
345
9.1
1.3
235
400
14.6
2.0
245
440
24.8
4.0
270
585
45.8
2.7
210
375
6.2
240
470
6.4
260
555
9.1
265
600
29.4
245
435
3.0
255
500
6.2
8.2
265
550
7.6
4.2
210
315
6.9
220
380
9.8
225
415
11.5
8.0
250
490
19.8
5.0
240
405
1.7
260
520
5.3
7.7
270
605
8.2
5.9
240
460
6.0
250
515
7.6
265
590
10.8
3.5
100% C
None
4.5
Welan gum
(0.07% of CM)
5.2
4.9
100% C
7.5
5.1
10% SF
6.3
10% SF
6.5
6% SF +
20% FA
7.2
8.2
Welan gum
(0.15% of CM)
Welan gum
(0.07% of CM)
Welan gum
(0.15% of CM)
Welan gum
(0.07% of CM)
100% C
None
9.4
270
635
11.8
100% C
6.0
220
420
1.8
10% SF
6.9
240
450
2.8
6% SF + 20% FA
250
490
4.1
50% SL
8.5
260
560
6.0
100% C
Cellulosic 1.0
9.3
265
580
7.7
10% SF
Cellulosic 1.0
2.1
220
405
10.0
6% SF + 20% FA
Cellulosic 1.0
230
440
10.1
50% SL
Cellulosic 1.0
245
490
10.5
100% C
4.3
265
540
12.5
10% SF
5.4
270
675
36.6
6% SF + 20% FA
3.1
220
410
2.9
50% SL
3.9
230
450
3.6
100% C
250
510
5.8
10% SF
Cellulosic 1.0
5.4
260
550
7.3
6% SF + 20% FA
Cellulosic 1.0
5.9
265
600
11.0
50% SL
Cellulosic 1.0
6% SF +
20% FA
7.8
Welan gum
(0.15% of CM)
2.9
50% SL
50% SL
*High-range
3.6
4.6
Welan gum
(0.07% of CM)
Welan gum
(0.15% of CM)
water-reducing admixture.
291
made with welan gum and supplementary cementitious materials. For a given w/cm, the increase in slump flow consistency by adding HRWR resulted in higher washout loss,
regardless of the dosage of AWA. This was especially the
case for concrete with no AWA or with low AWA dosage.
For a given AWA, additional HRWR can reduce yield value
and affect stability of the fresh concrete. This leads to the increase in free water content that reduces the ability of the
paste to retain water and suspended solid particles and fines.
For any given consistency, the increase in welan gum dosage from 0 to 0.15% or in cellulosic AWA from 1 L/100 kg
to 1.65 L/100 kg of cementitious materials resulted in a substantial reduction in washout loss. For example, for the
100% C concrete made with 0.41 w/cm and having a slump
flow of 450 mm, a reduction of 27 to 6% in washout loss was
observed with the increase of welan gum content from 0 to
0.07%. Further increases in welan gum to 0.15% yielded
limited enhancement in washout resistance.
For a given washout loss of 9%, an increase in welan gum
from 0 to 0.07% and to 0.15% for concrete with 0.41 w/cm
can enable the casting of concrete with slump flow increased
from 350 mm (slump of 210 mm) to 525 and 565 mm (slump of
255 and 265 mm), respectively. Therefore, the critical consistency beyond which sharp increases in washout loss occur can
be extended with further additions of AWA. This is due to the
increase in viscosity and water-retention capacity of the paste.
HRWR,*
Slump, Slump Washout
L/m3 AWA type dosage mm flow, mm loss, %
1.4
100% C
2.0
2.5
10% SF
3.5
4.1
1.9
6% SF +
20% FA
3.2
3.9
0.0
50% SL
1.9
2.6
Cellulosic AWA
(1.0 L/100 kg
CM)
Cellulosic AWA
(1.0 L/100 kg
CM)
Cellulosic AWA
(1.0 L/100 kg
CM)
Cellulosic AWA
(1.0 L/100 kg
CM)
292
255
465
5.9
265
555
8.5
240
400
3.6
255
510
5.9
265
535
6.4
240
400
3.6
270
490
4.1
275
555
4.8
240
380
3.7
260
525
6.4
275
610
8.6
100% C
10% SF
50
10% SF
40
AWA = 0%
Increasing
HRWR
30
6% SF +
20% FA
20
AWA = 1.0 l/100 kg CM
10
50% SL
0
300
350
400
450
500
Slump flow (mm)
550
600
650
25
0.07% AWA
W/CM = 0.41
AWA = Welan gum
100% C
0.15% AWA
20
50% SL
15
100% C
10% SF
Increasing
HRWR
6% SF + 20% FA
10% SF
6% SF +
20% FA
400
450
500
550
Slump flow (mm)
600
650
11.9
13.8
535
17.8
0.0
180
305
3.0
0.4
200
350
5.2
230
430
8.1
2.0
245
460
10.0
3.1
270
550
15.2
3.2
190
390
8.4
220
440
9.9
250
480
39.0
5.6
255
525
52.7
3.6
190
300
1.7
225
380
4.1
250
440
4.9
5.1
265
500
6.3
4.0
220
410
7.9
245
460
9.7
250
500
13.9
7.0
270
610
30.0
0.7
220
400
9.8
225
420
14.4
1.4
4.0
5.0
4.1
4.6
5.0
5.9
1.2
1.8
Welan gum
(0.15% of CM)
Welan gum
(0.07% of CM)
Welan gum
(0.15% of CM)
Welan gum
(0.07% of CM)
Welan gum
(0.07% of CM)
240
465
15.6
2.8
245
550
22.6
0.0
205
350
4.8
0.1
220
400
5.7
245
430
6.3
250
460
7.1
0.35
250
480
7.8
0.5
255
530
8.4
0.0
230
430
3.7
260
500
4.0
270
570
4.8
240
420
3.7
270
490
5.6
275
520
6.0
250
405
4.4
265
505
6.3
270
565
7.4
275
510
4.1
280
545
4.3
280
595
4.7
0.2
0.25
1.0
3.9
2.3
0.0
50% SL
9.7
475
490
3.0
700
430
240
260
1.0
6% SF + 20% FA
220
250
4.5
50% SL
Welan gum
(0.07% of CM)
2.9
3.1
10% SF
350
1.7
1.5
10
0
300
0.9
1.0
1.7
Cellulosic AWA
(1.0 L/100 kg
CM)
Cellulosic AWA
(1.65 L/100 kg
CM)
Cellulosic AWA
(1.0 L/100 kg
CM)
Cellulosic AWA
(1.0 L/100 kg
CM)
Cellulosic AWA
(1.65 L/100 kg
CM)
293
30
10% SF
6% SF + 20% FA
W/CM = 0.47
20
Increasing
HRWR
10
10% SF
50% SL
6% SF + 20% FA
0
300
350
400
450
500
550
600
650
700
Fig. 7Effect of w/cm and binder composition on variations of washout loss with slump flow.
CONCLUSIONS
Based on the results of this study, the following conclusions appear to be warranted:
1. The measurement of slump flow is more sensitive in reflecting changes in consistency of highly flowable AWA
(41%)
10% SF
100% C
10
5
0
600
650
Fig. 8Variations of washout loss with slump flow for mixtures made with different binder types (w/cm = 0.41 and
0.15% welan gum).
(41%)
30
10% SF
15
L
-1
%
50
FA
0%
SF
+2
SL
-1
-1
L
%
10
6%
-1
C
0%
SF
.6
-1
-1
0%
C
10
SF
10
0%
6%
650
SL
-1
-0
600
450
500
550
Slump flow (mm)
10
0%
400
6% SF + 20% FA
10
2
350
W/CM = 0.47
W/CM = 0.41
10
550 mm
50
100% C
450 mm
20
Increasing
HRWR
25
-1
50% SL
Cellulosic AWA
FA
W/CM = 0.41
Cellulosic AWA = 1.0 l/100 kg CM
0%
550
+2
500
10
0%
0% C-0
%
C
-0
10
0% .07
%
C
-0
10
.1
%
SF 5%
-0
6% 10
.0
7%
SF %S
F
6% +20 -0.
15
%
SF
%
F
+2 A0% 0.0
7
F
%
5 0 A-0
.1
%
S L 5%
-0
50
.0
%
SL 7%
-0
10
0% .15
%
C
-0
10
0% .07
%
C
-0
10
.1
%
SF 5%
-0
6% 10
.
SF %S 07%
+2 F-0
0% .1
5%
F
5 0 A-0
.0
%
S L 7%
-0
.0
7%
450
10
0
400
294
W/CM = 0.47
15
10
550 mm
W/CM = 0.41
20
6% SF + 20% FA
450 mm
25
-1
Increasing
HRWR
50% SL
(53%)
SF
10
W/CM = 0.41
Welan gum = 0.15%
30
12
50% SL
W/CM = 0.41
10
40
=
=
=
=
0.0039 in.
25.85 fl. oz/yd3
145 psi
1.685 lb/yd3
REFERENCES
1. Neely, B. D., Evaluation of Concrete Mixtures for Use in Underwater
Repairs, Technical Report No. REMR-CS-18, Department of the Army
Waterways Experiment Station, Vicksburg, Miss., 1988, 104 pp.
2. Khayat, K. H., and Hester, H. T., Evaluation of Concrete Mixtures for
Underwater Pile Repairs, ASTM Cement, Concrete and Aggregates, V. 13,
No. 1, 1991, pp. 32-41.
3. Khayat, K. H.; Gerwick, B. C., Jr.; and Hester, W. T., Self-Leveling
295