Professional Documents
Culture Documents
H I G H E R S C H O O L C E R T I F I C AT E
E X A M I N AT I O N
Chemistry
Section I
Pages 220
75 marks
This section has two parts, Part A and Part B
Part A 15 marks
Attempt Questions 115
Allow about 30 minutes for this part
Part B 60 marks
Attempt Questions 1626
Allow about 1 hour and 45 minutes for this part
Section II
Pages 2133
25 marks
Attempt ONE question from Questions 2731
Allow about 45 minutes for this section
115
Section I
75 marks
Part A 15 marks
Attempt Questions 115
Allow about 30 minutes for this part
Use the multiple-choice answer sheet for Questions 115.
Blue
(C)
Green
(D) Orange
The apparatus shown is used in a first-hand investigation to determine and compare the
heat of combustion of three different liquid alkanols.
Thermometer
Beaker of water
Gauze mat
Tripod
Spirit burner
with alkanol
Which is the independent variable?
(A) Type of alkanol used
(B)
(C)
(C) H2SO4
(D) HSO3
Three separate colourless solutions each contain one cation, Na+, Pb2+ or Ca2+.
Which of the following would be an appropriate reagent to unambiguously identify
the solution containing Pb2+ ?
(A) KI
(B) K2CO3
(C) K3PO4
(D) AgNO3
One test used for random breath testing in NSW involved crystals of potassium
dichromate reacting with ethanol. In this reaction the orange dichromate ion, Cr2O72,
changes to the green chromium ion, Cr 3+.
Which statement is true for this reaction?
(A) Chromium has lost electrons and reached a lower oxidation state.
(B) Chromium has lost electrons and reached a higher oxidation state.
(C) Chromium has gained electrons and reached a lower oxidation state.
(D) Chromium has gained electrons and reached a higher oxidation state.
10
Which of the following is the main organic product resulting from the reaction of
butanoic acid and pentanol?
O
(A) H3CH2CH2CC
OCH2CH2CH2CH3
O
(B)
H3CH2CH2CC
OCH2CH2CH2CH2CH3
O
(C)
H3CH2CH2CH2CC
OCH2CH2CH2CH2CH3
O
(D) H3CCH2CH2CH2CH2C
OCH2CH2CH2CH3
11
Step 2
Step 3
Step 4
Step 5
Screening
Chlorination
Step 3
Step 4
(A)
Flocculation
pH adjustment
Settling
(B)
pH adjustment
Flocculation
Settling
(C)
pH adjustment
Settling
Flocculation
(D)
Flocculation
Settling
pH adjustment
12
CH3 H
Cl
Cl
CH3
(A) 3,4dichloro2fluorohexane
(B) 3,4dichloro5fluorohexane
(C) 2fluoro3,4dichlorohexane
(D) 5fluoro3,4dichlorohexane
13
14
Citric acid, the predominant acid in lemon juice, is a triprotic acid. A student titrated
25.0 mL samples of lemon juice with 0.550 mol L1 NaOH. The mean titration volume
was 29.50 mL. The molar mass of citric acid is 192.12 g mol1.
What was the concentration of citric acid in the lemon juice?
(A) 1.04 g L1
(B) 41.6 g L1
(C) 125 g L1
(D) 374 g L1
The graph shows the maximum dissolved oxygen concentration in water as a function of
temperature at normal atmospheric pressure.
O2 Concentration (mg L1)
15
14
12
10
8
6
0
10 15 20 25
Temperature (C)
30
35
What is the volume of O2 that can dissolve in 10.0 L of water at 25C and normal
atmospheric pressure?
(A) 62.0 mL
(B)
63.5 mL
(C)
80.0 mL
(D) 124 mL
BLANK PAGE
Chemistry
Centre Number
Section I (continued)
Part B 60 marks
Attempt Questions 1626
Allow about 1 hour and 45 minutes for this part
Student Number
Question 16 (3 marks)
Describe how to prepare an ester in the school laboratory. Include a specific safety
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
116
Question 17 (4 marks)
Water and ethanol are both used as solvents.
Explain the differences and similarities in their solvent behaviour in terms of their
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
10
Chemistry
Centre Number
Question 18 (5 marks)
There has been an increase in the concentration of the oxides of nitrogen in the
atmosphere as a result of combustion.
Assess both the evidence to support this statement and the need to monitor these
oxides.
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
........................................................................................................................................
116a
11
Question 19 (6 marks)
Outline the chemical and physical processes involved in the production of ONE of the
following from a natural raw material:
a polyethylene bottle
a polyvinyl chloride pipe
a polystyrene cup.
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
12
Chemistry
Centre Number
Question 20 (4 marks)
(a)
Calculate the mass of ethanol that must be burnt to increase the temperature of
210 g of water by 65C, if exactly half of the heat released by this combustion
is lost to the surroundings.
What are TWO ways to limit heat loss from the apparatus when performing a
first-hand investigation to determine and compare heat of combustion of
different liquid alkanols?
...............................................................................................................................
...............................................................................................................................
117
13
Question 21 (6 marks)
The graph shows changes in pH for the titrations of equal volumes of solutions of two
monoprotic acids, Acid 1 and Acid 2.
14
12
Acid 1
pH
10
Acid 2
8
6
4
2
0
(a)
10
20
30
40
50
Volume of KOH(aq) (mL)
60
Explain the differences between Acid 1 and Acid 2 in terms of their relative
strengths and concentrations.
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
(b)
Name the salt produced by the reaction of an acid of the same type as Acid 2
with KOH(aq).
...............................................................................................................................
(c)
...............................................................................................................................
...............................................................................................................................
(d)
...............................................................................................................................
14
Chemistry
Centre Number
Question 22 (7 marks)
The nitrogen content of bread was determined using the following procedure:
A sample of bread weighing 2.80 g was analysed.
The nitrogen in the sample was converted into ammonia.
The ammonia was collected in 50.0 mL of 0.125 mol L1 hydrochloric acid. All of
the ammonia was neutralised, leaving an excess of hydrochloric acid.
The excess hydrochloric acid was titrated with 23.30 mL of 0.116 mol L1 sodium
hydroxide solution.
(a)
Write balanced equations for the TWO reactions involving hydrochloric acid.
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
(c)
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
118
15
Question 23 (6 marks)
The graph shows the variation in concentration of reactant and products as a function
of time for the following system.
COCl2(g) Cl2(g) + CO(g)
H = + 108 kJ
0.14
Cl2
0.12
0.10
CO
0.08
0.06
COCl2
0.04
0.02
0.00
8
10 12
Time (min)
14
16
18
Identify and explain each of the changes in conditions that have shaped the curves
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
16
Chemistry
Centre Number
Question 24 (5 marks)
Describe the principle of atomic absorption spectroscopy and its application in
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
.........................................................................................................................................
........................................................................................................................................
119
17
Question 25 (7 marks)
An analytical chemist determined the phosphate concentration of water samples from
three local streams.
Using the absorbance values in the table and graph, determine the mean
absorbance and mean phosphate concentration for each stream and complete the
table.
Stream
Absorbances
measured
Mean
absorbance
Mean phosphate
concentration (mg L1)
0.600
0.500
Absorbance
(a)
0.400
0.300
0.200
0.100
0.000
0.000
0.050
0.100
0.150
18
0.200
Question 25 (continued)
(b)
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
(c)
End of Question 25
19
Question 26 (7 marks)
An electrochemical cell is constructed using two half cells. One half cell consists of
an inert platinum electrode and a solution of Fe2+ and Fe3+. The other half cell consists
of a lead electrode and a solution of Pb2+.
Current will flow from one electrode to the other electrode when the cell is completed
using a voltmeter and a salt bridge.
(a)
Write relevant half equations and a balanced net ionic equation for the overall
cell reaction.
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
...............................................................................................................................
(c)
Identify the anode, cathode, metals and ions by labelling the following diagram.
e
V
(d)
...................
...................
...................
...................
20
Chemistry
Section II
25 marks
Attempt ONE question from Questions 2731
Allow about 45 minutes for this section
Answer the question in a writing booklet. Extra writing booklets are available.
Show all relevant working in questions involving calculations.
Pages
120
Question 27
Question 28
Question 29
Question 30
Question 31
21
(b)
Sulfuric acid is one of the worlds most significant industrial chemicals because
of the variety and importance of its uses.
(i)
(ii)
Outline the industrial process for the manufacture of sulfuric acid from
its raw materials.
(iii)
Account for the safety precautions associated with the industrial transport
of sulfuric acid.
H = 240 kJ
Initially 0.35 mol of ICl3(g) was introduced into a 1.0 L container and allowed
to come to equilibrium. At equilibrium there was 0.45 mol L1 of Cl2(g).
(i)
(ii)
(iii)
22
Question 27 (continued)
(c)
(d)
(e)
(i)
(ii)
Soap is one product of saponification. Name the other product and draw
its structural formula.
use
raw materials
production
waste
End of Question 27
23
Tins and cans are used to store a range of foods, beverages and general
household chemicals.
ZOOL
LA
O
C
in vinegar
Tun
rin
b
a in
(i)
(ii)
(b)
Galvanising is used outside the home on water tanks and fencing. Explain the
protection provided to iron by galvanising.
(c)
(ii)
The owners have decided to replace the guttering. They have steel screws
and a choice of aluminium or copper guttering.
Justify the course of action the owners should take, based on chemical
principles.
24
Question 28 (continued)
(d)
(i)
Power supply
Stainless steel
electrode (or mesh)
Iron artefact
Sodium hydroxide
solution
Explain how this process is used to conserve this iron artefact.
Describe, with the aid of a diagram, how a nickel spoon could be
silver-plated using equipment available in a school laboratory.
(ii)
(e)
Galvani
suggests
animal electricity
Volta makes
first battery
Davy
isolates
alkali metals
Faraday develops
laws of
electrolysis
With reference to the flowchart, describe how the work of the scientists led to
a better understanding of electron transfer reactions.
End of Question 28
25
(b)
(i)
(ii)
3.0
4.0
5.0
6.0
7.0
8.0
colourless
light
red
medium
red
dark
red
dark
red
colourless
26
Question 29 (continued)
(c)
The following energy diagram shows the energy change associated with the
combustion of glucose in kJ mol1 during cellular respiration.
181 kJ mol1
Energy
Reactants
2997 kJ mol1
Products
Progress of reaction
(i) Write a balanced chemical equation for the combustion of glucose.
Include the energy released per mole of glucose.
(d) Analysing the structure of the glycerol molecule helps explain many of its
properties.
(e)
(ii) Explain the solubility of both fatty acids and triacylglycerols in water in
terms of their molecular structures.
glycogen
ATP
production
muscle
cell contraction
muscle fatigue
and cramping
(i)
O
C
CH2
CH2
CH2
CH2
CH2
C
O
O
EDTA
(ii) With reference to EDTA, explain what is meant by the term polydentate
ligand.
(iii) Using copper as the ion and EDTA as the ligand, explain how bonding
occurs between a metal ion and a ligand.
28
Question 30 (continued)
(b)
(i)
(ii) Write the full electron configurations for a Ca atom in the ground state,
an excited Ca atom and a Ca+ ion.
(c)
1
2
2500
2000
1500
1000
500
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19
Atomic Number
Account for the trends in the graph in terms of the electron configuration of the
elements.
(d)
(i)
Gustav Kirchhoff formulated a law that states that a hot gas produces
light with spectral lines at discrete wavelengths.
29
Question 30 (continued)
(e)
refined
mineral
synthetic
inorganic
synthetic
organic
End of Question 30
30
(i)
CH3
CH2
SH
Alanine
Cysteine
31
Question 31 (continued)
(b) An oil spill occurred at a shipping port. To determine which ship was
responsible, a sample of the oil was collected and analysed by gas
chromatography. Samples of bunker oil were collected from three ships in port
at the time and analysed by gas chromatography.
The chromatograms of the samples collected are shown.
Signal
intensity
Ship A sample
3 4 5 6 7
Retention time / mins
Signal
intensity
Ship B sample
3 4 5 6 7
Retention time / mins
Signal
intensity
10
Ship C sample
3 4 5 6 7
Retention time / mins
Signal
intensity
10
(c)
10
3 4 5 6 7
Retention time / mins
10
(i)
(ii)
Question 31 (continued)
(d)
(e)
(i)
(ii)
sample
collection
initial examination
and classification
of material
instrumental
analysis
interpretation
of results
to a non-scientist
You are the forensic chemist investigating a crime scene and collecting samples.
With reference to the flowchart, describe how you would process the sample and
present the results. Illustrate your answer with relevant tests and appropriate
analyses.
End of paper
33
BLANK PAGE
34
BLANK PAGE
35
BLANK PAGE
36
Chemistry
DATA SHEET
Avogadro constant, NA .................................................................. 6.022 1023 mol1
Ionisation constant for water at 25C (298.15 K), Kw ................. 1.0 1014
Ba
Ca
K(s)
2.94 V
+ 2e
Ba(s)
2.91 V
+ 2e
Ca(s)
2.87 V
Na(s)
2.71 V
Mg(s)
2.36 V
Al(s)
1.68 V
Na + e
Mg
+ 2e
2+
3+
Al
+ 3e
Mn2+ + 2e
Mn(s)
H2O + e
12 H2(g) + OH
+ 2e
Zn(s)
0.76 V
+ 2e
Fe(s)
0.44 V
Ni(s)
0.24 V
Sn(s)
0.14 V
2+
2+
+ 2e
2+
+ 2e
2+
+ 2e
Fe
Ni
Sn
Pb
H+ + e
2
SO4
Cu
2+
+ 4H + 2e
+ 2e
1
O
(g) + H2O
2
2
+
+ 2e
Cu + e
12
I2(s) + e
12 I2(aq) + e
3+
+e
Fe
Ag + e
12
Br2(l) + e
1
Br
(aq) + e
2
2
1
(g) + 2H+ + 2e
O
2
2
1
2 Cl2(g) + e
1
Cr
O 2 + 7H+ + 3e
2 2 7
12 Cl2(aq) + e
MnO4 + 8H+ + 5e
1 (g) + e
F
2 2
120a
0.83 V
2+
Zn
1.18 V
Pb(s)
0.13 V
12 H2(g)
0.00 V
SO2(aq) + 2H2O
0.16 V
Cu(s)
0.34 V
0.40 V
Cu(s)
0.52 V
2OH
0.54 V
0.62 V
Fe2+
0.77 V
Ag(s)
0.80 V
1.08 V
Br
1.10 V
H2O
1.23 V
Cl
1.36 V
Cr3+ + 72 H2O
1.36 V
Br
Cl
Mn
F
1.40 V
2+
+ 4H2O
1.51 V
2.89 V
Aylward and Findlay, SI Chemical Data (5th Edition) is the principal source of data for
this examination paper. Some data may have been modified for examination purposes.
37
38
56
Ba
137.3
Barium
88
Ra
[226]
Radium
55
Cs
132.9
Caesium
87
Fr
[223]
Francium
Rutherfordium
104
Rf
[261]
Hafnium
72
Hf
178.5
Zirconium
90
Th
232.0
Thorium
Actinoids
89
Ac
[227]
Actinium
Protactinium
91
Pa
231.0
Praseodymium
59
Pr
140.9
Dubnium
105
Db
[262]
Tantalum
73
Ta
180.9
Niobium
41
Nb
92.91
Vanadium
23
V
50.94
Uranium
92
U
238.0
Neodymium
60
Nd
144.2
Seaborgium
106
Sg
[266]
Tungsten
74
W
183.8
Molybdenum
42
Mo
95.94
Chromium
24
Cr
52.00
Neptunium
93
Np
[237]
Promethium
Plutonium
94
Pu
[244]
Samarium
62
Sm
150.4
Hassium
Bohrium
61
Pm
[145]
108
Hs
[277]
107
Bh
[264]
Americium
95
Am
[243]
Europium
63
Eu
152.0
Meitnerium
109
Mt
[268]
Iridium
Osmium
Rhenium
Rhodium
77
Ir
192.2
Ruthenium
45
Rh
102.9
Cobalt
Iron
44
Ru
101.1
27
Co
58.93
26
Fe
55.85
Gold
79
Au
197.0
76
Os
190.2
75
Re
186.2
Technetium
43
Tc
[97.91]
Manganese
25
Mn
54.94
Atomic Weight
Atomic Number
KEY
111
Rg
[272]
Gold
79
Au
197.0
Silver
47
Ag
107.9
Copper
29
Cu
63.55
Curium
96
Cm
[247]
Gadolinium
64
Gd
157.3
Berkelium
97
Bk
[247]
Terbium
65
Tb
158.9
Darmstadtium Roentgenium
110
Ds
[271]
Platinum
78
Pt
195.1
Palladium
46
Pd
106.4
Nickel
28
Ni
58.69
Name of element
Symbol of element
Californium
98
Cf
[251]
Dysprosium
66
Dy
162.5
Mercury
80
Hg
200.6
Cadmium
48
Cd
112.4
Zinc
30
Zn
65.41
Einsteinium
99
Es
[252]
Holmium
67
Ho
164.9
Thallium
81
Tl
204.4
Indium
49
In
114.8
Gallium
31
Ga
69.72
Aluminium
13
Al
26.98
Boron
5
B
10.81
Fermium
100
Fm
[257]
Erbium
68
Er
167.3
Lead
82
Pb
207.2
Tin
50
Sn
118.7
Germanium
32
Ge
72.64
Silicon
14
Si
28.09
Carbon
6
C
12.01
Mendelevium
101
Md
[258]
Thulium
69
Tm
168.9
Bismuth
83
Bi
209.0
Antimony
51
Sb
121.8
Arsenic
33
As
74.92
Phosphorus
15
P
30.97
Nitrogen
7
N
14.01
Nobelium
102
No
[259]
Ytterbium
70
Yb
173.0
Polonium
84
Po
[209.0]
Tellurium
52
Te
127.6
Selenium
34
Se
78.96
Sulfur
16
S
32.07
Oxygen
8
O
16.00
Argon
Chlorine
Lawrencium
103
Lr
[262]
Lutetium
71
Lu
175.0
Astatine
85
At
[210.0]
Iodine
53
I
126.9
Bromine
Radon
86
Rn
[222.0]
Xenon
54
Xe
131.3
Krypton
36
Kr
83.80
18
Ar
39.95
17
Cl
35.45
35
Br
79.90
Neon
10
Ne
20.18
Helium
2
He
4.003
Fluorine
9
F
19.00
For elements that have no stable or long-lived nuclides, the mass number of the nuclide with the longest confirmed half-life is listed between square brackets.
The International Union of Pure and Applied Chemistry Periodic Table of the Elements (October 2005 version) is the principal source of data. Some data may have been modified.
Cerium
Lanthanum
Lanthanoids
57
58
La
Ce
138.9
140.1
Actinoids
89103
Lanthanoids
5771
Yttrium
Strontium
Rubidium
40
Zr
91.22
39
Y
88.91
38
Sr
87.62
37
Rb
85.47
Potassium
Titanium
20
Ca
40.08
19
K
39.10
Scandium
Magnesium
Sodium
Calcium
12
Mg
24.31
11
Na
22.99
22
Ti
47.87
Beryllium
Lithium
21
Sc
44.96
4
Be
9.012
3
Li
6.941
Hydrogen
1
H
1.008