Professional Documents
Culture Documents
PERIODIC PROPERTIES
(SUMMARY)
1.
Periodicity in :
From (L R) as no. of es
From (T B) as no. of es
2.
Z* Effective Nuclear charge
Z* = Z
Z at. no. of the given the specy.
Periodicity
From (L R) (Z* ) and therefore becomes dominating factor across the period.
From (T B) (Z* ) almost remains same & therefore size factor dominates down the group.
Ionisation energy :
It is the min. energy required to remove an e from an isolated gaseous specy from its. Ground
state.
A A+ + e
H = 1 of A
+
2+
A A + e
H = 2 of A and 1 of A+
2+
3+
Z* E.
also approx. E. 13.6
Z 2 eff
n2
TB
(size) dominates
(size) E.
Irreg. In E.
Be B but C Be
N O but F N
Stable config.
Page # 1
E. values (kJ/mol)
Li
Na
K
Rb
Cs
4.
520
496
419
403
376
Be
Mg
Ca
Sr
Ba
899
737
590
549
503
At. radius
* e is a wave so directly its distance from the nucleus cant be predicted.
Therefore at. radii is categorised into three types
(a) Covalent radius
r
d A A
2
r covalent radius of A
1.
d A A
2
* d A 2 r A + rA
*dAB < rA + rB dAB 0.09 (XA ~ XB) stevenson equation.
XA & XB are electronegativities on Paulings Scale.
2.
Crystal/Metallic Radii
CD = rcrystal
Metallic crystal of element X
3.
AB
Vanderwaals radius of H
2
CD
Vanderwaals radius of X
2
Periodicity
(L R)
(T B)
Z* r
size r
Page # 2
4.
Ionic radius
dist. of outermost e from the nucleus in the given ion.
* rA, < rA
* rB < rB
rn = 0.529
1
Z
* Vanderlwalls raidus normally for noble gases
* for other neutral species normally covalent radius
* for ions ionic radius
Irregularity in Radius
Noble gases > halogen family
Al Ga (due to d-orbital contraction)
4d 5d (due to lanthanoid contraction) also continuous in last two elements of P block.
* Largest atom Fr, Smallest atom H, Largest cation Cs+
smallest cation H+, Largest anion , smallest anion H
* also in 3d rCr to rCu remains almost const.
rn
Electron affinity
Erel. when an e is added to an isolated gaseous specy in its G.S.
A + e A
H = 1st E.A. of A
A + e A2
H = 1st E.A. of A & 2nd E.A. of A
* 2nd E.A. of A is Eabsorb
Factors affecting E.A. (assuming E.A. To be exel)
1. as size E.A.
2. as Z* E.A.
3. as E.A.
4. stable config. have Eabsorb while addition of e.
* While comparison of E.A., all Erel are kept an greater side than those of Eabsorb
* E.A. of Noble gases are said to zero or highly + ve.
In Pblock elements
3rd period has greater E.A. then 2nd period due to exceptionally small size and thus high e
density on the surface of 2nd period elements. (Valid only for Pblock density not for Sblock
element) Li > Na
Irreg. in E.A.
B > Be O > N
F > Ne
Li > Be
C>N
Li > Na
Also
N > Be (E.A.)
66kJ/mol
Reason Be being metallic has lesser tendency to gas es. This were H +ve 31 kJ/mol
ornegativity
Relative tendency to attract shared pair of e towards itself.
Difference between EN & EA
1. EA solated Gaseous atom whereas EN atoms in combined state.
2. EA Absolute value of whereas EN Relative value.
Three different scales of EN
1. Pauling Scale
XA ~ XB = 0.208/0.182
AB
where AB = E AB (E A 2 EB 2 )1/ 2
Page # 3
N
3.0
P
2.1
O
3.5
He
zero
F
4.0
Cl
3.0
Br. 2.8
Mulliken Scale :
EN =
I.E E.A
(Put magnitude of E.A. only & formulae not valid for stable config.)
2
X mulliken
also X
= 2.8
Pauling
XAR =
rA2
+ 0.744
rA covalent radii in
Zeff.e 2
( force of attraction
Factors affecting EN EN
2
1. as Z* EN
2. as n EN
3. as EN
4. as cationic charge EN (Mn2+ < Mn+4 < Mn+7) for the same element
5. as Anionic charge EN (A1 > A2 > A3) for the same element
6. as % s charac. EN
sp3 < sp2 < sp
Periodicity in EN
Across the period from (L R) Z* (EN)
down the group (T B) size (EN)
Irreg. in EN
* EN of Noble gases in zero.
Applications of EN
1.
Nature of Bond
(a) When XA ~ XB = 0, Pure covalent Bond.
(b) XA ~ XB < 1.7/2.1 Polar covalent Bond
Pure covalent Bond.
Given by Pauling
(c) XA ~ XB = 1.7/2.1 50% ionic and 50% covalent
(d) XA ~ XB > 1.7/2.1 more ionic lesser covalent.
* % ionic character = [16 | XA ~ XB | + 3.5 (XA ~ XB)2]
for 50 = 16 EN + 3.5 (EN)2 EN = 2.1
2.
Nature of Oxides
(cosidency
excess
X O
H2O
Page # 4
3.
1
* Vice versa is the order of the B. lnegth. B.h. B. Str.
4.
Page # 5