Pembuatan Larutan Kimia

Standard Iodine Solution (0.1 N)

Weigh 12.700 g of iodide and 19.100 g of potassium iodide into a beaker. mix the
dry iodine and potassium iodide. Add 2 to 5 mL of water to the beaker and stir
well. Continue adding small increments of water (approximately 5 mL each) while
stirring until the total volume is 50 to 60 mL . Allow the solution to stand a
minimum of 4 h to ensure that all crystals are throughly dissolved. Occasional
stirring during this 4-h period will aid in the dissolution. Quantitatively transfer to
a 1 L important that the standard iodide solution has an iodide to iodide weight
ratio of 1.5 to 1 . store the solution in an amber bottle
Standard Iodida Solution ( 0,1 N )
Timbang 12,700 g iodida dan 19,100 g kalium iodida ke dalam gelas kimia . mencampur
yodium kering dan kalium iodida . Tambahkan 2 sampai 5 mL air untuk gelas dan aduk
rata . Terus menambahkan sedikit demi sedikit air ( masing-masing sekitar 5 mL ) sambil
diaduk sampai volume total 50 sampai 60 mL . Memungkinkan solusi untuk berdiri
minimal 4 jam untuk memastikan bahwa semua kristal -benar dibubarkan . pengadukan
sesekali selama periode 4 - h ini akan membantu dalam pembubaran . Kuantitatif
transfer ke 1 L penting bahwa solusi iodida standar memiliki iodida untuk iodida
perbandingan berat 1,5 sampai 1 . menyimpan solusi dalam botol amber

Potassium Iodate Solution (0.1 N)

Dry 4 or more gram of primary standard grade potassium iodate (KIO3) at 110 C
for 2 h and cool to room temperature in a desiccator. Dissolve 3.5667 mg of the
dry potassium iodide in about 100 mL of distilled water. Quantitatively transfer to
a 1 L volumetric flask and fill to the mark with distilled water. Mix thoroughly and
store in a glass-stoppered bottle.
Kalium Iodat Solusi ( 0,1 N )
Kering 4 atau lebih gram primer standar iodat kelas kalium ( KIO3 ) pada 110 C selama 2
jam dan dingin untuk suhu kamar dalam desikator . Larutkan 3,5667 mg kalium iodida
kering di sekitar 100 mL air suling . Kuantitatif transfer ke labu ukur 1 L dan isi dengan
tanda dengan air suling . Aduk rata dan simpan dalam botol kaca bertutup

Strach Solution
Mix 1 g of strach with 5 to 10 mL of cold water to make a paste. Add an
additional 25 mL water while stirring, into 1 L of boiling water and boil for 4 to 5
min. This solution should be made fresh daily.
strach Solusi (Larutan Kanji)
Campurkan 1 g strach dengan 5 sampai 10 mL air dingin untuk membuat pasta .
Menambahkan tambahan 25 mL air sambil diaduk , ke dalam 1 L air mendidih dan rebus
selama 4 sampai 5 menit . Solusi ini harus dibuat segar setiap hari .

Standardization of Solutions
Standardization of 0.1 N Sodium Thiosulfat
Pipet 25 mL of potassium iodate (KIO3) solution into a 250 mL titration (or widemouthed Erlenmeyer) flask. Add 2 g of potassium iodide (KI) to the flask and
shake the flask to dissolve the poltassium iodide crystals. Pipet 5 mL of
concentrated hydrochoric acid into the flask. Titrate the free iodine with sodium
thiosulfat solution until a light yellow color is observed in the flask. Add a few
drops of starch indicator and continue the titration dropwise until one drop
produces a colorless solution. Determine sodium thiosulfat normality as follows:

N=
N
P
R
S

( P R )
Where:
S
=
=
=
=

Sodium Thiosulfat, N.
Potassium iodate, mL.
Potassium iodate, N.
Sodium Thiosulfat, mL.

The titration step should be done in triplicate and the normality result averaged.
Additional replications should be done if the range of values exceeds 0.03 N.
Standarisasi Natrium thiosulfat 0.1 N
Pipet 25 mL kalium iodat ( KIO3 ) larutan ke dalam 250 mL titrasi ( atau Erlenmeyer
bermulut lebar ) termos . Tambahkan 2 g kalium iodida ( KI ) ke tabung dan kocok labu
untuk melarutkan kristal poltassium iodida . Pipet 5 ml asam hydrochoric pekat ke dalam
labu . Titrasi iodium gratis dengan natrium thiosulfat solusi sampai warna kuning muda
diamati dalam labu . Tambahkan beberapa tetes indikator pati dan melanjutkan tetes
demi tetes titrasi sampai satu tetes menghasilkan larutan tidak berwarna . Tentukan
natrium thiosulfat normalitas sebagai berikut :

N=

( P R)
S

Dimana:
N = Sodium thiosulfat , N.
P = Kalium iodat , mL .
R = Kalium iodat , N.
S = Sodium thiosulfat , mL .
Langkah titrasi harus dilakukan dalam rangkap tiga dan hasil normalitas rata-rata .
ulangan tambahan harus dilakukan jika rentang nilai melebihi 0,03 N.

Standardization of 0.1 N Iodine Solution

Pipet 25 mL of iodine solution into a 250 mL widemouthed Erlenmeyer
flask. Titrate with standardized sodium thiosulfat until the iodine solution
is a light yellow color. Add a few drops of starch indicator and continue

titration dropwise until one drop produces a colorless solution. Determine

the iodine solution normality as follows:
N 2=

(S N 1)
I

Where:
N2
: Iodine, N.
S
: Sodium Thiosulfat, mL.
N1
: Sodium Thiosulfat, N.
I
: Iodine, mL.
The titration step should be done in triplicate and the normality result
averaged. Additional replications should be done if the range of values
exceeds 0.003 N. The iodine solution concentration must be 0.1 N.
Standarisasi 0,1 N Larutan Iodida.
Pipet 25 mL larutan iodida menjadi 250 mL widemouthed Erlenmeyer . Titrasi dengan
natrium standar thiosulfat sampai solusi iodida adalah warna kuning muda . Tambahkan
beberapa tetes indikator pati dan terus titrasi tetes demi tetes sampai satu tetes
menghasilkan larutan tidak berwarna . Menentukan solusi normalitas iodida sebagai
berikut :

N 2=

(S N 1)
I

Dimana:
N2 : Iodida , N.
S : Sodium thiosulfat , mL .
N1 : Sodium thiosulfat , N.
Saya : Iodida , mL .
Langkah titrasi harus dilakukan dalam rangkap tiga dan hasil normalitas rata-rata .
ulangan tambahan harus dilakukan jika rentang nilai melebihi 0,003 N. Konsentrasi
larutan iodida harus 0,1 N.

Procedure
The procedure applies to either powdered or granular activated carbon.
When granular carbon is to be tested, grind a representative sample (see
Practice E 300) of carbon until 60 wt % (or more will pass through a 325mesh screen) and 95 wt % or more will pass through a 100 mesh screen
(U.S. sieveseries, see Specification E 11). Carbon received in the
powdered from may need additional grinding to meet the particle size
requrenment given above.
Dry the ground carbon from 10.1 in accordance with Test Method D 2867.
Cool the dry carbon to room temperature in a desiccator.

Determination of iodine number requires an estimation of three carbon

dosages. Section 11.4 describes how to estimate the carbon dosages to
beused. After estimating carbon dosages, weigh three appropriate
amounts of dry carbon to the nearest miligram. Transfer each flask and
swirl gently until the carbon is completely watted. Loosen the stoppers to
vent the flasks, place on a hot plate in a fume hood, and bring the
contents to a boil. Allow to boil gently 30 s to remove any sulfur which
may interfere with the test result. Remove the flasks from the hot plate
and cool to room temperature.
Pipet 100 mL of 0.1 N iodide solution into each flask. Standardize the
iodide solution just prior to use. Stagger the addition of iodide to the three
flasks so taht no delays are encountered in handling. Immediately stopper
the flasks, and shake the contents vigorously for 30 s. Quickly filter each
mixture by gravity through one sheet of folded filter paper (Whatman No.
2V or equivalent) into a beaker. Filtration equipment must be prepared in
advance so no delay is encountered in filtering the samples.
For each filtrate, use the first 20 to 30 mL to rinse a pipet. Discard the
rimse portions. Use clean beakers to collect the remaining filtrates. Mix
cach filtrate by swirling the beaker and pipet 50 mL of each filtrate into a
clean 250-mL Erlenmeyer flask. Titrate each filtrate with standardized 0.1
N sodium thiosulfat solution until the solution is a pale yellow. Ass 2 mL of
the starch indicator solution and continue the titration with sodium
thiosulfate until one drop produces a colorless solution. Record the volume
of sodium thiosulfat used.