Constantes de Antoine

presin en mm Hg y T en C

xA

P B PvB
A PvA B PvB

yA

A PvA
xA
P

Sistema:
A
B
C

Agua(A)
8.07131
1730.63
233.426

1-butanol(B)
7.36366
1305.198
173.427

Ingrese la Presin,mm Hg =

l
^=_1_2/
+
_3
_

AGUA(1) 1-BUTANOL(2)

0.8608

__
3.2051

P B PvB
Ecuacion
xdeA Van
Laar :
P B PvB
ln _=_12 ((_21 _2)/A vA
(_12 _1+_21 _2)) ^2

A PvA
ln _=_21 y((_12
_1)/

x
A
A
(_12 _1+_21 _2)) ^2
P

xA supuesto

ngrese la Presin,mm Hg =
TsA=
TsB=

760
99.9968297
117.726852

T C

PsA

PsB

xAsupuesto

xA calculado

117.7268
117
116
115
114
113
112

1389.586796
1357.2626403
1313.8031489
1271.4976845
1230.322652
1190.2547657
1151.2710495

759.998596
740.618175
714.60641
689.337301
664.795173
640.964538
617.830094

0
0.0076564
0.01789903
0.02792025
0.03774665
0.04754858
0.05727539

2.3650519787
2.4181901969
2.487317609
2.5525747392
2.6140800113
2.6727989376
2.7283014251

1
0.9999151445
0.9995517101
0.9989461548
0.9981401879
0.9971540898
0.9960222965

5.5568E-007
0.007650672
0.017902045
0.027919302
0.037781519
0.047541875
0.057263641

1113.3488353 595.376727

0.06699127

2.7808386274

0.9947656572 0.066994492

1076.4657626
1040.5997773
1005.7291312
971.83238023
938.8883843
906.87630555
875.77560745
845.56605361
816.22770651
787.74092624
760.08636916
759.99973475

0.0767709
0.0866426
0.0966677
0.1068686
0.1172968
0.1279734
0.1390314
0.1504974
0.1623814
0.1748346
0.18795447
0.18799039

2.8306517899
2.8776847145
2.9219922723
2.9633986592
3.0018026672
3.0369354931
3.0688005295
3.096944024
3.1208406609
3.140145304
3.154199147
3.1542288653

0.9933999188
0.991945629
0.9904187466
0.9888424131
0.9872379571
0.9856351878
0.9840531923
0.9825357787
0.9811384732
0.9799148843
0.9789488834
0.9789467483

111
110
109
108
107
106
105
104
103
102
101
100
99.99682

573.589512
552.453711
531.954777
512.07835
492.810263
474.136538
456.043388
438.517215
421.544613
405.11237
389.20746
389.15771

0.076775738
0.086652254
0.09666423
0.106858473
0.117280514
0.127984279
0.13901541
0.150443075
0.16234833
0.174812884
0.187947072
0.187990389

DIAGRAMA P-x,y a Temperatura constante

Ingrese laTemperatura, C

=
PsA=
PsB=

60
149.03841921 mmHg
59.183256482 mmHg

puro
puro

xA supuesto

Pka

PsA

PsB

gA

gB

xA calculado

0
0.01
0.02
0.03
0.04
0.05

59.183256482
62.101276896
64.989116377
67.84645
70.672952454
73.4682918

149.038419
149.038419
149.038419
149.038419
149.038419
149.038419

59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482

2.3650519787
2.3540764795
2.3430203002
2.3318827995
2.3206633375
2.309361277

1
1.0000234609
1.0000952453
1.0002175325
1.0003926085
1.0006228724

0
0.01
0.02
0.03
0.04
0.05

0.06
0.07
0.08
0.09
0.1
0.11
0.12
0.13
0.14
0.15
0.16
0.17
0.18
0.19
0.2
0.21
0.22
0.23
0.24
0.25
0.26
0.27
0.28
0.29
0.3
0.31
0.32
0.33
0.34
0.35
0.36
0.37
0.38
0.39
0.4
0.41
0.42
0.43
0.44
0.45
0.46
0.47
0.48
0.49
0.5
0.51
0.52
0.53
0.54
0.55
0.56
0.57
0.58
0.59

76.232135825
78.964148959
81.663992978
84.33132709
86.965808024
89.567090132
92.134825501
94.668664076
97.168253797
99.633240744
102.0632693
104.45798234
106.8170214
109.14002692
111.42663843
113.67649484
115.88923471
118.06449652
120.20191899
122.30114144
124.36180418
126.38354887
128.36601902
130.30886041
132.21172163
134.07425464
135.89611538
137.67696438
139.41646753
141.11429678
142.77013099
144.38365684
145.95456974
147.48257493
148.96738857
150.40873896
151.80636787
153.16003199
154.4695044
155.73457634
156.95505894
158.13078525
159.26161231
160.34742353
161.38813113
162.38367892
163.33404519
164.23924601
165.09933862
165.91442532
166.68465752
167.41024027
168.09143715
168.72857554

149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419

59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482

2.2979759836
2.2865068267
2.2749531794
2.2633144201
2.2515899325
2.2397791068
2.2278813403
2.2158960381
2.2038226146
2.1916604938
2.1794091108
2.1670679128
2.1546363602
2.1421139278
2.1295001065
2.1167944043
2.1039963481
2.091105485
2.0781213845
2.0650436399
2.0518718705
2.0386057236
2.0252448766
2.0117890395
1.9982379575
1.9845914134
1.9708492307
1.9570112767
1.9430774654
1.9290477614
1.9149221832
1.9007008075
1.8863837735
1.8719712869
1.8574636253
1.8428611433
1.8281642777
1.8133735538
1.7984895919
1.7835131137
1.7684449501
1.7532860488
1.738037483
1.7227004607
1.707276334
1.6917666107
1.6761729646
1.660497249
1.6447415096
1.6289079989
1.6129991926
1.597017806
1.580966813
1.5648494667

1.000910843
1.0012591658
1.0016706209
1.0021481311
1.0026947705
1.003313774
1.0040085473
1.0047826782
1.0056399477
1.0065843427
1.00762007
1.0087515702
1.0099835341
1.0113209193
1.0127689687
1.0143332306
1.0160195801
1.0178342423
1.0197838183
1.0218753121
1.024116161
1.0265142683
1.0290780387
1.0318164172
1.0347389317
1.0378557393
1.0411776771
1.0447163182
1.0484840327
1.0524940552
1.0567605587
1.0612987363
1.0661248917
1.0712565382
1.0767125099
1.0825130837
1.0886801149
1.0952371894
1.1022097913
1.1096254916
1.1175141587
1.125908194
1.1348427965
1.1443562609
1.1544903127
1.1652904875
1.1768065594
1.1890930282
1.2022096717
1.2162221766
1.2312028583
1.2472314859
1.2643962291
1.2827947488

0.06
0.07
0.08
0.09
0.1
0.11
0.12
0.13
0.14
0.15
0.16
0.17
0.18
0.19
0.2
0.21
0.22
0.23
0.24
0.25
0.26
0.27
0.28
0.29
0.3
0.31
0.32
0.33
0.34
0.35
0.36
0.37
0.38
0.39
0.4
0.41
0.42
0.43
0.44
0.45
0.46
0.47
0.48
0.49
0.5
0.51
0.52
0.53
0.54
0.55
0.56
0.57
0.58
0.59

0.6
0.61
0.62
0.63
0.64
0.65
0.66
0.67
0.68
0.69
0.7
0.71
0.72
0.73
0.74
0.75
0.76
0.77
0.78
0.79
0.8
0.81
0.82
0.83
0.84
0.85
0.86
0.87
0.88
0.89
0.9
0.91
0.92
0.93
0.94
0.95
0.96
0.97
0.98
0.99
1

169.32205247
169.87234083
170.3799963
170.8456647
171.27009011
171.65412361
171.9987327
172.30501154
172.57419191
172.80765485
173.00694315
173.17377433
173.31005413
173.41789021
173.49960558
173.55775111
173.59511634
173.61473682
173.61989625
173.61412013
173.60115644
173.58493708
173.56951011
173.55892924
173.55707947
173.56740845
173.59251759
173.63354385
173.68922701
173.75450122
173.81836005
173.8606011
173.84682242
173.7206557
173.39156934
172.71545523
171.46325552
169.26938489
165.54529876
159.33153975
149.03841921

149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419
149.038419

59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482
59.183256482

1.5486693206
1.5324302537
1.5161364964
1.4997926594
1.4834037658
1.4669752859
1.4505131755
1.4340239191
1.4175145762
1.4009928342
1.3844670666
1.3679463975
1.3514407745
1.3349610502
1.3185190737
1.302127794
1.2858013773
1.2695553398
1.2534067
1.2373741518
1.2214782645
1.2057417128
1.1901895442
1.1748494893
1.1597523248
1.1449323009
1.1304276446
1.1162811585
1.1025409345
1.0892612118
1.0765034117
1.0643373971
1.052843012
1.0421119795
1.0322502569
1.0233809816
1.0156481874
1.0092215305
1.0043023597
1.0011315865
1

1.302535457
1.3237389746
1.3465398265
1.3710884158
1.3975533325
1.426124062
1.4570141743
1.4904650918
1.52675056
1.5661819714
1.6091147344
1.6559559226
1.7071735072
1.7633075513
1.8249838522
1.8929306533
1.9679992306
2.0511893972
2.1436812932
2.2468752636
2.3624422173
2.4923876741
2.6391338277
2.8056255261
2.9954682808
3.2131095792
3.4640793212
3.7553118407
4.0955817718
4.4961006714
4.9713435377
5.5402085669
6.22766696
7.0671445934
8.1040149211
9.4008093885
11.0451336923
13.1619358714
15.9329314592
19.6280874835
24.6579656897

0.6
0.61
0.62
0.63
0.64
0.65
0.66
0.67
0.68
0.69
0.7
0.71
0.72
0.73
0.74
0.75
0.76
0.77
0.78
0.79
0.8
0.81
0.82
0.83
0.84
0.85
0.86
0.87
0.88
0.89
0.9
0.91
0.92
0.93
0.94
0.95
0.96
0.97
0.98
0.99
1

yA
0
0.03306476
0.076962195
0.1192339
0.159735968
0.199035332
0.236714246

xA

experimental
yA

0
2.229864E-006
0.031431118
0.0757574051
0.1213801232
0.1683469512
0.2167077729

0
4.077092E-006
0.0561319502
0.1309609439
0.2030717706
0.2725277203
0.3393913941

diagonal
-0.0027614
0.02958791
0.08987944
0.15261718
0.19343394
0.23716752
0.29356652

0.272905109 0.2665147931 0.4037246916 0.37885976

0.307800775 0.3178226589 0.4655887989 0.40951196
0.341385305 0.3706885893 0.5250441776 0.45863735
0.373790179 0.4251725114 0.5821505535 0.51417716
0.40496545 0.4813372046 0.636966906 0.56897649
0.434979387 0.5392484539 0.6895514585 0.60315442
0.46375621 0.598975211 0.7399616686 0.65394499
0.491655395 0.6605897662 0.7882542193 0.74484786
0.51855676 0.724167929 0.8344850104 0.75392221
0.544258998 0.7897892209 0.8787091509 0.79355405
0.569045438 0.8575370785 0.9209809511 0.80913181
0.592913202 0.9274990699 0.9613539163 0.81921273
0.592964508 0.999767123 0.9998807402 0.85948242

0.1

0.2

Diagrama a T constan

yA
0
0.056496075
0.107464161
0.153673533
0.195756924
0.234239524

900
890
880
870
860
850

900
890
0.269560891
0.302091718
0.332146801
0.359995192
0.385868207
0.409965815
0.432461769
0.453507757
0.473236799
0.491766021
0.509198956
0.52562746
0.541133302
0.555789509
0.569661499
0.582808041
0.595282072
0.607131398
0.618399297
0.629125035
0.639344314
0.649089663
0.658390774
0.667274801
0.675766617
0.683889044
0.691663047
0.699107919
0.706241434
0.713079981
0.719638697
0.725931567
0.731971526
0.737770548
0.743339721
0.748689315
0.753828851
0.75876715
0.763512388
0.768072137
0.772453409
0.776662691
0.780705975
0.784588791
0.788316229
0.791892964
0.795323276
0.798611065
0.80175987
0.804772882
0.807652953
0.810402608
0.813024049
0.815519168

880
870
860
850
840
830
820
810
800
790
780

comp
liquid
comp
teri

770
760
750
740
730
720
710
700
690
680
670
660
650
640
630
620
0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

Diagrama Composic
1
0.9
0.8
0.7

Diagrama Composic
1
0.817889545
0.820136455
0.822260869
0.824263456
0.826144585
0.82790432
0.829542425
0.831058363
0.832451295
0.833720084
0.834863304
0.835879245
0.836765936
0.837521167
0.838142533
0.838627489
0.838973438
0.839177847
0.839238421
0.839153331
0.838921553
0.83854332
0.838020767
0.837358818
0.836566443
0.835658414
0.834657797
0.833599515
0.832535475
0.831542052
0.830731173
0.830266993
0.830391557
0.831465268
0.834032763
0.838934358
0.847503892
0.861942035
0.886077977
0.927092016
1

0.9
0.8
0.7
0.6
Y

0.5
0.4
0.3
0.2
0.1
0
0

0.1

0.2

0.3

0.4

0.5
X

0.6

compuestoexpeliquido

Diagrama a PCOMPONENTEDEVAPOR
cte
COMPONENTEEXPERIMENTAL
LIQUIDO

0.1

0.2

0.3

T constante

0.4

x, y

0.5

0.6

0.7

0.8

0.9

composicin
liquidaterica
composicinvapor
terica

0.8

0.9

a Composicin

a Composicin

0.5
X

0.6

0.7

0.8

0.9

0.9