I.

II.
III.

TITLE OF EXPERIMENT : The Equilibrium Constant

EXPERIMENT DATE
: March, 28th 2016
THE PURPOSE
:
Determine the equilibrium constant of a reaction.
attention to the equilibrium constant not depend on the initial concentration of
the reaction

IV.

BASIC THEORY

The equilibrium constant, K, is an expression expressing the relationship

between products and reactants of a reaction at equilibrium with respect to a specific
unit. There are two different types from equilibrium reactions: (1) heterogeneous and
(2) homogeneous. Below we illustrate the difference between the two, explain how to
write equilibrium constants for both, and introduce calculations involved with both the
concentration and the pressure equilibrium constant.
Homogeneous
The simpler one, a homogeneous reaction, is one where the states of matter of
the products and reactions are all the same (homo=same). In most cases, the solvent
determines the state of matter for the overall reaction. For example, the synthesis of
methanol

from

a carbon

monoxide-hydrogen

mixture

is

a gaseous homogeneous mixture, which contains two or more substances:

CO(g) + 2H2(g)CH3OH(g)
At equilibrium, the rate of the forward and reverse reaction are equal, which is
demonstrated by the arrows. The K however tells you the ratio of the units (pressure or
concentration) when the reaction is at equilibrium.
The

synthesis

of

ammonia

is

another

example

of

a gaseous homogeneous mixture:

N2(g)+3H2(g) 2NH3(g)
Heterogeneous
A heterogeneous reaction is one where one or more states within the reaction
differ (heteros=different). For example, the formation of anaqueous solution of lead(II)
iodide

is

a heterogeneous mixture dealing with

the solid and aqueous states:

molecules

in

both

PbI2(s) Pb+2(aq)+2I(aq)
The decomposition of sodium hydrogen carbonate (baking soda) at high
elevations is another example of a heterogeneous mixture, this reaction deals with
molecules in both the solid and gaseous states:
2NaHCO3(s) Na2CO3(s)+H2O(g)+CO2(g)
C(s) +O2(g)CO2(g)
Writing an Expression for Kc
We are going to look at a general case with the equation:

No state symbols have been given, but they will be all (g), or all (l), or all (aq) if the
reaction was between substances in solution in water.
If you allow this reaction to reach equilibrium and then measure the equilibrium
concentrations of everything, you can combine these concentrations into an expression
known as an equilibrium constant.
The equilibrium constant always has the same value (provided you don't
change the temperature), irrespective of the amounts of A, B, C and D you started
with. It is also unaffected by a change in pressure or whether or not you are using a
catalyst.

Compare this with the chemical equation for the equilibrium. The convention
is that the substances on the right-hand side of the equation are written at the top of the
Kc expression, and those on the left-hand side at the bottom.
The indices (the powers that you have to raise the concentrations to - for example,
squared or cubed or whatever) are just the numbers that appear in the equation.

Kc in Homogeneous Equilibria
This is the more straightforward case. It applies where everything in the
equilibrium mixture is present as a gas, or everything is present in the same solution.
A good example of a gaseous homogeneous equilibrium is the conversion
of sulphur dioxide to sulphur trioxide at the heart of theContact Process:
A commonly used liquid example is the esterification reaction between
an organic acid and an alcohol - for example:

Kc in Heterogeneous Equilibria
Typical examples of a heterogeneous equilibrium include:
The equilibrium established if steam is in contact with red hot carbon. Here we have
gases in contact with a solid.
If you shake copper with silver nitrate solution, you get this equilibrium involving
solids and aqueous ions:

Factors That Affect Equilibrium Constant

Chemical equilibrium is a very delicate system that represents a perfect
balance between forward and reverse reaction. A small disturb in the equilibrium may
shift the equilibrium position either to right forming more products or to left forming
more reactants. This reaction by the system is of course temporary and eventually the
system will come back to equilibrium. This phenomenon can be expressed in the form
of Le Chateliers Principle.
Le Chateliers Principle
An important and very interesting qualitative principle governing the
equilibrium is the principle of Le Chatelier. This principle, which is named after the
French chemist Henry Louis Le Chatelier (1850-1936), may be stated as follows: if an
external stress is applied to a system at equilibrium, the system will tend to react in

such way as to relieve the applied stress and tries to reestablish the equilibrium. In
chemical reaction terminology, the stress means change in concentration, pressure,
volume or temperature.
Le Chateliers principle can be understood either qualitatively or quantitatively
doing some problems. However, we restrict ourselves only to qualitative exlanation.
1. Change in Concentration
If the concentration of the reactants is enlarged , it will shift the reaction
equilibrium to the product , and vice versa .
2. Changes in Pressure and Volume
Pressure does not have any effect on concentrations of species that are present
in solid, liquid or solution form. On the other hand, the change in pressure affects the
concentrations of gases. According to ideal gas law, pressure and volume are inversely
proportional to each other; the greater the pressure, the smaller the volume, and vice
versa. Thus, it is just enough to understand the affect of change in pressure on the
equilibrium system.
3. Changes in Temperature
A change in concentration, pressure or volume alters the position of the
equilibrium but not the magnitude (value) of the equilibrium constant. However, the
change in temperature changes the value of the equilibrium constant. To understand
the effect of temperature, we must know whether the reaction is endothermic
(absorption of heat) or 2exothermic( release of heat).
4. The Effect of a Catalyst
The function of a catalyst is to speed up the reaction by lowering the activation energy.
The catalyst lowers the activation energy of the forward reaction and reverse reaction
to the same extent. Due to this, there is no shift in equilibrium or the change in trhe
value of the equilibrium constant. Therefore, we conclude that thecatalyst has no
effect on the equilibrium system.
V.

TOOLS AND MATERIALS

Tools:

Tools
Burette
Volumetric pipette
Erlenmeyer
Measuring glass
Beaker glass
Pipette

Size
50 mL
5 mL
250 mL
10 mL
50 mL

Materials:
No.
1.
2.
3.
4.
5.

Materials
NaOH 2 N
PP indicator.
Absolute ethanol.
HCl 2 N.
Acetic acid.

Quantity
1
1
4
1
1
4

VI.

PROCEDURE

5 mL of HCl 2 N + 1 mL5 of
mLethanol
of HCl +
2 N + 2 mL5 of
mL
ethanol
of HCl +
2 N + 3 mL5 of
mLethanol
of HCl +
2 N + 4 mL of ethanol +
4 mL of CH3COOH
3 mL of CH3COOH
2 mL of CH3COOH
1 mL of CH3COOH

Inserted to Erlenmeyer Inserted

I
to erlenmeyerInserted
II
to erlenmeyerInserted
III
to erlenmeyer IV

Kc1 CH3COOC2H5

Closed the erlenmeyer

Put into room

Recorded the room temperature
Save until 1 week (minimal 3 days)

Added 2 drops of PP indicator

Titration with NaOH 2 N

Kc2 CH3COOC2H5

Make Blanco Solution

5 mL of HCl
-

Inserted to erlenmeyer
Added 2 drops of PP indicator
Titration with NaOH 2 N

Pink Solution

Kc3 CH3COOC2H5

Kc4 CH3COOC2H5

VII.

TABLE OF EXPERIMENT

No

Experiment Procedure
5 mL HCl 2N
1 mL C2H5OH
4 mL CH3COOH

5 mL HCl 2N
5 mL HCl 2N
5 mL HCl 2N
2 mL C2H5OH
3 mL C2H5OH
4 mL C2H5OH
3 mL CH3COOH 2 mL CH3COOH 1 mL CH3COOH

Observing Result
Before:

HCl solution:

CH3COOH

colorless
Ethanol : colorless
CH3COOH solution:

CH3COOC

colorless
Entered into the erlenmeyer 1, 2, 3, and 4 that has been given a label
PP indicator :
Closed
Put into room / steanbath
Save for 3 days (minimum)
Added PP indicator 2 drops
Titration with NaOH 2 N
Determine mole of ethanol and and mole of acetat acid

After:

HCl + ethanol:

colorless
HCl + ethanol +

CH3COOH: colorless
HCl + ethanol +
CH3COOH +

indicator: colorless
After titration with

NaOH : soft pink

V NaOH = 33.7 ml

Erlenmeyer 2

HCl + ethanol:

colorless
HCl + ethanol +

CH3COOH: colorless
HCl + ethanol +
CH3COOH +

indicator: colorless
After titration with

NaOH : soft pink

V NaOH= 17.3 mL

+H2O(l)
CH3COOC

+NaOH (a

CH2COON

colorless

Erlenmeyer 1

Observing result solution

Hypothesis
C2H5OH (a

C2H5OH (a
Kc theoriti
mol/l

Erlenmeyer 3

HCl + ethanol:

colorless
HCl + ethanol +

CH3COOH: colorless
HCl + ethanol +
CH3COOH +

indicator: colorless
After titration with

NaOH : soft pink

V NaOH= 5.3 mL

Erlenmeyer 4

HCl + ethanol:

colorless
HCl + ethanol +

CH3COOH: colorless
HCl + ethanol +
CH3COOH +

indicator: colorless
After titration with

NaOH : soft pink

V NaOH= 3.3 mL

Kc theoritic for ethyl

acetat = 4.2 x 10 -2
Room temperature =
31 C
Blanko Solution

Before:

HCl (aq) + Na

5 mL HCl 2N
Inserted to erlenmeyer
Added 2 drops indicator PP
Titration with NaOH 2 N

HCl solution:

colorless
NaOH solution:

colorless
Indicator PP:
colorless

Volume of NaOH

After:

HCl +PP = colorless

HCl + PP + titration
with NaOH the
solution become =

soft pink (+)

V NaOH = 2.7 ml
Mole of blanko
solution = 0.0054 mol

NaCl(aq) +H2

VIII. Calculation and Analysis

Blanco Solution
Known :
Volume of NaOH
= 2,7 mL
N NaOH
=2N
N HCl
=2N
Asked
:
Mol of Blanco Solution ?
Answer :
Mol of Blanco Solution = N NaOH x V NaOH
= 2 N x 2,7 mL
= 5,4 mmol 0,0054 mol

Esterification

Known

CH 3 COOH
et h anol

= 1,092 gram/mL
= 0,79 gram/mL

Mr CH3COOH

= 60

Mr ethanol

= 46

Volume of NaOH for Erlenmeyer I

= 33,7 mL

II

= 17,3 mL

III

= 5,3 mL

IV

= 3,3 mL

Asked

Erlenmeyer I

Mol of CH3COOH

Mol C2H5OH

Mol equivalent [H+]

xV
Mr

=
=

1,049 x 4
0,0728 mol
60

xV
Mr

0,79 x 1
0,01717 mol
46

= Mol equivalent [OH-]

= N NaOH x V NaOH for erlenmeyer 1
= 2 x 33,7
= 67,4 mmol 0,0674 mol
= Mol equivalent [H+] - Mol of Blanco Solution
= 0,0674 0,0054
= 0,062 mol

Mol equilibrate

CH3COOH (aq) +
M 0,0728
R 0,0108
S 0,062

C2H5OH (aq)
0,01717
0,0108
0,00637

CH3COOC2H5 (aq) +
0,0108
0,0108

M CH3COOH

0,062
=6,2 M
0,01

M C2H5OH

0,00637
=0,637 M
0,01

M CH3COOC2H5 =

KC I =

H2O (l)
0,0108
0,0108

0,0108
=1,08 M
0,01

[ CH 3 COOC 2 H 5 OH ]
1,08
=
6,2 x 0,637 = 0,2735 mol/L
[ CH 3 COOH ] [C 2 H 5 OH ]

Erlenmeyer II
Mol of CH3COOH

=
=

xV
Mr
1,049 x 3
0,0546 mol
60

Mol C2H5OH

Mol equivalent [H+]

Mol equilibrate

CH3COOH (aq) +
M 0,0546
R 0,0254
S 0,0292
M CH3COOH
M C2H5OH

0,79 x 2
0,03435 mol
46

= Mol equivalent [OH-]

= N NaOH x V NaOH for erlenmeyer II
= 2 x 17,3
= 34,6 mmol 0,0346 mol
= Mol equivalent [H+] - Mol of Blanco Solution
= 0,0346 0,0054
= 0,0292 mo

C2H5OH (aq)
0,03435
0,0254
0,00895

CH3COOC2H5 (aq) +
0,0254
0,0254

0,0292
=2,92 M
0,01

0,00895
=0,895 M
0,01

M CH3COOC2H5 =

KC II

xV
Mr

H2O (l)
0,0254
0,0254

0,0254
=2,54 M
0,01

[ CH 3 COOC 2 H 5 OH ]
2,54
= [ CH 3 COOH ] [C 2 H 5 OH ] = 2,92 x 0,895 = 0,97 mol/L

Erlenmeyer III
Mol of CH3COOH

Mol C2H5OH

xV
Mr

1,049 x 2
0,0364 mol
60

xV
Mr

0,79 x 3
0,05153 mol
46

Mol equivalent [H+]

Mol equilibrate

CH3COOH (aq) +
M 0,0364
R 0,0312
S 0,0052

= Mol equivalent [OH-]

= N NaOH x V NaOH for erlenmeyer III
= 2 x 5,3
= 10,6 mmol 0,0106 mol
= Mol equivalent [H+] - Mol of Blanco Solution
= 0,0106 0,0054
= 0,0052 mol

C2H5OH (aq)
0,05153
0,0312
0,02033

CH3COOC2H5 (aq) +
0,0312
0,0312

M CH3COOH

0,0052
=0,52 M
0,01

M C2H5OH

0,02033
=2,033 M
0,01

M CH3COOC2H5 =

KC III =

H2O (l)
0,0312
0,0312

0,0312
=3,12 M
0,01

[ CH 3 COOC 2 H 5 OH ]
3,12
=
0,52 x 2,033 = 2,95 mol/L
[ CH 3 COOH ] [C 2 H 5 OH ]

Erlenmeyer IV
Mol of CH3COOH

Mol C2H5OH

Mol equivalent [H+]

Mol equilibrate

xV
Mr

1,049 x 1
0,0182 mol
60

xV
Mr

0,79 x 4
0,069 mol
46

= Mol equivalent [OH-]

= N NaOH x V NaOH for erlenmeyer IV
= 2 x 3,3
= 6,6 mmol 0,0066 mol
= Mol equivalent [H+] - Mol of Blanco Solution
= 0,0066 0,0054
= 0,0012 mol

CH3COOH (aq) +
M 0,0182
R 0,017
S

0,0012

C2H5OH (aq)
0,069
0,017
0,052

M CH3COOH

0,0012
=0,12 M
0,01

M C2H5OH

0,052
=5,2 M
0,01

M CH3COOC2H5 =

0,017
=1,7 M
0,01

KC IV

CH3COOC2H5 (aq) +

H2O (l)

0,017

0,017

0,017

0,017

[ CH 3 COOC 2 H 5 OH ]
1,7
= [ CH 3 COOH ] [C 2 H 5 OH ] = 0,12 x 5,2 = 2,724 mol/L

Kc average

KcI + KcII + KcIII+ KcIV

4

=
0,2735
=

mol
mol
mol
mol
+0,97
+2,95
+2,724
L
L
L
L
4

= 1,729 mol/L

Analysis
The purpose of this experiment is to knowing the constants of equilibrium reaction and
observing if the constants of equilibrium not depend the initial reaction concentration. The
technique for determine constants of equilibrium is titration. This titration is for knowing the
solution that have been saved until 1 week or minimal 3 days to reach good or perfect
equilibrium.
The first experiment was inserted 5 ml of HCl 2 N into 4 erlenmeyer. Erlenmeyer I
was added 1 mL of ethanol and 4 mL of CH3COOH, produce the colorless solution. And then
closed that erlenmeyer with plastic wrap, because ethanol very easy to evaporated and to
maintain temperature inside erlenmeyer for process of reaction. Function of added HCl is as
catalyst that will be formed ionic of H+ and will accelerate the esterification reaction. After
that, for Erlenmeyer II, III, and IV be given the same activity with erlenmeyer I, but different
composition. This is the data:
Erlenmeyer

HCl 2 N (mL)

Ethanol (mL)

Acetate Acid

I
II
III
IV

5
5
5
5

1
2
3
4

(mL)
4
3
2
1

Fourth erlenmeyer was saved 3 days into room temperature (31 oC), this function is to reach
esterification reaction. The reaction:
CH3COOH (aq) + C2H5OH (aq)
Acetate Acid

Ethanol

CH3COOC2H5 (aq) + H2O (l)

Ethyl Acetate

After solution have been saved until 3 days, then each erlenmeyer was titrated with NaOH 2
N. Before that, we product the Blanco Solution, it was inserted 5 mL of HCl 2 N into
erlenmeyer and added 2 drops of PP indicator, after that titrated it with NaOH 2 N until produce
pink solution and recorded the volume of NaOH 2 N. The volume of NaOH 2 N was 2,7 mL.
The reaction:
HCl (aq) + NaOH (aq) NaCl (aq) + H2O (l)
Next, fourth erlenmeyer that have been saved until 3 days, was added 2 drops of PP indicator,
the function is to produce the pink color and to knowing the equivalent point when titration.
Then, each erlenmeyer was also titrated with NaOH 2 N until produce pink color of solution
and recorded the volume of NaOH 2 N. PP indicator have pH range 8,0-9,6. When pH was < 7
(acid solution), the color of solution was colorless. When pH was > 7 (base solution), the color
of solution was red or pink. The reaction:
CH3COOC2H5 (aq) NaOH (aq)

CH3COONa (aq) + C2H5OH (aq)

Volume NaOH 2 N for erlenmeyer I was 33,7 mL. For erlenmeyer II was 17, 3 mL. For
erlenmeyer III was 5,3 mL. And last for erlenmeyer IV was 3,3 mL.

To knowing constants of equilibrium, firstly we calculating the mol of Blanco Solution with
this equation:

Mol of Blanco Solution = N NaOH x V NaOH

And then, calculating the mol of CH3COOH and mol of ethanol with this equation:

n CH 3 COOH =

n et h anol=

CH 3 COOH x V CH 3 COOH
Mr CH 3 COOH

et h anol x V et h anol
Mr et h anol

After that, calculating the mol of titration with this equation:

Mol of Equilibrate = Mol Equivalent of [H+] - Mol Equivalent of Blanco Solution
So, we can calculating the Constants of Equilibrium, with this equation:

Kc=

[CH 3 COOC 2 H 5 ]
[ CH 3 COOH ] [ C2 H 5 OH ]

The result constants of equilibrium (Kc) for Erlenmeyer I was 0,2735 mol/liter, Erlenmeyer II
was 0,97 mol/liter, Erlenmeyer III was 2,95 mol/liter, the last Erlenmeyer IV was 2,724
mol/liter. The constants of equilibrium (Kc) average for fourth erlenmeyer was 1,729 mol/liter,
but the theoretical constant of equilibrium (Kc) was 0,042 mol/liter.
IX.

DISCUSSION

The constants of equilibrium for each erlenmeyer:

Kc Erlenmeyer I

= 0,2735 mol/liter

Kc Erlenmeyer II

= 0,97

mol/liter

Kc Erlenmeyer III

= 2,95

mol/liter

Kc Erlenmeyer IV = 2,724 mol/liter

The constants of equilibrium (Kc) for Erlenmeyer I, II, III, and IV was equilibrate, because
was positive (+). And the average for fourth erlenmeyer was 1,729 mol/liter. But the theoretical
constant of equilibrium (Kc) was 0,042 mol/liter. That was not same with theoretical constants
of equilibrium (Kc), because of the storage time that just saved until 3 days, even it should
saved until 1 week. The other factor that can influence is room temperature that not constant, so
it will disturb the process of equilibrium reaction. We need thermostat bath for set the constant
temperature.
X. CONCLUSION
From the experiment that have been performed and the data have been obtained can be
conclude as follows :
a.

The average of Kc is 1.729 mol/mL

b.

The equilibrium constant not depend on the initial concentration of the reactants, but depend
on concentration after reaction

XI. REFERENCES
Anonym. Determining Equilibrium Contant http://en.wikipedia.org/wiki/Determination_

of

_equilibrium_constants. (Accesed in March 27th)

Anonym. Equilibrium Contant.http://en.wikipedia.org/wiki/Equilibrium_constant. (Accesed in
March 27th)
Ari, Sagita Devina. Penentuan Konstanta Kesetimbangan Reaksi. http://devinarisagita.
wordpress.com/2012/11/28/konstantahj/. (Accesed in March 27th)
Atkins, P. W. 1986. Kimia Fisika. Jakarta: Erlangga
Bahl, Arun, B.S. Bahl, G.D. Tuli. 2002. Essential Of Physical Chemistry. New Delhi: S. Chand
& Company LTD.
Kartohadiprojo, Irma I. 1999. Kimia Fisika (Jilid 1, Edisi keempat). Jakarta: Erlangga.
Tjahjani, Siti. 2013. Petunjuk Praktikum Kimia Fisika II. FMIPA UNESA.

XII.

QUESTIONS ANSWER

1. Create a table observations and the results of the calculation of the concentration of
each component in the mixture of the above!
Answered :
No.
1.

2.

Procedure
Blanko
Solution

Concentration
Mol blanko = N NaOH x V NaOH
= 2 N x 2.7 mL
= 5.4 mmol = 0.0054 mol
[CH 3 COO C2 H 5]
[1.08 ]
1.08
Kc=
=
=
3.9494
[ CH 3 COOH ] [C2 H 5 OH ] [ 6.2 ] [0.637]

Erlenmeyer 1
0. 2735 M
Kc=

3.

Erlenmeyer 2

K 1=

[CH 2COOC 2 H 5]
[ CH 3 COOH ] [C 2 H 5 OH ]

[CH 3 COO C2 H 5]

[ CH 3 COOH ] [C2 H 5 OH ]

[2.54 ]
2.54
=
2.6134
[ 2.92 ] [0.895]

0.97 M

4.

5.

Erlenmeyer 3

Erlenmeyer 4

Kc=

Kc=

[CH 3 COO C2 H 5]
[3.12]
=
=2.95 M
[ CH 3 COOH ] [C2 H 5 OH ] [ 0.52 ] [2.033]

[CH 3 COO C2 H 5]

[ CH 3 COOH ] [C2 H 5 OH ]

[1.7 ]
=2.724 M
[ 0.12 ] [5.2]

2. What is the function of HCl in a mixture of the above?

Answered :
HCI serves as a catalyst only one that serves to accelerate equilibrium reaction yet to
be in balance, because catalyst can not shift the equilibrium.

3. Write the equation for the reaction and the reaction mechanism of esterification of the
above!
Answered:
Blank solution: HCl (aq) + NaOH (aq) NaCl (aq) + H2O (l)
Erlenmeyer: CH3COOH (aq) + C2H5OH (aq) CH3COOC2H5 (aq) + H2O (l)
After titrated
CH3COOC2H5 (aq) + NaOH (aq) CH3COONa (aq) + C2H5OH (aq)
4. Determine the value of Kc at the temperature of observation!
Answered :

Erlenmeyer 1 Kc = 0.2735 M

Erlenmeyer 2 Kc = 0.97 M

Erlenmeyer 3 Kc = 2.95 M

Erlenmeyer 4 Kc = 2.724 M

Kc average = 1.729 M

XIII. ATTACHMENT
NO

PICTURE

NO

PICTURE

Tools that needed for experiment

equilibrium constant
3

Materials that needed for experiment

equilibrium constant
4

Put 5 mL HCl 2N into measuring glass

Put 5 mL HCl 2N into erlemeyer 1
5

Put 5 mL HCl 2N into erlemeyer 2

Put 5 mL HCl 2N into erlemeyer 3

Put 5 mL HCl 2N into erlemeyer 4

Put 1 mL ethanol into erlemeyer 1 that

contained 5 mL HCl 2N
10

Put 4 mL acetic acid into erlemeyer 1

that contained 5 mL HCl 2N and 1 mL
ethanol
11

Put 2 mL ethanol into erlemeyer 2 that

contained 5 mL HCl 2N
12

Put 3 mL acetic acid into erlemeyer 2

that contained 5 mL HCl 2N and 2 mL
ethanol

Put 3 mL ethanol into erlemeyer 3 that

contained 5 mL HCl 2N

13

14

Put 2 mL acetic acid into erlemeyer 3

that contained 5 mL HCl 2N and 3 mL
ethanol

15

Put 4 mL ethanol into erlemeyer 4 that

contained 5 mL HCl 2N

16

Erlemeyer 1,2,3,4 that was sealed with

aluminum foil
17

Save until 3 days in the room

temperature
18

Titration process

Result erlemeyer 1 after titrated with

NaOH 2N

19

20

Result erlemeyer 2 after titrated with

NaOH 2N
21

Result erlemeyer 3 after titrated with

NaOH 2N
22

Result erlemeyer 4 after titrated with

NaOH 2N
Blanko solution
1

Put 5 mL of HCL 2N into erlemeyer

Put 2 drops PP indicator into erlemeyer

that contained 5 mL of HCl 2N

Titration with NaOH 2N

Result after titrated with NaOH 2N