KINETIKA REAKSI

Reaksi pembentukkan Epichlorohydrin berdasarkan reaksi :

C3H6Cl2O + NaOH ------------------> C3H5Cl2 + NaCl + H2O
dari literatur diperoleh data sebagai berikut :
1.Waktu Reaksi =
1-3 jam
2.Suhu Operasi =
40oC
3.Konversi yang dicapai =

0.96

Neraca Massa

C3H6Cl2O + NaOH ------------------> H2O

A

Umpan masuk :
C3H6Cl2O (A) =
NaOH (B) =
H2O (C) =

Cao (T50)

BM

------------------>

+ C3H5ClO
+

+ NaCl

kmol/j
f.mol
kg/jam
f.massa
129
57.81200
0.08512
7457.72500 0.37547
40
55.48200
0.08169
2219.26400 0.11173
18
565.85100
0.83318 10185.31000 0.51280
679.14500
1.00000 19862.29900 1.00000

0.777213

Waktu reaksi ()

=
T
Konversi
XA
=

1 jam (pada suhu 50 oC)

85
358
0.95
k

= XA
Cao(1-XA)(M-XA)t

0.935
3,293221 x (1 - 0,935)(0,9596 - 0,935) x 1
2521.03258

Waktu reaksi ()

=
Cao
Konversi
T

3 jam (pada suhu 50oC)

0.773355
0.95
75
348

XA

0.95
k

XA
Cao(1-XA)(M-XA)t

= 844.5368384

maka :
T1
=
T2
=

0.935
3,293221 x (1-0,935)(0,9596 - 0,935) x 3

358 oK ------>
348 oK ------>

k1
k2

=
=

2521.03258
844.53683844

persamaan empiris Arhenius

k Ae ( E . RT )
atau

ln k ln A

B
T

ln

2521.03258

ln A

ln

844.5368384

ln A

1.093635494

1.093635494

ln

=
2521.03258 =

A
B

=
=

7.832423851 =
ln A
=
A
=
8.5149E+019
-13624.9484

8.5149E+019

/(3
+
58@)
/323
+

348
124584

-10 B
124584
-13624.948434

ln A

ln A
+
45.890939029
8.51494E+019

atau

XA
0

t
0

exp ( -13624.948434 /T)

XA

0.000065962
0.0001679504
0.0003315586
0.0006079072
0.0011102221
0.0021283155
0.00458555
0.0127833556
0.0769434888
0.1038366471
0.1478503008
0.2283255844
0.4059374761
1
-40.4181687094
-1.6016444644
-1.2317321213
-1.6673636623
0

0.1
0.2
0.3
0.4
0.5
0.6
0.7
0.8
0.9
0.91
0.92
0.93
0.94
0.95
0.96
0.97
0.98
0.99

Rho
Vol
1351.00000 5.52015
1200.00000 1.84939
1000.00000 10.18531
17.55485

A
C3H6Cl2O
NaOH
H2O

B
0.4188
0.19975
0.3471

A
C3H6Cl2O
NaOH
H2O

Tc
0.24779
0.09793
0.274

B
0.4188
0.19975
0.3471

dens (kg/l )dens (kg/m3)

0.28571 0.352207 352.207142771
0.25382 0.119365 119.364801801
0.28571 0.294227 294.226944024

dens (kg/l )dens (kg/m3)

0.28571 0.349996 349.996179893
0.25382 0.119115 119.11543302
0.28571 0.29255 292.549992598

633
2820
647.13

Tc
0.24779
0.09793
0.274

633
2820
647.13

-13624.94843
358
-38.05851518

358
124584

volume
21.17426
18.59228
34.61719
74.38373

volume
21.30802
18.6312
34.81562
74.75484

Tinjauan Kinetik
k

XA
t x Cao x (1-XA) x (M-XA)

M
=
Cao =
k
=

0.959696949
0.777212977
19 exp(

Suhu
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87

40.78996673
46.46173394
52.87976602
60.13660231
68.33554507
77.59182676
88.03389446
99.80482232
113.0638636
127.9881552
144.7745878
163.6418576
184.8327139
208.6164214
235.2914555
265.1884496
298.6734178
336.1512751
378.0696807
424.9232314
477.2580345
535.6766912
600.8437232
673.4914812
754.4265706
844.5368384
944.7989653
1056.286709
1180.179853
1317.77391
1470.490647
1639.889484
1827.679842
2035.734502
2266.104066
2521.03258
2802.974427
3114.612564

-13624.95 /T)

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

Xa
k
0.816692 40.78997
0.825996 46.46173
0.83475 52.87977
0.842984 60.1366
0.850724 68.33555
0.857997 77.5918
0.948263 2092.412
0.948569 2162.399
0.948866 2234.282
0.949155 2308.101
0.949436 2383.893
0.949708 2461.697
0.949973 2541.554
0.95023 2623.502
0.95048 2707.583
0.950723 2793.837
0.950959 2882.305
0.951188 2973.03
0.95141 3066.052
0.951627 3161.416
1.036608 477.2579
0.952041 3359.339
0.952239 3461.986
0.952432 3567.148
0.952619 3674.871
0.952801 3785.199
0.947685 1949.09
0.94797 2006.929
0.948247 2066.14
0.948517 2126.746
0.948781 2188.772
0.949037 2252.241
0.949287 2317.176
0.949531 2383.598
0.949769 2451.542
0.95 2521.033
0.950226 2592.083
0.950445 2664.724

88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105

3458.878214
3838.972109
4258.387399
4720.934342
5230.766909
5792.411419
6410.797369
7091.29059
7839.728898
8662.460404
9566.384671
10558.99689
11648.43531
12843.53207
14153.86776
15589.82981
17162.67514
18884.59713

1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1

0.95066
0.950868
0.951072
0.95127
0.951463
0.951652
0.951835
0.952014
0.952189
0.952359
0.952525
0.952687
0.952844
0.952998
0.953148
0.953294
0.953436
0.953575

2738.982
2814.881
2892.448
2971.709
3052.689
3135.415
3219.914
3306.213
3394.337
3484.315
3576.174
3669.941
3765.644
3863.311
3962.969
4064.648
4168.375
4274.18

1
0.95
0.9
0.85

f(x) = - 0.0008098546x^2 + 0.103742

R = 0.8861282721

1
0.95

f(x) = - 0.0008098546x^2 + 0.103742

R = 0.8861282721

0.9
0.85
0.8
0.75
0.7
45

50

55

60

65

70

8098546x^2 + 0.103742599x - 2.3621828375

2721

Column D

8098546x^2 + 0.103742599x - 2.3621828375

2721

Column D
Polynomial (Column D)

60

65

70

75

Cao brbg suhu

T
T
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95

323
324
325
326
327
328
329
330
331
332
333
334
335
336
337
338
339
340
341
342
343
344
345
346
347
348
349
350
351
352
353
354
355
356
357
358
359
360
361
362
363
364
365
366
367
368

Cao
0.763783
0.764164
0.764545
0.764926
0.765307
0.765689
0.76607
0.766452
0.766834
0.767216
0.767599
0.767981
0.768364
0.768747
0.76913
0.769513
0.769896
0.77028
0.770664
0.771048
0.771432
0.771816
0.7722
0.772585
0.77297
0.773355
0.77374
0.774125
0.77451
0.774896
0.775282
0.775668
0.776054
0.77644
0.776826
0.777213
0.7776
0.777987
0.778374
0.778761
0.779149
0.779536
0.779924
0.780312
0.7807
0.781088

Umpan mas
BM
C3H6Cl2O (
NaOH (B) =
H2O (C) =

129
40
18

kmol/j
57.81200
55.48200
565.85100
679.14500

96
97
98
99
100
101
102
103
104
105

369
370
371
372
373
374
375
376
377
378

0.781477
0.781866
0.782254
0.782643
0.78303
0.783422
0.783811
0.784201
0.784591
0.784981

f.mol
kg/jam
0.08512
7457.72500
0.08169
2219.26400
0.83318 10185.31000
1.00000 19862.29900

50
A

C3H6Cl2O
NaOH
H2O
T

B
0.4188
0.19975
0.3471

Tc
0.24779
0.09793
0.274

633
2820
647.13

51

Cao

dens (kg/l )dens (kg/mvolume

0.28571 0.356671 356.6711 20.90925
0.25382 0.119865 119.8651 18.51468
0.28571 0.29761 297.6097 34.22371
73.64764

0.7849809929