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.

S1 S2 . C = 5,0.10-2 mol.L-1
: S1 pH =1,3
: S2 ) (Vitamine C pH = 2,7
(1 AH .
(2 CAH V= 100ml

(3 :
( 1.3 .
(2.3 .
(4 :
(1.4 .
(2.4 .
(5 4 : .
(1.5
(2.5 S2 .
: : / HBr/Br - ; C6H8O6/ C6H7O6- :

(1

(2

+ H 3O + aq

aq

AH + H 2O A

H 3 O+

A-

H2O



AH



CAH.V

x=0

   




CAH.V- X

 
)(mol

Xmax

Xmax



CAH.V- Xmax

x = x max

 
 )(mol

Xf

Xf



CAH.V- Xf

x=xf

 

 )(mol

 (3 :
(1.3 Xmax=X f
Xmax CAH.V- Xmax= 0 Xmax = CAH.V = 5.10-2. 0,1 = 5.10-3 mol :

Xf pH = 1,3 : H3O+
. [H 3O + ] f = 10-pH =10-1,3=5,0.10-2 mol.L-1

n f ( H 3O + ) = H 3O + .V = 5,0.10 2.0,1 = 5,0.10 3 mol

Xmax =X f = 1 = 100 0 0
+

HBr + H 2 O
H 3 Oaq + Br aq

(2.3 :
(4 :

+ H 3 O+

C6H7O6-

C6H8O6

+ H2 O





CAH.V

x=0

   




CAH.V- X

 
)(mol

Xmax

Xmax



CAH.V- Xmax

x = x max

 
 )(mol

Xf

Xf



CAH.V- Xf

x=xf

 

 )(mol

(1.4
- : Xf

= 10 pH = 10 2,7 = 2.10 3 mol.L1

] [H O
+

X f = n f = H 3O + f .V = 2.10 3.0,1 = 2.10 4 mol

Xmax = CAH.V = 5.10-2. 0,1 = 5.10-3 mol ::

4

2.10
= 4.10 2 = 4 0 0 :
3
5.10

Xf

X max

(2.4 1
(5
(1.5
.
(2.5 : (1.4
= 10 pH = 102,7 = 2.103 mol.L1

[C 6 H 8O6 ] f

] [H O ] = [C H O

= 5 . 10 2 2 . 10 3 = 4 ,8 . 10 2 mol

H3O ) C6H7O6 ( Xf

 
] [C 6 H 8 O 6 ]0 = [C 6 H 8 O 6
 ] + [C 6 H 8 O 6
 ] [C 6 H 8 O 6
 
] = [C 6 H 8 O 6 ]0 [C 6 H 8 O 6
L 1