03-04-14 SR - Iit All Streams & Lt-Iit Phase-II JEE-Main GTM-6 Q'Paper-p19u9undbj1b7319mpv91bd54

NARAYANA IIT ACADEMY
INDIA
Sec: Sr.IIT ALL STREAMS & LT-IIT
PHASE -II
GRAND TEST-6
Date: 03/04/14
Max Marks:360
JEE-MAIN
IMPORTANT INSTRUCTIONS:
There are three parts in the question paper A, B, C consisting of Maths, Physics and
Chemistry having 30 questions in each part of equal weightage. Each question is allotted 4
(four) marks for each correct response.
Candidates will be awarded marks as stated above in instruction for correct response of each
question. 1/4 (one fourth) marks will be deducted for indicating incorrect response of each
question. No deduction from the total score will be made if no response is indicated for an
item in the answer sheet.
There is only one correct response for each question. Filling up more than one response in
each question will be treated as wrong response and marks for wrong response will be
deducted accordingly as per instruction
MATHEMATICS
1.
If each of the roots of the equation x2a1x a2 a 8 0 is greater than 1, then

the range of 'a' is
11
1
) 3 , 2
2 2 2,
3
3
)
2)1, 3
4)2 2,
3
1
,
2.
If a variable 'X' takes values 1, 2, 3, 4, 5 with corresponding frequencies 1, 2, 3, 4, 5;
then the Mean Deviation of X, from mean X is equal to

1) 2
2) 3.2
3.
3) 1.2
4) 16
15
Let ABC be a triangle with vertices at points A2, 3, 5, B, 3,, C7, 5,10 in three
dimensional space. If the median through A is equally inclined with the coordinate
axes, then
cos1
1)
2)
23
3)
4)
Narayana IIT Academy
4.
03/04/14_ Sr.IIT ALL STREAMS & LT-IIT _Phase-II_JEE-Main_GTM-6
Statement (S1): If x 0 then the set of all x such that
sin x cos x is 1 , 1
1
Statement (S2): The function sin1 x is increasing in1,1
5.
1) S1 is true, S2 is true and S2 is a correct explanation for S1

2) S1 is false, S2 is true
3) S1 is true, S2 is true and S2 is not a correct explanation for S1
4) S1 is true, S2 is false
A number x is chosen at random from the set1, 2, 3, ...........,15. If E denotes the
event that sinxc is positive, then the odds in favour of E is_________
xc means x radians
1) 2 : 3
6
.
2) 3 : 5
3) 3 : 2
4) 5 : 3
Let f : 7 , 90, be a continuous function such that f1 x fx for all

2 2
x 7 , 9 . If R is the numerical value of the area of the region bounded by
2
2
y fx, 2x 7 0, 2x 9 0 and the x axis , then the value of x f xdx
1) R
2
2) 2R
3) 4R
4) R
Sr.IIT ALL STREAMS & LT-IIT_JEE-MAIN
Space for rough work
Page 2
7.
8.
Statement (S1): The only circle having radius 10 , with a diameter

along the line 2x y 5 and passing through the origin is x2 y2 6x 2y 0
and no other circle will exist with the given conditions
Statement (S2): 2x y 5 is a normal to the circle x2 y2 6x 2y 0
Statement (S1): The statement AB A is equivalent to AA B
Statement (S2): The statement A B A B is a
9.
10.
11.
tautology
If S n denotes the sum of the terms in the nth bracket of the series
1 3 5 7 911 1 3151719 . ......, thenS11 S9
1) 362
2) 432
3) 602
4) 632
The number of 4 - digit natural numbers, such that the sum of the digits of each
number is equal to 9 is
1) 165
2) 210
3) 265
4) None of these
Let f(x),g(x) be two continuous functions defined from R R ,such that f x1 f x2
and g x1 g x2 ,x1 x2 . Then the complete solution set
of g 2 2 f g3 4 is given by
f
1)
,1
2)4,
12.
3) R1,4 4)1,4
Let A : sin tan and B : sec 1 be two sets.
Then
1) B A
2 ) A B an d B A
3) A B
4) A B
Page 3
13.
If r1,r2,r3 are the ex-radii ofABC , then the value of r2

1) Positive
14.
2) Negative
3) Non-positive
If 1 x x2 x3 10
a0 a1x a2x2 a3x3 ....... a30x
following is true?
1) a2 a4 a6...... a28 a30 1
r1
r3
r2
r3
r3
r1 is
r1
r2
4) Non-negative
then which of the
30
2) a1 a3 a5 a7 .......... a27 a29 0

3) a0 a1 a2 a3 ........... a30 219
4) Both (1) and (2)
15.
Let A1 be the area of the region bounded by the curves y ex, y ex and x loge 2.
Let A2 be the area of the region bounded by the curves
y logex, y logex, and x e . Then
1) A1 A2
2) A1 2A2
3) A2 2A1
4) A2 4A1
1
6
.
Let A be a non - singular matrix such that A1
8 . Then the value of
100 100 99
detadj2A det2A
17.
1) 8
2) 12
3) 16
4) 28
The equation of the curve passing through2,2 and satisfying the differential
equation dy 2xy x23 dy is
d
x
dx
1
)
2) y 2 x y y 2
4) x 2 x y y 2
3) y 2 x y x 2
Page 4
18.
If,, are the roots of x3 3x2 3x 7 0 and is a complex cube root of unity,
then the value of
111 is equal to q for some p,q Z . Then the

p

11
number of ordered pairsp,q such that p q15 is

1) 0
2) 1
3) 2
4) infinite
If x0,10then the number of points of intersection of the curves
19.
y sinx and ysin cos where. denotes the greatest integer
function is
1
10
20.
10
3) 3
4) infinite
2) 2
1
If0,1,1,1 and1,0 are the mid-points of the sides ofABC, then the abscissa of
in-centre ofABC, is equal to
1) 2tan
2) 2tan
3) 2 tan
4) 2 tan 38
38
21.
The equation of the parabola to which the straight line m2y10 mx1 0 is a
tangent for any real value of m is
1) y2 4x 4
2 ) x 2 4 y 1 0
3) x2 4y10
22.
4)y102 4x1
Let f be a real function satisfying fx fx 3 fx 6 fx 9. Then the

x12
f
u
n
c
t
i
o
n
g
23.
t dt is
1) a constant function
2) a linear function of x
3) an exponential function of x
4) a pure quadratic function of x
If both the pointsa,0 and0,a lies inside the triangle formed the straight lines
8x 7y 56 0, 6x11y 66 0 and x 2y 2 0 , then the range of 'a ' is
1
2)1,7
3)2,7
4)1 ,6
x2
2
,
6
24.
The radius of the circle passing through the foci of the ellipse 16 y9 1 and having
centre at0,3 is
1) 3
2) 4
3) 5
4) 2 3
Page 5
25.
Statement (S1): If the straight line given by r2i xi 2 j 3k,

j
R and the points with position vectors i 2 j 3k , i j k are coplanar, then
the value of x is 7
Statement (S2): Three vectors a, b, c are coplanar iffa, b,

c 0

3) S1 is true, S2 is false 4) S1
is false, S2 is true
2
6
.
The value of
1)
sin 2 sin
0
2)
2
2
7
.
3)
4)
On set of all real numbers R define a relation S by xSy if and only if x y 2 is an

irrational number. Then S is
1) Reflexive, symmetric, but not transitive 2)
Reflexive, transitive, but not symmetric
3) An equivalence relation
4) Neither symmetric nor transitive
If the points Az, Bz, C1 z in argand plane are vertices of an equilateral
triangle, then z
28.
1) 1 i 23
2) 11 i
3) 11
4
3i
4) 11
3
3i
Page 6
5x 7 for x 2
2
9
.
Statement (S1): Let fx1|1 t| dt for x2
Then f is not differentiable at x 2
Statement (S2): A function fx is not differentiable at x a ,if f is not continuous at

x a , where fx is defined in the neighbourhood of ' a '
30.
1) S1 is true, S2 is true and S2 is correct explanation for S1

3) S1 is true, S2 is true but S2 is not a correct explanation for S1
The sides of the rectangle of the greatest area that can be inscribed in the ellipse
x2 2y2 8 are given by
1) 4 2 , 4
2) 4, 2 2
3) 2, 2
4 ) 2 2, 2
PHYSICS
31.
32.
A particle moves in the XY plane according to the law X a sint and

y a1 cost where a and are constants. Then, the trajectory of the particle is
1) a parabola
2) a straight line equally inclined at X and Y - axes
3) a circle
4) an ellipse.
A particle is fired from a point on the ground with speed u making an angle with the
horizontal. The radius of curvature of the projectile at a point where the tangential
acceleration becomes zero is
1) u cg s
2
o2
2) ug
2
33.
4) u tan
3) u
sign2
2
2
2
A block is gently placed on a conveyor belt moving horizontally with constant speed,
at t = 4s the velocity of the block becomes equal to the velocity of the conveyor belt. If
the coefficient of friction between belt and block is 0.2, then the velocity of the
conveyor belt is g10 m / s2
1 ) 2 m s1
2 ) 4 m s1
3 ) 6 4 m s1
4 ) 8 m s1
Page 7
34.
A long horizontal rod has a bead which can slide along its length, and initially placed at
a distance 'l' from one end A of the rod. The rod is set in angular motion about A with
constant angular acceleration ' '. If the coefficient of friction between the rod
and the bead is , and gravity is neglected, then the time after which the bead starts
slipping is
1)
2)
3
5
.
3) 1
4)
A force Fky ^i x ^j (Where k is a positive constant) acts on a particle moving in
the xy plane . Starting from the origin, the particle is taken along the positive
x axis to the pointa, 0 and then parallel to y axis to the pointa, a. The total
work done by the force F on the particle is

1)2ka2
2) 2ka2
3)ka2
36.
A particle of mass m is made to move with uniform speed v0 along the perimeter of a
regular hexagon, inscribed in a circle of radius R. The magnitude of impulse applied at
each corner of the hexagon is
1) 2mv0 sin
3
7
.
4) ka 2
2) mv0 sin
3) mv0 sin
4) 2mv0 sin
A solid sphere is set in motion on a rough horizontal surface where the coefficient of
friction is " " . The linear speed of c.m. is v0 in the forward direction and an angular
speed about the c.m. is v0 in the anticlockwise direction as shown in figure. The
R
magnitude of angular momentum of sphere about the origin "O" when it starts rolling
is
y
1 ) z e ro
2 ) Mv 0 R
0 v 0
R
3) 7 M v0 R
5
v0
4 ) 3 M v 0R
5
Page 8
38.
A stick lying on smooth ice is struck at one end by a lump of mud of mass equal to that
of the stick and travelling horizontally at a velocity v. The mud sticks to the stick.
After collision, the system of stick and mud
v
ice
Stick
1) Move forward with velocity v and spin about the centre of the stick
2
v
2) Move forward with velocity and spin about the centre of the stick
2
3) Move forward with velocity v and spin about the lump of mud
2
4) Move forward with velocity v and spin about their common centre of mass
2
The gravitational field in a region is given by g2i 3 N / kg. What is the work
j
9
.
done in moving a particle of mass 2 kg from1m,1m to2m, 1 m along the line
3
y
2
x
i
s
1) zero
2) 20J
3) 15 J
4 ) 2J
Page 9
40.
A cubical block is floating in a liquid with half of its volume immersed in the liquid.
When the whole system accelerates upwards with a net acceleration of g . The fraction
3
of volume immersed in the liquid will be
g3
1) 1
41.
2) 3
4) 3
A particle is executing vertical SHM about the highest point of projectile. When the
particle is at the mean position, the projectile is fired from the ground with velocity u
at an angle with the horizontal. The projectile hits the oscillating particle. Then, the
possible time period of the particle is
1) u
2) 2u
sin
sgin
42.
3) 2
3)
g
4) All of the above
2u3sgin
The following four wires are made of the same material. Which of these will have the
largest extension when the same tension is applied?
l ength l. diametre D
1) l 1.0 m , D1.0 mm
2) l 2.0 m, D 2.0 mm
3) l 3.0 m, D 3.0 mm
4) l 0.5 m, D 3.0 mm
Page 10
43.
44.
At critical temperature, the surface tension of a liquid

1) is zero
2) is infinity
3) is the same as that at any other temperature
4) cannot be determined
The ends of a stretched wire of length L are fixed at x 0 and x L . In one
experiment, the displacement of particles of the wire is Y1 A sinLx sint and
energy is E1 and in another experiment it is Y2 A sin2x sin 2t and energy is E2 .
Then
1) E2 E1
4
5
.
2) E2 2E1
3) E2 4E1
4) E2 16E1
A vessel contains a mixture of one mole of oxygen and two moles of nitrogen at 300K.
The ratio of the average rotational kinetic energy per O2 molecule to that per N2
molecule is
1) 1 : 1
2) 1 : 2 3) 2 : 1
4) Depends on the moments of inertia of the two molecules
A gas mixture consists of 2 moles of oxygen and 4 moles of argon at temperature T.
Neglecting all vibrational modes, the total internal energy of the system is
46.
47.
1) 4 RT
2) 15 RT
3) 9 RT
4) 11 RT
A black body is at temperature of 2880 K. The energy of radiation emitted by this
object with wavelength between 499 nm and 500 nm is U1 , between 999 nm and 1000
nm is U2 and between 1499 nm and 1500 nm is U3 . The Wein's constant
b 0.28 cm K. Then
1) U10
2 ) U3 0
3) U1 U2
4) U2 U1
Page 11
48.
49.
A 2.0 V potentiometer is used to determine the internal resistance of 1.5V cell. The
balance point of the cell in the open circuit is 75 cm. When a resistor of resistance 10
is connected across the cell, the balance point shifts to 60cm. The internal
resistance of the cell is
1) 1.5
2) 2.0
3) 2.5
4) 3.5
A rod with linear charge density is bent in the shape of circular ring. The electric
potential at the centre of the circular ring is
1)
5
1
.
3)
2)
50.
4) 2
A particle moves in a region having a uniform magnetic field and a parallel uniform
electric field. At an instant, the velocity of the particle is perpendicular to the field
direction. The path of the particle will be
1) a straight line
2) a circle
3) a helix with uniform pitch
4) a helix with non - uniform pitch
A metal rod moves at a constant velocity in a direction perpendicular to its length. A
constant, uniform magnetic field exists in space in a direction perpendicular to the rod
as well as its velocity. Select the statement(s) from the following
1) The entire rod is at the same electric potential
2) There is an electric field in the rod
3) The electric potential is highest at the centre for the rod and decreases towards at its
ends.
4) The electric potential is lowest at the centre of the rod, and increases towards at its
ends.
In an ideal transformer an alternating current of 2 ampere is flowing in the primary
coil. The number of turns in the primary and secondary coils are 100 and 20
respectively. The value of the current in the secondary coil is
52.
1) 0.08 A
2 ) 0 .4 A
3) 5 A
4) 10 A
Page 12
53.
A convex lens forms a real image of a point object placed on its principal axis. If the
upper half of the lens is covered, then
1) The image will be shifted downward
2) The image will be shifted upward
3) The intensity of the image will increase
4) The intensity of the image will decrease
54.
The angular momentum of an electron in the hydrogen atom is h , where h is Planck's
55.
56.
5
7
.
58.
constant. The potential energy of this electron is

1)13.6 eV
2)6.8 eV
3)3.4 eV
4)27.2 eV
Speed of electromagnetic wave is the same
1) for all wave lengths
2) in all media
3) for all frequencies
4) for all intensities
A P type semi conductor is
1) Positively charged
2) Negatively charged
3) Un charged
4) None
The magnetic susceptibility is negative for
1) Paramagnetic materials only
2) Diamagnetic materials only
3) Ferromagnetic materials only
4) Para and Ferromagnetic materials
A TV tower has a height of 100m. If the radius of earth is 6.37106 m and average
3
population density around the tower is 10 per m2 then the total population covered
by the TV broad coast will be nearly
1) 10106
2) 20106

Narayana IIT
Academy
1
1
59.
0
0
3) 30106
1
B
0
1
4) 40105
Page 13
1
1
Y1
The above table is truth table for
1) OR gate
2) AND gate
3) NAND gate
4) NOR gate
Which part of the electromagnetic spectrum has the largest
Penetrating power?
1) Micro waves
2) Radio waves
3) Ultra violet rays
4) rays
60.
CHEMISTRY
61.
Arrange the following compounds in order of their increasing boiling points

(I) Ethanol
(II) Propan - 1 - ol (III)
Butan - 1 - ol
(IV) Pentan- 1 - ol
1) IV < III < II < I
2 ) II III IV I
3) I < II < III < IV
4 ) III II IV I
Select the appropriate reaction to prepare the following ether
62.
CH 3
CH3 C OC2H5
CH3
1)
CH 3
CH3 C Br C2H5 O
2)
CH3
CH3 C O C2H5 Br
CH3
CH3
3)
CH3 CH CH2 Br C2H5 O
4) Both (1) and (2)
CH3
Page 14
63.
1
)
Choose the correct reaction given below

O
CH3 CH2 CH2 CH2 OH CH3 CH2 CH2 C H CrO3H2SO4
O
C
COCH3
2)
OH
)MnSOKd
(i)K (ii
O4 ( il)4 / OH
H2
CH3
CH3
3
)
enaO4
KM
Ht
CH2 OH
4
)
CO O H
C OOH
CH2 NC
CH2 Br
H
B
KC
64.
65.
6
6
.
Which of the following is incorrect?

1) Monomers of Bakelite are phenol and formaldehyde
2) Monomers of Melamine polymer are Melamine and Formaldehyde
3) Monomers of Buna - N are 1, 3-Butadiene & Acrylonitrile
4) Monomer of neoprene is isoprene
Which of the following compounds will show Cis-trans isomerism.
1)CH32 C CH C2H5
2) CH2 CHBr
4) CH3CH CC
l 2
3) C6H5 CH CH CH3
When HCl reacts with finely powdered iron, it forms ferrous chloride and not ferric
chloride. Why?
1) Liberation of hydrogen prevents the formation of ferric chloride.
2) FeCl2 acts as reducing agent
3) FeCl3 acts as reducing agent
) HCl is strong acid
Page 15
67.
68.
69.
70.
71.
72.
73.
What is the magnetic moment of a divalent ion in aqueous solution if its atomic
number is 25.
1) 4.8BM
2) 3.9BM
3) 5.9BM
4) 1.7BM
What would be the IUPAC name and symbol for the element with atomic number
120?
1) unbinilium,ubn
2) unnilbium, unb
3) unbibium, ubb
4) unnilnilium , unn
Time required to decompose SO2Cl2 to half of its initial amount is
36 minutes. If the decomposition is a first order reaction, the rate constant of the
reaction is
1) 1.925104 /moles /Sec
2) 1.925102 / min
3) 1.925104 / min
4) 1.925102mole / sec
If 1010 wheat grains are distributed in each second. The time required to distribute
one Avogardro's number of wheat grains is
1) 1010 sec
2) 6.02 1023 sec
3) 6.02 1033 sec
4) 6.02 1013 sec
Identify incorrect statement
1) PCl3 hydrolyses in the presence of moisture giving fumes of PCl3
2) Pt does not react with oxygen directly
3) Boric acid is polymeric due to the presence of hydrogen bonds
4) In electrolytic refining of copper Impure copper and Pure copper are anode and
cathode respectively
Hydrolysis of sucrose gives
Sucrose + H2O Glucose + Fructose
Equilibrium constant KC of the reaction is 2 1013 at 300 K. ThenG 0 of the
reaction at 300 K is
1)7.64 104J /mole
2) 7.54103J /mole
3)7.64 104k.J /mole
4) Data insufficient
The ionization constant of HCN at 298 K is 4.8 109 . The ionization constant of its
conjugate base is
1) 4.8 109
2) 2.08 105
3) 2.08 106
4) 6
Page 16
74.
7
5
.
Vapour pressure of chloroform and dichloromethane at 298K are 200 mm Hg and 415
mm Hg respectively. Calculate the vapour pressure of the solution prepared by mixing
25.5 gm of CHCl3 and 40 gm of CH2Cl2 at 298K
1) 367 mm Hg
2) 348 mm Hg
3) 567 mm Hg
4) 448 mm Hg
Statement-I:Vmix andSmix for an ideal solution is zero
Statement-II: A ----B Interaction in an ideal solution are same as between A---A and
B---B.
1) Both true and Statement - II is correct explanation of Statement - I
2) Both true and Statement - II is not correct explanation of Statement - I
3) Statement - I is false and Statement - II is true 4)
Statement - I is true and Statement - II is false
A compound is formed by two elements M and N. The element N forms CCP and
atoms of M occupy 1 rd of tetrahedral voids. The formula of the compound is
3
76.
2) M2N3
1 ) M 3N 2
4) M 4N3
77.
3 ) M 3N 3
A photon of wavelength 410 m strikes on metal surface, the work function of the 7
metal being 2.13 ev. Then kinetic energy of emitted electron is
1) 3.093 ev
2) 0.56 ev
3) 2.97 ev
4) 0.97 ev
7
8
.
At low pressure Vander Waal's equation is written as p v 2v RT . The
compressibility factor is
then equal to
1
)
R
T
V
2
) 1
1 a
1
RTV
RTV
3)
4)
RTV
Page 17
79.
80.
81.
Identify the correct statements

i) Dielectric constant: H2O D2O
ii) Dihedral angle: H2O2s H2O2g
iii) KO2 is paramagnetic & K2O2 is diamagnetic
1) i & ii only
2) ii & iii only
3) i & iii only
4) All
Which of the following exhibit geometrical and optical Isomerism?
1)CoNH34
2)Coen2
Cl2Cl
Cl2 Cl
3)Coen3
4)CoNH33
Cl3
Cl3
XeF6 on hydrolysis gives

1) XeO3, XeOF4 , XeO2F2 and HF
3) XeO3,O2 and HF
2) XeO3 and HF
4) XeO3,HOF and HF
8
2
.
CH3 CH CH CH2 CH2 CN 1)Al2H)Hi .The product formed is

1) CH3 CH2 CH2 CH2 CH2 CN
2Ou 2
O
||
2) CH3 CH CH CH CH C H
2
O
||
3) CH3 CH CH CH CH C H
2
O
||
4) CH3 CH CH CH CH C OH
8
3
.
Choose the correct acidity order for the following compounds.
||
||
i) NO2 CH2 C OH
iii) CCl3COOH
1) i > ii > iii > iv
3) ii > iii > i > iv
ii) NC CH2 C OH
iv) CF3COOH
2) iv > iii > i > ii
4) iii > ii > i > iv

CH
84.
O
Page 18
03/04/
14_
CH
Sr.IIT ALL STREAMS & LT-IIT _Phase-II_JEE-Main_GTM-6
C OH
CH 2 O H
O
Select the suitable option for the above conversion.
2) LiAlH4
1) NaBH
4
+
+
3) H /Etheleneglycol, LiAlH , H O 4) Pd/C
4
85. In formation of glucosazone number of moles of phenylhydrazine used are

1) 2
2) 3
3) 4
4) 1
86. CH3 C CH A B the product 'B' is
e
hydrolysis
x
c
e
s
s
H
B
r
1) propanol
2) propanal
3) Acetone
4) propanoic acid
O
H
O
8
7
.
88.
8
9
.
22
Cs
major product formed is
Br
1) o-bromophenol
2) p-bromophenol
3) 2,4,6 trybromophenol
4) 2,4 dibromophenol
Which of the following is purine base
1) Guanine
2) Cytosine
3) Thymine
4) Uracil
Correct statements among the following
I) Freundlich adsorption isotherm curves always seem to approach saturation at low
pressures
II) Freundlich adsorption isotherm curves always seem to approach saturation at high
pressures
III) Freundlich isotherm is an approximation on the behavior of adsorption
IV) Freundlich isotherm holds good over a limited range of pressure
1) I, II only
2) II, III only
3) II, III, IV only 4) All
Page 19
90.
Predict the order of reactivity of following compounds in SN1 path way

C
C6H5
CH3
H
3
1
)
C6H5 C Br > C6H5 C Br > C6H5 C Br >
C H CH Br
C
6
65
CH3
C H3
C6H5
2
)
C6H5 C Br > C6H5 C Br > C6H5 C Br >C
H CH Br
CH3
3
)
65
C6H5
C6H5
CH3
C6H5 CH2 Br > C6H5 C Br > C6H5 C Br > C H C Br

H
4
)
CH3
C6H5 C Br > C H5 C Br > C H C Br

6
C
6
H
5
CH3
> C6H5 CH2 Br
Page 20

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NARAYANA IIT ACADEMY

If each of the roots of the equation x2a1x a2 a 8 0 is greater than 1, then

If a variable 'X' takes values 1, 2, 3, 4, 5 with corresponding frequencies 1, 2, 3, 4, 5;

then the Mean Deviation of X, from mean X is equal to

Narayana IIT Academy