*

!!

:
22 B C0 = 10,9 mol.L
) (S0
)NH3 (aq) + H2O (l) = HO (aq) + NH4+ (aq). (1
: 25 C
Ke = 1,00.1014

K1 = 1,6.105 :
.1
1.1 / )Dfinir la constante dacidit(1
1.2 AH/A-
1.3 )(1
.2 pH
) (S0 pH 50mL ) (S1 ) (S0 C1 =C0/10
pH) (S1 pH = 11,62
(12 V0 ) (S0 )(S1
(22 )(S1
-3
-1
(32 )[HO ](S1)= 4,17.10 mol.L (S1
(42 ) (1 ) (S1 V1 =1L . Xm
(52 [HO -](S1)/C1 = 1 : .
(62 Qr,1 )[HO -](S1 C1 . .
(72 NH4+/NH3 Qr,1 Ke .
.3
: 25 C :
(HO) = 19,9.103 S.m2.mol1
(NH4+) = 7,34.103 S.m2.mol1
= i [ Xi ]. ) (S2 ) (S1
C2 = C1/100 = C0/1000 ) .(S2 ) (S2 = 0,114 mS.cm1.
(13 .
(23 ) (S2 ).[HO](S2
(33 ) [HO -](S2 pH ). (S2
(43 2 .
(53 ) (
-1

:

. AH

. AH H2A+ / HA . HA / A
H2A+ AH A .

pKA2 ( HA / A) = 7,0 :

pKA1(H2A+ / HA) = 4,3

pKe = 14,0

.1 HA
(11 HA
(12 K .
.2. HA .
(21 .

 (22 K KA1 KeK

.3
(13 pH H2A+, HA et A . pH
(23 .

)NH4+(aq

HO(aq) +

)H2O(l

NH3(aq) +

= n1

= xf

= xmax