BALANC DE MATERIA

problema de examen
F1=
1)
2)
3)
7)

10 gmol/h
6 gmol/h
1 gmol/h
2 gmol/h
1 gmol/h

CH4 + 2O2 -----> CO2 + 2H2O

H2 + 1/2 *O2 -------> H2O
CO + 1/2 *O2 ------> CO2
reaccion 1
CH4
6 gmol/h
O2
12 gmol/h
CO2
6 gmol/h
H2O
12 gmol/h
reaccion 3
CO
O2
CO2

2 gmol/h
1 gmol/h
2 gmol/h

1) CH4
2) H2
3)CO
4) O2
5) N2
6) CO2
7) H2O

reaccion 2
H2
O2
H2O

16.04303
2.01594
28.01055
31.9988
28.00134
44.0103
18.01534

gmol

1 gmol/h
0.5 gmol/h
1 gmol/h

CANTIDAD DE AIRE
O2 (1) =
O2 (2) =
O2 (3) =
O2 TOTAL =
O2 EXCEDENTE
O2 TOTAL

12 gmol/h
0.5 gmol/h
1 gmol/h
13.5 gmol/h
2.025 gmol/h
15.525 gmol/h

F2 (aire)
O2
N2

13.5 gmol/h
50.7857143 gmol/h

F2 total

64.2857143 gmol/h

21%
79%

F3 (gases de salida)
CO2
8 gmol/h
N2
50.7857143 gmol/h
O2
13.5 gmol/h
H2O
14 gmol/h
F3 TOTAL

72.2857143

F1 TOTAL
CH4
H2
CO
H20

MASICO
96.25818
2.01594
56.0211
18.01534

F2 TOTAL
O2
N2

F1
ENTRADAS
F3 TOTAL
CO2
N2
O2
H2O
SALIDAS

172.31056
2091.15998
MASICO
352.0824
1422.06805
64.79757
252.21476
2091.16278

F2

MASICO
496.78137
1422.06805

1918.84942

BALANCE DE ENERGIA
CON LOS PARAMETROS
Q=
0
W=
0
UTILIZANDO LA FORMULA
Q = m CP (Ts- Te)
donde
Q= 0
m = flujos
CP = calor especifico molar
Ts = temperatura de salida
Te = temperatura entrada

CH4
H2
CO
O2(g)
H2O(g)
H2O(l)
N2
CO2

ECUACION GENERAL
0 = Fn * CP * (Ts - Te)

0 =( 6 * 35.73 *(Ts - 298.15)) + (1*28.82*(Ts - Te))+(2*29.26*(Ts-Te))+(13.5

0= (214.38Ts - 63, 917.397 + 28.82Ts -8, 592.683 + 58.52Ts - 17, 447.738
0= -678.885Ts +202, 392. 6792
678.885 Ts = 202, 392. 6792
TS = 202, 392. 6792/678.885
TS = 298.125 C

0 = 357.3 TS - 106,528.995 + 288.2TS - 85, 926.83 + 292.6TS -87, 238.69

0 = - 8, 607.4196 Ts + 2, 566, 302.105
Ts = 298.14 K

CP (J/mol k)
35.73
28.82
29.26
29.35
33.58
75.29
29.12
37.11

s - Te))+(2*29.26*(Ts-Te))+(13.5*29.35*(Tf-Te))+(50.7857143*29.12*(Ts-Te))+(1*33.58*(Ts-Te))-(50.785*29.12*(Ts

2.683 + 58.52Ts - 17, 447.738 + 396.225TS - 118,134.4838 + 1,478.879Ts - 440, 927.948 + 33.58Ts - 10, 011.8
0 = -1, 732.945 Ts + 516, 660.6682
Ts = 516, 660.6682 / 1,734.945
Ts = 298.14 K

926.83 + 292.6TS -87, 238.69 + 58.7TS - 17, 501.405 +58.24Ts - 17,364.256 -2,178.4672 Ts + 649, 509.9957

3.58*(Ts-Te))-(50.785*29.12*(Ts-Te))-(2.025*29.35*(Ts-Te))-(8*37.11*(Ts-Te))-(14*33.58*(Ts-Te))

, 927.948 + 33.58Ts - 10, 011.877 -1,478.8592Ts +440, 921.8705 -59.43375Ts + 17,720.17256 - 296.88Ts + 88

,178.4672 Ts + 649, 509.9957 - 2,195.6735Ts + 654, 640.0054 - 2,776.1991 Ts + 827, 723.7617 - 2, 512.1198 +

3.58*(Ts-Te))

+ 17,720.17256 - 296.88Ts + 88, 514.772 - 1, 054.06 + 314, 267.989

+ 827, 723.7617 - 2, 512.1198 + 748, 988.5184