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C A .VA = CB .VB
-./ (5
0
%
% ( 1
"2
0 & 34 1
1 5(
CV
0,1 25
CB = A A =
= 5.102 mol.l 1
VB
50
Xr
X r = C A .VA X f
:#$
X f = C AVA X r
3
X f = 2,5.10 7, 5.10
2, 5.10 mol
Xf
Xm
=1
^,,C
CH
X=0
CB.VB
!
Xf
#$
NH
CB.VB - X
CB.VB - Xf
Xm=
+ H 3O
CH
NH
+
3
+ H
ni =CA.Vi A
ni(H3O+) - X
ni(H3O+) Xf
Xf
Xm
CB.VB - Xm ni(H3O ) Xm
CA.VA,E
X m=
#$(Q-6?"-,'
M,9)
_.,I7'`3Z ->SZG46 VA = 10 ml &"/<
Y2U
7,'(6
Xm = CAVA = 10-1.10.10-3mol = 10-3mol =1mmol
:
'&7"
#*
$a/`3Z&5'6(7
pH = pK A + log
[CH 3 NH 2 ]
CH 3 NH 3+
[CH 3 NH 2 ] 10 pH pK A = [CH 3 NH 2 ]
pH pK A = log
CH 3 NH 3+
CH 3 NH 3+
CBVB X q
[CH 3 NH 2 ]
CH 3 NH 3
+
10 pH pK A =
CBVB X q
(VA + VB )
=
X q
X q
(VA + VB )
: b,'
$D65'$
\$
CBVB X q
X q
`3Z10ml ae9
pH&3
79VA &'d
6pHBQc,'3 Xq&3^,,C
X
S'CBVB $pKA$pH:&765''&fg9pH 10,2 :
79
10,2 10,7
10
2, 5.103 X q
X q
X q (1 + 100,5 ) = 2, 5.103
www.pc1.sup.fr
X q 2.10 mol
(5f?5'&6Mh$f#65=iVA =10ml &"/<
X f &T4'&37'(8
= 1 Xf = Xm
:
'(9
:#$ 10
pH pK A
[CH 3 NH 2 ]
CH 3 NH 3+
:DCj
' K =
1
CH 3 NH 3+
q
[CH 3 NH 2 ]q H 3 O + q
pK
10,7
10
D"I$P:.,'
"! MQ:K k$ K = 10 pH pK . H O + = 10 pH pK .10 pH = 10 = 10 5.10
3 q
8?5'&S,9
A
( ##$ ) #$ #' ( #+- . /
#'
HA(aq)
HO- (aq)
A- (aq)
(I
H2O(11
(21
+
[H3O ] = 10
-pH
= 10-4 mol/l
pH = 4 (121
Ke
HO =
= 1010 mol.l 1 :
'(221
H 3 O +
(321
HA(aq)
CAVA
HO- (aq)
CBVB
*
A- (aq)
0
H2O
CAVA - X
CBVB - X
!
CAVA - Xf
CBVB - Xf
Xf
Xf = CB.VB = 1,44.10 mol : CBVB - Xf=0 ;<:
7'I
3l'.,
-4
PT4'U
7,'&59E5=(412
HO
n0 ( HO ) n f ( HO ) 2,88.102.10.103 1, 72.1012
reagit
=
=
=
1
n0 ( HO )
2,88.102.10.103
HO
0
pH = pKA + Log
[ AH ]
:Y.'$
\AHn:
*$A-n:
*(
'
Xf
A
Xf
VA + VB
1, 44.104
=
=
=
=1
[ AH ] C AVA X f C AVA X f 2,88.102.10.103 1, 44.104
VA + VB
A
= 0 pH = pK A = 4
log
[ AH ]
K b,'&,6o(13
A
eq
K=
[ AH ]eq HO
eq
A . H 3O +
eq
eq
=
[ AH ]eq . HO . H 3O +
eq
eq
A
K
1
eq
=
.
= A = 1010
+
+
Ke
HO . H 3O [ AH ]eq . H 3 O
eq
eq
eq
(
pH ) pH
6( II
.*&'(&7"&C,'B+5=(
pp$
q).,J.,`
m
?"-,'D7 ,(12
.
: ,7
@'(22
C3&7
L
s"?@
-,'>S=D":D,r& 7
L
dpH/dV :&''
3
&
76a/`3ZPI
2 pH>7 (32
&,6o(&3:7*36PT
'n:t'Qc*
@7J"&/<(42
se@
7J&3:&
6
,'P(d.
fJPuQcd#
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www.pc1.sup.fr