-

--

2h:

17 :
2014

)7(
HCOOH .

CH3COO
:
: C25

eau 1g / cm 3
: mS.m2.mol-1 :
CH3COO- = 3 = 4,1

Na+ = 4 = 5

HCOO- = 1 = 5,46

35

= 2

= H3O+

V C0
)0.5
(
)0.5
(

p 90 0 0
:

M (HCOOH ) 46 g .mol 1
-1

)n(HCOH

)0.5
(
)1
(

)1
(

V :

eau
-2

p d
V ) M(HCOOH C0 = 23,86mol.l-1 :
)(S1
)HCOOH(aq
C1 = 10-2mol.L-1 . V1 ) (S1 :

)0.5
(
)1
(

d = 1,22 :

1 49mS .m 2 .mol 1
2.1
2.2

.
1

1
)0.5
(

2.3
2.4
-3

1 2 C1
-HO .
.1 .
pH ).(S1
K C1 1 .
) (S1
)(S2
. C2 = 10-3 mol .L-1 2

-4

.
) n (S1 ) (S '
) .(S 1>>1 >>:' 1

= 1n

:
)1
(

CH3COO

-3

n0 = 10 mol

n0 = 10

mol

CH3COONa V=100ml :
)1
(

HCOOH aq CH 3COO aq
HCOO aq CH 3COOH aq

q 101,33mS .m 1
-1

-2

qV
. n 0 3 4
1 3

xq

. xq
Qr,q no xq
. +H3O -HO .

3/1

)7(
:
Pu 19
238
94

238
94

Pu
:238-

Pu

t 12 2, 77.109 s
: :238 -

Pu 238g .mol 1

238

U 234 g .mol 1

234

)0.5
(

N A 6, 02.10 23 mol 1
:
234
92

238
94

Pu

)1
(

-1

-2

Pu

N0

a0 9.1010 Bq

238
94

m0

(2-1 m0
(2-2 t
.

)0.5
(

)1
(

0, 43

234
92

Pu

238
94

r
N
N

:
)1
(

) N ( 234U

t 12

N0
t

t 12
-

r t

.
. t

234
92

U
- t m

:
235-
:
148
85
1
n 235
92U 57 La 35 Br 3. 0 n

1
0

: :
)1
(

nuclon

148La 8,19 Mev

U 7,58 Mev

235

nuclon

)0.5
(

Br 8,97 Mev
85

nuclon

)1
(

U 234,9935u

235

m n 1, 0087u

)0.5
(

27

1u 1, 66.10 vg 931,5Mev .c
1Mev 1.6.1013 J

(1
(2

E1 235-
Ei

(3

Ef E Mev
Pe = 900Mw : %30
EN Ee m 235
.

3
1

2
1

H
(4

H 13H 3/2
24He
01n

2
1

:
3
1

2
1

E2
=17,46Mev E2
.

)6(


) (C . C
.
E :

R ' 10

R 10

)1
(

)1
(

-1

) K(1-

( )1
)
(2

t = 0
k
K )(1

(1.1
UR R
C :
(1.2

U R AeUR

R
: A
) (R.C

Ln (U R ) Ln ( E )

1-- :
(1.3
)1
(

)1
(

) (-2- Ln(UR) : t
UR )Ln(UR) (V
E : .C
C1 ) (C1
) (C

(1.4

1 3

1.6
1

) (
.

0.9

-2
1

t = 0
K
) (2
'

)t(s

U C Ee

UC :

'

7.10-10

(2-
(2-1 )-
.t =
i
(2-2 ) (C t
2t
'

)1
(
)1
(

E e t E 0e

E0

) (C = t

0
.t =

 3/3