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ELGHZIZALS SCRIBD DOCUMENTS

@ @b@@@ b@- @pbnbi@a@pzna@Zbna@y


 
 .
"! #$pH0>7 ( )VA = 0
  (  1
 : (('&2
CH 3 NH 2 + H 3 O +  CH 3 NH 3+ + H 2 O

      )


           
: (   # 71 "  !
  % &  # # % 
( !     '  ( & ) :  % % 
,&  90  88 " *&+     % :  %  % 
: (% 
 (&./
  0  1' 23456 ('&+,-*)
 (76 89:=
<;$>456+,-*)
(pHE = 6 ; 25ml )
ABC3D @6:?"-,'@&79(3
:?"-,'( 
4
 :m E5=CB*
 
m
n M
CB = =
m = CB .V .M
V
V
V = 0, 5l
M = 12 + 14 + 5(1) = 31g .mol
m = 0, 775 g

 
C A .VA = CB .VB

-./ (5
 0
%
 %  ( 1
"2  0 & 34 1
  1 5(
CV
0,1 25
CB = A A =
= 5.102 mol.l 1
VB
50

   6 7 8


    + 
  #M,,C-NI$ pH0&" +FG'  3'&C0(IJK2 .*&L&C0(
  pH = pK e + log CB  : !":
7'O-.* :<;$ pH 11, 6 #67VA = 0
11, 6 14 + log 5.102 = 12, 7 :D7 ,'

.P:QRJK2 .* !"P','6$

.   6 7 8


    +  :?5' +S'
PT4'U
7,'&59E5=+@,?5'GI &6MV'
pH@9YZ-N['$P7,H3O+ (&3:XrP35'Xf

W-XPT4'pH&3
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ELGHZIZALS SCRIBD DOCUMENTS

  Xr

= H 3 O + VS = 10 pH .VS = 106 (25 + 50).103 = 7, 5.107 mol


f

X r = C A .VA X f

:#$

X f = C AVA X r
3

X f = 2,5.10 7, 5.10

2, 5.10 mol

Xm = CBVB = 5.10-2.50.10-3 = 2,5.10-3 mol   CB.VB - Xm=0 $


\xmE5=

 P:  <;.*

Xf
Xm

=1

^,,C






CH

 

X=0

CB.VB

  

 ! 

Xf

#$ 

NH

CB.VB - X
CB.VB - Xf

Xm=

+ H 3O

 CH

NH

+
3

+ H

ni =CA.Vi A



ni(H3O+) - X



ni(H3O+) Xf

Xf



Xm



CB.VB - Xm ni(H3O ) Xm

CA.VA,E

X m=

#$(Q-6?"-,'
M,9)
_ .,I7'`3Z ->SZG46 VA = 10 ml &"/<
 Y2U
7,'(6
Xm = CAVA = 10-1.10.10-3mol = 10-3mol =1mmol
 :
'&7" #*
$a/`3Z&5'6(7
pH = pK A + log

[CH 3 NH 2 ]

CH 3 NH 3+

[CH 3 NH 2 ] 10 pH pK A = [CH 3 NH 2 ]
pH pK A = log
CH 3 NH 3+
CH 3 NH 3+


CBVB X q

[CH 3 NH 2 ]
CH 3 NH 3
+



10 pH pK A =

CBVB X q
(VA + VB )
=
X q
X q
(VA + VB )

: b,' 
$D65'$
\$

CBVB X q
X q

 `3Z10ml ae9
 pH&3 79VA &'d
6pHBQc,'3 Xq&3^,,C

  X 
S'CBVB $pKA$pH:&765''&fg9pH 10,2 :  79
10,2 10,7

10

2, 5.103 X q
X q

X q (1 + 100,5 ) = 2, 5.103

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X q 2.10 mol



ELGHZIZALS SCRIBD DOCUMENTS


 (5f?5'& 6Mh$f#65=iVA =10ml &"/<
 X f &T4'&37'(8

= 1 Xf = Xm
 :
'(9
:#$ 10

pH pK A

[CH 3 NH 2 ]
CH 3 NH 3+

:DCj
' K =
1

CH 3 NH 3+
q

[CH 3 NH 2 ]q H 3 O + q

pK
10,7
10
D"I$P: .,'
"! M Q:K k$ K = 10 pH pK . H O + = 10 pH pK .10 pH = 10 = 10 5.10
3 q
 8?5'&S,9
A



 
( ##$ )  #$ #' ( #+- . /  #'
 
 HA(aq)

HO- (aq)

A- (aq)

(I

H2O(11

 (21
+

  [H3O ] = 10

-pH

= 10-4 mol/l

pH = 4 (121

Ke
HO =
= 1010 mol.l 1 :
'(221
H 3 O +

nf(HO-) = [HO-]. (VA + VB) = 1,72.10-12 mol :




(321



 



HA(aq)
CAVA

HO- (aq)
CBVB


*

A- (aq)
0

H2O


  

CAVA - X

CBVB - X



 ! 

CAVA - Xf

CBVB - Xf

Xf




 Xf = CB.VB = 1,44.10 mol :  CBVB - Xf=0  ;<:
7'I
3l' .,
-4

  PT4'U
7,'&59E5=(412
HO
n0 ( HO ) n f ( HO ) 2,88.102.10.103 1, 72.1012
reagit

=
=
=
1

n0 ( HO )
2,88.102.10.103
HO
0

 O60-C2`m  .,'GI(3, P','6$P: .,'0, -N


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ELGHZIZALS SCRIBD DOCUMENTS


 

pKA &3D7 ,'(512


A

pH = pKA + Log

[ AH ]


 :Y.'$
\AHn: *$A-n: *(
'
Xf

A
Xf
VA + VB
1, 44.104
=
=
=
=1
[ AH ] C AVA X f C AVA X f 2,88.102.10.103 1, 44.104
VA + VB

A
= 0 pH = pK A = 4
log
[ AH ]

K b,'&,6o(13
A
eq
K=
[ AH ]eq HO

eq

A . H 3O +
eq
eq
=
[ AH ]eq . HO . H 3O +
eq

eq

A
K
1
eq
=
.
= A = 1010

+
+
Ke
HO . H 3O [ AH ]eq . H 3 O
eq
eq
eq

 .&765'BM,,CdD"I$P: .,'0, -N


<;M Q: K


(
pH ) pH    6( II
 .*&'(&7"&C,'B+5=( pp$ q ).,J.,`
 
m ?"-,'D7 ,(12
 . 
 : ,7 @'(22
C3&7 L 
 s"?@ -,'>S=D":D,r& 7 L 
dpH/dV :&''
3

 &
76a/`3ZPI  2 pH>7 (32
 &,6o (&3:7*36PT
'n:t'Qc* @7J"&/<(42
 se@ 7J&3:&
6

,'P (d. fJPuQcd#



#' 78#+ (    III

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ELGHZIZALS SCRIBD DOCUMENTS


(13

?"-,'@&79 Lv*#"@9&7@G'$n -' mI+C au-'"! pH =8 k(23


VA >SZf (M`3Z&( 3: (33
n(AH) =CAVA = 2.10-2.14,4 = 2,88.10-1 mmol
. " ! # (  43
0,288mmol " 10ml '(" *) # -.- ' / /1 2* -
.  '( 9! 100ml "#  ! 5 ) 8
: "''5 n = 10(0,288mmol) "" !  #  ' / :
;
m(AH)= n.M(AH) = 2,88.10-3.176=507.10-3g 500mg
5 &' KY 0u<I$

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