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Coagulant Dosage
Raymond D. Letterman
Department of Civil and Environmental
Engineering, Syracuse University
A method* for:
selecting the coagulant type
estimating the coagulant dosage
estimating acid or base requirements, if any
Hydrolyzing metal salt coagulants
Removal of NOM (natural organic material)
Al(H 2 O)
3+
6
Al(OH)(H2 O)
Bicarbonate ion
Hydrogen ion
2+
5
+ H
Carbon dioxide
2H + HCO H 2 CO 3 (CO 2 + H 2 O) + H
3
Al(OH)(H2O)52 +
mononuclear species
Al13O4 (OH)724+
polynuclear species
Al(OH)3 (s)
Al(OH)-4
High pH
Alum
=B
Prehydrolyzed Al product
with B = 75%
=M
=A
300
A
300
10
+
=
+
= 0.181 meq/mg Al
100(AW) EW(M) 100(27) 49(2.9)
Basicity (B, %)
A, weight %
pure acid
M, weight %
metal
Aluminum
Sulfate (Alum)
4.3 (Al)
0.111
Polyaluminum
Chloride
(PACl)
80
12.3 (Al)
0.022
Acid
Supplemented
Alum
(Acidized
Alum)
10 (H2SO4)
2.8 (Al)
0.184
Ferric Sulfate
(with 2%
excess acid)
2 (H2SO4)
10 (Fe)
0.058
The effective acid content can also be measured by titration with strong base.
Ferric sulfate
7.0
Alum
pH
PACl (B=75%)
PACl (B=50%)
6.0
Alum (A=5%)
Alum (A=10%)
Ferric Chloride
PACl (B=10%)
5.0
4.0
0
10
20
30
Label in
Figures
Alum (A=10%)
0.168
Alum (A=5%)
0.135
Alum
0.111
PACl (B=10%)
0.100
PACl (B=50%)
0.056
Ferric Chloride
Ferric Chloride
0.054
Ferric Sulfate
Ferric Sulfate
0.054
PACl (B=75%)
0.028
7.0
Alum
PACl (B=75%)
pH
PACl (B=50%)
6.0
Calculated
Alum (A=5%)
Alum (A=10%)
Ferric Chloride
5.0
PACl (B=10%)
4.0
0.0
0.5
1.0
1.5
2.0
Al(OH)3 precipitate
log[Al(III)]
-5
Temperature =
25C
-6
-7
-8
Al(OH)4-
AlOH2+
-9
Al3+
-10
-11
4
8
pH
10
11
Temperature = 25 C
-6
log[Fe(III)]
-7
-8
Fe(OH)3 precipitate
-9
FeOH2+
-10
Fe(OH)2+
-11
Fe(OH)4-
Fe3+
-12
4
8
pH
10
11
pHm
6.5
6.4
6.3
6.2
6.1
6.0
5.9
0
10
15
20
Temperature (degrees C)
25
30
25
20
15
10
0
0
10
15
20
Temperature (degrees C)
25
30
10
0.1
9
Soluble Al
0.01
pH
Al added
0.001
0.01
0.1
1
Al Dosage (mg Al/L)
10
100
4
0.01
0.1
1
Al Dosage (mg Al/L)
10
100
10
Al added
1
7
0.1
pH
100
0.01
Soluble Al
5
0.001
0.01
0.1
1
Al Dosage (mg Al/L)
10
100
4
0.01
0.1
1
Al Dosage (mg Al/L)
10
100
Simple proportionality
Van Benschoten and Edzwald, and others
4.0
3.5
R (mg M/mg C)
iron salts
M = Al
3.0
2.5
2.0
aluminum
salts
1.5
1.0
0.5
0.0
3
6
pH
Pernitsky-Edzwald (2006)
Edzwald-Kaminski (2009)
Tambo-Kamei-Itoh (1989)
TOC removal %
does not depend
on the final pH.
The SUVA of the
raw water NOM
is an important
indicator.
80
y = 13.871x - 7.1312
R2 = 0.5497
70
60
50
40
30
20
10
0
0.0
1.0
2.0
3.0
4.0
5.0
SUVA = UV light
absorbance at
=254 nm
divided by TOCo.
Alkalinity (milliequivalents/L)
pHo = 7.7
pHf =
3.0
6.12
2.5
7.0
2.0
7.5
1.5
8.5
1.0
0.5
0.0
0
Calculated final
alkalinity (meq/L)
alk o - alk f
X
= EAC of coagulant solution (meq/mgM)
m
m
Calculated dosage of
coagulant (mg M/L)
m = R x TOCo
alk o - alk f
mg of additive
Dosage (mg/L) = m
- EAC
m
meq
mg
alk - alk f
Note : When o
quantity is a negative number.
- EAC < 0 the additive must be a base and the
meq
m
pH adjustment chemicals
Additive
Sodium
Bicarbonate
(NaHCO3)
Sodium
Carbonate
(Na2CO3)
Hydrated Lime
(Ca(OH)2
Sodium
Hydroxide
(NaOH)
Sulfuric Acid
(H2SO4)
Hydrochloric
Acid (HCl)
Carbon Dioxide
(CO2)
Additive
Dosage
Change in
alkalinity
(meq/L)
Change in inorganic
carbon concentration, CT
(moles C/L)
1 mg/L
1.19 x 10-2
1.19 x 10-5
1 mg/L
1.89 x 10-2
9.43 x 10-6
1 mg/L
2.7 x 10-2
1 mg/L
2.5 x 10-2
1 mg/L
-2.04 x 10-2
1 mg/L
-2.82 x 10-2
1 mg/L
2.0 x 10-5
Example calculation
Temperature = 25 C
alko = 1.5 meq/L (75 mg/L as CaCO3)
pHo = 7.5
pHf = 6.1
-5
-6
-7
-8
-9
-10
-11
4
8
pH
10
11
5.0
4.5
M = Fe
4.0
M = Al
R (mg M/mg C)
3.5
3.0
2.5
2.0
1.5
1.0
0.5
0.0
3
6
pH
Alkalinity (milliequivalents/L)
25 degrees C
pHf =
3.0
6.12
2.5
7.0
2.0
7.5
1.5
8.5
1.0
0.5
0.0
0
300
A
+
100( AW ) EW ( M )