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Tool for calculating the carbon footprint for wastewater treatment plants

This tool for calculating the carbon footprint for wastewater treatment plants has been created in t
Calculation of the carbon footprint from Swedish wastewater treatment plants (SVU 12-120).
The tool consists of this file with 13 sheets.
The sheets are divided in three different categories:
Group 1: Input data

Group 2: Results

Group 3: Emission factors, GWP and constants (purple sheets)

Group 4: References and indata

Two types of colours are used to mark which type of data that is used in the tool:

Red text shows that the user are supposed to choose which alternative is the most relevant for the
Blue text in the sheet detailed results shows that the results are based on calculations with value
The users name, year and plant:
WWTP
Year
Name

ool for calculating the carbon footprint for wastewater treatment plants

his tool for calculating the carbon footprint for wastewater treatment plants has been created in the project
Calculation of the carbon footprint from Swedish wastewater treatment plants (SVU 12-120).

he tool consists of this file with 13 sheets.

he sheets are divided in three different categories:


Group 1: Input data (blue sheets)
Input WWTP
Input chemicals
Input energy
Input transports
Input sludge and waste

Group 2: Results (green sheets)


Results
Detailed results

Group 3: Emission factors, GWP and constants (purple sheets)


Emission factors
Chemicals
GWP and constants

Group 4: References and indata (dark grey sheets)


References
Input data

wo types of colours are used to mark which type of data that is used in the tool:
Light grey cells are used for input of data from the wwtp.
Dark grey cells are used for automatic calculation based on input data and shall not be

ed text shows that the user are supposed to choose which alternative is the most relevant for the plant.
ue text in the sheet detailed results shows that the results are based on calculations with values from litte

e users name, year and plant:

n the project

shall not be filled by the user.

the plant.
alues from litteratur rather than data from measurements at the plant.

Observe that only light grey cells, and not dark grey cells shall be used for input data.

WWTP processes
Wastewater
Flow
COD influent
BOD7 influent

m3/h
ton/year
ton/year
ton/year
ton/year

N influent
P influent

pe

N2O and CH4 emissions from WWTP


Site specific data - water treatment
Measured methane emissions (CH4)

ton

Measured nitrous oxide emissions (N2O)

ton

Site specific data - sludge treatment


Measured methane emissions (CH4)

ton

Measured nitrous oxide emissions (N2O)

ton

N2O and CH4 emissions from sludge liquor treatment


Measured methane emissions (CH4)

(put 1 if these emissions are exc

Measured nitrous oxide emissions (N2O)


Flow sludge liquor
Amount of total nitrogen that has been reduced at the sludge
liquor treatment process by:
Nitrification - denitrification (SBR)
Only nitritation (with dosage of NaOH)
Nitritation-anammox in SBR with continous aeration
Nitritation-anammox in SBR with intermittent aeration
Nitritation-anammox in granule reactor
Nitritation-anammox in MBBR with continous aeration

(put 1 if these emissions are


m3/h

ton/year
ton/year
ton/year
ton/year
ton/year
ton/year

If data about nutrients

External organic material

Type 1
Amount
TS
VS
COD
BOD7
N
P

ton/year
%
% av TS
0 ton/year
ton/year
0 ton/year
0 ton/year
Total external organic material

Amount
TS
VS

0 ton/year
0 ton TS/year
0 ton VS/year

COD
BOD7
N
P

0 ton/year
0 ton/year
0 ton/year
0 ton/year

Effluent wastewater
Total nitrogen in effluent wastewater
Total COD in effluent wastewater
Total phosphorus in effluent wastewater
Total BOD7 in effluent wastewater
Sea
Lake or estuary

ton
ton
ton
ton
(put 1 if the effluent wastewater
(put 1 if the effluent wastewater

be used for input data.

1 if these emissions are excluded from the CH4 emissions above)


1 if these emissions are excluded from the N2O emissions above)

If data about nutrients in the external organic material is missing, than data from sheet "GWP and constants" can be used.

organic material

Type 2
Amount
TS
VS
COD
BOD7
N
P

Type 3
ton/year
%
% av TS
0 ton/year
ton/year
0 ton/year
0 ton/year

Amount
TS
VS
COD
BOD7
N
P

ton/year
%
% av TS
0 ton/year
ton/year
0 ton/year
0 ton/year

Type 4
Amount
TS
VS
COD
BOD7
N
P

ton/year
%
% av TS
0 ton/year
ton/year
ton/year
ton/year

1 if the effluent wastewater is going to the sea)


1 if the effluent wastewater is going to a lake or estuary)

onstants" can be used.


Type 5
Amount
TS
VS
COD
BOD7
N
P

ton/year
%
% av TS
0 ton/year
ton/year
ton/year
ton/year

Observe that only light grey cells, and not dark grey cells shal

Chemicals
Carbon sources Producer
Methanol Helm Skandinavien A/S
Ethanol (25%) Perstorp
Sekundol 70 - heads
Sekundol 85
Mosstanol L
Acetic acid
Glycerine
Coagulants
FeSO4
Quickfloc (FeSO4) Kronos Titan
COP (FeSO4)
FeClSO4
PIX-118, 318
Fe2(SO4)3
PIX-113
FeCl3
PIX-111, Plusjrn S 314 Feralco Nordic
PIX-110
AlFeCl
Ekomix 1091
PAC
PAX-18, Ekoflock 90
PAX-15, XL61 Kemira
PAX-XL100
PAX-215
Alcalinity
CaO Nordkalk
Ca(OH)2 Nordkalk
CaCO3
NaOH 50 %
Polymers
Polymers from SNF
Nerolan CG144, CG147X Afridana
Other chemicals
Activated carbon - biogenic origin
Activated carbon - fossil origin
Octanol
Nitric acid (HNO3)

Ton/year

Distance from
WWTP (km)

Ion exchange salt


Phosphoric acid 75 %
Sulfuric acid (H2SO4) - Swedish origin
Hydrogen peroxide (H2O2), 50 % in H2O
Propane
Lithium chloride
Anti-foaming agent Citru-Ren
Hydrogen chloride (HCl)
Sodium hypochlorite (NaClO)
Citric acid
Other chemicals
Other chemicals
Other chemicals
Other chemicals
Other chemicals
Other chemicals
Transports total

d not dark grey cells shall be used for input data.

Times/year

km/year

Storage place

0 Kge, Danmark
0 Perstorp, Sverige
0
0
0
0
0

0 Norge
0
0
0
0 Slvesborg, Sverige
0
0
0
0 Vetlanda, Sverige
0
0
0 Norra Gotland, Sverige
0 Norra Gotland, Sverige
0
0
0 Kpenhamn, Danmark
0 Kpenhamn, Danmark
0
0
0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0 km/year

Observe that only light grey cells, and not dark grey cells shall be used for input data.

Energy
Electricity
Used at the plant (total)
Purchased electricity

MWh
MWh

Produced by wind/solar energy at the WWTP


Produced by biofuels (not sludge) at the WWTP
Produced by natural gas at the WWTP
Produced by oil the WWTP

MWh
MWh
MWh
MWh

Used at the plant (total)


Purchased heat

MWh
MWh

100%

Heat

Produced by biofuels (not sludge) at the WWTP


Produced by wind/solar energy at the WWTP
Produced by oil the WWTP
Produced by natural gas at the WWTP
Local emission factor for heat
Emission factor (local heat)

MWh
MWh
MWh
MWh
(if there is a local emission factor for h
g CO2e/kWh

Cooling
Used cooling
Purchased cooling
Produced cooling at the WWTP

MWh
MWh
MWh

Heat exchanger effluent wastewater


Heat factor
Total heat production by heat exchanger

(put 1 if the produced heat and the ele


MWh heat per MWh electricity
MWh

Biogas
Produced biogas
Methane content in biogas

Measured biogas emissions from anaerobic digestion (excl upgrading)

Nm3
%

Nm3 biogas

Biogas use
Direct biogas flow to atmosphere
Torch
Used in gas engine
Used in gas boiler

Nm3
Nm3
Nm3
Nm3

Used as vehicle fuel (after compressing and transport in tubes in


a truck)
Grid injection (assumed to be used as vehicle fuel)
Transport distance for compressed biogas in a truck
Total amount of upgraded biogas
If propane is added to the gas, put 1 in the box
Added propane to produced gas
Energy use at upgrading facility
Chemical adsorption - mean value from literature

Nm3
Nm3
km
0 Nm3
ton

PSA - mean value from literature


Waterscrubber - mean value from literature

0 MWh
0 MWh
0 MWh

Measured energy use at upgrading facility

MWh

Total energy use for upgrading

0 MWh

0
0
0

Methane emissions from upgrading


Chemical adsorption - mean value from literature

0 Nm3 CH4

PSA - mean value from literature


Waterscrubber - mean value from literature
Methane emissions at upgrading facility, as methane gas
Total methane emissions from upgrading

0 Nm3 CH4
0 Nm3 CH4
Nm3 CH4
0 Nm3 CH4

0
0

Natural gas used for upgrading

Nm3

be used for input data.

Of which is based on renewable energy sources (%)

re is a local emission factor for heat, put 1 and the emission factor in cell C22 below)

if the produced heat and the electricity used in the heat exchanger is excluded in total energy use above)
heat per MWh electricity
Biogas per input energy
Energy in biogas
Used energy
Ratio
If there are no measurements, do not
fill in this cell. A theoretical value will be
used instead.

0 MWh
0 MWh
#DIV/0!

If there is no measurement:
(put 1 if this technology is used)
(put 1 if this technology is used)
(put 1 if this technology is used)

If there is no measurement:
(put 1 if this technology is used)
(put 1 if this technology is used)
(put 1 if this technology is used)

Observe that only light grey cells, and not dark

Transports (not including transports of chemica


Sludge to storage
Distance from wastewater treatment plant

km

Times per year


10 km/year

40 ton

Sludge to farmland
Distance from wastewater treatment plant

60 ton

km

Times per year


10 km/year

60 ton

km

Times per year

60 ton

km

Times per year

60 ton

km

Times per year

60 ton

km

Times per year

60 ton

km

Times per year

60 ton

km

Times per year

Ashes
Distance from incineration facility
Times per year

Max load: (put 1 in the cell that corresponds be


40 ton

Use of compost
Distance from composting facility to end use
10 km/year

Max load: (put 1 in the cell that corresponds be


40 ton

Sand
Distance from wastewater treatment plant
10 km/year

Max load: (put 1 in the cell that corresponds be


40 ton

Screenings
Distance from wastewater treatment plant
10 km/year

Max load: (put 1 in the cell that corresponds be


40 ton

Sludge to incineration
Distance from wastewater treatment plant
10 km/year

Max load: (put 1 in the cell that corresponds be


40 ton

Sludge to composting facility


Distance from wastewater treatment plant
10 km/year

Max load: (put 1 in the cell that corresponds be


40 ton

Sludge to soil production/land fill/land fill cover


Distance from wastewater treatment plant
10 km/year

Max load: (put 1 in the cell that corresponds be

Max load: (put 1 in the cell that corresponds be


40 ton

60 ton

km

Max load: (put 1 in the cell that corresponds be


40 ton

10 km/year

Sludge from reed bed


Distance from reed bed to end use

km

Times per year


10 km/year

60 ton

Max load: (put 1 in the cell that corresponds be


40 ton

60 ton

cells, and not dark grey cells shall be used for input data.

transports of chemicals)

e cell that corresponds best to the vehicle used)

e cell that corresponds best to the vehicle used)

e cell that corresponds best to the vehicle used)

e cell that corresponds best to the vehicle used)

e cell that corresponds best to the vehicle used)

e cell that corresponds best to the vehicle used)

e cell that corresponds best to the vehicle used)

e cell that corresponds best to the vehicle used)

e cell that corresponds best to the vehicle used)

e cell that corresponds best to the vehicle used)

Observe that only light grey cells, and not dark grey cells shall be used for input data.

Sludge and waste


Sludge
Sludge storage before further handling
Ton sludge each year
TS

days
ton
%

0 ton TS
VS content after anaerobic digestion

% of TS

Amount VS

0 ton

Ton dried sludge per year

ton

TS

Screenings
Amount of screenings
TS content in screenings (general use)
Heat content in screenings for incineration
TS content in screenings for incineration

ton/year
%

TS 40% %

Can be used if there is no site specific data on TS-content in screenings

TS 50% %

Can be used if there is no site specific data on TS-content in screenings for inc

-2.1 MJ/ton
%

Sand
Amount genererated sand

0 ton/year

Nutrients in sludge
Before storage

If site specific data on nutrients in sludge, than values from the sheet "GWP and constants" can be u

After storage

N-content before storage


P-content before storage

kg N/ton TS
kg P/ton TS

K-content before storage

kg K/ton TS

C-content before storage

kg C/ton TS

0.0 kg C/ton TS Can be used if there is no site specific data on C-content in sludge

N-content after storage


P-content after storage
K-content after storage
C-content after storage

0.0
0.0
0.0
0.0

kg N/ton TS
kg P/ton TS
kg K/ton TS
kg C/ton TS

Sludge use
Farmland
Incineration after dewatering
Incineration after drying

%
%
%

Land fill/land fill cover

Reed bed

Fertilizer after drying


Soil production (without composting)
Composting

%
%
%

Use of compost
Land fill cover
Farmland
Soil production
Land fill

%
%
%
%

Incineration
Land fill
Anaerobic digestion

%
%
%

Reuse
Land fill

%
%

Screenings

Sand

0 (put 1 if these emissions are excluded


0 (put 1 if these emissions are excluded
0 (put 1 if these emissions are excluded in total energy use)

Note! If sludge is composted than the use of the compost are to be filled in below.

dark grey cells shall be used for input data.

sed if there is no site specific data on TS-content in screenings

sed if there is no site specific data on TS-content in screenings for incineration

in sludge, than values from the sheet "GWP and constants" can be used.

sed if there is no site specific data on C-content in sludge

s are excluded in total energy use)


s are excluded in total energy use)

s are excluded in total energy use)

se of the compost are to be filled in below.

80% Volume reduction in reed beds

Energy use

Wastewater treatment

0 ton CO2e

0 ton CO2e

10000
8000
6000
4000
2000
0
-2000
-4000
-6000
-8000
-10000

10000
8000
6000
4000
2000
0
-2000
-4000
-6000
-8000
-10000

Total

#DIV/0!

CO2e per pe (70 g BOD7 per day)

#DIV/0!

CO2e per m3 treated wastewater

#DIV/0!

CO2e per removed N-tot

#DIV/0!

CO2e per removed P-tot

#DIV/0!

CO2e per removed COD-tot

#DIV/0!

CO2e per influent N-tot

#DIV/0!

CO2e per influent COD-tot

#DIV/0!

CO2e per influent P-tot

#DIV/0!

Chemicals
0 ton CO2e

10000
5000
0
-5000
-10000

Treatment efficiency

Transports

N-reduction

#DIV/0!

P-reduction

#DIV/0!

COD-reduction
BOD7-reduction

#DIV/0!
#DIV/0!

Recipient

0 ton CO2e

10000
8000
6000
4000
2000
0
-2000
-4000
-6000
-8000
-10000

10000
5000
0
-5000

ton CO2e/year

-10000

1
1
1
0

Transports

Recipient

Chemicals

astewater treatment

Sludge use

Energy use

Transports

Recipient

Chemicals

Wastewater treatment

Sludge use

Energy use

0 ton CO2e
10000
5000
0
-5000
-10000

Total external VS used for biogas production (ton/year)

ton CO2e per year

Sludge use
#DIV/0! ton CO2e

kg
kg
ton
ton

10000

ton

5000

ton

ton
ton

-5000
-10000

Effluent wastewater
N-concentration

#DIV/0! mg/l

P-concentration

#DIV/0! mg/l

COD-concentration
BOD7-concentration

#DIV/0! mg/l
#DIV/0! mg/l

Screenings and sand


ton CO2e

0 ton CO2e
10000

10000
5000
5000
0
0
-5000
-5000
-10000

Total carbon footprint

Biogas use

Screenings and sand

Transports

Recipient

-10000

Chemicals

astewater treatment

Biogas use

Total carbon footprint

Biogas use

Screenings and sand

Transports

Recipient

Chemicals

Wastewater treatment

00

00
0

00

00

Energy use
Sludge use
Wastewater treatment
Chemicals
Recipient
Transports
Screenings and sand
Biogas use

ton CO2e/year % of total carbon footprint % of negative carbon footprint


0
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
#DIV/0!
0
#DIV/0!
#DIV/0!
0
#DIV/0!
#DIV/0!
0
#DIV/0!
#DIV/0!
0
#DIV/0!
#DIV/0!
0
#DIV/0!
#DIV/0!
0
#DIV/0!
#DIV/0!

Total carbon footprint

Percent of category "wastewater treatment"


Fossil carbon source for denitrification

#DIV/0! ton CO2e/year


#DIV/0!
%
#DIV/0!

of negative carbon footprint

Blue text = Data based on standard values from literature (theoretical emissions)

Electricity use - purchased

EU future

0 ton CO2e
0 ton CO2e

EU average

0 ton CO2e

Nordic

0 ton CO2e

Swedish

0 ton CO2e

Produced electricity from biofuels at the WWTP

0 ton CO2e
0 ton CO2e

EU marginal

Electricity use - internal production


Produced electricity from solar/wind energy at the WWTP
Produced electricity from natural gas at the WWTP
Produced electricity from oil at the WWTP
Total CO2e from internal electricity

0 ton CO2e
0 ton CO2e
0 ton CO2e

Heat
Used heat with local emission factor

0 ton CO2e

Used heat with standard emission factor

0 ton CO2e

Produced heat from biofuels at the WWTP

0 ton CO2e

Produced heat from solar/wind energy at the WWTP

0 ton CO2e

Produced heat from natural gas at the WWTP

0 ton CO2e

Produced heat from oil at the WWTP

0 ton CO2e

Wastewater based heat from heat exchangers

0 ton CO2e

Total CO2e from heat

0 ton CO2e

Used cooling

0 ton CO2e
0 ton CO2e

Cooling
Produced cooling at the plant
Total CO2e from cooling

0 ton CO2e

Transports
Chemicals
CO2e
Sludge to storage

0 ton

CO2e

0 ton

Sludge to farmland
CO2e

0 ton

Sludge to incineration
CO2e

0 ton

Sludge to composting facility


CO2e

0 ton

Sludge to soil production/land fill/land fill cover


CO2e

0 ton

Sludge from reed bed


CO2e

0 ton

Screenings
CO2e

0 ton

Sand
CO2e

0 ton

Use of compost
CO2e

0 ton

Ashes
CO2e
Biogas (not grid injection)

0 ton

Emissions from transport of compressed biogas in truck

Total CO2e from transports

0 ton CO2e

0 ton

Screenings- and sludge handling


Screenings
Electricity production from incineration of screenings
Heat production from incineration of screenings
Total energy production from incineration of screenings
Emissions from incineration of screenings
Emissions from screenings on land fill

0.0 MWh
0 MWh
0 ton CO2e
0 ton CO2e
0 ton CO2e

Sand
Emissions from recovery of sand

0.0000 ton CO2e


0.0000 ton CO2e

Total waste handling

0 ton CO2e

Emissions from sand on land fill

Chemicals
Carbon sources

Methanol
Ethanol (25%)
Sekundol 70 - heads
Sekundol 85

0 ton CO2e
0 ton CO2e
0 ton CO2e
0 ton CO2e

Acetic acid

0 ton CO2e
0 ton CO2e

Glycerine

0 ton CO2e

Mosstanol L

Coagulants
FeSO4
Quickfloc (FeSO4)
COP (FeSO4)

0 ton CO2e
0 ton CO2e

FeClSO4
PIX-118, 318
Fe2(SO4)3

0 ton CO2e

PIX-113
FeCl3

0 ton CO2e

PIX-111, Plusjrn S 314

0 ton CO2e

PIX-110

0 ton CO2e

AlFeCl
Ekomix 1091

0 ton CO2e

PAC
PAX-18, Ekoflock 90
PAX-15, XL61
PAX-XL100
PAX-215
Alcalinity

0 ton CO2e
0 ton CO2e
0 ton CO2e
0 ton CO2e

CaO
Ca(OH)2

0 ton CO2e
0 ton CO2e

CaCO3

0 ton CO2e
0 ton CO2e

NaOH 50 %
Polymers
Polymers from SNF
Nerolan CG144, CG147X
Other chemicals
Activated carbon - biogenic origin
Activated carbon - fossil origin
Octanol
Nitric acid (HNO3)

0 ton CO2e
0 ton CO2e
0 ton CO2e
0 ton CO2e
0 ton CO2e
0 ton CO2e

Phosphoric acid 75 %

0 ton CO2e
0 ton CO2e

Sulfuric acid (H2SO4) - Swedish origin

0 ton CO2e

Ion exchange salt

Hydrogen peroxide (H2O2), 50 % in H2O


Propane
Lithium chloride
Anti-foaming agent Citru-Ren
Hydrogen chloride (HCl)
Sodium hypochlorite (NaClO)
Citric acid
Other chemicals
Other chemicals
Other chemicals

0 ton CO2e
0 ton CO2e
0 ton CO2e
0 ton CO2e
0 ton CO2e
0 ton CO2e
0 ton CO2e
0 ton CO2e
0 ton CO2e
0 ton CO2e

Other chemicals

0 ton CO2e
0 ton CO2e

Other chemicals
Total chemicals

0 ton CO2e
0 ton CO2e

Other chemicals

Respiration
Methanol
Ethanol (25%)
Sekundol 70 - heads
Sekundol 85

0 ton CO2e
0 ton CO2e
0 ton CO2e
0 ton CO2e

Acetic acid

0 ton CO2e
0 ton CO2e

Glycerine
Total respiration

0 ton CO2e
0 ton CO2e

Mosstanol L

Chosen
electricity (put 1
in the cell):

EU average

0
1
0

Nordic

Swedish

EU marginal
EU future

Total electricity use

0 ton CO2e

Wastewater treatment - direct


emissions
Measured emissions
CH4
N2O

0 ton CO2e
0 ton CO2e

Calculated emissions
N2O water treatment

0 ton CO2e

N2O sludge liquor treatment

0 ton CO2e

CH4 water treatment


CH4 sludge liquor treatment

0 ton CO2e
0.00 ton CO2e

Total (calculated)
Total CH4-emissions

0 ton CO2e
0 ton CO2e

Total N2O-emissions

0 ton CO2e

Total emissions

0 ton CO2e

Total CO2e per year


CO2e per pe (70 g BOD7 per day)
CO2e per m3 treated wastewater

#DIV/0! ton
kg
#DIV/0! kg
#DIV/0!

CO2e per removed N-tot

#DIV/0!

ton

CO2e per removed P-tot

#DIV/0!

ton

CO2e per removed COD-tot

#DIV/0!

ton

CO2e per influent N-tot

#DIV/0!

ton

CO2e per influent COD-tot

#DIV/0!

ton

CO2e per influent P-tot

#DIV/0!

ton

Measured emissions - sludge processes


CH4
N2O

0 ton CO2e
0 ton CO2e

Summa:

0 ton CO2e

Sludge storage
N2O-emissioner from sludge storage before use
CH4-emissioner from sludge storage before use
Ton CO2e

0.0 ton N2O


0.0 ton CH4
0 ton CO2e

Sludge handling
Loading

0 ton CO2e

Ton N after storage

0 ton N

Ton P after storage

0 ton P

Ton K after storage

0 ton K

Ton C after storage

0 ton C

Farmland
Sludge spreading

0 ton CO2e

Substituted synthetic fertilizer

0 ton CO2e
0 ton CO2e

0.00 ton CO2e

Direct N2O-emissions

0.00 ton CO2e


0 ton CO2e

CH4-emissions
Indirect N2O-emissions
Incineration of sludge
N2O-emissions
CH4-emissions

0 ton CO2e
0 ton CO2e
0 ton CO2e

Heat production from sludge incineration

0 ton CO2e
0 ton CO2e

Energy use sludge incineration

0 ton CO2e

Electricity production from sludge incineration

Land fill
N2O-emissions
CH4-emissions
Emissions from energy use
Energy recovery from land fill
Incineration of land fill gas (N2O-emissions)
Incineration of land fill gas (CH4-emissions)
Reed bed
N2O-emissions
CH4-emissions

0 ton CO2e
0 ton CO2e
0 ton CO2e
0 ton CO2e
0.0 ton CO2e
0 ton CO2e
#DIV/0! ton CO2e
#DIV/0! ton CO2e

Emissions from energy use


Sludge use as fertilizer after drying

0.00 ton CO2e

Emissions from energy use


CH4-emissions

0 ton CO2e
0 ton CO2e

Direct N2O-emissions

0 ton CO2e
0 ton CO2e

Indirect N2O-emissions

Substituted synthetic fertilizer


P

0 ton CO2e
0.0 ton CO2e

0.000 ton CO2e

Composting
Direct N2O-emissions
Indirect N2O-emissions

0 ton CO2e
0 ton CO2e

CH4-emissions

0 ton CO2e

Emissions from energy use

0 ton CO2e

Use of composted sludge on farmland


Substituted synthetic fertilizer
N

0.0 ton CO2e

0 ton CO2e
0.00 ton CO2e

K
Direct N2O-emissions
Indirect N2O-emissions

0 ton CO2e
0.0 ton CO2e

CH4-emissions

0 ton CO2e

Use of composted sludge for soil production + soil


prouction of sludge without composting
Direct N2O-emissions
Indirect N2O-emissions

0 ton CO2e
0 ton CO2e

Peat substitution
CH4-emissions

0 ton CO2e
0 ton CO2e

Use of composted sludge as land fill cover


Direct N2O-emissions
Indirect N2O-emissions

0.00 ton CO2e


0.00 ton CO2e

CH4-emissions

0.00 ton CO2e

Land fill of sludge after composting


Direct N2O-emissions
Indirect N2O-emissions
CH4-emissions

0 ton CO2e
0.00 ton CO2e

Emissions from energy use

0 ton CO2e
0 ton CO2e

Energy recovery from land fill


Incineration of land fill gas (N2O-emissions)

0 ton CO2e
0 ton CO2e

Incineration of land fill gas (CH4-emissions)

0 ton CO2e

Total CO2e-emissions from sludge handling

#DIV/0! ton CO2e

External use of biogas

Substitution of electricity

0 ton CO2e
0 ton CO2e

Substitution of heat

0 ton CO2e

Total

0 ton CO2e

Direct biogas flow to atmosphere

0 ton CO2e

Substitution of vehicle fuel

Biogas emissions
Biogas slip (excluding slip during upgrading)
Measured
Calculated

0 ton CO2e
0 ton CO2e

Biogas slip upgrading facility


Calculated

0 ton CO2e
0 ton CO2e

Total

0 ton CO2e

Energy use upgrading

0 ton CO2e

Energy use and dosage of propane for grid injection


Incineration of propane

0 ton CO2e
0 ton CO2e

Incineration of natural gas

0 ton CO2e

Energy use for compressing biogas for transport in truck

0 ton CO2e

Total biogas use and distribution

0 ton CO2e

Use in vehicles

0 ton CO2e

Torch

0 ton CO2e

Gas engines

0 ton CO2e
0 ton CO2e

Measured

Biogas use and distribution

N2O from biogas use

Gas boiler
Total N2O

0 ton CO2e

CH4 from biogas use


Torch

0 ton CO2e
0 ton CO2e

Gas engines

0 ton CO2e

Use in vehicles

Gas boiler
Total CH4

0 ton CO2e
0 ton CO2e

Total N2O- and CH4-emissions from biogas use

0 ton CO2e

Sea N2O

0 ton N2O
0 ton CO2e

Recipient
Sea CH4
Lake and estuary N2O
Lake and estuary CH4

0 ton CO2e
0 ton CO2e

Total recipient

0 ton CO2e

Carbon sequestration
C-tot

0 ton

CO2e

0 ton

Emission factors
Bold values

Electricity production
EU marginal
EU future
EU average
Nordic
Swedish

750
350
415
58
10

Wind electricity
Biofuel based electricity
Natural gas based electricity
Oil based electricity

13
23
474
582

Heat production
CO2e local

CO2e Sweden

88.6
10.8
24.8
248
295

Biofuel based heat


Solar based heat
Natural gas based heat
Oil based heat (E01)

Cooling - production
CO2e Sweden

0.22

Energy substituted by use of biogas


Production and use of petrol with 5 % ethanol

77
277

Production and use of petrol

80
287

Production and use of diesel

81
291

Production and use of natural gas

69
248

Biogas use
Methane emissions from incineration of biogas in gas engine/gas boiler:
min
average

0.002
0.003

max

0.034

Nitrous oxide emissions from incineration of biogas in gas engines/gas boiler:


min
average
max
Incineration of upgraded biogas in vehicles
Nitrous oxide emissions

0.00
0.004
1.56
1.4E-05

Methane emissions
Biogas production
Biogas slip (excluding emissions during upgrading)
Methane emissions (chosen value)

0.00073

Methane emissions

2.1

Biogas distribution
Compression of upgraded biogas
Transport of compressed biogas
Propane dosing
Propane dosage (for grid injection)

0.18
0.0016
0.001
131

Emissions from incineration of propane

3.00

Methane emission from upgrading of biogas


Chemical adsorption - mean value from literature
PSA - mean value from literature
Waterscrubber - mean value from literature
Energy use in biogas upgrading
Chemical adsorption - mean value from literature
PSA - mean value from literature
Waterscrubber - mean value from literature

2.8

0.2
2.5
2
0.15
0.25
0.25

Direct emissions from wastewater treatment


Respiration with external carbon source
Methanol use

1.375

Ethanol use

1.913

Acetic acid use

1.467

Isopropanol use

2.200

Mosstanol use (65 % etanol 35 % isopropanol)

2.013

Glycerin

0.000

Methane emissions from WWTP (water treatment)


Swedish average
Max

0.0025
0.007

Theoretical N2O-emissions from sludge liquor treatment


Nitrification - denitrification (SBR)

0.05

min
max
Only nitritation (with dosage of NaOH)
Nitritation-anammox in SBR with continous aeration
Nitritation-anammox in SBR with intermittent aeration
Nitritation-anammox in granule reactor
Nitritation-anammox in MBBR with continous aeration

2.98
6.75
0.06
0.01
0.02
0.03
0.01

Theoretical N2O-emissions from wastewater treatment (water treatment)


BNR1

min
Average
max

0.000471
0.0157
0.0471

CH4 dissolved in digested sludge

20

Energy use at incineration of sludge


Dewatering (gravity)
Dewatering (mechanical)
Dewatering (chosen value)
Energy use drying
Energy use incineration

50

100
75
1100
200

Energy recovery at incineration of sludge


Total energiy recovery
Electricity production
Heat production

82%
19%
63%

Energy content in not digested sludge


Energy content in digested sludge
Energy content in dried sludge

14000
8485
11667

Energy use land fill


Electricity use

21.7

Diesel use

6.7

Energy recovery land fill


CH4 production

348

CH4 collection
Electricity production of the collected gas
Heat production of the collected gas

58%
30%
45%

Oxidation of the collected gas

25%

Energy use composting


Electricity use
Diesel use
Fuel oil

41
12
1.8

Electricity use reed bed


Electricity use (pumps)

0.1

Emissions from transports


Petrol consumption in truck
Total weight 40 ton
Total weight 60 ton
Energy content in used diesel

3
4.5
35.28

Emissions from diesel use


Emission factor truck 40 ton
Emission factor truck 60 ton

80
8.5
12.7

Emissions from sludge storage


N2O emissions from sludge storage
1.10%
N2O emissions from sludge storage
0.50%
CH4 emissions from sludge storage
0.0007
NH3 emissions from sludge storage
4%
C-emissions from sludge storage 0.0003764

Emissions from sludge spreading on farmland


Loading
Total CO2e emissions loading

29
2.3

Spreading
Sludge spreading on farmland
Synthetic fertilizer spreading on farmland
Total CO2e spreading sludge
Total CO2e spreading of synthetic fertilizer

80
23
6.5
1.9

Use on farmland
Direct N2O emissions from composted sludge
Direct N2O emissions
NH3 and NO3 emissions from sludge

1.4%
1%
20%

Indirect N2O emissions


NH3 and NO3 emissions from synthetic fertilizer

0.0157
10%

Direct N2O emissions from synthetic fertilizer

0.0157

Indirect nitrous oxide emissions from NH3-emissions from synthetic


fertilizer and sludge
CH4 emissions
min

0.01
0

used value

max
CH4 emissions from synthetic fertilizer
Substituted production of synthetic fertilizer
N

0.0096
0

0.51

0.38

2.9

N
Peat production

5.29

Min

330

Max
Used value
Peat substitution ratio
Min
Max
Used value
Phosphorus availability
Min (sludge)
Max (sludge)
Used value (sludge)

1197
400

3.9

0.2
1
0.30
25
75
70

Phosphorus availability in compost


Nitrogen availability in sludge
Nitrogen availability in compost
Potassium availability in sludge
Potassium availability in compost

70
32.5
30
100
100

Emissions from sludge handling - excluding


farmland
Incineration
Nitrogen loss during drying
Land fill
min
average
max

0.99
0
8%
0.002
0.0082
0.016

CH4 average
Land fill cover
N2O emissions
NH3 emissions

0.017
1.40%
1.60%

Composting
N2O emissions
CH4 emissions
Total N loss
NH3 emissions

2%
0.75%
30%
66%

Indirect N2O emissions from composting


Weight reduction during composting
C-loss during composting

0.0157
50%
20%

Reed beds

#DIV/0!
#DIV/0!

Emissions from screenings handling


LHV (lower heat value) in screenings (per 10%)
Share of plastic in screenings
g C/kg plastic waste

2.05
20%
644

amount CO2 which is generated per C (corresponding to 100% conversion)


kg fossil CO2/kg screenings

3.67
0.473

Emissions from sand handling


Sand (silica)

0.0174

Carbon sequestration
COD in sludge
Carbon in paper (in screenings)
Carbon reduction during composting of digested sludge
Carbon sequestration
Min
Average

44.8%
87%
30%
0
0.1

Max

0.2

Emissions in recipient
CH4 emissions
Effluent wastewater to sea/lake/estuary
min
Used value
max
N2O emissions
Effluent wastewater to lake/estuary
Effluent wastewater to sea/lake/estuary

0
0
0.025
0.0005
0.003

Bold values are standard values used in the calculations

ton/GWh
ton/GWh
ton/GWh
ton/GWh
ton/GWh
ton/GWh
ton/GWh
ton/GWh
ton/GWh

ton/GWh
ton/GWh
ton/GWh
ton/GWh
ton/GWh
ton/GWh

MWh el/MWh cooling

g CO2e/MJ
ton CO2e/GWh
g CO2e/MJ
ton CO2e/GWh
g CO2e/MJ
ton CO2e/GWh
g CO2e/MJ
ton CO2e/GWh

kg CH4/kg burned CH4


kg CH4/kg burned CH4
kg CH4/kg burned CH4

g N2O/kg burned CH4


g N2O/kg burned CH4
g N2O/kg burned CH4
g N2O/kg burned CH4

g CH4/kg burned CH4

kWh/Nm3
kWh diesel/Nm3, km
kWh/Nm3
g/Nm3
g CO2/g C3H8

%
%
%
kWh/Nm3 upgraded biogas
kWh/Nm3 upgraded biogas
kWh/Nm3 upgraded biogas

kg CO2e/kg methanol
kg CO2e/kg ethanol
kg CO2e/kg acetic acid
kg CO2e/kg isopropanol
kg CO2e/kg mosstanol
kg CO2e/kg glycerin

kg CH4/kg CODinfluent
kg CH4/kg CODinfluent

kg N2O/kg NH4-Ninfluent
% N2O of Ninfluent
% N2O of Ninfluent
kg N2O/kg NH4-Nreduced
kg N2O/kg Nreduced
kg N2O/kg Nreduced
kg N2O/kg Nreduced
kg N2O/kg Nreduced

kg N2O/kg Ndenitrified
kg N2O/kg Ndenitrified
kg N2O/kg Ndenitrified
g CH4/m3 , 35C

kWh/ton TS
kWh/ton TS
kWh/ton TS
kWh/ton TS
kWh/ton TS

MJ/ton (TS 25%)


MJ/ton (TS 33%)
MJ/ton (TS 60%)

kWh/ton TS waste
l diesel/ton TS waste
Nm3/ton VS

kWh/ton TS sludge
l/ton TS sludge
l/ton TS sludge

kWh/m3 sludge

liters/10 km
liters/10 km
GJ/m3
kg CO2e/GJ
kg CO2e/10 km
kg CO2e/10 km

of N-tot in sludge
of N-tot in sludge
Nm3/ton VS, h
of N-tot in sludge
kg C/ton VS, h

MJ diesel/ton TS
kg/ton TS

MJ diesel/ton TS
MJ diesel/ton synthetic fertilizer
kg/ton TS
kg/ton synthetic fertilizer

of N-tot in compost
of N-tot in sludge
of N-tot in sludge
kg N2O-N/kg emitted NH3-N
of N-tot in sludge
kg N2O-N/kg N applicated synthetic fertilizer
kg N2O/kgNH3-N
kg CH4/kg TS applicated
kg CH4/kg TS applicated
kg CH4/kg TS applicated
kg CH4/kg TS applicated
kg CO2e/kg
kg CO2e/kg
kg CO2e/kg
kg CO2e/kg
kg CO2e/kg
kg CO2e/ton
kg CO2e/ton
kg CO2e/ton

%
%
%

%
%
%
%
%

kg N2O/ton dried sludge


kg CH4/kg dried waste
% of N-tot in sludge
kg N2O/kg N applicated
kg N2O/kg N applicated
kg N2O/kg N applicated
kg CH4/kg VS organic material in the land fill
of N-tot in compost
of N-tot in compost

% of total N loss
% of C-tot
% of total N loss during composting
% of total N loss
kg N2O/kg NH3

kg N2O/kg TS sludge
kg CH4/kg TS sludge

MJ/ton
g C/kg plastic
kg CO2/kg fossil carbon
kg CO2/kg TS screenings

kg CO2e/ton

of TS

kg C/kg C-applicated
kg C/kg C-applicated

kg C/kg C-applicated

kg CH4/COD in effluent wastewater


kg CH4/COD in effluent wastewater
kg CH4/COD in effluent wastewater
kg N2O/kg N in effluent wastewater
kg N2O/kg N in effluent wastewater

he calculations
Reference
Elforsk (2008)
Kimming and Sundberg (2011). 30 % renewables year 2020. 70 % of 500 ton/GWh --> 350 ton/GWh
Elforsk (2008)
Elforsk (2008)
Elforsk (2008)
Gode et al. (2011), table 75
Gode et al. (2011), table 75
Gode et al. (2011), table 75
Gode et al. (2011), table 75
Reference
Gode et al. (2011) table 70
Gode et al. (2011) table 67
Gode et al. (2011) table 67
Gode et al. (2011) table 67
Gode et al. (2011) table 67
Reference
Atterhg (2008)
Reference
Gode et al. (2011) table 67
Gode et al. (2011) table 49
Gode et al. (2011) table 53
Gode et al. (2011) table 67

Fruergaard and Astrup (2010)


Brown et al. (2010)
Doka (2003) according to Foley et al. (2010b)

Fruergaard and Astrup (2010)


Brown et al. (2010)
Doka (2003) according to Foley et al. (2010b)
Fruergaard and Astrup (2010)

Fruergaard and Astrup (2010)

SGC (2013)

Avfall Sverige Utveckling (2009)

Benjaminsson and Nilsson (2009)


Benjaminsson and Nilsson (2009)
Benjaminsson and Nilsson (2009)
Benjaminsson and Nilsson (2009)
Ecoinvent database 2.0

SGC (2013)
SGC (2013)
SGC (2013)

Reference
Calculations for emissions at respiration during denitrification can be found in the sheet "GWP and
constants"

By product

Gustavsson and Tumlin (2012)


STOWA (2010)

Bjrlenius (1994)
Bjrlenius (1994)
Bjrlenius (1994)
Gustavsson and la Cour Jansen (2011)
Joss et al. (2009)
Weissenbacher et al. (2010)
Kampschreur et al. (2009b)
Christensson et al. (2011)

Foley et al. (2010b) and Foley et al. (2008)


Foley et al. (2010b) and Foley et al. (2008)
Foley et al. (2010b) and Foley et al. (2008)
de Haas et al. (2008)

Reference
Balmr (2012)
Balmr (2012)
average value of C104 and C105
Balmr (2012)
la Cour Jansen et al. (2007)
stlund (2003). page 8
stlund (2003). table 4, according to Stockholm
stlund (2003). table 4, according to Stockholm
IPCC (2006c) Part 3 Waste Incineration, page 458, chapter 1.1.4
stlund (2003). table 1
stlund (2003). table 1
Reference
Manfredi et al. (2009), calculated from 30 % TS
Manfredi et al. (2009), calculated from 30 % TS
Davidsson (2007), Gabriel et al. (2003)
CCME (2009)
Manfredi et al. (2009)
Manfredi et al. (2009)
CCME (2009)
Reference
Kirkeby et al (2009)
Kirkeby et al (2009)
Kirkeby et al (2009)
Reference
Uggetti et al. (2012)
Reference
Andersson (2005)
Andersson (2005)
Gode et al. (2011)

Reference
Willn et al. (2011)
Hther et al (1997) i Kirkeby et al. (2005), storage during 4 months
Gabriel et al. (2003)
Kirkeby et al. (2005), storage during 4 months
Gabriel et al. (2003)
Reference
Johansson et al. (2008)
Gode et al. (2011)

Johansson et al. (2008)


Johansson et al. (2008)
Calculation
Calculation

Bruun & Stoumann Jensen (2005) i Kirkeby et al. (2005)


IPCC (2006b); table 11.1
IPCC (2006b); table 11.3
IPCC (2006b); table 11.1
IPCC (2006b); table 11.3
IPCC (2006b); table 11.1
IPCC (2006b); table 11.3
de Haas et al. (2008)
IPCC (2006b)
de Haas et al. (2008)
Assumed that there is no COD in synthetic fertilizer
Used value
Jenssen & Kongshaug (2003)
Jenssen & Kongshaug (2003)
Yara AB (2013)
Jenssen & Kongshaug (2003)
Hagberg and Homberg (2008)
Boldrin et al. (2009)

Boldrin et al. (2009)


Boldrin et al. (2009)

Foley et al. (2010b)


Foley et al. (2010b)
Hospido et al. (2008); Peters and Rowley (2008)

Assuming the same as in sludge


Jnsson (2012)
Boldrin et al. (2009)
Assuming the same as in compost
Boldrin et al. (2009)

Reference
IPCC (2006) chapter 5 table 5.7
IPCC (2006) chapter 5 table 5.7
Sahln et al. (2011)
de Haas et al. (2008)
de Haas et al. (2008)
de Haas et al. (2008)
Davidsson (2007), CCME (2009)
Kirkeby et al. (2005)
Kirkeby et al. (2005)

Kirkeby et al. (2005)


Kirkeby et al. (2005)
Vogt et al. (2002)
Boucher et al. (1999)
IPCC (2006b); table 11.1
Assumed value
Uggetti et al. 2012
Uggetti et al. 2012
Reference
Bengtsson (2013)
Assumed
Bjarnasdottir et al. (2003) table 3.3
Bjarnasdottir et al. (2003)

Reference
Ecoinvent database 2.0

Reference

Boldrin et al. (2009)


Foley et al. (2010)
Foley et al. (2010)

Foley et al. (2010)


Reference

IPCC (2006a) table 6.2 and 6.3


IPCC (2006a) table 6.2 and 6.3
IPCC (2006a) table 6.2 and 6.3
Foley et al. (2008)
Foley et al. (2008)

350 ton/GWh

Production of chemicals
Carbon sources
Methanol
Ethanol (25%)
Sekundol 70 - heads
Sekundol 85
Mosstanol L
Acetic acid

744 kg CO2e/ton
671 kg CO2e/ton
2146 kg CO2e/ton
2146 kg CO2e/ton
1455 kg CO2e/ton
1750 kg CO2e/ton

Glycerine
Coagulants
FeSO4

3560 kg CO2e/ton

Quickfloc (FeSO4)

0 kg CO2e/ton
0 kg CO2e/ton

COP (FeSO4)
FeClSO4
PIX-118, 318
Fe2(SO4)3

82 kg CO2e/ton

PIX-113
FeCl3

153 kg CO2e/ton

PIX-111, Plusjrn S 314

145 kg CO2e/ton
145 kg CO2e/ton

PIX-110
AlFeCl
Ekomix 1091

420 kg CO2e/ton

PAC
PAX-18, Ekoflock 90
PAX-15, XL61
PAX-XL100
PAX-215
Alcalinity

455 kg CO2e/ton
379 kg CO2e/ton
470 kg CO2e/ton
110 kg CO2e/ton

CaO
Ca(OH)2

322 kg CO2/ton
243 kg CO2/ton

CaCO3

900 kg CO2/ton
1096 kg CO2/ton

NaOH 50 %
Polymers
Polymers from SNF
Nerolan CG144, CG147X
Other chemicals

805 kg CO2e/ton polymer


805 kg CO2e/ton polymer

Activated carbon - fossil origin

1190 kg CO2/ton
2370 kg CO2/ton

Octanol
Nitric acid (HNO3)

353 kg CO2/ton
551 kg CO2/ton

Ion exchange salt

110 kg CO2/ton
1417 kg CO2/ton

Activated carbon - biogenic origin

Phosphoric acid 75 %

Sulfuric acid (H2SO4), Swedish origin


Hydrogen peroxide (H2O2), 50 % i H2O

30 kg CO2e/ton
1060 kg CO2e/ton

Lithium chloride

602 kg CO2e/ton
kg CO2e/ton

Anti foaming agent Citru-Ren

kg CO2e/ton

Hydrogen chloride (HCl)

kg CO2e/ton

Sodium hypochlorite (NaClO)


Citric acid

890 kg CO2e/ton
730 kg CO2e/ton

Other chemicals

kg CO2e/ton

Other chemicals

kg CO2e/ton

Other chemicals

kg CO2e/ton

Other chemicals

kg CO2e/ton

Other chemicals

kg CO2e/ton

Other chemicals

kg CO2e/ton

Propane

Reference

Comments

EcoInvent Database 2.0


Perstorp
EcoInvent Database 2.0
EcoInvent Database 2.0
EcoInvent Database 2.0
EcoInvent Database 2.0
EcoInvent Database 2.0

Kronos Titan (2012)

By-product

Kronos Titan (2012)

By-product

Kemira (2013)
Kemira (2013)

Kemira (2013)
Data from Kemira. report, U-704, from IVL 2003.
Assumed to be the same as for Kemira (2011)

Kemira (2013)
Kemira (2013)
Kemira (2013)
Data from Kemira. report, U-735, from IVL 2003.
Nordkalk (2012)
Nordkalk (2012)
Brown et al. (2010) based on Carnegie Mellon Green
Design Inst. Available on p www.eiolca.net
(Downloaded 28th of August 2010).
Simapro 7 (2011)
SNF Nordic (2011)
Afridana (2012)
EcoInvent Database 2.0 according to Swedish HBK
EcoInvent Database 2.0 according to Swedish HBK
Approximation in relation to Pentanol in EcoInvent Database 2.0, according to Swedish HBK
Yara (2010)
Krger Aqua (2012)
EcoInvent Database 2.0

Data from Kemira according to Swedish HBK


per 100 % H2O2. EcoInvent Database 2.0 according to Swedish HBK
EcoInvent Database 2.0

IPCC AR5
IPCC AR5

GWP and constants


Global warming potentials (GWP)
Carbon dioxide - 20 year
Carbon dioxide - 100 year
Carbon dioxide - 500 year
Methane - 20 year
Methane - 100 year

Reference:
kg
CO
/kg
CO
1
Forster et al. (2007)
2e
2
kg
CO
/kg
CO
1
2e
2 Forster et al. (2007)
1 kg CO2e/kg CO2 Forster et al. (2007)
86 kg CO2e/kg CH4 IPCC (2013)
34 kg CO2e/kg CH4 IPCC (2013)

Nitrous oxide - 100 year

7.6 kg CO2e/kg CH4 Forster et al. (2007)


268 kg CO2e/kg N2O IPCC (2013)
298 kg CO2e/kg N2O Forster et al. (2007)

Nitrous oxide - 500 year

153 kg CO2e/kg N2O Forster et al. (2007)

Methane - 500 year


Nitrous oxide - 20 year

Convertion factors for energy


1 liter Diesel = MJ

35.2

Miljfaktaboken, 2001 table 4.1

1 liter fuel oil = MJ

35.9

Miljfaktaboken, 2001 table 4.1

1 kWh =

3.6 MJ

Energy conversion efficiency


Gas boiler

91% %

Dansih Energy Agency (2010). Technology h

Gas engine

42% %

Dansih Energy Agency (2010). Technology h

Energy data
Energy content in propane
Density propane
Energy content in methane
Density methane
Density CO2
Density in biogas
Energy content in oil
Energy content in natural gas

46.44 MJ/kg
2011 g/m3
9.97 kWh/m
717 g/m

Svenskt Gastekniskt Center (www.sgc.se)


3

Biogasportalen (www.biogasportalen.se)

Svenskt Gastekniskt Center (www.sgc.se)

1978 g/m
1978 g/m3

Svenskt Gastekniskt Center (www.sgc.se)


Svenskt Gastekniskt Center (www.sgc.se)

37.25 kWh/m3

Energihandbok (www.energihandbok.se)

11 kWh/Nm3

Biogasportalen (www.biogasportalen.se)

Correction factor for N2O-N


N2O = 28 + 16 = 44 g

1.57

1 g N = 44/28 g N2O = 1,57


Correction factor for NH3-N
NH3 = 14 + 3 = 17 g

1.21

1 g N = 17/14 g NH3 = 1.21


Correction factor for CH4-C
CH4 = 12 + 4 = 16 g

1.33

1 g C = 16/12 g CH4 = 1.21


Correction factor for COD-C
Correction factor for COD-VS
Molar ratio C-CO2

0.37 kg C/kg COD


1.48 kg COD/kg VS

University of Cape Town, City Council of Joha

3.67

Theory, Design and Operation of Nutrient Re

Respiration calculations
1. 6 NO3- + 5 CH3OH + 10 H+ 3 N2 + 5 CO2 + 13 H2O
MW 6*62

5*32

10*1

3*28

5*44

13*18

1 mol MeOH 1 mol CO2


44/32 = 1,375
1,375 kg CO2e/kg MeOH
2. 4 NO3- + 2 C2H5OH + 5 H+ 2 N2 + 4 CO2 + 6 H2O
MW 4*62

2*46

5*1

2*28

4*44

6*18

1 mol EtOH 2 mol CO2


(44*4)/(46*2) = 1,913
1,913 kg CO2e/kg EtOH
3. 2 NO3- + CH3COOH + 4 H+ N2 + 2 CO2 + 4 H2O
MW 2*62

1*60

4*1

1*28

2*44

4*18

1 mol acetic acid 2 mol CO2


(44*2)/(60) = 1,467
1,467 kg CO2e/kg acetic acid
4. 4 NO3- + C3H7OH + 13 H+ 2 N2 + 3 CO2 + 7 H2O
MW 4*62

1*60

13*1

2*28

3*44

7*18

1 mol isopropanol 3 mol CO2


(44*3)/(60) = 2,200
2,200 kg CO2e/kg isopropanol
4. 4 NO3- + C3H7OH + 13 H+ 2 N2 + 3 CO2 + 7 H2O
MW 4*62

1*60

13*1

2*28

3*44

7*18

1 mol glycerine 3 mol CO2


(44*3)/(60) = 2,200
2,200 kg CO2e/kg glycerine
External organic material

TS (%)

VS (% of TS)

COD (kg/ton)

N-tot (g/kg TS)

Household waste

33

84.8

414

27

Grease trap waste

17.3

98.3

252

24

No data

100

No data

No data

Glycerine

Nutrients in digested sludge


Nitrogen

Min (kg/ton
TS)
Max (kg/ton TS)

Mean (kg/ton
TS)
Reference

21.8

57.7

49.7

Phosphorus

11

46

28.6

Potassium

0.7

12.6

3.5

Nine Swedish WWTPs year

cy (2010). Technology handbook for power plants.

cy (2010). Technology handbook for power plants.

Center (www.sgc.se)

w.biogasportalen.se)
Center (www.sgc.se)
Center (www.sgc.se)
Center (www.sgc.se)

w.energihandbok.se)

w.biogasportalen.se)

own, City Council of Johannesburg, and National Institute for Water Research of the CSIR. (1984).

Operation of Nutrient Removal Activated Sludge Processes. Water Research Commission, Pretoria.

P-tot (mg/kg TS) Reference


400

Davidsson et al. (2007). Methane yield in source-sorted organic fraction of municipal solid waste. Metha

No data

Davidsson et al. (2008). Co-digestion of grease trap sludge and sewage sludge. Waste Management, 2

No data

SGC (2009), Substrathandboken. Rapport SGC 200.

e Swedish WWTPs year 2010 and 2011. Gustavsson & Tumlin (2013)

nic fraction of municipal solid waste. Methane yield in source-sorted organic fraction of municipal solid waste. Waste management, 28,

nd sewage sludge. Waste Management, 28, pp. 986-992.

aste. Waste management, 28, pp. 406-414.

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Davidsson, ., Gruvberger, C., Christensen, T.H., Lund Hansen och la Cour Jansen, J. (2007). Methane yield in source-sor
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de Haas, D., Foley, J. och Barr, K. (2008). Greenhouse gas inventories from WWTPs the trade-off with nutrient removal. I
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eport_1432.pdf.

ession 10 , pp. 265-282.

Input data
Input data needed in the calculation tool is presented in the table below. Grey cells means that
there are literature values to choose from if input data from the WWTP is missing. Input data that
are very important for the results are shown in bold style.

Process

Parameter

Influent wastewater (sheet 2)

Flow

Wastewater treatment
(sheet 2)

Load COD, BOD, N and P


Emissions of methane wastewater treatment
Emissions of nitrous oxide wastewater
Amount of external organic material1
TS, VS, N, P, BOD and COD in external material
Emissions of methane from sludge treatment
(excl biogas)
Emissions of nitrous oxide from sludge
treatment (excl biogas)
Sludge liquor flow

Recipient
(sheet 2)
Use of chemicals
(sheet 3)
Energy (sheet 4)

Removed amount of nitrogen at sludge liquor


Kind of sludge liquor treatment process
Ntot, Ptot, BOD and COD in effluent wastewater
Kind of recipient (sea of lake/estuary)
Used chemicals (incl. external carbon sources
and polymers)
Transport distance from chemical distributor to
Number of deliveries per year
Total electricity use
Total purchased electricity
Share of purchased electricity that is
Exported electricity from internal production
Internally produced electricity from other
sources than wastewater/biogas
Total heat use
Total purchased heat
Exported heat from internal production
Internally produced heat from other sources
than wastewater/biogas
Local emission factor for heat
Used cooling
Purchase cooling
Produced cooling at WWTP
Heat factor for heat exchanger of effluent
wastewater

Biogas use (sheet 4)

Total heat production by heat exchangers


Produced biogas
Methane content in biogas

Biogas use (sheet 4)


Biogas emissions (upgrading excluded)
Torched biogas
Direct emission of biogas to atmosphere
Used biogas in gas engine and gas boiler
Upgraded amount of biogas that has been
compressed and transported on truck
Upgraded amount of biogas for grid injection
Transport distance for compressed biogas on truck
Added propane gas
Energy use during upgrading
Methane emissions during upgrading
Transports (sheet 5)

Sludge handling
(sheet 6)

Waste handling
(sheet 6)

Transport of sludge to different applications


Transport of screenings/sand/ashes
All transports - number of times per year
Number of days for storage of digested
Amount of dewatered digested sludge
TS-content in sludge before storage
VS-content in sludge before storage
Ntot, Ptot, K and Ctot before storage
Ntot, Ptot, K and Ctot after storage
Share of sludge to farmland/incineration/land
fill/reed beds
Volume reduction after reed bed treatment
Amount of screenings
TS-content in screenings
TS-content in screenings for incineration
Amount of sand
Share of screenings for incineration/land
Share of sand to recycling/land fill

1 Data for organic material can be found in the sheet GWP and constans if data for the WWTP is missing.

Grey cells means that


missing. Input data that

Unit
m3/h
ton/year
ton CH4/year
ton N2O/year
ton/year
% or ton/year
ton CH4/year
ton N2O/year
m3/h
ton/year
ton/year
ton/year
km
No
MWh
MWh
%
MWh
MWh
MWh
MWh
MWh
MWh
g CO2e/kWh
MWh
MWh
MWh
kWh heat
/kWh
MWh
Nm3
%

Nm3
Nm3
Nm3
Nm3
Nm3
Nm3
km
ton
kWh
Nm3
km
km
No
No of days
ton/year
%
% av TS
kg/ton TS
kg/ton TS
%
%
ton/year
%
%
ton/year
%
%

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