1    

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 .

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 .


    4

 .

  (1   . S

    V0       :
   :  S
CS = C0/100
V = 1,00 L
  
    nS :

   :  &% ) S0% .
C0 = 1,1 mol.L-1
? V0
= nS :
C0
V0 = V /100
= C0.V0 = CS.V
.V
V0 = 10,0 mL
100
! 2 1  / -.* *) ('&  $ 10,0mL 34!   -.
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(2$=  
: S
(12
    
 
  Ca = 0,015 mol.L1 :

pH&

1 & ./
  S

2,45

pH


*+,%-

(22$ $= :

) H2O( l

NH4+(aq) +

)NH3(aq) + H3O+(aq

(32A A =@
(132
dpH
-&= B: C 34 HG  A VaE D.E I. BA : C
dVa
mL
-&= B=L : J ' ): =Q OEPVaE = 14 mL : A4 ( N

=) f(Va Va E = 14 :

! =L BA -EU(  CDT &=

 X : V 1E A 2*( VaE 34 =J 1 12=N$ 1& 2 $NL 1 34. . OEP

5    



 .

CS :
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232


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nacide verse = n NH3initiale

Ca. VaE = CS.VS

Ca.Va E
VS
C0 = 100.CS
CS =

0,015 14
= 1,05102 = 1,1
102 mol.L-1
20
C0 = 1001,05102 = 1,1 mol.L-1
CS =

.

3
4-5
2
1
C0
-.
/0
,



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pH E 6
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pH = f(Va )
CD
EF-
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4

.
7G%

0(
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I


7N%
J(K
('
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S
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O
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(13


NH3(aq) + H2O( l )
NH4+(aq) + HO(aq)

(2)



K
:
'P
(I
T
(113

HO(aq ) . NH 4(+ aq )
q
q
K=


NH 3( aq ) q

(2 )
$

/
(3 )
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I
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$(I
Ke
U
K
I7*
1
&
I
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(213

(3)NH4 (aq) + H2O( l ) = NH3(aq) + H3O

NH 3( aq ) q . H 3O(+aq )
q
KA2 =
+
NH 4( aq )
q

6    



 .

HO(aq ) . NH 4(+ aq ) H 3O(+aq )

q
q
q
.
K=
+
NH 3( aq ) q
H 3O( aq )

K=

Ke
K A2

K=

10 pKe
=
10 pKA2

10(pKA2 pKe )

K = 109,2 14 = 1,6105
S
J(K
W7*
(23
(123


NH3(aq) +

H2O( l ) = NH4 (aq) + HO (aq)



( mol)

(  mol)

!"

CS.US

#$%

>
X

xq

CS.US xq

S7(I

xq

xq

:
4M7-

3
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K
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K=

HO

. NH
q
NH 3( aq ) q

( aq )

+
4( aq )

xq xq
.
xq2
US US
=
=


C S .U S xq (C S .U S xq ).U S
US


CS.US
[
%

xqJ
-2ZI

2
q

: '\!

CS .US2

CS.US
CS.US xq


:
]H0
.I
H
&
4
(1323

xq K.CS.US

1, 6 105 1,1102 1, 0 = 4,2104 mol

xq =

CS.US
_
[
`<%

^CDN xq
'P[

(.
!'
:
Q
Y

4
.B

xq << CS.US: )' CS.US = 1,1102 mol : '

:
N
(a
.I
 Q(
33



= 8,52.10 -3 S.m-1

:

M
(133



:
J(c
N(

?M7*
WHb

M

= (HO (aq)).[HO (aq)]q + (NH4 (aq)). [NH4+(aq)]q

[HO(aq)]q = [NH4+(aq)]q

:

(2)
$

4




:
'\!

= ((HO (aq)) + (NH4 (aq))).[HO (aq)]q

[NH4+(aq)]q = [HO(aq)]q =

( HO( aq ) ) + ( NH 4+( aq ) )
[NH4+(aq)]q = [HO(aq)]q =

8,52 10 3
= 3,1310 1 mol.m-3 = 3,1310 4 mol.L-1
4
(199 + 73,4) 10

7    



 .

pH ,# .( 233
pH =log([H3O+(aq)]q) = log(

Ke
)
HO(aq )
q

14

1, 0 10
) = 10,495 10
3,13 104
%8 I $F 7"$ pH C E$ ()5=> 7?@ #A )9'' <; . /" #1 2!' 3$% 456 78 1'
11 10 .
pH = log(

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