AEDC-TR-65-58

TABLES OF THERMODYNAMIC PROPERTIES

OF AIRIN CHEMICAL EQUILIBRIUM
SINCLUDING SECOND VIRIAL CORRECTIONS
FROM 1500 0K TO 151000 0K
Joseph Hilsenrath and Max Klein
National Bureau of standards
Washington, D.C.

-------

~HARD

___

COPY

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$*7-i

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ARNOLD ENGINEERING

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DEVELOPMENT

CENTE

AIR FORCE SYSTEMS COMMAND

PN4OLD AIR FORCE STATION., TENNESSEE

:R d

Best Available Copy

AEDC-TR.65-58

TABLES OF THERMODYNAMIC PO0PERTIES 01' AIR

IN CHEMICAL EQUILIBRIUM
INCLUDING SECOND VIRIAL CORRECTIONS
FROM 15000 K TO 15,000 K

Joseph Hilsenrath ani Max Klein*

National Bureau of Standards

*preseiat address:
Rehovoth, Israel

A'

The Weizmann Institute

At "

I> A

WQCCdC

4od

of Science,

PAGES
ARE
MISSING
IN
ORIGINAL
DOCUMENT

ACDC.TR-65.58

FOREWORD
The work reported herein was done by the National Bureau
of Standards, Department of Commerce, Washington, D. C. for
the Arnold Engineering Development Center (AEDC), Air Force
Systems Command, Arnold Air Force Station, Tennessee under
Delivery Orders 40(600)59-24, 40(600)63-136, and 40(600)64-195
and Program Elements 62405334/8950, 895003 and 61405014/8951,
89603.
This report supercedes AEDC-TDR-63-161 which has the same
title.
It represents a considerable amplification of Table L
(the equilibrium concentration of 28 species entering into the
calculations are given as mole fractions).
Aside from this
addition, the thermodynamic properties given here are fully
consistent with those in the earlier
report.
The inclusion of
28 additional numbers for each point on the isotherm required
a change in format (it
being no longer possible to display all
of the information for one temperature on a single page).
Advantage was also taken of the opportunity to make a number
of minor changes mostly corrections of typographical errors,
more precise reference citation, etc.
The authors wish to express their appreciation for the
assistance rendered by Mrs. Ruth Varner in carrying through
certain modifications of the computer program, and Mrs. Carla
G. Messina who is responsible for most of the figures and for
the performance of many side calculations incidental to checking out the main computing program.
We are indebted to Mr.
Adolf R. Hochstim for permission to reproduce an excerpt from
his forthcoming publication on theoretical calculations of
thermodynamic properties of air;
to Mr. Lester Haar for supplying unpublished values of ideal-gas thermodynamic functions
for certain species; and to Dr. Harold W. Woolley for invaluable support, cooperation, and advice, over a period of years.
A qualified requester may obtain a copy of all
material
tabulated in

Table L on IBM tape from DCS/Research,

This report has been reviewed and is

Terry L. Hershey
Captain, USAF
Aerospace Sciences Division
DCS/Research

ii

AEDC.

approved.

Donald R. Eastman
DCS/Research

A E DC.T R,65-50

ABSTRACT

Tables for the thermodynamic properties for air are presented which take into account the effect of dissociation and
ionization and the limiting-law Debye-f'Uckel and second virial
corrections upon the thermodynamic properties and the equilibrium compositions.
Values are tabulated from 1500 0 K in
steps of 100 0 K to 15,000K at close spacings in the logarithm
of the density [loglo p/po - -7.(0.2)2.2] for the compressibility factor Z = PV/RT; the dimensionless functions for:
internal energy, E/RT; enthalpy, H/RT; entropy, S/R X ;
log1 0 P (atm) and Z* -7. C .
The underlying equations and
the input data are discussed briefly.
The effects of the
real gas corrections on the equilibrium properties are illustrated graphically.
The equilibrium composition is given for
selected temperatures over the tabulated density range.
The
wide range of temperatures and densities over which the thermodynamic properties have been tabulated make the tables useful in a variety of engineering design and test programs, and
in scientific research and development.

iii

AEDC.TR-.65-58

CONTENTS
Page

AISTRYICT

....

i.i

1
1

. . . . . .. . .

V. THE SECOND VIRIAL CORRECTIONS

. . .
VI. DISCUSSION OF THE TABLES ......
. .
REFERENCES ..........................

. . ..

..

12

..
.
. .
I. INTRODUCTION.........
II. EQUILRIUM IN
GASEOUS SYSTI:
.
III. TiKEREUODYNAMiIC PROPERPIES OF TILE EQUILIBRIUM
IV.

MIXTU11E

. . . . . .. . . . . .

DISCUSSION

OFTHE INPUT DATA . .

.
.

..

.
.

APPENDIX I - THEORETICAL CALCULATIONS OF

THERMODYNAMIC

PROPERTIES OF AIR

15

29

ILLUSTRATIONS
Figure
1.

Compressibility

2.

Corrected and Ideal Compressibility Isotherms

for Air

3.
4.

Isotherms for Air

a.

T =: 20001-

c.

Tm. 8000 0 K.

d.

e.

.......

......................
12,0000.K .........

- 15,000 K

33

..............
.

.. 34
.

# .

* .

35

Limiting-Law Debye-Auckel Effect on the Compressibility

for Air ..........
.................
..

36

Equilibrium Composition of Air

a.
T - 20000 .K
.................

37

b.

T -

6000K

c.
d.
e.

T T T -

9000K 0 '.39
12,000 0.K
15,000 K
...............

...........

38

40
41

TABLES

A.
B.

Equilibrium Equations for the Species Included

in the Calculations for Air .....
.........
.

43

Incidence Matrix of r ik

44

Values for Air

AEDC.TR-65.58

Page
C.

Mass and Charge Balance Equations for Air .

D.

Densities Corresponding to the Tabulated

E.

Arguments

..

0..
. .

Input Data for Air Calculations at 6000,

and 12,000 K

*.

.*..

H.

51

61

9000,

12,000,

a .

ior r

at 60000 K

I.

Values

J.

Values for Fi(2) at 6000K

K.

Equilibrium Composition at 6000K0

L.

Thermodynamic Properties and Chemical

Composition......

vi

(1)

. .

47

and 15,000 K .
.

50

and 15,000 K

46

0.

Property Dfferences at 6000,

.

Second Virial Coefficients and Derivatiges

12,000,

G.

9000,

45

Incidence Matrix for Virial Coefficients

6000,

9000,
.

F.

at 2000,

65
.

.
.

.
.

* .

66
67

68

AEDC-TR-65-58

SECTION I
INTRODUCTION
This report represents the third NBS approximation to
the thermodynamic properties of air
in chemical equilibrium
at temperatures below 15,000K.
The tables differ from those
in the previous report (Ref. 1) in the following respects:
1.

2.

3.

The tables now include the limiting-law DebyeFffckel corrections in both the equilibrium compositions and the gross properties.
The tables include the second virial
effects (on
both the equilibrium compositions and gross properties)
for interactions between neutral-neutral
species and ion-neutral species.
The thermodynamic functions for the diatomic moleNO+
cules and molecule ions N2 , 02' NO, N+, O,
above 50000K are taken from new unpublished calculations of L. 11aar.
Aside from these changes the
thermodynamic functions are essentially those used
in Ref. 1.

The program used here for computing the equilibrium

compositions and properties is a modification of that given

by Hfilsenrath, Klein, and Sumida (Ref. 3).
The modifications
were made primarily to accommodate the limiting-law DebyeIHUckel and second virial
corrections.
These corrections have
the effect of making the equilibrium constants density dependent.
They are based on the detailed formulation of the
thermodynamic properties of partially
ionized gases by H. W.
Woolley (Ref. 4).
In the sections which follow, the formulation of the
properties of a dissociated and ionized gaseous mixture made
up of ideal gases is discussed first.
The various real-gas
effects which are here considered are then applied either as
factors or as additive terms to the ideal representation.
Among other things this treatment permits the preservation of
much of the calculation flow and logic of the ideal-gas computer program.
This involves no loss of generality and makes
it easier to add still
further corrections in the future.
SECTION II
EQUILIBRIUM IN HOMOGENEOUS GASEOUS SYSTEMS

The number of moles of molecules, molecule ions, and

atomic ions in a gaseous mixture in chemical equilibrium can
be written for the ideal mixture in terms of products of the
number of moles of certain reference species, Ck, and equilibrium constants, (Kp)i, as follows:

I I

II I

I I

I I

I I

AEDC-T R-65-58

(po)

(To-
(T

(1)
k

where
Ck - the number of moles per mole of low temperature
air

of the reference

species (the neutral atoms

and electrons in our treatment) k = 1,

2,

... 6

Ci . the number of moles per mole of low temperature

air of all but the reference species
p/po - the density relative to the density at standard
273.15 0 K
po M 1 atmosphere, To
conditions:
T - the Kelvin temperature
I1-zrik ' the Pet change in the number of particles across
the reaction
r ik - the incidence matrix representing the multiplicity of the reference species k present in each
ordinary species, i
(Kp)i - the equilibrium constant for the formation of
the ith species from the reference species
The eq'tilibrium constant Kp is
Kp

where AF 0 is
reaction.
If

(1)

ep

the change in the Gibbs free energy across the

we set

coi

ki
Eq.

computed from the relation

(Kp)

(i)

(2)

can be written as
Ci = Ri

(\o')

CCkik

(3)

In this equation the equilibrium constant R is a funcVarious real gas effehts appear
tion of temperature only.
as additive corrections to the frpe energy of the individual
constituents or to the energy difference across the reaction.
Since these appeor as exponents of e (the base of the natuLral
logar.thm), the corrections can be written as-multiplicative
Thus, for
facto-'s (Ref. 4) of the equilibrium constant Ki

AEDC-TR-65-58

a mixture of real gases in

the equation
C i ,,

I'i

equilibrium at a fixed temperature,

(4 )

11 C kf'k

i
I.I"(n)7,

I'ia li

Pk

provides such real gas corrections to the equilibrium as can

be represented by the density dependent gammas.
Woolley has
formulated such corrections (Ref. 4) for a number of real
gas effects.
In the present work we have included only two
such corrections - the Debye-Hickel limiting-law and the
second virial
corrections.
For the Debye-HUickel
rium concentrations

limiting-law effect on the equilib-

*a,

PO

Z
1

the ionic charge of the

units

species in protonic

the electronic charge

E-

=dielectric constant for air, assumed here as unity

number of non-reference species

Boltzmann constant

Avagadro's number

V0

M 22414.6 cm /mole

th

For the second virial correction to the equilibrium

concentrations
in

(2z)

-2

(f+

ri

CaB

(6)

where
B i-the second virial coefficient in units of cm3 /mole
for the interaction of the as

with the i t

peciEs

AEDC-TR-65-5

Bak ' the secnd virial coefficient (in

units of cm /mole)

for the interaction of the ath species with the ksth

reference species
(3)
Corrections have not yet been incorporated for ri(),

r 1(4),

and r (5)

which represent

the influence on the equilib-

rium of third and higher virial

coefficients, of certain ionic
effects, and of the shift
of the ionization potential.
These
corrections are believed to have only a small influence on
the thermodynamic properties of the mixture in the temperature
and density range covered here.
In addition to the above equations, a gas in equilibrium
must also obey one or more mass balance equations, and a charge
balance equation.
These equations can be written in the above
notation as
a+5

Xk =

5
i=1

rik

k = 1, 2 ... ,5

Ci;

(7)

for the conservation of atomic nuclei, and

n

Ca+6

i=1

ri 6 Ci

(8)

for the charge balance.

In the above equations Xk represents the maximum possible number of moles of reference species (in this case the
number of moles of atoms of each of the elements in the mixture).
Values of rik and Xk are given in Tables B and C for
the constituents of air
considered in these calculations.
The incidence matrix, rik, given in Table B corre.sponds to
the chemical reactions given in Table A for which Eq. (3) is
a representation.
SECTION III
THERMODYNAMIC PROPERTIES OF THE EQUILIBRIUM MIXTURE
The thermodynamic properties of the equilibrium mixture
can be computed from the corresponding properties of the individual species (atoms, molecules, atomic and molecular ions,
and the electrons) and tie number of moles, Ci, of each species
in the mixture.
To simplify the presentation the thermodynamic
properties of the mixture are written in three parts:
the

A EDC.T R,,65-58

properties of the corrected mixture considering the species

as iaeal gases; the contribution, A1 , of the limiting-law
Debye-fIUckel effect; and the contribution, A2 , of the second
virial
interactions.
Thus, for one mole of gas at standard conditions
1 atm) we compute for each value of T and p/po:
the total

(273.15 0 K,

number of moles per mole of low temperature air,

(9)

n+

Xi

Ci/Z*

i=1

the mole fractions,

(10)

and the compressibility factor,

Z - PV/RT = Z* + A, Z + A, Z

(11)

where
6i2845.3
3 9

-Z -

PO)

= zi 2 Ci

(Pj'

(12)

and
n+6

'

(13)

n+6

Y.---l

Y.

A-Z

In the right-hand side of Eq. (12), Zi is the ionic charge of

thi ith
species in protonic units.
In Eq. (13), V 0 - 22414.6
cm /mole, Ca and C are the number of moles of the species a
and p and B
is the second virial
coefficient (in units of
cm 3/mole) for their interaction.
The program is written to
handle pair interactions between all
of the species in the
mixture.
Since practical considerations often limit the
availability
of virial
coefficients for certain interactions,
the program permits the inclusion or exclusion of any reaction
via an incidence matrix.
Further discussion of the virial
corrections is given in section 5.0.
The internal energy,

E!RT

I I

n+6

Ci (E/RT)i

II I

15/T

A1 (E/RT)

(14)

,"2 (E/RT)

AEDC-TR.65.58

where
(E /RT)i = the dimensionless internal energy,
species
of the ith
D

the reaction energy discussed in

A, (E/Wr')
and

The pressure in

,E/

=o

a=1

P=1

section 4.0

= 3 .\, Z

(15,

( ) n+6 n+
.
"A,
(E./R)

(E-E)/RT,

dBa

C, Co T

dT

(16)

atmospheres,
P)

ZRT

(17)

The enthalpy,
II/RT

E/RT + Z

(18)

The entropy,

A,

Xi In Xi-

In

(19)

where

A, (S/R)

AZ

(20)

and

A,-A,R =

V0 o

n+6

n+6

a-1 Pe-t
Y
CaC,

(aC
B

+ T

d( a,
dT

(21)

SECTION IV
DISCUSSION OF THE INPUT DATA
The tables and figures presented in this
report result
from the solution of the equations given in the previous sections.
The calculations, which were performed on an IBM 7090
computer, considered the equilibrium between atoms, molecules,
atomic ions, and molecule ions of the elements N, 0, A, C, Ne,
and the electrons.
The 28 species considered
in the calculations are shown in Table B.
The thermodynamic functions for

AEDC.TR-6558

the atoms and atomic ions are the sarme as those used in our
earlier calculations.
They approximate closely functions
obtaixcd by direct sun.-maticn, of the obsmervod atomic energy
levels (Ref. 5) up to and in'cluding levels for n
5.
The
thermal functions for CO,-, C(:, 1C2, and 02 i,re taken from
NDS Circular 5C4 (hcef. 6) ul to 500001.
The thermodynamic functions for the diatomic molecules
N2 , 02, and NO above 5000 0 1C and the molecule ions ILT, O,
and
NO+ over the entire range are from unpublished calculations
by L. Haar who his reinvestigated the treatment for the diatomic molecules at high temperature and has carried out new
calculations at close temperature spacings.
These functions
represent improvements over the earlier values published for
these substances by Beckett aond Haar (Ref. 7).
The thermodynamic functions for NO2 and F20 and the
extension to higher temperatures for CO and CO2 were computed
from the harmonic oscillator approximation.
The thermodynamic
functions for 02 are from unpublished calculations based on
constants extrapolated from halogen oxides (Ref. 8).
The reaction energies - dissociation energy, heat of
formation, electron affinity, or ionization potential - for
the 28 species in air are given in temperature units in the
last column of Table B.
These are in substantial agrocement
with values used by Gilmore (Rlef. 2) and flochstim (Ref. 9).
The equilibrium constants, computed from these values and
the ideal gas free energies, are given together with the internal energy and entropy for selected temperatures in Table
E.
Here the internal energies for the molecules, the molecule
ions, and the atomic ions have been referred to a common
reference -

that of the energy (E0 -

0)

of the atoms at ab-

solute zero.
It should be noted that this choice would give
a negative internal energy for the mixture at low temperatures - before appreciable dissociation has set in.
For this
reason the term D/T has been added to Eq. (14) to restore the
reference energy of the mixture to that for the molecules.
Here D - Z Xi Di/R where the Di are the dissociation energies
of the molecules in the mixture and the Xi are their corresponding mole fractions.
The atomic composition shown in Table C is based on the
following low temperature composition of air:
0.78084 N
0.20946 02, 0.00934 Ar, 0.00033 CO 2 , and 0.00003 Ne.
This
composition corresponds to a molecular weight of 28.967.
This value together with the 6as constant R - 1.98726
cal/mole 0 K can be used to convert certain of the dimensionless
thermodynamic properties to a specific set of units.

AEDC-TR.65-58

T,1 SEC-C

SECTICA V
D VIRIAL CC?1F CTiOCS

The second virials and their delrivatives used for

neutral-neutral and ion-neutral pairs are based on empirical
pair potentials where available, and otherwise on a combination of theoretical relations and cmpirical correlations described elsewhere (Ref. 10).
For the attractive dispersiontype potentials, the theoretical formulas of Slater and Kirkwood (Ref. 11) or Hornig and Hirschfelder (Ref. 12) were used,
but with empirical adjustments where possible.
The empirically
known geometric mean combination rule has also been used instead of pure theory when application was feasible.
A form
of Margenau's theoretical induced quadrupole energy (Ref. 13)
and the theoretical induction energy were also accepted for
ion-neutral pairs.
A semi-empirical correlation of inter-atomic repulsive
potentials was based on interatomic Lennard-Jones parameters
converted directly from corresponding parameters for molecules.
For this conversion, the atomic pair excluded volume
was based on an extension (Ref. 10) of Kihara's sphero-cylindrical treatment for diatomic molecules so as to cover also
sphero-conical diatomic molecules which are then models for
pairs involving diatomic compounds.
By this means, atomic
exclusion radii were obtained from molecular excluded volumes
and internuclear distances within the diatomic molecules.
The
assumption of additivity of long-range dispersion forces between atoms of separate molecules then led to a selection of
non-bonding atom-atom energy parameters with the help in
some cases of extensions of familiar combination rules commonly used for mixtures.
A good correlation of the resulting
coefficients of the inverse twelfth repulsion energy term
was obtained by converting to a basis conforming to the exponent for Slater wave functions, with the internal shielding
essentially as given by Slater's rules.
The numberical values for the second virial coefficients,
and derivatives, for the various pairs of interest have been
taken from the same source (Ref. 10).
They were based on a
specialization from a general polyreciprocal potential to
the particular case of a general 12, 6, 4 potential approximately covering ion-neutral and neutral-neutral pair effects.
The interactions considered in these calculations are shown
in the intidence matrix in Table F.
The virial coefficients
and temperature derivatives for certain selected temperatures
are given in Table G.
In computing the corrections to the
properties (Eqs. (13), (16),
(21)), the program was arranged
to consider the contribution of the included pairs when the
product C x C exceeded 10-40.

AEDC-TR.65-58

SECTICN Vi
DISCUSSION OF THE TADLES

Table L gives the folllc-inz thermodynamic j2operties:

the compressibility factozr, Z - PV/PT; the dL cnsionless internal energy, E/RT; enthnlpy, H/RT; the entropy, S/R;
logl 0 P (atm); and the number of moles Z* - Z C . The tables
are presented at iCO-deg intervals from 1500 to 15,000 K.
They were compu~ed at uniform intervals (0.2) in lo_ P/P
from p/po - 10
to somewhat over 100 times normal d nsity.
The densities corresponding to the logarithmic arguments are
given in Table D. The compressibility isotherms are shown
graphically in Figs. la and b.
Unlike the ideal calculations, the tabulated values of
Z are the compressibility factors and not the number of moles.
These two values are coincident only when gas imperfections
are small.
The influence of the gas imperfections on the
compressibility are shown graphically for selected temperatures in Figs. 2a, et seq., for the second virials and in
Fig. 3 for the limiting-law Debye-HUckel effect.
It will be
observed from Eqs. (13), (18), and (20) that for the limitinglaw Debye-IfUcltel effect the corrections to the internal energy,
enthalpy, and entropy are simple multiples of AlZ.
Thus,
Fig. 3 can be used to assess this influence on four of the
thermodynamic properties tabulated.
The thermodynamic properties presented here result from
the solution of equations involving the equilibrium between
28 species shown in Table B.
The equilibrium compositions
for selected temperatures are shown in Figs. 4a, et seq.
Numerous works have appeared (largely in the form of
technical reports) representing various approximations to
the thermodynamic properties of air and its constituent gases
at high temperatures.
The earlier works are discussed or
cited by Gilmore (Ref. 2) and in Ref. 1. Some of the more
recent results for a number of gases have been compared in a
detailed review by Rudin and Ragent (Ref. 14), and those for
air by Hochstim, in a comprehensive treatment (Ref. 9) of
closed form solutions for the equilibrium calculations for
air.
Part 1 of that work seems suitable to supplement this
report and is reproduced herein as Appendix I with the permission of the author, Pergamon Press, and the Advisory
Group for Aeronautical Research and Development.
In view of
the scope of the treatment in Appendix I, this report is confined to a comparison of the present results for the imperfection corrections with those in Ref. 15, the only other
work we have seen which attempts such corrections.

AEDC-TR-65535

the basic input data from which

As indicated earlier
the present tables wcre conputed are, with the exception of

small diffcrences, consistent with the innut used in certain

earlier vorlrs (Refs. 1 and 2). For e.a [Jo, the neglect of
0 and CIT in our preosnt calculations d~c not influe!nce the
Gi!!Aore's results shou
thermodyna.,ic properties tabulated.
the maxrmuin concentration of ozone to b) approximately 10-6
moles per mole of air at 50000 X and 10 times normal density
For CN the largest concentration shown (Ref. 15)
(Ref. 2).

is approximately 7.10-6 moles per mole of air at 8000 0 K and

The concentrations of these species
10 times normal density.
fall
off very rapidly with density as well as with temperaWhile these and other minor species do not contribute
ture.
very much to the thermodynamic properties of the mixture,
they often play importaat roles in radiation and other phenomena at high temperatures.
In view of the above, those portions of the present
tables where the real gas effects are small should be in
good agreement with the work of Gilmore (Ref. 2) and Ref. 1.
For this reason the comparisons made in Appendix I of earlier
works (Refs. 16, 17, 18, 19, and 20) with those of Gilmore
can be considered as comparisons with the ideal portions of
the present tables.
The magnitude of the real-gas effects considered here
can best be ascertained from Figs. 2a, et seq., and 3, and
from Table 11 which gives the property differences, exclusive
of the equilibrium compositions resulting from
of the shift
corrections.
the Debye-Hffckel and the second virial
, to the equilibrium
corrections r
The second virial
of the species
concentrations
constants (and hence to the
non-reference species.
present) are greater than unity for all
thereby
constants,
This effect increases the equilibrium
over
that of
favoring the formation of the molecules and ions
These effects appear most dramatically in
the neutral atoms.
the elevated temperatures region only at high densities where
on the conThe influence of the virials
the ions persist.
This inin Fig. 4b.
centrations of the ions is seen first
fluence b comes more pronounced at higher temperatures until,
at 12,000 K (Fig. 4d) and above, sharp minima occur in the
Corresponding inconcentration curves for the atomic ions.
creases in the concentrations of the molecule ions and the
molecules, though present, do not appear so dramatically.
The overall effect of the changes in the concentrations
The
on the properties of the mixture is small, however.
major effect of the gas imperfections as shown in Figs. 2a
The same
through d is from the deltas computed in Eq. (13).

10

AEDC-TR-65-58

may be said for the corrections to tile internal energy,

entropy, etc., given in Eqs. (16) and (21).
As early as 1959 Gilmore carried out a number of spot
calculations of the effect of the gas imperfections on the
compressibility, internal energy, enthalpy, entropy, and
pressure of air
(Ref. 15).
He computed second and third
virial
coefficients for "air" as a single substance on the
assumption that a Lennard-Jones 6-12 interaction potential
with the constants C/k = 102 0 K and a = 3.62A applied.
His
results for the compressibility factor, Z, as shown in Figs.
2a through c, serve to confirm the general trend of the corrections which are computed in detail here.
Although only
approximate, the corrections by Gilmore corroborate the assumption that influence of the third virial
corrections in
the region of between 10 and 100 times normal density is
small compared to that of the second virial
contribution.
Above 100 times normal density the neglect of the third and
is obviously more serious.
higher virials
The influence of the basic input data on the equilibrium
properties has been amply discussed elsewhere (Refs. 1, 2, 9,
15, and 21).
While the tables presented here represent a
closer approximation to the properties of air than has been
computed heretofore, they are by no means the last
word.
The
improvement of the tables depends upon further theoretical
formulations for the inclusion of higher ionic and higher
virial
corrections, as well as a significant increase in
knowledge to be gained from a variety of experiments.
Much
more information is needed on excited states
of molecules
and molecule ions; on interaction potentials between the
neutral and between the charged species present in high temperature gases; and on such data as heats of formation, dissociation energies, ionization potentials, etc.
For a number of reasons it is obvious that the tables
are given to one or, in some instances, two places more than
is warranted by the uncertainties in the input data.
This is
done to ensure smoothness for further mathematical manipulations.
Although the computer program and the results have
been checked in a number of ways, it would be unrealistic to
The authors
assume that the tables are entirely error free.
hope that such errors as remain are small and would appreciate
having any remaining errors called to their attention.
The tables presented here provide only one third of the
complete ensemble of properties required in modern technology.
In addition to these tables it is important to have consistent
derived properties including: the specific heats, the specific
heat ratio,
isentropic expansion coefficient, and sound velocity.
Equally important for many applications are tables of

11

AEDC-TR.65-58

equilibrium properties across normal shocks.

In the past,
other authors have computed numbers of tables and charts of
these properties from Ref. 1 by employing numerical or graphical techniques.
These tables and charts now require revision
of greater or lesser degree on two counts - the influence of
the real-gas corrections at the higher densities, and inaccuracies arising from the numerical differentiation of the energy.
Work is now underway at NBS for the direct calculation
of specific heats and the other derived properties, as well
as for the properties across normal shocks.
Tables of these
quantities should be available in late 1965.
REFEREtRCES

1.

Hilsenrath, J., Klein, M., and Woolley, H. W. "Tables of

Thermodynamic Properties 0 of Air Including Dissociation
and Ionization from 1500 K to 15,000 0 K.11 AEDC-TR-59-20,
December 1959.

2.

Gilmore, F. R.
"Equilibrium Composition and Thermodynamic
Properties of Air to 24,0000 K.'' The Rand Corporation,
RM-1534, August 24, 1955.

3.

Hilsenrath, J., Klein, M., and Sumida, D. Y. "Mechanizeld

Computation of Thermodynamic Tables at the National
Bureau of Standards.
II.
The Calculation of the
Equilibrium Compositions and Thermodynamic Properties
of Dissociated and Ionized Gaseous Systems."
Thermodynamic and Transport Properties of Gases, Liquids
and Solids, An,.
Soc. Mech. Eng., New York, 1957-

4.

Woolley, H. W. "Thermodynamic Properties of Gases at

High Temperature: I.
Chemical Equilibrium among Molecules, Atoms, and Atomic Ions Considered as Clusters."
J. Research NBS, Vol. 61, RP2916, 1958, pp. 469-490.

5.

Moore, C. E.
Atomic Energy Levels.
National Bureau of
Standards Circular 467, Vol. I, 1947, Supt. of Documents, Government Printing Office, Washington 25, D.C.

6.

Hilsenrath, J., Beckett, C. W., Benedict, W. S., et al.

Tables of Thermal Properties of Gases.
National
Bureau of Standards Circular 564 (1955).
Reprinted
as Tables of Thermodynamic and Transport Properties
of Air, etc.
Pergamon Press, Oxf
1?--

12

AEDC.TR-65-50

7.

Beckett, C. W. and Haar, L.

Proceedings of the Conference on Thermodynamic and TYranpnt4
J.opcrtiesol
Fluids.
Institution
of Mechanicial Lngincers, London,
27-33.

8.

Woolley,

9.

Hochstim, A. R.
"Theoretical Calculations of Thermodynamic Properties of Air."
Fifth AGARD Combustion and
Propulsion Colloquium.
Pergamon Press, 1963, pp. 3-44.

10.

Woolley, H. W.
"The Calculation of Thermodynamic Properties
of Gases at High Temperatures."
AFSWC-TDR-62-21,
March 1962.

11.

Kirkwood, J. G.
Physik Zeits,

12.

Hornig, J. F. and Hirschfelder, J. 0. "London Dispersion

Forces between Unlike Molecules." Letter in Journal
of Chemical Physics,
Vol. 20, November l532,Tp.7l--T12.

13.

Margenau,

14.

Rudin, M. and Riat:ent, B.

"High Temperature Thermodynamic
Properties of Selected Gases."
Office of Technical
Services, Department of Commerce, Washington 25, D.C.,
ARL 62-358, May 1962.

15.

Gilmore, F. R.
"Additional Values for the Equilibrium
Composition and Thermodynamic Properties of Air."
Rand Corporation Report, RM-2328, December 30, 1959.

16.

Logan, J. G. and Treanor, C. E.

"Tables of Thermodynamic
Properties of Air from 3000 to 10,O000K at Intervals
of 1000 K."1 Cornell Aeronautical Laboratory, Buffalo,
New York, Report BE-A-3, January 1957.

17.

Landis, F. and Nilsen, E.

"Determination of Thermodynamic
Properties by Direct Differentiation Techniques."
Progress in International Research on Thermodynamic
and Transport Properties. ASME, Academic Press, 1962.

18.

Stupochenko, E. V., et al. "Thermodynamic Properties of

Air in the Temperature Interval from 1000 to 12,000OK
and Pressure Intervals from 0.001 to 1000 Atm."
Physical Gasdynaamics, Academy of Sciences of U.S.S.R.,
1959, pp. 3-33; English translation in J. Amer. Rocket
Soc., VYl. 30, 1960, pp. 98-112, and also published by

H.

PergajwJn

H.

W.

Unpublished Calculations.

"Theory of Atoms; with Many Electrons."

Vol. 33, January 15, 1932, pp. 57-60.

Philosophy of Science,

Press,

Vol.

8,

1941,

p.

603.

1961.

13

AE DC.T R-65-58

19.

Hochstim, A. R. "Tables of Equilibrium Composition,

Thermodynamic and Shock Properties of Air with Additives." General Dynamics/Convair Physics Section
Report ZPh-122, December 1, 1961.

20.

Wachman J. and Linevsky, M. "The Chemical Composition

of Thermodynamic Properties of Ai2-Carbon Mixtures."
General Electric Co., Report R59SD349, April 1959.

21.

Neumann, K. K.
"Discussion of Errors in the Calculation
of Simultaneous EquilibriF.."
Progress in International
Research on Thermodynamic and Transport Properties,
X-"aaemic Press, 1962, pp.2-YU9217.

14

AE DC-TR-65.58

APPENDIX I
THEORETICAL CALCULATIONS
PROPERTIES OF AIR

OF THERMODYNAMIC

By
Adolf R.

Ilochstim*

Space Science Laboratories,

General Dynamics-Astronautics,
San Diego,

California

(Reprinted by permission from Fifth AGARD Combustion

and Propulsion Colloquium, Pergamon Press, London,
1963.)

*Present address:
Washington, D. C.

Institute

for Defense Analysis,

AEDC-TR-65-58

REVIEW OF M1 il -TM.1 PZATURES ECUILIMJUM

THERtiODYN,"AW61C
During the past six years,

expended in

Q7OPERTIES OF AIR
considerable effort hns been

computing the theodynamic properties of high-

The discussion here vill be limitcd

temperature dry air.
only to treatments based on the high (9.7 eV) value of the
dissociation energy of nitrogen, which was overwhelmingly
Several of the treatments betsupported by many authorsI- 7 .
ter known in the U.S.A., but unpublished, will be discussed
and then compared with the papers by authors in the U.S.S.R.
and Germany.
One of the most elaborate and accurate calculations was
done in 1955 by GilmoreB, who computed species concentrations
thermodynamic properties (internal' energy,
and first-order
for 11
compressibility, entropy) of high-temperature air,
temperatures (1000 < T < 24,000UK) and 11 densities (-6 <
< 1), usiing tie ideal free energies for 30 constitlog P/o
910

In 1956
uents in air computed by standard techniques-".
3
calculated ideal thermodynamic properties
Beckett and Haar'
N2 , N2 +, NO, and NO+ above 50009K, using for the
of 02, 02+
ground electronic state the Morse potential function and calculating convergent thermodynamic functions of these species
coefficient by a
through the evaluation of the second virial
4
Thereafter, based on
technique described by Woolley- .
Ref. 13, Hilsenrath and Beckett' 5 issued tables of firstorder ideal thermodyLamic properties of a high-temperature
Their
mixture of 21.153 percent 02 and 78.897 percent N2 .
tables contain data for closely spaced temperatures up to
From these tables, Feldman1 6 and
15,000K and 45 densities.
7
Korobkin and Hastings1 prepared Mollier diagrams, and normal
shock properties in air were calculated by Feldman" 6 and
Hochstim' 8 . The Hilsenrath and Beckett tableq were inverted
by numerical interpolation to give values at constant presnumerically
sure and entropy by Blackwell et al.1 9 , and fitted
Hochstim2 1 obtained
by various authors (e.g. Grabau 2 ").
thermodynamic properties of second order (velocity of sound,
specific heats, and various isentropic exponents) by numerical differentiation of the Hilsenrath-Beckett tables and by
numerical interpolation of various properties at constant
Also in 1957, independently of Hilsenrath and
entropies.
Beckett, Logan and Treanor 2 2 calculated thermodynamic propof air (78.0881 percent N2 , 20.9795 percent 02, and
erties
0.9324 percent A) from 3000 to 10,0000 K, at closely spaced
temperature intervals and for 11 densities, using computational methods for thermodynamic properties of species similar
to those of Gilmore but with fewer species; these 'authors
include in their tables the velocity of sound and specific heats.

17

2 3 also e:xtendled the N.B.S.

Silsenrath, Green, and Eec!:ett
tables (including contributions frc:- radiation) to highly

ionized vir up to 5 x 106 o for selected valuez of tciporaEilscnrath, Klein, and Uoolley2 4 rcissued :aore closely
tures.
p.opa-tics o: air
Ayn-nmc
spaced tables of first-order thor c.
from 14O0 to 15,00001C, which includz -rgon and cnrbon dioxide
in the s.zMe ratios as used by Gilmore.
The results of Gilmore, Hilscrrath et al., and of Logan
and Trennor were obtained for an iceal mixturi as a function
of temperature and density, and by solving the nonlinear set
of algebraic equations involving equilibrium constants and
the equations of mass and charge conservations for the norRecently, Stupochenko et a1 2 7 - 3 0 ,
malized concentrations.
of the U.S,.S.R., tabulated molar fractions and thermodynamic
properties of air (omitting carbon dioxide) as a function of
Burhorn and Wienecke 3 ' in Germany
temperature and pressure.
used only a few major species and tabulated partial pressures
for air as a function of temperature and pressure; however,
their partial pressures often disagree considerably with
other tabulations (e.g. Refs. 8 and 39), although the heats
of formations and the internal partition functions for diatomic molecules are in good agreement.
In 1958, Hansen 32 derived a very simple closed form solution for high-temperature air, starting with an approximate
Ile used approximate partition functions for
physical model.
N2 , 02, N, 0, N+, and 0+ (for the rigid rotator and harmonic
few electronic levels) and
oscillator and only the first
divided the tables of air into three parts: oxygen dissociation r4gime, nitrogen dissociation r4gime, and a r4gime with
only ionization of nitrogen where he assumed that the equilibrium constant for the atomic oxygen ionization reaction is
approximately the same as for atomic nitrogen ionization.
Hansen's method gave different solutions for each r4gime.
The results reproduced closely the compressibility and internal
energy as compared with more detailed calculations, especially
Hansen
at lower densities at which nitric oxide is negligible.
as a function of temperature and pressure.
obtained 3 solutions
Hochstim 3, 3 4 extended Hansen's method to a single continuous
solution as a function of temperature and density applicable to
the entire dissociation r4gime of 02 and N2 . The solution inoxide using a modified form of partition
corporated nitric
functions for diatomic molecules and diatomic ions, together
derivatives 3 5
with closed form expressions for various partial
of concentrations and approximate electron concentrations 3 4 .
In 1958, a new numerical technique was introduced by
White, Johnson, and Dantzig of RAND Corporation3 6 y37 . This
technique ("the RAND method") is based on a numerical method

18

AEDC-TR-65-53

of minimization of the Gibbs free energy, or of the Helmholtz

free energy, and one can obtsin a solution as a function of
either tepora-ptu.e and pressure or tc;.:U2rature and density.
Also, one does not need to restrict tU2 form of eql'iations 1y
z..This
tec!,.,u:.
of speocies or ......
chaniring the nVi:'.r
of
b
as a fncti
%
on1 ofLta...
was applied i
also as a function
pressure and tc:::jerature by Fcige... s
and density for air and air with additives by
of temperature
Hochstim3 9, and for carbon-air mixtures by Wachman and
Linevsky4o.
The high-temperature ideal second-order thermodynamic
properties (specific heats and velocity of sound) above
1500 0 K do not smoothly join the lower temperature values
(50-3000 0 K) of Hilsenrath et al. 4 1 , because of neglect of the
concentrations of nitric oxide, oxygen and nitrogen and the
The second-order thermocorresponding partial derivatives.
dynamic proper'I.es in the transition r6gime were computed in
this paper and are listed in Table 6 and Table 7 [not reproThis r6gime was lately approxduced in this appendix - Ed.].
imated by Curtis and Wohlwill 4 2 .
Comparison of the calculations of Gilmore,
et al.

1 5

'

2 4

Logan and Treanor 2

Hilsenrath

, Feigonbutz 3 8 , Hochstimn 9 ,

and Predvoditelov, Stupochenho et al.272 9 , shows that the

The larger
thermodynamic properties agree within 1 percent.
discrepancies (up to 4 percent) are in the entropies, as
reported by Predvoditelev et al. 2 7 , and in their electron
concentration, due to their omission of 07 and 02 and to their
choice of a rather high value of ionization energy for nitric
oxide (9.5 eV vs 9.25 used by Gilmore 8 and Rochstim3 9 , since
the lower value seems to be confirmed 4 3 .
The collision frequency needed for the electromagnetic
properties of air was computed by Shkarofsky, Bachynski, and
Publications
Johnston 4 4 ' 45 as a function of electron energy.
on the normal shock properties of air are very
numerous, *8,i6,18,

4649

19

AED~C-TFZ-65-58

PropW't-s of

Species Used in the Calculation of TL:r;no'ynarnt

Air In Equili!~Tlun,
(X used;

not uccd)
Refcaence

ft

0O, No.N,O0

x
x
x

x
x
x

e-

x
x
x

NO
0+,N,,N,0
NO+

x
x
x

0+,N+x

0-,
N+++,

0++

0,

x
x

x
x
x
x

x
x
xe

x*

X
X

Ne, Ne+

C1.1 CO, c0I

-.

x
x

-O

CN

NO,
N,O

x+
x

0-

x
x+
4

x
x
x
-

--

X
x

A-x

A+

x
x

x
X
X*

X
X

)(

*Used only above 6000'K. "Ref. 8b +Ol

N+ and 01 above 60000 K. No
0+2, N+,. +O+ above 16,000'KZ. 0+0, only. ARer. 8a, Gilmore. DRef. 15,
Hilsenrath-Beckett. rRef. 22, Logan-Treanor. DRef. 24, Hilsenrath-Klein-Woolley. FRer. 38, Feigernbutz-Solum. F'Ref. 28, Stupochenko el ad. GRer. 31,
Burborn-Wienecke. "Rdr. 39, Hochstirn.

20

AEDC.TFR.65. 513

00r
M~JC~

~C4 A C~0
-n6

C4

Lzo

')

C6

en

c;

'!.

'K

'-

co C4

-l

C~1 L"I

Cn Q0I4C
'IQ0--

-:

Ip

Cj

on

en

0-

An

-01IIH

rJ-

0 to
0,1 c,'

+ ++ +~

~++

++

21

C~Ir-

C~
4

C-! .
w

r,

-,'

taU

C41

'0'P cn0

I~tf

__

pf
II

"44

ii
o

a.

S~
22pr-e

co

f,.,

~
I

v~

u A

)-

AEDC-TR.61'-!.

REFP

,: S

1.

Dougl-s,

2.

Tho.:.f;, N. , Gayd on...,

2..0, 309 (1952)

3.

Kistiakows!y, G. B., Knight, If. T.

Chem. Phys. 20, 876 (1952).

4.

Farber, M. and Darnell,

(1953).

5.

'Wynen, 11. H.
(1953).

6.

tlendrie,

7.

Clarke, E.

8.

Equilibriuna Composition and ThermodyGilmore, F. R. (a)

namic Properties of Air at 24,OOOOK, The RAND Corporation, 1700 Main Street, Santa Monica, California',
Report Rri-1543, 24 August, 1955 and (1) Additional
Values for the Equilib.,iuu Composition and Thermodynamic Properties of Air, Report R14-23213, 30 December
1959.

9.

The Specific Heat of Air up to 25,000 C,

Bethe, H. A.
OSRD Report 369, 9 February 1942.

A. E.

J.

C;npd. J. E-u.
A. G.

M.

J.

and Erower,

A. J.

J.

L.

(152).
J. Clh'c

and LValin,
Chem.

.J.

Chem.

Pylys.

22,

1503 (1954).

J.

Phys.

32,

764 (1954).

Cnnad.

Chem.

Phys.

Y-i. .m.

M. E.

Phlys. 21,

H. A.

and Taylor,
M.

30, 302

J.

172

21, 233

10.

Project RF-316 (ONR Project No.

Johnston, H. L. et al.
NR058005), Ohio State University Research Foundation,
Technical Reports No. 4 (02) 6 (CO), 9 (N2 ) and
1949-53.
10 (NO),

11.

Mayer, J. E. and Mayer, M. G.

Wiley, New York (1950).

12.

Woolley,

H. W.

289

(1954).

13.

J.

Res.

Statistical Mechanics,

Nat. Bur.

Stand.

(U.S.A.)

52,

Thermodynamic Properties at
Beckett, C. W. and Haar, L.
Ideal Gas Thermal Functions to
High Temperatures:
25,000K for Diatomic Molecules:
Oxygen, Nitrogen,
Nitric Oxide and Their Molecular Ions, Proc. of the
Joint Conference on Thermodynamic and Tr-ansportF-F6po0 -- IC-E-hanical
erties of Fluids, pp. 27-34,7nstit--tion
Engineers, London (1957).

23

AEDC-TP*-(-50

14.

roollcy, 11.
Thermaodynamic Properties of Gasec at IiZh
Temperatu re:' Chemical Equilibrium Among Yolecules,
Atoms, and Atomic Ions Considcred as Clustcrs, J.
Res. Eat. Bur. Stand. (U.S.A.) 61, 469 (I1SS).

15.

Ililsenrath, J. and Eocloett, C. W. Tables of TLcaodynamic

Properties of Argon Froe Air to 15,0001K, N.B.S. and,
Arnold Engineering Development Center, Report T4-5G-:
12, AD 93974, MIPR-AEDC-l, September 195G.

16.

Feldman, S.
Hypersonic Gas Dynamic Charts for Equilibrium
Air, AVCO Research Laboratory, Everett, Massachusetts,
January 1957.

17.

Korobkin, I. and Hastings, S. M. Mollier Chart for Air

from 2000 to 15,0008K, U. S. Naval Ordinance Laboratory, White Oak, Maryland, Report 4446 (May 1951).

18.

Hochstim, A. R. Gas Properties at Hypersonic Velocities,

I. Normal Shocks in Air, Convair-San Diego, Physics
Section Report ZPh-002, ASTIA Document No. 134398,
January 1957.

19.

Blackwell, F. et al.
Properties of Argon Free Air, the
Ramo-Wooldridge Corporation, P. 0. Box 299, Los
Angeles 45, California, Report GM-TR-76, October 1956.

20.

Grabau, M. A Method of Forming Continuous Empirical Equations for the Thermodynamic Properties of Air from
Ambient Temperature to 15,000K with Applications,
Arnold Engineering Development Center, ASTIA Document
No 366945, AEDC-TN-59-102, August 1959.

21.

Hochstim, A. R.
Gas Properties Behind Shocks at Hypersonic Velocities, III.
Tables of Thermodynamic Properties of Air, Convair-San Diego, Physics Section
Report ZPh-004, 1957, revised 1 August 1958.

22.

Logan, J. G. and Treanor, C. E.

Tables of Thermodynamic
Properties of Air from 3,000 to 10,000K at Intervals
of 100 0 K, Cornell Aeronautical Laboratory, Buffalo,
New York, Report BE-A-3, January 1957.

23.-

Hilsenrath, J., Green, M. S. and Beckett, C. W. Thermodynamic Properties of Highly Ionized Air, National
Bureau of Standards, AFSWC-T1-56-35, ASTIA Documept
No. 96305, Kirtland Air Force Base, N. M., April 1957.

24.

XLilsenrath, J., Klein, M. and Woolley, H. W. Tables of

Thermodynamic Properties of Air Including Dissociation
and Ionization from 1500 to 15,000OK, National Bureau
of Standards OSS-59-24 (AEDC-TR-59-20), December 1959.

24

AECC.TFR-6S-.0

25.

Nilsen, E. N. and Landis, F.

Thermodynamic Properties of
Ionized and Dissociated Air from 1500 to 15,000K,
Pratt and Whitney Aircraft Co., East Hartford, Conn.,
Report 1921, January 1131.

26.

Landis, F. and Nilsen, E.

Deteri:minntion of ni T'-c(.namic
Properties by Direct Differentiation Techniques in
Progress in International resoarch on Thermodlynamic
anTdTranspo.:t Properties,
Academic Pres

27.

Predvoditelev, A. S., Stupochenko, E. V. et al.

Tables of
Thermodynamic Functions of Air for Temperature Range
Infosearch Lim-,ited,

Lon-don-, i-E3.

28.

Stupochenko, E. V. et al.
Thermodynamic Properties of
Air in the Temperature Interval from 1000 to 12,000K
and Pressure Intervals from 0.001 to 1000 atm., in
Physical Gasdynamics, pp. 3-38, Academy of Sciences
o-fU.S.S.
UI-9.Y
English translation in J. Amer.
Rocket Soc. 30, 98-112 (1960) and also publish,
y-Pergahion Press (1961).

29.

Predvoditelev, A. S. et al.
Tables of ThermcrT1:1,J1.iC
Functions of Air (for T /.......
fro.m l.....to
-G:i: --a-d Pssures
from.
Oi to -UU Eti'I),
1iiubl.
by A-_Eemy of Scieuces , U.'ST.h.,
61 .oscow,
(in
Russian).

30.

Stupochenko, E. V. et al.
Thermodynamic Properties of
Air at High Temperatures. Eighth Symposium (International) on Combustion, Williams and Wilk-ins,
Baltimore (1952).

31.

Burhorn, F. and Wienecke, R.

Compositicn of
Density, Enthalpy, and Specific Heats of
Nitric Oxide and Air for 1, 3, 10 and 30
Temperatures between 1000 and 30,000K.
Z. Phys. Chem. 215, 269 (1960); 212, 105

32.

Hansen, F. C.
Approximations for Thermodynamic and Transport Properties of Hign-Temperature Air, NACA Report
TN-4150 (March 1958) and revised as NASA Report TNR-50,
1959, Ames Research Center, Moffett Field, California.

33.

Hochstim, A. R.
Approximations to High Temperature Thermodynamics of Air in Closed Form, in Kinetics, Equilibrium and Performance of High Temperue ystems,
o-utterwat
s,. Washington and London (19160.

Plasma,
Nitrogen,
atm, for
(in German).
(1959).

25

AEDC-TR-65-50

34.

Hochsti., A. 11.
Electron Concentration in Closed Form
for 'Igh Temporatu:re Air and Air vith Additives in
Electrc.' -rnetic
E1ffcts of Re-entry, Pergamon Press,

35.

Hochstii-l, A. R. and Adams, B.

Closed Form Exact Solutions
for the First Partial Derivatives of Concentrations
of Chemically Reacting, Mixtures in Equilibrium,
Specific Heats and Related Quantities, in Progress
in International Research on Thermodynamic- -nd--ir-ans,= cademic Press 1962).
port
-roperties,A

36.

White. W. B.,
Phys. 27,

37.

Kinetics, Equilibrium and Performance of High Temperature

Systems, Proceedings of the First Conference, Western
States Section, The Combustion Institute, Ed. by G.
S. Bahn and E. E. Zukoski, Butterworths, 1960.

38.

Feigenbutz, L. and Solum, E.

Thermodynamic Properties of
Air, Convair-San Diego, Thermodynamics Group, Report
ERR-SD-005, April 1960.

39.

Hochstim, A. R. Tables of Equilibrium Composition,

Thermodynamic and Shock Properties of Air with Additives, General Dynamics/Convair Physics Section
Report ZPh-122, 1 December 1961.

40.

Wachman, J. and Linevsky, M. The Chemical Composition

of Thermodynamic Properties of Air-Carbon Mixtures,
General Electric Co., Report R59SD349, April 1959.

41.

Thermal Properties of Gases,I

Hilsenrath, J. et al.
National Bureau of Standards Circular 564, 1955, U.
S. Dept. of Commerce.
Published also as Tables of
Thermodynamic and Transport Properties of Air, CO,
CO, H2 , N2 , 02, and Steam, Pergamon Press (1960).

42.

Curtis, M. W. and Wohlwill, H. E.

Thermodynamic Properties of Air from 1000 to l0,6000 K and 4500 to
14,800 0 K Aong Contours of Consta.nt Density, Enthalpy
and Entropy.
Space Technology Laboratories, Inc.,
P. 0. Box 95001, Los Angeles 45, Calif.
Report 71020012-MU-000, 3 March, 1961 and Repcrt 7102-0012-MUAOl, 21 June 1961.

43.

Cloutier, G. G. and Schiff,

793 (1959).

26

Johnson, S.
751 (1958).

M. and Dantzig,

H. T.

J.

G. B.,

Chem.

Phys.

J Chem.

31,

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44.

Shkar~fshy, I. P., Bachyn.A:i, M. P. and Johnston, T. W.

Collision Frequency Associated with High Temporature
Air in Elec.tro.,magnetic Effects of Re-entry, P-rgamon
Press (EEth.).

45.

Bachynski, M. P., Johnston, T. W. and Shkarofsky, I. P.

Electromagnetic Properties of High-Temperature Air,
47, 3,347-356 (March 1960).
Proc. IRE.

46.

Romig,

47.

Thermodynamic and Gasdynamic

Rozdestvenskii, I. B.
Normal Shock with an Account
Air
Behind
Properties of
Article in
of Dissociation and Ionization of Air.
Physical Gasdynamics. Publ. by Academy of Sciences,
U.S.S.R., Moscow 1959 (translated into English by
Pergamon Press (1961)).

48.

Normal and Oblique Shock CharBachelder, R. A. et al.

Douglas Air'raft
acteristics at Hypersonic Speeds.
Co., Engineering Report No. LB-25599 (Dec. 1957) and
Supplement I (Feb. 1959).

49.

Determination of GLsdynamic Prop,rties

Gorban, N. F.
of Flow behlind Normal Shock Wave with Correction for
Variable Specific Heats and Dissociated Air, Article
in Physics Gasdynamics, Published by Academy of
Sciences, U.S.S.R., Moscow, 1959 (translated into
English by Pergamon Press (1961).

M. F.

J.

Aero.

Sci.

23,

185 (1956)

27

AEDC-TR-65-E3

14 WP

__00

15.' 0000
11:0000>L1 .0 00 2 >83

5000P
See
Fig. lb40P

-5
log p/P 0

-10

Fig. I Compressibility Isotherms for Air

29

AEDC.TR.SS-S1

2.5

rm

15, V55 K
14, COCt,!-'

12, CE'2
10, vo":,"

20~

1.5

1.0

2,O O K / "
3

1
log p/P
Fig. 1 Concludad

30

-1

-2

AEDC-TiR.-50

0-I

A[ D,,.: "i7',.,o cO
GiI-norc Cn%e.
6)

1.6

1.5

1.41
I-

N 1.3

1.2

Ra

Real
1.10,
1.0

0.4

---

---

1.0

2.0

2.8

log pip0
a. T

2000'K

Fig. 2 Corrected and Ideal Compressibility Isolherms for Air

31

AEDC.TR-65-58

1.7
o Giimorc (?.6)
"1.6

} .........
--

1.5

1.4
c-

1.3

1.2

--

1.1

----

Real

....-

E z

1.0w20.4

1.0

2.0
log P/P0
L. T = 6000cK
Fig. 2 Continued

32

2.8

AEDC.TR.65.58

1. 7

......

I1-

This CacuL=j
o

Gilmore (a-c

1.6.

1.5

1.4
S1.3--------------------------

--.

1.-

1.0
0.4

1.0

2.0

2.8

log p /Po0
. T = 8000'(
Fig. 2 Continued

33

AEDC-Tfl.65-S,

1.9

1.8

1.7

This Calculation
AEDC-TR-59,-20

--

1.6--

"w

/Real

0-

Id

"1.2-

0.4

2.0

1.0
log pIp0
d. T

12,0000 K

Fig. 2 Continued

34

2.8

AEDC-TR-65.53

2.1~~~

11J-I1 --

--

2.0

___

____

This CU cu!.-tion

1.9

--

,i

eat

1.8

--

1.7

Idea

N 1.6

1.5

1.4

1.3 ,

1.2

0.4

----

1.0

2.0

2.8

log p /po
..

15,000-(

Fig. 2 Concluded

35

AEDC.Tr!.654e5

0-1

36-

AE DC-TR-65-58

100

N2

_ ___........

N2

C)2

10-

0.1
02

NO-

1.0

0.01

NO

,-NO2
2

0.1

-0.001

C2
C02

N-

0.
4

N2 0\

C02
'CO

Ne

Xo0.o00001
-2

-4

-6

-8

log piP0
a. T = 2000'K
Fig. 4 Equilibrium Composition of Air

37

AEDC-T R-65-50

10 -3

--2

0.1

10.

00.0
1.0

2O.
C+

0.

1_

NOo.

O1
/

0.1

0C+
.0001

co-.

0.0001
0.01

0. 001

--,-

.000

N+

-\

-2
log p/p 0
b. T - 6000-K
Fig. 4 Continued

38

2Ne

e-

-4

-6

-8

AEOC-TR-65-58

100

1.0

NO
10.0

020

0.010

00

0.01

0__001_

0c.

T0.0000
Fig. 4 Cotn+

N229

AEDC-TR-65-SB

//-----_ 0
I0

1.0

. '"-

-N

NO
\

O+
.

0.1

02 -

'-

O.O1

t.

N "-

O.1

0.01

,_

"

,,

0.001

N20C

i,.

,A+

C+

O2

0. 000l

N++

A+"

0. 001
4

/
2

,....
-2
log p Ipo

d. T = 12,000
Fig. 4 Continuecl

40

-4

-6

.....

0. 00001
-8

AEDC-T,1-6S5-5

1001.

100

0.01
NO

U)C0+

0.01

+ 0.001

0
NC+

0 o2o

0.OC

_____

4 +

6-

2pp

NO

..

Fig.
02

5,00A9

Conlude
41

AEDC.TR,,65-5

it

of
u

11
0z

SZ 0 ZO
-

0-.

u u z z z

of
II

N-0..

o
z

0cc

'0 0

0
-O

7-0

,
-

"

"
0 0
- - -)

Sz

:z ::,z,. r
0

b..

0)

-"

zf

+
-

fI

0 0
- - --

TO.-.
-

"

0+

0+o

, c00

Z. .

+0 0.

C2-

. N
l N

l
In

t-

'2-

JC'rJ N ... '.N .

C'4

-r
LU

;0

0.

c'

;q-

00 0

0~

"N"

"-

NOO+++++

"

.-4
"-

"0

0
"

"-

KI
u'

NC',

NNOO

I It NI
of
0.- Z

I
is

0I
zz

of

"--

---

00

C.

C440 0
0

C14CM0
N1

+NC, 0

00

+V r +

o
+

0+

t0+40

~0

00)

Ct0
0)j
+
z
zn 0n z

o o
+

"OzO0
O
+

0 +z~~ +

++

0I

4)0

z0

0I

".
'l

0'

0<~

.5

uZ

ia+
0

z,-

-~~~

z00

'

U
0

00

0"
D

0i

CNINO0

~a)on

"'

(0 1'C

C'Iq

00

a)

0-"

laO
'N

+
0

003+ z

01

V'

Wj
5

t0

r-

+CC 44u +

00

0)

Ut

r.

.-

43

43

AEDC-TR-65-5O

TADLE

VITn,

C,;.

C
rVLE

,42A

Dj/R
i

Species

r il

ri12

r0

ri14

r i-

ri16

(OK)

16

-113258.

08

-59366.

NO

-75502.

Co

-128903.8

CO2

-192233.3

NO2

-111614.5

N20

2.

-132709.2

N34

-1

67561.7

0*

-1

82424.5

10

02-

-70968.

11

NO+

-1

31943.

12

C04

-1

33718.3

13

0-

14

N*

-I

168647.5

15

N*+

-2

512162.6

16

0+

-1

158033.

17

0++

-2

566006.1

18

-1

182885.7

19

A +

-2

503479.3

20

C+

-1

130663.2

21

C++

-2

413616.2

22

Ne+

-1

250252.9

23

24

25

26

27

Ne

28

44

-1

-16834.

AEDC-TR-65-50

TADLE C
MASS AND CHAR GE CA LA-

Specie

Mn+k

2 CCUATI4NS FCR AIR

Equations

n+5
1

NitrozCn

1.56100

1.60IG3

a 1.1 rlCi

n+5

OxyCon

.41958

.41053

a ilr

2 Ci

iai
3

Argon

.00934

.00034

CarLon

.00033

.OC033

Neon

.00003

.00003

Electrons

!rj 5 Cj

r",,rib CI

Cn+ 6
jul

45

AEUC-TR-65-18

TACLE D
DEINSITUI

log

f'

g lc n3

1.8

63.0957

8.15909*

101
I"12

1.6

39. 8107

5.14804.

12

1.4

25.1189

3.24820.

10-2

1.2

15.8489

2.04947 10-2

1.0

10.

1.29313 1i0

2.0

100.

1.29313"

0.8

6.30957

8.15909 10-3

0.6

3.98107

5. 14804. 103

0.4

2.51189

3.24820.

0.2

1. 584i9

2. 04947 10-3

0.

1.0

1.29313 10-3

-0.2

0.630957

8. 15909

10-4

-0.4

0.398107

5.14804-

10-4

-0.6

0.251189

3.24820

10-4

-0.8

0. 158489

2.04947 10-4

-1.0

0.1

1.29313

etc.

46

TO 14,7 TACULATED t~~

CUCZC:,V

etc.

10-3

104

AEDC-TR-65-58

TABLE E
INPUT DATA FOR AIR CALCULATEZ2S AT 6C00, 9003, A,!D 12,MClc

T
SPECIES
N2
02
NO
CO
C02
N02
N20
N2+
02*
02NO+
CO+
0N+
N++
0*
0++
A+
A++
C+
C.
NE*
N
0
A
C
NE
E-

3.94132E C2
5.84742E-02
3.48537E 00
2.46053E 03
3.91751E Cl
1.69248E-C3
9.94877E-03
7.71096E-09
2.31700E-0
8.67838E-08
8.85084E-07
6.70142E-C7
1.42717E-Ct
[.12874E-10
8.41234E-34
1.36530E-10
0.
2.61866E-11
2.0528IE-32
1.84423E-08
8.57236E-28
3.63364E-16
I.O0000E 00
1.OOOCOE 00
1.00000E 00
1.O0000E 00
1.O0000E 00
1.O0000E CO

=6000'X(

E/Rr*

ENTROPY

-15.56283
-6.18353
-9.18277
-18.16646
-26.00205
-13.00966
-16.79296
15.10438
L7.16682
-7.96400
8.62903
8.93529
-1.05357
29.68155
86.88795
27.86555
95.9052Z
37.07092
85.59220
23.28803
70.43642
43.26383
1.62184
1,56565
1.50024
1.62431
1.50000
1.50000

35.236L0
37.757C0
37.86700
36.C3800
45.40730
47.75482
44.76437
36.821C0
37.33500
38.80900
36.06700
36.69053
26.e5933
26.80756
26.33521
26.16025
26.96614
27.8q%44
28.39357
26.10544
24.31331
26.87900
26.t)7791
27.00013
26.11574
26.67565
25.09160
10.Cl4eO

The internal energy has been reduced to refer it

energy for atoms.

to the reference

47

AEDC-TR-65-S3

TABLE C (Continucd)
T
SPECIES

48

90000K
LNTRnPY

X/Rr

N2
02
NO
CO
C02
N02
N20
N2
02+
02NO+
Cc+
0N+
N+
0+

7.02030E-01
2.83035C-03
5.58997E-02
2.00465E CO
1.53469E-C3
4.62911E-C6
7.11292E-06
7.34251E-07
4.8612SE-C8
6.43418E-08
9.72265E-06
8.40936E-06
3.58387E-02
2.29934E-06
5.92088E-21
1.62112E-06

-9.11822
-2.60372
-4.01221
-10.90144
-15.09479
-6.67819
-9.29952
L1.55666
12.93948
-3.87733
6.97412
7.16554
0.45226
20.37078
58.42733
19.21595

37.166C0
40.C0500
39T.6000
37.91141
48.53595
50.58673
47.47567
39.03700
39.54300
40.95900
37.9570C
38.56532
28.64272
27.92113
27.35113
27.33587

0++
A+
A++
C+
C++
NE+

1.09884E-23
1.28074E-06
1.05177E-19
4.54176E-05
2.59481E-17
7.42240E-10

64.49418
21.89523
57.66698
16.03926
47.47478
29.34419

28.04784
28.92578
29.53352
27.13480
25.34606
27.89470

N
0
A
C

1.00000E
1O00000E
1.00000E
1.00000E

00
00
00
00

1.87547
1.62247
1.53057
1.68846

27.44195
28.10822
27.16263
27.817C5

NE

1.00000E 00

1.50000

26.10530

E-

1.O0000E 00

1.50000

II.C2840

The internal energy has been reduced to refer it

energy for atoms.

to the reference

AEDC-TR-65-50

TABLE E (cccncluej)
T
SPECIES

N2
02
NO
Co
C02
N02
N20
N2?
02+
02NO+
CO+
0N+
14+
O4
0++
A+
A++
C+
C++
NE+
N
0
A
C
NE
I-

2.70412?--02
6.85?3'%C-0.
6.Th",0C-03
5.741hirE-02
I.0eC74L-C5
2.40C2)4E-01
1.7213HE-07
7.6912?)T-C6
9.06t.33E-07
5.132 M
:1)E-C0
3.43814:E-C5
3.3971U-05
1.89291E-C2
3.49t4,)E-C4
1.85V13E-14
2.071W-E-0
1.74415E-16
3.14387E-04
3.07152E-13
2.50321E-03
5.73629E-12
1.205571-06
1.O0000E c0
1.O000CE CO
I.OOCOE CO
1.000o0E 00
i.0000:t 00
1.OOOOOE CO

12,000"K
E/RT*

ENTROPY

-5.72667
-0.76487
-2.52593
-7.25702
-9.61861
-3.51055
-5.55698
9.77254
11.10421
-1.94600
6.18582
6.29601
1.43310
15.73247
44.2036?
15.01039
48.81267
16.89023
43.76927
12.45449
36.07256
22.38372
2.07210
1.66374
1.80838
1.73926
1.50000
1.50000

36.72600
41.65900
41.39200
39.25802
50.78219
52.59828
49.39500
40.596G0
41.43500
42.35800
39.34200
39.91341
30.17816
28.73122
28.084E7
28.31006
28.H4372
29.74839
30.41582
27.91009
26.16707
28.61460
28.49509
28.91000
28.19648
28.64810
26.82450
11.74770

The internal energy has been reduced to refer it

energy for atoms.

to the reference

49

AEDC-1 R-65-58

TABLE F
INCIDEI1CE M4ATRIX FCR VIRAL CCZ.FF!CIDNTS
E
NE
C
A

0
0
1

o
N
NE+
C,
C*
A,+
A+
0#
N*
N*
CCO.
NO+
0202+
N2+
N20
NO2
CO2
CO
NO
02
N?

E
NE
C
A
o
N
NE*
C**
c*
A**
A+
0++
0+
N+*
N*
0CO+
NO+
02OZ0
N2#
N20
NO2
Ca?
Co
NO
02
N2

50

I
0
0
0
0
0
0
1
0
1
0
0
1
0
0
0
1
0
1
1
1
1
1
N2

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
N++

0
0
!
1

0
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
1
1
I
1
1
C2

0
0
0
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0*

0
0
I
1

I 1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
o
0
0
0
0
0
0
0
0
C 0
1
1
0
0
1
1
1
1
1
1
1
1
1
1
NO CO

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
a
0
0
0
0
0
0
0
0
0.*

0
0
0
0
1
1
0
0
0
0
0
0
0
C
0
0
0
0
0
0
0
0
0
0
0
0
0
0
A+

0
0
1
0
t
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
1
1
1
1
1
C02

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
o
0
0
0
0
A++

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
o
0
0
0
0
0
0
0
0
0
0
0
0
NO?

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
C*

3
0
1
0
I
1
0
0
0
0
0
0
0
0
o
o
0
0
0
0
0
1
0
1
1
1
1
1
N20

0
0
0
0
0
%,
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
N2.

0
o
0
o
C
0
0
o
0
0
0
0
0
0
0
0
0
0
0
o
0
0
0
0
0
0
0
0
o
o
0
0
0
0
0
0
C
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
C*+NE#

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
00
0
0
0
0
0
0
0
0
02*

0
o
1
I
1
1
0
0
0
0
1
0
1
0
I
1
0
1
0
0
1
1
0
1
1
1
1
1
N

0
0
0
0
0
0
0
0
0
u
0
0
0
0
0
o
0
0
00
0
0
0
0
o
0
0
0
02-

0
o
1
1
1
0
0
0
0
1
0
1
0
1
0
0
1
0
0
0
1
0
1
1
1
1
1
0

0
0
0
0
1
1
0
0
0
0
0
0
0
0
0
0
0
0
00
0

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0

0
0
0
0
0
I
0
0
0
0
0
0
0
0
0
0
0
0
00
0

1
0
0
0
0
0
0
0
0
0
0
0
0
00
0

0
0
0
0
0
0
1
NO+

0
0
0
0
0
0
0
COC

0
0
0
0
0
0
0

0
0
C
0
1
0
1

0-

N+

0
0
1
1
1
1
0
0
0
0
0
0
1
0
1
0
0
0
0
0
0
0
0
0
1
1
1
1
A

0
0
1
1
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
i
0
1
1
1
1
1
C

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
b
0
NE

0
0
0
1

0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
E

AEDC.TR-65-58

TACLE G
SECO5I:)
T
2000.
2003..
0
2O.
2000.
?000.
2000.
2C00.
200C.
2000.
2000.
2000.
2000.
2000.
2000.
2000.
2000.

VIRIAL CM-:r!rici.TS MD:!AVATiVZS AT

2000, 60 T,C'0, 12,040, ANlD 13,0C0"1
B

Pair
A
CO
J
N2
NO
0

A
A

TdB/dT

T2 d2B/d2

2.t85b

26.1'.
31000
23o94Y
29.558
28.910
21.562
27.288
-55.951
-35.733
32.911
42.607
27.692
28.302
32.386
35.869
249513

0.250
2.166
3.100
1.100
2.840
81.282
57.319
7.350
6.380
0.100
-1.805
-0.,49
2.539
-. 1451

-10.7t9
-12.663
-6.829
-11.766
-180.859
-126.048
-22.734
-26.950
-5.957
-2.034
-5.780
-12.887
-1.999

-0

i.

N
0
CO2
N20
A
C
Co
C02
N

A
A
A
A
A
A,
A+
A
A
C
C
C
C
C

N2
N00
NO
,

C
c
C
C

30,952
45.946
30.532
22.394

-0.587
2.5/4
0.071
-0.736

-'.167
-14,981
-6o4P2
-3.077

O2

28.739

A
C
C2
CN
CO
CO2
N
N2
N20
NO
0

C2
C2
C2
C2
C2
C2
C2
C2
C2
C2
C2

35.184
36.400
45.484
.42.021
40.843
43.656
31.950
39.051
55.300
38.317
29.103

0o)6
2.083
-1.009
0.834
1.071
1.49Q
6.536
-0.705
1.181
7.123
2.195
0.342

-5,974
-11.764
-5.598
-11.216
-11.006
-11.680
-23.147
-5.123
-10.629
-26,e08
-12.653
-6.766

02

C2

36.551

2.016

-11.898

A
C
CN
CO
C02
N
N2
N20

CN
CN
CN
CN
CN
CN
CN

32.265
33.516
39.039
37.740
40.360
29.242
36.033

2.185
-0.748
1.276
1.680
b.54 7
-0.479
1.342

-11.38C
-5.356
-10.827
-11.426
-22.496
-5.042
-10.346

2000.
2non.
2000.
2000.
2000.
2000.
2000.

NO
0
02
CO
C02
N2
N20

CN
CN
CN
CO
CO
CO
CO

35.432
26.775
33,5t8
36.353
38.725
34.69S
49.5i6

2*322
0.491
2,125
e.063
7.052
1.714
7.865

-12.329
-6.602
-11.518
-i1.962
-23.2o2
-10.567
-27.236

20.00
2oUC.
20U3.
2000.
20C0.
2(
2000.

NO
02

34.016
32*1')3

2.711
2.475

-12.b75
-11.991

38.827

15.60"

-41.080

49.814
28.297

17e865
-0.215

-'t9.223
-5.408

?000.
20009
2r0n.

2000.
2000.

21000.
200n.
2000.
2000.
20C0.
2000.
2000.
2000.
2000.
2000.
2000.
2 0,.
2000.
2000.
00o0.
2000.
2000.
20C0.
2000.
2000.

02

CN

CO
CO
I02 02
N20 C02
N
CO

51.384

7.198

-26.160

(00.
002

31.278

2.rlC

-11.577

21.112

-1.153

-1.927

51

A t DC.T P .65 53

TABLE G (C?ainu,'!)
T
200.O0
20006
200()
2CCO,
2000,
2000.
2000.
2('00,
LO'00,
2000,
2ni-in,
2000.,
2000,
20C0,
2000,
2000.
2000.
20000
2000,
2GOC, 0
2()W),
2000,
2 1)n.

2()00 .
2Of)0
2O0.
2000,
20001

2000.
2r)O0*
2000,
2000,
2t00O,
200
r .,,
2000.1
2000.

2000,
2000o
2000.

52

Pair

N?2

N20
Nr
02
A
N
N2
NJ

N
N
N
N
N+
N+
N+
N4

#I+
CO2
N2
N20
N

N20
CO2
N2
N20
NO
02
N
N2
O
(0
C02
N
N,?2
N2 .)

N2
N2
N2
N2+
N20
NO
NO
NO
NO
NO
to+
NO+
NO+

0
0
O

B
26o815
40)593
26,567
24o887
-462.108
-65*802
-V3.3V6
-100.500
-42o715
37,225
33,175
47o738
-45,446
62,741
35o659
32.607
469390
31.901
30.004
-44.845
-65*552
-28o67?
25.627
28.068
19.01-2

N0

0
'
0

24 e.37(,
-6. 771
23o987

0
U2

0
0

A
N
N2

0+
0+

17e227
22 .4'..
-561.906
-73*171
-104.2;9

0+

v0,46V

12U.02Q
138.034
62,235
6,337
1393
7e046
71*981
2090b3
6,843
2.326
8o976
3o347
3.071
,1.
4H
101.226
22.230
0o749
3,873
-0,530
0557
4 3.Ej7
1.1

0oO./
O)12t
1301.352
99.592
1420. 14

T2 d2B/d
-4,618
-14o029
-6.012
-:.o534
-3288.199
-206.310
-294,884
-322o458
-138,744
-210398
-9o874

-25,091
-157*329
-56*623
-22*162
-11*754
-2.o019
-13.814
-12o845
-15ill30
-222.299
-113,851
-6.917
-14.167
-2o837
-6.246

-1

6'

-7 ,4V9

- , /13
-6.b53
-546h.5S1
2.2926

-337o2WO

-48.166

67.333

-154o263

-61.2Q3

87.122

02

34,1QQ

7.413

02
02
02

3).*81)
439939
289431

2o121
8.334
2.820

-196.379
-2 10
2
-10,941
-,7.120
-11.0.059

r)

N
C02
N2
N20
02

TdB/dT
-0.432
26!115
0.235
0.175
88V,548

AE DC. T R-65-58
TABLE G (Cont;nued)
TdB/dT

T2 d2 B/dT2

25.655
29.912
22*071
28o3b4
28,333
20 IC 1
26,6"1
-6,101
-0,477
34.539
44,027

-2.61i6
-3.305
-2.,)58
-3.209
-2.908
-2.454
-2,765
22.254
15.588
-2.427
-3.402

0222
0.789
1b666
0.904
0.281
Co956
0o318
-48,646
-34,611
-2.010
-1.913

25.406

-3.466

2.044

-4'.007
-4,188
-3.915
-3*443
-4.0.43
-5,183
-3.831
-3.001
-3.620
-3.937
-4.832
-,.532
-5.039
-4.788
-3.959
-4.197
-4.638
-5.284
-4.305
-3.586
-4.125
-3,545

3o287
2.737
3.153
2,776
2.721
1.914
2.278
2o164
29182
1,382
3o400
2*939
;.529
2.173
-0.712
2.871
2*234
-0.194
1.551
2*000
1.528
109)7

-4.405
-4.614
-4.,54

3,017
2.175

Pair

T
6(. 0,
6000.
6000.
6bC00,
6r00a

A
(O
N
N2
NO

A
A
A
A

6V000,

6000.
6030.
6000.
6000.

60006

02
N
0
CO2
N20

6000.

60009
60000
6000.
6000.
6000,
6r'('O
6000.
60C0,
0000.
6000.
6600.
6000.
6000.
60GO.
6W000
6r00,
6000.
6C00.
60009
6000.
6000.
6000o

C
CO
C02
N
N2
N2O
NO

A
A
A+
A+
A
A
C
C
C
C
C
C
C
C
C
C
C2
C2
C2
C2
C2
C2
C2
C2
C2

C2
C2

02
A

C2
CN

24.802
29o375
34*366
2195t0
27,972
43,594
27,988
20.1*4
26.307
33*464
32*701
42.136
39.109
38.2c0
43.897
28,13
36.459
54.912
36.399
26.845
34.674
30*853

6000.
6000o

C
CN

CN
CN

30.20
36.504

6000.
6(000
6000.
6000.
6n00,
6000.
601,0
6000o
6bCO.
6000.
6000o
6000o
6000.
6000.
6000.
6On0,
6000,
6000,
6000o

CO
C02
N
N2

35,560
40o884
26,472
33.79A

NO

CN
CN
CN
(N
CN
CN

(N

24.804

02
CO
C02
N2
N21
N,
02
C02
N20
C')
C02
N

CN
CO
CO
Co
CO
CO
CO
C02
C02
N
N
N

32.001
34.522
39.688
32.793
500059
32*77A
30.962
44.857
56,277
25,759
30.146
18.620

0
02
A
C
C2
CN
CO
CO2
N
N2
N20
NO

N20

-3*544
-3.801
-4.220

51,37]

-4.775

33.834

-3.911
-3.25b
-3,722
-4.,09

-3.222
-3.963
-4.386
-3.641
-3.467
-1,29'
-- ,147
-3.617
-3.344
-2.941

1.826
-0.965
2.524
1.905
-no535
1.253
1.730

1*233
,,483

-1.395
1.574
-1.031
0,906
0.913
-6.538
-7*0'4
2,285
o,823
2.329

53

A EDC-T R-65. 58

TABLE G (Continued)
T
6000.
6000.
6000.

N2
N20
NO

N
N
N

6000.
6000.
6000.
6000.
6000.
6000.
6000o
6000.
6000.
6000.
6000.
6000o
6000.
6000s
6000o
6000,
60n0,
600r.
6000.
6000.
6000.
6000.
6000s

02
A
N
N2
NO
0
C02
N2
N20
N
N20
C02
N2
N20
NO
02
N
N2
0
(o
(02
N
N2

6000o

N20

6000.
6000.
6000.
600C,
6000,
bo00.
6000o
6000.
6000o

NO
0
02
A
N
N2
0
N
C02
N2

N
N+
N+
N+
N+
N+
N2
N2
N2
N2+
N20
NO
NO
NO
NO
NO
NO+
NO+
NO+
0
0
0
0
0
0
0
0
0+
0+
0+
0+
002
02

6000o

N20

6000.

6000.

54

Pair

02

TdB/dT

T2 d2B/dT2

24.280
18.736
24,458

-3.464
-4.492
-3.292

2.310
1.464
1.874

22.884
-87.892
-11.012
-16,324
-18.144
-4,596
37,887
319211
47,941
-0,951
69.442
36*754
311251
47,859
31,220
2?)40n
-0.887
-3.144
3.456
23.909
28.026
17*188
22.648

-3.094
117o893
24.393
34.169
36,253
16,995
-3,199
-3.846
-4.353
19.739
-3.253
-2*&,d7
-3,I
-5.738
-3.226
-3.0'61
19.t2n
27.762
13.998
-3 .o5
-2.6,2
-2.540
-2.0)3

1.784
-276o395
-52.719
-73o843
-78.431
-37,095
-1,072
10654
-0,716
-43.739
-7o479
-1.497
1.037
-1.a9?
0,355
) 4 8t
-43o269
-61.232
-31s779
1.483
-t,257
1,787
1.507

36.273

-3.fC01

-8.232
35o757
29.485

-2.741
-21150
-2,612
132o259
26.175
36.787
180305
23.628
-2,573
-3*377

02

45*230

-3.579

02

27o725

-2o913

22.668
15.822
21.149
-97,65(n
-13.767
-20*222
-6.965

0.115

1.092
1,254
1.133
-3230149
-56.537
-19.54+8
-31,744

-51.358
-1,952
1.027
-1.785

0,416

AEDC-TR-65-58
TABLE G (Continued)
T

Pair

TdB/dT

T2 d2B/dT2

A
A
A
A
A
A
A
A+
A+
A
A
C
C
C
C
C
C
C
C
C
C
C2
C2
C2
C2
(2
C2
C2
C2
C2
C2
C2
C2
CN
CN
CN
CN
CN
(N

24,429
28.399
20.786
26.903
26,971
1-o304
25o402
1.049)
4o485
33.245
42.287
23e906
23.1>!
27.%?2
32o59(,
20.114
26.247
41.27rl
26.332
18.776
24.744
31.6V4
30.649
39.719
36.898
36.172
41,968
27,025
34.416
52,391
34.467
25.285
32.824
29.249
28.344
34.469
33*623
39.134
24.848

-3.360
-4.078
-3.338
-3.914
-3.722
-2.908
-3.522
13.646
9.342
-3.833
-5.081
-3.881
-4.185
-4o602
-4,760
-3.612
-4,.417
-6.174
-4.283
-3,231
-4.038
-4,713
-5,231
-6,299
-5s786
-5.573
-5.422
-'A,971
-5.356
-6.991
-5,141
-4.052
-4.913
-4.292
-4.796
-5.344
-5,117
-4.959
-4o164

2.023
2,7r7
2,713
2o670
2.258
2o122
2o16e
-30.548
-21.b36
1.211
1.969
3*206
30989
3.956
3.273
3.412
3o843
4.449
3.550
2.896
3.364
3.358
4.638
5.OZO
4.528
4o233
2.745
4.003
4.139
3,89,
3.684
39283
3.543
2.980
4.203
4e103
3.804
20358
3o602

N2

(N

31.925

-4,914

3.727

N20
NO
0
02
CO
C02
N2
N20

CN
CN
CN
CN
CO
CO
CO
CO

49.067
32.067
23.382
30.322
32.687
38.060
31.024
47.901

-6.434
-4.722
-3.708
-4.480
-4.880
-4.677
-4.685
-6.102

39407
3.300
29955
3.153
3.502
1.989
3,435
2*953

9000,
9'00.
9000.
90no,

NO
02
C02
N20

CO
CO
C02
C02

31o109
29*381
43,779
54,755

-4.481
-4.250
-3.818
-5.115

2*994
2.866
-0*184
-0.518

90(l.

CO

24e205

-4.000

3.392

9000.
9000.

C02
N

N
N

28.617
17.390

-4,118
-3.100

2.747
2.902

9000.
90oo,
9000.
9000,
91000.
V)CO0.
9c000
90CC0
9000.
9000.
9000.
90009
9000.
9000.
9g00.
9c00.
9000.
9000.
9000.
9000.
9000.
9000.
9000.
9000.
9000.
90000
90030
9000.
9000.
9000,
9000,
9000.
9000.
9000.
9000.
9000.
9000.
90000
9000.

A
,CO
N
N2
NO
0
02
N
0
C02
N20
A
C
Co
C02
N
N2
N20
NO
0
02
A
C
C2
CN
CO
C02
N
N2
N20
NO
0
02
A
C
CN
CO
C02
N

9000.

9000.
90000
9000.
9000,
0000,
9000.
9000.
90000

55

TABLE G (Continuad)
T
900
C0'd

Pair

90

22 7o

00. '20
N'

36.

r4,(LOj

90
9"0.

9NP^
91V3,
9000,

9000,
or'.
90W0.
9r300.

A.
.t
92
N(

p000.
9C0.
9fl(y3
900C,

vnin,
S006,'
9000,

9000.
9",00.
9
900.
9 "irl
9000.
900) .
9000,

9000.
9o00.
9000,
9000.

56

'N
t!+

f+

N't+ n

C-02
r03..
%2

N2
a?2

"2"0
N2
N N
2+
N20) N20

to2p

'
(0
(02
ji
w

1 1.5,,
-5np s
-3
513
-V-" 1 3
-6.4 3
.;6
h

11.416

-5,9'40

.,297
6

29.638

%N0

4"A

UNO+
0
0
0
0

-3.41'
60.864
] 5.165
21.268
22.572

41,8.2',

NO

0O+

L5

4.q

29. 714
27.0 13

11.052
-4.325
-44
5, *94

5.724
7,86nt
22.567
2b.7
16.1i1n
21.?6c
34,57 r

-4o692

N20

NO
0
(11.20
?
,A
N
%'2

0
0
0
0+
0+
)+

0
r)-1
N

O-

06.
-0,624

(02
,N2
N20
02

02
02
02
02

34.3y7
27.955
43.405
26.37?

21.44.
14.831
19q99C'
-5(.)1!3
-5.302
-8. 34'6

o0 25

2. o0
-156.061,
-33.201
-46*43'"
-496M
-23.

-3.240
-r.411
-3.058
76.40(.
16. 33
22. 57
11 31'
14.572

-4.007
_4.05
-.212
-3.685

;33r

2.6V
39370
3Nu3t

-27.390

-b.bbt9
-4.270

-4. 115
-3 0891
11.714
16.774
8.149
-3,518
-3.521
-2.1t.Y
-3.36s

5.331

3 . 1?

-3.7n7

-,. 543
-4,507

7,3.
35.278

NO
W +

t.'i18
.o0

-5.'.

36.292
2'0.50!

N,,

(02

,1
.0 9(:C
r)
v
n,oO
F , *
n2
nrn p,
N!

70.'

23.

. 09 o2

T2 d 2 B/dT 2

TdB/dT

0.1')4
1. 70.-3

2696?
2.1!o
2o519
2.406
-27.
9 ,
-38.4
-19.691
2.,'26
2.438
20650
2.730

2.377
1 .0 385
2.204
-174,.n27
e-..
8
7
-24

'

-),;

-32.*311

1.333
2.83
20l1
2.302

TABI.E G (Conth,{)
T
12000
12000
12r000.
12n000
12000.
12000.
12000.
12000.
12000.
12000.
12000.
12000.
12000.
12no00.
12000.
120)0.
12000.
12000,
1200,)*
12000.
12000.
12000.
12000.
12000o
120(.O
12000.
12O0.
12000.
12n00,
1zooo.
121000*
12000.
12000.
12000.
12000o
12000.
12000.
12000.
12000.
12000.
12000,
12000,
12000.
12000.

12000.
12000.
12000.
12000o
12n00,
12000.
12n000.
12000o
120009
12000.
12000o

PaIr

A
Co
N
NQ
NO
0
02
N
0
C02
N20
A

C
CO
CO2
N
N2
N20
NO
0
02
A
C
C2
CN
CO
(02
N
N2
N20
NO
0
02
A
C
CN
CO
C02
N
N2
N20
NO
0
02

CO
C02
N2
N20
NO
02
C02
N20
CO
C02
Nl

A
A
A
A
A
A
A
A+
A+
A
A
C
(
C
C
C
C
C
C
C
C
C2
C2
C2
C2
C2
(2
C2
C2
C2
C2
C2

23.414
27.176
19.805
25.736

-3.665
-4.385
-3.467
-4.192

25o85n

-4.055

18.440
24.3L0
4.341
6.712
32.047
40.713
22.767
21.925
26.237
31.I,
19o070
24.958

-3.(80
-3o631
9.461
6.e97
-1.450
-568iO
-4,01P
-4.?r3
-4.721
-5.096
-3.6Th
-4.526

39*434

-6.1)54
-4.432

CN
CN
CN
(N
CN
CN
CN
CN
CN
CN

25.n75
17.838
23.56n
30.291
29.126
37.864
35,19r)
34o523
40.312
25o692
32.834
50.269
32.937
24.094
31.3C4
27.9%b
26.946
32.889
32.106
37.614
23,632
30.471
47,108
30.659
22.289

CN

(2

CO
CO
CO
CO
CO
Co
(02
C02
N
N
N

TdB/dT

-3.29,
-4.175
-5.012
-5.138
-6.168
-6.053
-5.*62
-6.041
-'.()77
-5.616
-7.703
-5,462
-4.212
-5.2 4

2
22
T1dB/dT
Ti
2.P60
3.591
3.176
3.481
3.176
2.652
1.O17
-21.b89
-15.346
,741
3.806
3.718
4.26L
4.482
4.245
3.666
4.32'4
5.60"

4,10)
3.204
3,882
4.259
5.163
5,947
5.422
5.161
4.367
4.486
4 ,9C)4
5.198
4.656
3.851
4.460

-4.51,4

3.841

-4.c40b
-5.610
-5.402
-5.56A
-4.272
-5.170
-7.132
-5.037
-3.866

4.710
4.971
4.700
3.922
4,067
4.54';
5.254
4.237
3.501

28.987

-4.774

(*030

31.235
36.618
29.633
46.033
29.768
28.110
42.504
53078
23.034
27.384
16.493

- .13
-5.305
-4,959
-6.832
-4.814
-4.560
-4,n70
-6.461
-4,120
-4.426
-3.125

4.422
3.587
4.280
4.850
3.954
3.764
1.692
2.646
3,874
3.632
3.133

57

A EDC-T R-65-50

TABLE G (Cct,.nuod)
T

58

Pair

TdB/dT
-3.917
-5.773
-3.H48
-3#607
49.365
10,707
15.0,2
16,004
7.219

T2d2B/dT 2
3,12o
3,594
3,321
-107o875
-23,922
-339466
-35-440
-16,71z

12000.
12000.
1z000.
12000.
12000,
12000,
12000.
12000.
12000.

N2
N20
NO
02
A
N
N?
NO
0

N
N
N
N
N+
N+
N+
N+
N+

21.675
25.095
21.940
20.521
-33.872
0,155
-0,106
-0,931
3,376

12000.

C(C

34,8c7

12000.
12000.
12C00,
12000o

N
N20
N
N20

N2
N42
N2

N2+
N20

0o012)
65e207

0.00
-8.236

12000s
12n00,
12000,

C02
N2
N20

33.957
28.347
44.227

-4.870
-4.627
-6.332

3,224
3.854
4.177

12000,
120Cn,

Nn
02

NO
NO
'Q0
NO

-4.478
-4.228

3.121
3.342

1200C.
12000.
12000.
12000.
12000.
12000.
12000.
120009
120009
12000,
12000o
12000.
12000.
12000o
12000.
12000.
12000.
12000,
12000,
12000.

N
N2
0
co
C02
,1
"2
IW0
NO
0
02
A
N
N2
0
N
C02
N2
N?2
02

28.47"
26.8rl
8.1 4

0,O
NO+
NO+
NO+
0
0
0
0
0
0
0
0
0+
)+
0+
0+
002
02
02
02

4.

18

3.549

28,168

-4175

4,150

44.0C12

9.73)
9.773
21.528
25.692
15.309
20.368
33.151
20.482
14,183
19.O84
-38.161
-1,320
-2.723
1.678
2,905
33.148
26,733
41,775
25,264

-,1

6
b)

7.902
11.414
5,291
-3.687
-3.899
-2.806
-3.514
-5.l40
-3.428
-2.499
-3,223
53,451
11.606
16,345
7.933
10.184
-4.634
-4.376
-6.004
-3,998

4.799

-1),440
3,872

-19.231
-27o341
-139780
3.284
2.883
2.711
3,161
3*948
2.961
2.307
2*818
-118,18r
-25.585
-35.891
-17,960
-23,204
2.899
3,660
3.995
3.176

AEDC-TR-65.58

TABLE G (Continued)
Pair

T
15000.
15000.
15000.
15000.
15000.
15000.
15000.
15000,

A
CO
N
N2
NO
0
02
N

15000.

15000,
15000,
15000.
15000,
15000.
1000.
15000,
15000.
15000s
15000i ,
15000.
15000.
15000.
15000.
15000.
15000,
150000
15000.
15000.
15000.
15000.
15000o
15000.
150000
15000,
15000,
15000,
15000,
15000.
15000.
15000.
150000
15000.
15000.
15000.
15000.
15000.
150ri0,
15000.
15000.
15000.
15000,
15000.
15000.
1.0000
15000.

C02
N20
A
C
CO
C02
N
N2
N20
NO
0
02
A
C
C2
CN
CO
C02
N
N2
N20
NO
0
02
A
C
CN
CO
C02
N
N2,
N20
NO
0
02
CO
C02
N2
N20
NO
02

C02
N20
CO
C02
N

A
A
A
A
A
A
A
A+
A+

4
A
C
C
C
C
C
C
C
c
C
C
C2
C2
C2
C2
C2
C2
C2
C2
C2
C2
C2
C2
CN
CN
CN
CN
CN
CN
CN
CN
CN
CN
CN
CO
CO
C0
CO
CO
e70
C41e322
C02
CO2
N
N
N

TdB/dT

22,579
269183
19.025
24*785
24.926
17.744
23.468
6.166

-3o808
-4,523
-3*509
-4*31j
-4.211
-3.151
-3o975
6.992

7*909

4*499

319016
39,373
21,865
209990
25.179
30.015
16.261
23.945
379952
24e080
17.103
22o623
29*157
27.933
36.387
33e827
33e201
38.928
24,646
31.568
48.509
31e701
23.147
30.185
?6*930
25*848
319624
30,886
36,337
22,675
29.305
45.476
29.518
21.420
27.9C6
30,063
35.39'
28,51'
44,465
28s676
27,076

-4.768
-b.180
-4,059
-4,172
-4.754
-5.235
-3.612
-4*545
-6.712
-4,476
-3.292
-4.214
-5.139
-5.349
-6.66i
-6.150
-5.974
-6,345
-40693
-5.714
-8.045
-5o597
-4.264
-5.340
-4,710
-40923
-5.711
-5,517
-5.862
-4*293
-5.270
-7.471
-5.173
-3.921
-4.900
-5.31n
-5.620
-5.70
-7,194
-4.962
-4,697
-5.595
-7.186
-4.150
-4.562
-3.109

5105[o
22.111
26*380
15.797

T2d2B/dT2
30322
4.073
30418
.392
3o682
2.937
3.489
-16s796
-11b635

3*600
4o843
3.982
49385
4,748
4,773
3.779
4.e65
6o226
4.397
3.354
4oJ49
4,746
59421
60433
5.894
59656
5,274
4.728
5.448
6e859
p.181
4*147
4.955
4.309
4.962
5.431
5s179
4*799
4.300
49987
69284
4s744
3.787
4o505
4.918
4.488
4o734
5,913
49479
4*253
3.237
49466
4.119
4e116
3.238

59

AEDC-TR-65-SC

TAC~LE G
Pair

60

15000.
15000.
15(O10
15000.
15o00,
15000,
15000,
15000.
15000.
150000
15000.
15000
15000.
15000.
15000.
15000,
15000.
15000,
15()000
15000.
15000.
15000.
15000.
15000.
150000

N2
N20
NO
02
A
N
N2
NO
0
C02
N2
N20
N
N20
Co2
N?
NO
NO
02
N
N2
0
CO
CO2
N

NO+
NO+
NO+
0
0
0

15000.
150O00

N2
N20

0
0

15000,
15000.
15000.
15000o
15000.
15000.
15000.
15000.
15000.
15000o
15000,
15fl000

NO
0
02
A
N
N2
0
N
C02
N2
N20
02

0
0
0
0+
0+
0+
0+
C02
02
02
02

N
N
N
M
NI
N
N+
N+
N+
N2
N2
N2
t12
N20
NO
NO
NO
NO
NIO

TdB/d f

20s798
33.788
21,075
19.710
-24o184
2o640
2o829
2.193
4.768
33.720
27.095
42o497
9o646
63.272
32.835
27.298
42.7( 7
27,4',4
25.839
9.627
11.919
10.758
20o697
24.800
14.682

-3.937
-5o927
-3,893
-3,647
37o992
8.084
11.396
12.150
5*334
-5.405
-4.850
-6o939
5o727
-9o061
-5,173
-4,759
-6.729
-4,647
-4,384
5.652
d.251
3.606
-3o750
-4,082
-2.811

T2 d2B/dT2
3o942
5.443
3.798
3,565
-820211
-180497
-25,897
-27.438
-129821
4o381
4.565
5o783
-14o753
5.982
4*079
4o336
5*296
4,075
3.857
-14o:86
-20,814
-100290
3o579
3,442
2o840

19.577
31*978

-3,568
-5o353

3o430
4*623

19,708
13o622
18,356
-27.696
0.949
0*474
3e217
4.878
32.076
25,741
40o391
24,354

-3o505
-2.525
-3o289
40,949
8o834
12,470
5o942
7.599
-4o956
-4o497
-6.375
-4,143

3o274
2.473
3.098
-89.jo42
-190829
-27*827
-13.845
-17.864
3o784
4.110
5.041
3.657

AEDC-TR-65.58

TABLE H
PROPERTY DV7FF

CES AT lC0, 900, 12,C71, 1-1S,CI

T - 60C00(

E /RT

-7.00
-6.80
-6.60
-6.40
-6.20
-6.00
-5.80
-5.60
-5.40
-S.20
-5.00
-4.80
-4.60
-4.40
-4.20
-4.00
-3.80
-3.60
-3.40
-3.20
-3.00
-2.80
-2.60
-2.40
-2.20

-0.00000
-0.00000
-0.00000
-0.00000
-0.00000
-0.00000
-0.00000
-0.00000
-0.00000
-0.00000
-0.00000
-0.00000
o-0.00000
-0.00000
-0.00000
-0.00000
-0.00000
-0.00000
0.00000
0.00000
0.0000c
0.00000
0.00000
0.00001
0.00001

-0.00001
-0.00001
-0.00001
-0.00001
-0.00001
-0.0000t
-0.00001
-0.00001
-0.00001
-0.00000
-0.00000
-0.00000
-0.00000
-0.00000
-0.00000
-0.00000
-0.00000
-0.00000
-0.00000
-o.COOOO
-0.00000
-0.00000
-0.00000
-0.00000
-0.00000

-0.00002
-0.00002
-0.00001
-0.00001
-0.00001
-0.00001
-0.00001
-0.00001
-0.00001
-0.00001
-0.00001
-0.00000
-0.00000
-0.00000
-0.00000
-0.00000
-0.00000
-0.00coo
-0.00000
-0.00000
-0.00000
0.00000
0.00000
0.00001
0.0000!

-0.OUCOO
-. 000ooo
-o.0ocoo
-C.oocoo
-. 000coo
-0.o0coo
-0.00000
-.occoo
-0.00000
-U.00000
-U.00.oo
-0.00co0
-0.000co
-0.00000
-0.00000
-o.oouoc
-L.oocoo
-U.00coo
-o.0cooc
-0.000o0
-u.ooocC
-0.coooC
-u.o0o0I
-0.0oCo0
-0.00co0

-2.00
-1.80
-1.60
-1.40
-1.20
-1.00
-0.80
-0.60
-0.40
-0.20
0.
0.20
0.40
0.60
0.80
1.00
1.20
1.40
1.60
1.80
2.00

0.00002
0.00003
0.00005
0.00007
0.00011
0.00017
0.00027
0.00043
0.000f7
0.00105
0.00165
0.00253
0.00405
0.00633
0.00990
0.01547
0.02417
0.03775
0.05899
0.09222
0.14423

-0.00000
0.00000
0.00000
0.00001
0.00001
0.00002
0.00003
0.00005
0.00008
0.00013
0.00020
0.00032
0.00050
0.00078
0.00122
0.00190
0.00295
0.00458
0.00713
0.01109
0.01727

0.000J2
0.00003
0.00005
0.00008
0.00012
0.00019
0.00030
0.00048
0.00075
0.00118
0.00185
0.00290
0.00455
0.00711
0.01112
0.01i37
0.02711
0.04233
0.06611
0.10331
0.16150

-0.00002
-0.00003
-U.00C04
-0.OOCO6
-C.00010
-0.0001%
-u.00024
-0.00U38
-0.C0059
-0.00612
-0.00144
-U.00226
-0.C0355
-0.00555
-0.00868
-U.01357
-C.02121
-0.03316
-u.05186
-0.08112
-U.12675

2.20

0.22550

0.02689

0.25239

-U.19C60

LOG

H /RT

SA

61

AEDC-T R-65-5rl

TABLE UC:.~~
T

E /IRT

LOG P/%0

:-.80
-5.60

-C.0C054
-C.OCC64
-C.OCC75
-C.0CCC04
-C.0CC92
-C*CCC97
-C.00100
-C.OClOl

:5.40
-5.20
-5.00
-4.80
-4.60
-4.40
-4.20
-4.00
-3.80
-3.60
-3.40
-3.20
-3.00
-2.C0
-2.60
-2.40
-2.20
-2.00
-1.80
-1.60
-1.40
-1.20
-1.00
-0.80
-0.60
-0.40
-0.20
0.
0.20
0.40
0.60
0.80
1.00
1.20
1.40
1.60
1.80
2.00
2.20

-C.0CC99
-C.C0096
-C.OCC9I
-C.0CCa5
-C.CCC79
-C.OCC73
-C.OCC67
-C.OCC61
-C.00C55
-0.00050
-C.00045
-C.OCC4O
-C.CCC36
-0.00032
-C.CCC29
-C.CCO0C5
-C.CCC22
-C.OCCI8
-C.CCC14
-C.OCC1O
-C.CCCC4
C.00004
C.OCCIS
C.00030
C.CCC53
C.00CC6
C.0C135
C.002C9
0.00319
C.0C487
C.0C744
C.01137
0.01743
C.02677
C.C4123
C.C6359
0.09820
C.15171
0.23427

-7.00
-6.80
-6.60
-6.40
6-.20
-6.00

62

-O.00m1C63
-C.CCIO,3
-C.00224
-0.00252
-0.00275
-0.CC292
-C.OC301
-0.00303
-0.00207
-C0C0287
-0.00273
-0.UC256
-0.0C238
-0.00219
-0.00200
-0.CCle2
-0.CC165
-0.CO14S
-0.00135
-0.00121
-0.CC1oq
-0.0CC93
-C.CcCO3
-0.CC078
-0.CCC7C
-C.C0063
-0.00056
-0.0004S
-C.CC044
-0.OCC38
-0-CCC32
-0.C0027
-0.CCO2C
-0.0C013
-0-CCO04
0.CCOC9
0.00027
C.00053
C.00093
0.CC153
0.00245
C-CC387
OIC0605
0.00940
0.01455
0.02242
0.03435

14 /flT
-0.00211C
-0-OC25C
-0.0029e
-0.00336
-0.00167
-0.0030i9
-0).00401
-0.00403
-0.00397
-0.00303
-O.0C364
-0.00341
-0.003!7
-0.OC292
-0.00267
-0.00243
-0.0022C
-0.0019S
-0.00180
-0.00161
-0.00145
-0.00130
-0.00116
-0.C0103
-0-00092
-0.00001
-0.,00070
-0.00059
-0.00047
-0-00034
-o.0oooe
0.00004
0.0C033
0.00073
0.00132
0.00218
0.0C346
0.00541
0.00837
0-0129C
0.0198C
0.03065
0.04728
0.07299
0.11215
0.17413
0.26863

S /R
-C.COC54
-C.00C64
-L.00075
-C.00C64
-L.000 9 2
-0.00(97
-C.001C0
-u;.00101
-c.ooc99
-C.00096
-C.00Cg1
-C;OOC85
-C.00079
-L.0C013
-C.00067
-C.00061
-C.OOC55
-C.rcc5C
-C.00C45
-C.00041
-C.CiCC37
-L.00C33
-C.00030
-C.00027
-0.00025
-C.00023
-C.00(23
-0.00023
-L.0CC25
-L.00028
-L.00035
-0.00C46
-L.C0063
-G.00C89
-L.00130
-C.00191
-L.00284
-C~..00425
-C.00641
-G.0C974
IC.01487
-L.02279]
-C.03504
-C.05403
-C.08345
-C.12901
-C.19949

AEDC-TR.65-58

TADLE H (Cantnuvd)

T = 12,000O1(
LCG p/po

E /RT

H~ /R1

S/R

-7.00

-.
C.Gcct.o

-0.C0I2C

-0.00160

-C.00040

-6.80
-6.60
-6.40

-C.0C050~
-C.COC63
-C.OCCOGU
-C.CC1CO

-C.COIsi
-C.OCl9C
-0.00239
-0.C0300

-0.0C201
-0.00253
-0.00318
-0.CC4OC

-C.00050
-L.CCCf63
-C.00080

-C.CC125
-C.CC157
-C.CC156
-C.CC243
-C.CC300
-C.0C366
-0.0C441
-C.C0520
-0.OC600
-0.00673
-0.00133
-C.00176
-0.007q9
-C.00003
-C.0C790
-C.0C763
-0.00726
-C.UC683
-0.00636
-0.00588
-C.G0540
-0C.00493
-C.0C447
-0.004C3
-C.CC359
-C.CC315
-C.C0267
-0.00214
-0.00149
-C.00064
C.000S2
CoOC218
C.00460
0.00813
C.01333
C.02100
C,03234
C.04920
C.07433
C011193
C.16811
C,25109

-C.CC376
-C.CC'j71
-C.00588
-0.0073C
-0.009CC
-0.01099
-C.01322
-0.01561
-C.01799
-C.C2C19
-0.02200
-C4C2328
-0.02391
-C.02409
-C.02369
-0.02289
-0.02180
-0.02C51
-0.01912
-G.01769
-0.C1627
-0.01489
-0.01359
-0.01237
-C.01123
-0.01018
-0.00922
-0.CC832
-0.00749
-0.00669
-0,00592
-0.CC512
-0.00427
-0.00329
-0.CC212
-C..00C63
C.C0135
C.C0406
0.00784
C.C1309
0.02003
0.02699

-0.00501
-0.00628
-0.00783
-0.00973
-0.0120C
-0.01465
-0.01763
-0.02081
-0.02399
-0.02692
-0.02933
-0.03104
-0.03196
-0.03211
-0.03159
-0.03052
-0.02906
-0.02734
-0.02548
-0.02357
-0.02167
-0.01982
-0.01806
-0.01639
-0.01482
-0.01333
-0.01189
-0.0104C
-0.00898
-0.00734
-0.00539
-U.00294
0.00033
0.00484
0.01121
0.02037
0.03369
0.05325
0.08217
0.12501
0.188t4
0.21009

-t,.C0125
-C.00157
-u.00196
-c.OC?43
-0.00300
-L.CC366
-L.C0441
-.C.052C
-C.OC(CC
-L.00613
-0.00133
-C.00776
-0.00199
-L.OCPC3
-C.00790
-L.00763
-C.00727
-L.006~84
-L.00638
-0.00591
-0.00544
-0.00500
-0.00459
-L.00421
-C.00389
-L.00363
-L.00345
-C.00337
-0.00345
-0.00373
-C.00432
-0.00536
-U.00707
-C.00976
-0.01387
-C.O2CIC
-C.02947
-0.04355
-6.06472
-0.09668
-L.14508
-C.21883

-6.20
-6.00
-5.80
-5.60
-5.40
-5.20
-5.00
-4.80
-4.60
-4.40
-4.20
-4.00
-1.80
-3.60
-3.40
-3.20
-3.00
-2.80
-2.60
-2.40
-2.20
-2.00
-1.80
-1.60
-1.40
-1.20
-1.00
-0.80
-0.60
-0.40
-0.20
0.
0.20
0.40
0.60
0.80
1.00
1.20

1.40
1.60
1.80

2.00
2920

-C.OCICO

63

AEDC-Tn-(.5-S3

TAIDLE HI (Coclubki)
TLCG p/p

64

15,000et

E /RT

-7.00
-6. o0

-C.0CC35
- Z. Cot,2

-COCC106
-C
5

-O.C0142
-0. onI f,7

-C.0CC35
- L."",L 2

-6.60
-6.40
-6.20
-6.00
-5.80
-5.60
-5.40
-5.20
-5.00
-4.80
-4.60
-4.40
-4.20
-4.00
-3.80
-3.60
-3.40
-3.20
-3.00
-2.80
-2.60
-2.40
-2.20
-2.00
-1.80
-1.60
-1.40
-1.20
-1.00
-0.80
-0.60
-0.40
-0.20
o.
0.20
0.40
0.60
0.80
1.00
1.20
1.40
1.60
1.80
2.00
2.20

-C.Occ5o
-C.OCC6L
-C.CCC75
-C.00093
-C.CCIl6
-C.OC145
-C.OCI0
2
-C0.C228
-C.0C286
-C0CC359
-C.CC449
-C.0C562
-C.CCTCO
-C.0C867
-C.OIC6s
-C.C1295
-C.01549
-C.C1815
-C.02C76
-C.C2311
-C.C25CI
-C.C2633
-C.027C2
-C.0271t
-C.C2669
-C.C2587
-C.C2475
-C.02342
-C.02196
-0.02C43
-C.01883
-C.01716
-0.01536
-C.01332
-C.01C86
-0.00768
-C.0C332
C.00290
C.01197
C.02531
C.04484
0.07310
C.11303
C.16574
C.19891

-O.Col5
-C.CC183
-C.0C225
-C.0C279
-O.0C348
-0.CC435
-0.00545
-C.0CC68
-0.CC052
-C.I076
-C.C1348
-0.C1685
-C.C209S
-0.02601
-C.03196
-0.03884
-0.04646
-C.C5445
-0.06229
-0.Cf935
-0.C7504
-0.07899
-0.06107
-C.08138
-O.C801s
-0.07773
-0.C7444
-C.G7061
-0.C6648
-C.06227
-0.05812
-0.05413
-0.05C3e
-0.04689
-0.04369
-0.04075
-0.03606
-0.C3557
-0.03326
-0.C3115
-0.02944
-0.02893
-0.03228
-0.05055
-0.18162

-0.0020C
-0.004
-0.OC30C
-0.00372
-0.00464
-O.CC58C
-0.0C727
-0.00911
-0.01144
.0.01434
-0.01797
-0.02246
-o.C279e
-0.03467
-0.04262
-0.05179
-0.06194
--0.07261
-0.08306
-0.0924;
-0.10005
-U.10532
-C.1C809
-0.10849
-0.1C684
-0.10359
-0.09919
-0.09403
-0.08845
-0.08270
-0.07695
-0.07129
-0.06574
-0.06021
-0.05455
-0.04843
-0.04138
-0.03268
-0.02129
-0.00584
0.0154C
0.04418
0.08075
O.1151e
0.01729

-C.OCCSC
-U.00C61
-C.OCC?5
-0.00093
-L.00116
-L.00145
-C.OCI8z
-L.C228
-C.0C286
-C.CC359
-0.00449
-C.CC562
-C.CC700
-C.0Ce67
-C.01C65
-L.01295
-C.01549
-C.01815
-C.U2C77
-0.02312
-C.C25C2
-L.02634
-L.02703
-C.02714
-0.02E14
-L.02595
-C.02489
-C.02366
-C.C223#6
-C.021C8
-C.01990
-C.0189C
-C.O1e17
-0.01785
-C.01810
-0.01920
-C.02156
-C.02579
-L.03282
-C.04398
-C.06123
-C.08747
-C.12726
-L.18,901
-L.30712

H /Rt

S/i

AEDC-TR-65-58

TABLE I

4o
N2
C2
Nc
CC
CC2
NL2
N2C
N2+
G2+
czNC*
CC+
0N+
N++
0+
0.4
A*
A*#
C+
C++
NE*
N
0
A
C
NE
E-

VALUES FCMR

AT6
A(1)

2.20

2.0
I.OOCOCE
1.0OCCCE
i.OOOOCE
I.CCCCOE

1.OOCCCE
I.COCCCC
i.OCCCCE
1.29422E
1.29422L
1.COCCCF
1.29422E
1.29422E
1.O00CCE
1.29422E
z.167811
L.29422E
2.16781E
1.29422E
2.16781E
L.29422E
2.1676LE
1.29422E
L.GCCCCE
1.0000CE
1.OOCOCE
L.OOCOCE
I.OOCCCE
j.OOCCOE

CO
CC
CC
CO
CO
CO
CO
CO
CO
0C
CO
CO
00
CO
00
00
O0
CO
00
00
CO
CO
O0
00
00
00
00
00

L.OO0COE
I.OCOCOE
L.3COCOE
1.OOO00E
1.OOOCOE
L.OOCCOE
I.OCCCOE
1.39050E
L.39C50E
I.OCOCOE
1.39050E
1.39050E
1.O0000E
1.39C50E
2.68852E
1.39050E
2.68852E
1.39C50E
2.68852E
1.39050E
2.68852E
1.39C50E
I.OCOCOE
j.OOOCOE
1.OCCCOE
1.0OOCOE
IOOCCOOE
1.O0000E

2.40
CC
o0
CC
CC
CC
CC
CC
CC
CC
CC
00
O
CU
CC
00
CC
CC
CC
OC
00
CO
00
00
CO
00
CC
O
CC

I.CCCOCE
J.CCCOCE
t.OCCCCE
I.OCCOCE
I.OCCCCE
I.OCCCCE
I.OCCCCL
1.55311E
I.55311E
I.OCCCCt
1.5531LE
1.55311E
i.OCCCCE
1.55311E
3.74636E
L.553IIE
3.7463tE
1.55311,E
3.74f36f
1.55311E
3.74636E
l.55311E
1.0CCOGE
1.CCCOCE
L.OCCCCE
I.OCCOCE
I .OCCOCE
I.OCCOCE

CC
CC
CO
CO
CO
CC
CO
CC
CC
CC
CC

CC
CC
CO
00
CC
CC
CC
00
CO
CC
CC
CO
CC
CC
CC
GO
00

65

TABLE J
VALUES FOR P( 2 ) AT 6
log

N2
02
NC
CC
CC2
N02
N20
N2#
02.
02NC*
CC+
aN+
N+4
G*
0a#
A*
A*+
C+
C**
NE*
N
C
A
C
NE
E-

66

2.00
I.I7CI4E
1.1324C
1.1521CE
1.17444E
1.38207E
1.87801E
1.23683E
1.55374E
1.5C666E
1.5Ct66E
1.55519E
1.5820CE
1.22781E
1.433621
1.24641E
1.41299E
1.22746E
1.29417E
1.29331E
1.28C84E
1.28C86E
1.00000C
L.COCCCt
1.COCCOE
I.COCCCE
I.O0000CCE
1.0000CCE
I.OOCCCE

2.20
00
00
00
CO
00
00
Co
0O
00
O0
00
CO
00
00
CC
CC
00
00
00
O0
CO
CC
CC
CO
00
0
00
CO

1.23095C
1.2519e
1.25005E
1.2883SE
1.66530E
2.69789E
1.39869E
2.00153E
1.90701E
1.90701E
2.0066SE
2.05904E
1.30142E
1.76461E
1.41473E
1.72061E
1.38094E
1.50032E
1.4990cE
1.49lC4E
1.491C4E
I.OCOOOE
I.O0000E
I.OCCCOE
1.OOOOE
1.O0000E
1.O0000CE
1.O0000E

CO
O(:

CC
G'
uO
CG
CC
00
CO
CC
CO
CC
CO
O0
CO
CO
CC
CO
CC
CO
00
CC
CC
CO
GO
CO
CC
O0

2.40
1.47646E
t.42424E
1.42094C
1.48987L
2.2318SE
4.76318E
1.6S70CE
2.97806E
2.7602CE
2.7602CE
2.99513E
3.11351E
1.66205E
2.44559E
1.7256fE
2.34362E
1.66139E
1.89161E
1.8E975C
1.874C4E
1.874041
I.COOCE
I.CCOCCC
I.COCOCE
I.OCCCCE
1.0000CC
1.000CCE
I.OCCOCE

CC
O0
Co
CC
00
Co
CC
CC
00
CO
CC
CC
CC
00
CO
CC
CO
CO
CC
CO
CO
CC
CO
CC
CC
CC
CC
00

TAnLC K

log P/po
N2
02
NO
CO
C02
N02
N20
N2+
024
02NO+

EQUILIr2UM c1:?:I'C AT M37"'

2.00
=
2.20
=

2.40

6.60784E-01
7.01322L-02
1.55115E-01
2.61787E-04
5.13831E-05
1.2R625E-03
1.84692E-04
1.38409E-08
2.93152E-07
2.13583E-10
4.28728E-05

E.69753F-01
8.34753E-02
1.68212E-Cl
2.3125eE-04
8.bu6u7E-05
4.41123E-03
3.13047E-04
1.69215E-08
3.61909C-07
6.6050CE-10
5.08338E-05

CO+

7.74392E-11

6.65236E-01
7.74053E-02
1.62625E-01
2.49979E-04
6.77133E-05
2.25220E-03
2.42292E-04
I.37087E-0
3.14937E-07
3.60959E-IC
4.46889E-05

0N+
N++
0+
0++
A4
A++
C+
C++
NE+
N
0
A
C
NE
E-

2.79629E-05
4.81119C-I0
3.2S334E-30
1.54642E-08
0.
2.42209E-tO
1.95006E-28
1.65735E-13
8.03902E-30
8.34137E-18
3.68747E-03
9.94179E-02
8.86387E-03
8.64771E-09
2.84707E-05
1.52330E-05

3.25402E-05
3.79253E-I0
2.1240EE-3C
1.26709E-08
0.
2.37387E-10
1.74283E-2P
i.10174E-13
4.90022E-30
7.0519nE-1
2.82464E-03
8.00152E-02
8.96336E-03
5.9435fE-09
2.97902E-05
1.24902E-05

4.05981E-C5
3.28565E-I0
1.51510E-30
1.12313E-08
0.
2.53381E-I0
1.73997E-28
7.6406CE-14
3.11413E-30
5.97007E-18
2.IC826E-03
6.22162F-02
9.0603CL-03
3.91569E-09
2.91016E-05
1.06238E-05

7.30561E-11

7.43117E-11

-3.0
-6.6
-6.6
-t.4
-6.1
-6.0
- 3.0
-. 0.6
-34
-32

V.012-01
7.9-0
V.095-03
7.3-0
3.10-14
3.f10
.0119-013
1 . ao-o
.000-01
1.600-01

1.01 3-111
.C77-03
?.ore-373
.033-03
ip:03
20-01
-C
1.074-'11
2 .090-01
1.041-013
1'.fe0- 0 1

-3.0

T.Ani-01

-4.4
-4.6

7.Rto
7. P1-03

I .070
A-031
I2.017.c(-0 13

-4.4

3.A01-03

-4.1
7.81N03-0
-4.0
?. to3-01
-3.0 3.00-03
16.601-01
-1I1030
-0.2n
7.030
-3.0

-2.b
.
-14
-

?.$(1 -01
?.A6 1-03
Y.303-03

.003-03
72?
.001-03

-2.0
-3.0
-1.6
-34
-3.33
-. 0
-. 6
-. 4
-. 2
.0
.2
.4
.4
3.0
3.2
3.4
1.4
3.6
.1.0
2.2z
?.4

No9i
3 *17-03
3 0
.3,34-01
1. W -03
3.7-0
1.116je*h-01
131*36-03
1.33-03
3. )?-03
1.11'r-01

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1.062-09
0.443-10
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3.33074.00
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1.04028.00
3.06701.00
3.01141.00
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1.03914400
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3.00170400
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3.00276.00
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3.02207400
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3.09016400
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3.99712.00
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3.19077400
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9.31789400
9.283S0C0C
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9.11044*00
40.01014.00
0.4974s.00
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7.31649.00
6.90440400
6.S0440.00
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4.81629400
4.70910400
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4.32479400
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4.33094400
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4.30410400
4.21643400
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4.06102403
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9.427-18
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LOG P
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5.345-06

2.324-07
3.391-07
5.404-07
8.603-07
1.368-06
I.|22-06
3.44.-06
5.463-06
0.646-06
1.366-05

-5.0

1.?31-02

8.S35-76

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-4.2
-4.0
-3.8
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-7.4
-3.2
-3.0
-2.8
-2.6
-2.4
-2.2
-2.0
-1.8
-3.6
-3.4
-1.2
-1.0
-. 0
-. 6
-. 4
-. 2
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3.0
1.2
1.4
1.6
1.8
2.0

3.dq3-02
2.e89-02
4.312-12
6.277-02
8.860-02
3.231-01
3.sq49-0
2.024-01
2.482-01
2.950-01
3.408-01
1.42-01
4.Z41-01
4.597-01
4.930-03
5.1r9-01
S.406-01
5.5q6-03
S.752-01
5.680-01
5.983-03
6.067-O0
6.135-01
6.192-01
6.241-01
6.283-01
6.327-01
6.3?0-01
6.43s-o0
6.442-01
6.509-03
6.557-01
6.604-03
6.649-01
6.692-01

3.950-07
2.116-0?
3."6-07
5.64-07
9.115-07
1.494-Co
2.446-06
4.016-06
6.591-06
1.032-05
1.772-05
2.P9)-15
4.641-05
7.58c-03
1.219-04
i.q49-04
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4.8q9-04
7.69S-04
3.200-03
1.853-03
2.613-03
4.271-03
6.345-03
9.2)3-0)3
3.312-02
1.833-02
2.431-02
3.354-02
3.900-0
4.815-02
3.683-62
6.533-02
7.356-02
8.075-02

2.2

6.732-01

8.727-02

LOG c
-7.0

c21.2?7-24

N04
8.At1.-06

CC4.036-10

096.173-11

-6.6

3.402-24

3.C;9-05

3.746-10

3.037-10

-6.4
-6.2
-6.0
-3.8
-5.6
-5.4
-5.2
-5.0
-4.8
-4.6
-4.4
-4.2
-6.0
-3.8
-3.6
-3.4
-3.2
-3.0
-2.8
-2.6
-2.6
-2.2
-2.0
-3.8
-3.6
-3.4
-1.2
-3.0
-. 8
-. 6
-. 4
-. 2
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.2
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.6
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1.0
1.2
1.4
1.6
1.8
2.0
2.2

Y.C09_-?
1.409-23
2.p29-23
S.640-23
3.140-22
2.291-22
4.609-22
9.2q8-22
1.884-21
3.843-21
7.134-23
1.653-20
3.504-20
7.578-20
1.672-19
3.756-19
8.565-19
4.972-18
4.565-18
1.058-17
2.447-17
0.639-31
1.293-16
2.946-16
6.669-16
1.500-15
3.346-33
7.404-39
1.622-14
).513-14
7.500-34
1.573-13
3.223-13
6.433-13
1.242-12
2.30A-32
4.111-12
7.007-12
1.144-13
1.795-13
2.732-11
4.0833-|
6.082-31
9.263-33
1.492-10

1..09-05
1.752-05
i.208-0s
2.779-05
3.492-05
4.380-05
5.479-05
6.826-05
8.455-05
1.038-04
1.260-04
1.502-04
1.753-06
1.992-04
2.197-04
2.352-04
2.445-04
2.4?7-04
2.453-04
2.384-04
2.280-04
2.333-04
2.C03-04
1.860-04
1.709-04
1.559-04
1.416-04
1.280-04
3.332-04
1.014-04
9.260-05
8.271-01
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6.A62-05
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S.190-05
4.619-05
4.339-05
3.6W-25
3.321-03
3.019-05
2.784-05
2.626-05
2.563-0%
2.641-05

8.725-10
3.257-0q
t.785-09
2.3CO-09
3.451-09
4.6q8-09
6.30S-09
8.344-09
3.068-06
1.394-06
3.730-08
2.142-08
2.334-08
2.872-08
3.087-08
3.123-08
2.95?-08
2.631-08
2.234-08
1.783-08
1.383-06
1.047-08
.7.93-09
3.728-09
4.175-09
3.021-09
2.368-09
3.580-09
1.141-09
6.249-30
5.984-10
4.j62-10
3.201-10
2.370-30
1.773-30
1.344-10
3.034-10
8.084-11
6.424-1
5.191-11
4.269-11
3.578-11
3.0-11
2.709-11
2.497-31

3.333-30
1.663-10
2.3C4-10
2.662-10
3.3b9-10
4.268-30
5.415-10
6.89c-10
8.806-10
31.33-Cq
3.472-C9
3.939-C9
2.596-C9
3.543-Cq
4.934-C9
6.999-09
3.008-08
3.465-08
2.143-C8
3.137-CO
4.568-08
6.685-08
9.699-08
1.400-C7
2.010-07
2.870-C?
4.073-C?
3.747-Cl
6.038-7C
3.120-06
I.342-06
2.100-06
2.820-06
3.722-06
4.840-06
6.066-06
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8.819-06
1.029-05
1.161-CS
1.286-05
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O.590-0 2.32q-C4

T.

362

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1.622-17
4-315-17
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4.C67-|6
3.337-33
3..4-15
8.969-15
2.446-14
6.587-14
1.752-33

2.006-04
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8.070-04
1.280-01
2.027-0
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S.043-03
7.906-03

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1.680-C7
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1.531-C6
2.535-C6

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-6.8
-6.6
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-5.6
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1.523-16
3.861-16
9.768-16
2.?466-15
6.217-13
1.564-14
3.129-14
9.845-14

37CC

-3

5.157-03
4.cq9-03
3.251-03
2.586-03
2.044-03
1.61T-03
1.275-03
3.002-03
7.832-04
6.067-04
4.643-04
3.494-04
2.5?3-04
13.84-04
1.285-04
8.684-CS
5.703-CS
3.641-05
2.282-05
3.403-03
8.473-06
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2.590-06
1.752-06
1.020-06
5.913-07
3.415-07
1.968-07
1.134-01
6.534-00
3.775-08
2.190-08
3.279-06
7.532-C9
4.487-09
2.71-09
3.t66-c9
3.043-09
6.666-IC
4.351-10
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1.092-IC
8.28Y-13

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1.215-19

1.161-04
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3.7-36
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2.475-33
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7.613-C1
1.707-01

2.036-01
2.066-01

4.629-03
4.647-03

4.7e3-05
5.619-01

1.490-05
1.494-06

-6.6
-6.4
-6.2
-6.0
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-6.6
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-5.2

9.937-05
9.035-01
8.071-05
7o.73-05
6.109-05
5.32C-05
4.503-06
3.750-03
3.00-05
2.4q0q-O
1.qt0-05
1.562-05
1.141-05
8.161-C6
5.533-05
3.53S-06
2.115-06
1.188-06
6.317-07
3.210-07
3.636-07
7.630-08
3.555-08
1.665-08
7.649-09
3.522-C9
I.e39-09
7.653-10
3.442-10
1.598-10
7.483-Il
3.542-11
1.702-11

9.S9I-17
7.139-17
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3.566-17
2.458-17
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5.122-21
1.840-21
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1.240-13
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3.696-01
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2.607-01
2.247-01
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2.075-01
2.082-01
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2.093-01
2.098-01
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2.117-01
2.k27-01
2.147-01
2.163-01
2.194-Cl
2.235-01
2.289-01
2.357-01
2.436-01
2.525-01
2.620-01
2.015-01
2.808-01
2.896-01
2.973-01
3.040-01
3.036-01
3.139-01
3.170-01
3.188-01
3.192-01
3.183-01
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4.670-03
4.677-03
4.683-03
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4.091-03
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1.335-04
1.99-04
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3.704-05
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2.305-25
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1.169-05
7.704-06
5.033-06
3.273-06
2.120-06
1.372-06
8.800-07
6.760-07
3.751-07
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1.497-05
1.499-05
1.601-05
1.303-05
1.506-05
1.508-05
1.512-06
1.Sk7-05
1.524-05
1.S34-05
1.549-06
1.5?1-05
1.601-05
1.640-05
1.619-OS
1.748-05
1.813-06
1.882-05
1.933-05
2.023-05
2.089-05
2.151-05
2.206-05
2.255-03
2.298-05
2.33%-03
2.360-05
2.396-06
2.42-05
2.446-05
2.467-05
2.489-03
2.513-05

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1.0
1.2
1.4
3.6
1.8
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1.115-21
6.656-29
4.113-29
2.646-29
1.768-29
1.229-29
8.698-30
6.734-30
S.369-30
4.588-30

4.174-12
2.140-12
1.139-12
6.228-13
3.515-13
2.044-13
1.222-13
7.486-14
4.691-14
3.002-14
1.960-14

1.641-28
6.397-29
2.610-29
1.118-29
5.031-30
2.375-30
1.173-30
6.036-31
3.224-31
1.783-31
1.029-31

1.C03-17
7.625-18
6.889-30
4.624-18
3.690-18
2.590-18
2.456-18
2.039-18
1.705-18
1.431-18
1.199-18

1.786-C2
1.43C-07
1.146-02
9.176-03
7.344-03
S.068-03
4.675-03
3.707-03
2.918-03
2.271-03
1.737-03

2.718-01
2.551-01
2.339-01
2.146-01
1.917-01
1.684-01
1,453-01
1.232-01
1.026-01
8.373-02
6.667-02

7.9n6-03
8.080-03
8.184-03
8.294-03
8.410-03
8.626-03
8.640-03
8.749-03
8.851-03
8.96.-03
9.032-03

7.277-08
4.969-00
3.441-08
2.415-08
1.713-08
3.729-08
8.851-09
6.372-09
4.653-09
3.199-09
2.181-09

2.565-05
2.695-05
2.629-03
2.664-05
2.701-03
2.739-06
2.776-03
2.610-06
2.843-05
2.873-05
2.901-05

LOG C
-7.0
-6.8
-6.6
-6.4
-6.;
-6.0
-56.
-5.6
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-5.2
-5.0
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1.117-02
8.917-03
7.112-03
5.671-03
4.,21-i
3.605-03
2.876-03
2.297-03
1.838-03
1.476-03
1.189-03
9.655-04
7.916-04
6.567-04
6.687-04
4.788-04
4.209-04
3.769-04
3.426-04
3.146-04
2.906-04
2.689-04
2.48e-04
2.291-04
2.103-04
1.923-04
1.730-04
3.687-04
1.433-04
3.?89-04
1.355-04
1.C33-04
9.165-05
8.106-05
7.121-05
6.221-06
5.382-05
4.607-03
3.896-05
3.251-03
2.677-05
2.176-06
1.750-03
1.397-06
1.112-05
8.898-06
7.241-06

z
2.01713600
2.00844*CO
2.0046'+00
2.C0023+00
1.93833CO
1.99354430
I.qq257.00
1.98906400
1.98447.00
1.97807400
1.96804.00
3.96542400
1.93618.00
1.90941-00
1.87376.00
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1.77573100
3.716713CO
1.865024c0
1.5q387400
1.53590.00
1.48792.00
1.43583.00
1.3949S.00
1.359994c0
1.39047.00
1.30568,00
1.23472.00
1.26713300
1.25212-00
1.23904400
1.22730400
1.21637.00
3.?0571500
1.19503400
1.18388-C0
1.37216.c0
1.1993.00
1.14739,00
1.13689,00
3.12397400
1.11943-00
1.11847+00
1.12L17.00
1.14704.00
1.18789.00
1.25906.00

"-6.0
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3.447-28

8.33-32

4.386-28

Ne*

A-*

-7.0
-0.8

LOG C

1o337-17

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"-4.2
-4.0
-3.8
-3.6
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-3.0
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-. 4
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2.13976*03
2.14144.01
2.12980.01
2.11016.03
2.11190-01
2.10440.01
2.09696.01
2.08977-01
2.078?0401
2.06576601
2.04639001
2.01939401
1.98097401
1.9277.501
1.370C6.01
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1.66302.03
1.64637403
1.42448.01
1.30373401
1.18937401
1.08495,01
9.92567.00
9.12124-00
8.43793+00
7.86367400
7.38599.00
6.98990-00
6.66314400
6.39275300
6.16735*00
S.97678400
5.81396400
6.66487*00
':.52826+00
5.36623*00
5.26406.00
5.12886.00
4.98981400
4.84819300
4.70091.00
4.56969400
4.44015600
4.32123.00
4.21489.00
4.32220400
4.0.372.00

2.228-c?

2.896-03

7.900-03

3.030-07

2.638-05

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2.35707301
2.34228.C1
2.33C26-01
2.3202S.01
2.3137!.01
2.30395601
2.29622.01
2.28767.01
2.27716.01
6.263074C0
2.24328-01
Z.21493-01
2.1?*34qC|
2.i38654CI
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1.95103401
1.84159401
1.71809.01
1.58999*01
1.46312401
1.34296401
1.23325301
1.13595+01
i.C5062-'0
9.979100
9.194094CO
8.69113700
8.27463*00
7.93C28"00
7.64WIT:
7.40639400
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7.02833+00
6.87037.C0
6.7232840
6.58411C"C
6.43622400
6.288?9*C0
6.13741300
6.98408C+0
5.03288.00
3.61912.00
5.56862-C0
6.44744C00
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5.31009*C0
5.30278.00

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7.74180.01
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7.53333I01
7.43S54.03
7.336C7401
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7.03536401
6.93068401
6.82091401
6.7C353-01
6.57540-01
6.43368+01
6.27684401
6.10364401
5.91349.01
5.71641401
3.51688401
5.32033-01
6.13492+01
4.96102401
4.8C125-01
4.65535801
4.57411401
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4.29627401
4.19707401
4.3C565.03
4.02063400
3.94071-01
3.66847.01
3.79212*01
3.72164401
3.65270.01
3.58472403
3.51726.01
3.45004.01
3.38300401
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2.99376401
2.93082+01
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1.99554400
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1.99257-00
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1.98906400
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1.044?7.00
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1.97807.00
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1.96004-00
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1.95542+00
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1.93618.00
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1.90961+00
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1.07376.00
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1.8288.00
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3.77673400
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2.006-06
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2.641-04
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3.606-23
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2.393-21
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3.310-16
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4.040-14
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3.700-13
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1.490-12
2.304-12
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3.373-06
3.S17-06
3.gt2-08
2.627-06
3.341-06
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4.798-06
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2.002-07
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4.203-07
6.067-07
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4.205-02
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7.269-03
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3.384-09
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LOG 0
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3.045-18
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9.627-19

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1.4
1.6
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J.813-19
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7.484-21
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6.650-22
3.614-22
1.690-22
9.630-23
3.100-23
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1.7-3
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3.307-23
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1.320-04
13675-694
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1.64 -04
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3.616-08
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2. 1q- 04
3.543 71
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3.403-05
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1.345-03
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4. j20-r9
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-4.0

3.705-Ce

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1.32-03

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7.252-3
7.300-03
3.390S-03
7.3ql-03
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1.217-03
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6.023ICl
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6.. 27-Cl
0.792-Cl
0.239-03
4.470-Cl
4.300-03
3.537-03
2.002-03
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2.707-03

4.254-04
5 .099-04
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3.370-03
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3 .36-f3
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Z.038-13
2.043-03
2 .(601- 01
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2.3:0-03
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1.374-01
2.W3503
2.240-03
1.3046-03
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2.)75-03
2.304-03
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2.111-0'.
2.2 3"-t
03
2.0468-03

2)I
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1.))-03
?2.55s2-0 3
2.940-03
3.214-00
3.454-03

-4.2

T.409-00
5.030-CQ

-4.0
-1.0
-3.6
-3.4

3.113-09
2.392-CO
1.402-09
9. 600b-3Ic0

-3.2

6.143-1C

-3.0
-2.6
-2.6
-2.4
-2.2
-?.0
-3.0
-3.6
-3.4
-3.2
-3.0
-. 8
-. 6
-. 4
-.2
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.2
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1.0
3.2
3.4
3.6
3.0
2.0
2.2

4.174-10
2 .74 0-310
1.193-10
3* 30-30
7.420-13
4.954-31
3.21A-31
2.000-33
3. 308-33
0.391-12
5.768-12
3.777-32
2.4M6-12
3.647-32
3.303-12
?.414-13
5.002-33
1.920-33
2.472-33
13.762-13
3.279-33
9.544-34
7.446-14
8.243-34
5.911-14
6.020-34
1.222-13

13.030
t-9

9.q40-05
9.077I-00
0.074-00
0.407-05
7048-05
6.036-03
6.3038-00
S.42-09
4.682-09
3.097-00
3.370-05
2.834-00
2. 162-015
3.000-09
3.633-0
3. 333 -00
3.9-5
8.904-C6
7.370-04
5.073-0t
4.3750-6
3.273-06
2.3130-0
3.704-06
1.22C-06
q072'4-07
7.306-07

.0 3311-30

136*37-10
3.024-30
7.S-12-133
S.S64-33
4.C290-11
2.813-33
2.036-31
1.423-33
9.340-32
6.7?5'-312
4.600-32
3.3123-12
2.3371-32
3.4331-3
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9.4600-13
6.5501-3
4.447-313
3.032-33
2.029-33
1.353-33
B.09?-314
S.774-34
3.746-14
2.404-34
3.089-34
3.037-34
3.660-134

3 *203-06

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4.097-09
3. 269-C9
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3.363-310
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3.430-10
1.549-310
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0.402-33
0.612-11
80103-33
0.376-33

ILOG. C
-7.0
-6.0
-6.6
-4.4
-6.2
-6.0
-5.5
-9.6
-0.4
-5.2
-5.0
-4.0
-4.6
-4.4
-4.2
-4.0
-3.0
-3.6
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-2.6
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-2.2
-2.0
-3.0
-3.6
-1.4
-3.2
-3.0
-. 9
-.6
-.4
-.2
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3.0
3.2
3.4
3.6
3.0
2.0
2.2

f4.007-03
4.90)4-03
4.003-01
4.074-03
4.9?8-03
6.900-03
4.945-01
4.930-03
4.060-01
4.800-03
4.703-01
4.066-01
4.303-01
4.166-01
3.900-01
3.597-03
3.247-03
2-922-01
2.575-01
2.239-01
3.923-03
3.630-03
1.369-03
1.140-01
9.422-02
7.139-02
6.320-02
9.149-02
4.370-02
3.335-02
2.738-02
2.234-02
3.702-02
1.402-02
13.3334-02
9.634-Cl
7.943-03
6.039-03
5.022-03
4.691-03
4.033-0..
3.493-03
3.073-03
2 .7T43-03
2.497-03
2.304-03
?.404-C3

3.01374.00
3.91403.00
3.97430.00
3.060843*00
3.00334.00
3.002 79.00
3.93004+00
3.01214.CO
3.07736400
3.832407+00
3.75502-00
3.463134,00
3.04470*00
3.40350.00
3.259193.0
3.31033300f
2.90330.00o
2.00734,00
21.6794.00
2.00004.00
2.40913300
2.37355.00
2.3)0?27.00
2.24264*00
Z.319364-00
2.15344.00
1.32046.00
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2.07066,00
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1.000836.00
3.07726.00
3.093i20*0
1. '.21.00
1.u7687.00
3.32499.00
3.74033*00
3.70332.00
1.64629.00
3.sq?705.00
1.93714.00
1.40330'00
3.47630.00
3.47729*00
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4.42520.01
0.42242*03
4.43310.03
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4.40323*031
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4.36055010
4.32332.03
4.:267
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4.38704.01
4.07542.01
3.92703.03
3.74423.03
3.32024*03
3.29230.01
1.00749.03
2.O0945.03
1.51721-01
2.3690q0.0
2.18464.01
21.02-06.01
1.33039.01
3.77?.73.03
3.63002.03
3.40390.03
3.00797*03
3.43I66.0*0
1.44279401
3.40?19.01
3.37700.03
3.33343.01
3.32770,01
1.30330503
1.23703.03
3.24737.03
1.Z1059.03
1.16930+01
3.333250.0
3.04053.01
0.02069.00
9.13663.00
0.45943.00
7.81906.00
1.2)163400
6.70000.-00
6.24149*00
3.34369.00

3.403-03

3.841-03
3.097-03
4.31/4-03
4.2)S-03
4.326-00
4.404-03
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4.533-03
4.594-03
4.b660-03
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4.833-03
4.049-03
9.090-00
0.270-03
0.490-03
S.72A-01
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6.253-03
6.037-03
6.639-03
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3.76o-06
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7.2610-0
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3 .7710-05
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4.79102,03
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4.78C48.01
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4.60'30.03
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3.50034303
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0.07923,03
4.93339.03
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1.40241.01
4.0322b.031
4.69-58-01
3.39200;.03
1.29304-01
4.06021.01
3.12249.03
4.43042.01
4.2615q010
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-1.0
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A

AOSTRACT

Tables for the thersmodynanic properties for air are pres;ented wl

take into account the effect of dio.sociation and ionizaticn and
liriting-law, Debye-IHtcIeol and second virial corrections upon th(
thermodynamizc properties and the equililbr "um compositions.
Valt
are tabulated fromi 15001% in steps of 100 K to 15,000K at close
spacings in the logarithtj of the density [logl 0 p/Po = -7.(0.2)'
for the compressibility factor Z = PV/RT; the dimensionless func
tions for:
internal energy, E/RT; enthalpy, H/RT; entropy, S/R
loglOP(atm) and Z* - Z Ci.
The underlying equations and the inj
data are discussed briefly.
The effects of the real gas correct
on the equilibrium properties are illustrated graphically.
The
equilibrium composition is given for selected temperatures over
tabulated density range.
The wide range of temperatures and den
sitics over which the thermodynami-c properties have been tabulat
matne the tables useful in a variety of engineering design and te
programs, and in scientific research and development.

DD I

1473

UNCLASSIFIED
Security Classification

UNCLASSIFIED
Secuity Classification
S

LINK 8
ROLW

LINK A
ROL
WT

KEY WORDS

LINK C
POt.
WT

. air
thermodynamic properties
dissociation
ionization
tables

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number of pages containing information,

13. ABSTRACT: Enter an abstract giving .a brief and factual

summery of the document indicative of the report, even though
it :nay also appear elsewhere in the body of the technical report. If additional space is required, a continuation sheet s8%all
be attached.

7b. NUMBJER OF REFERENCES:

references cited in the report,

It is highly desirable that the abstract of classified reports

be unclassified, Each paragraph of the abstract shall end with

Enter the total number of

8a. CONTRACT OR GRANT NUMBER: If appropriate, enter

the applicable number of the contratt or grant under which
the report was written.

an indication of the military security classification of the information in the paragraph, represented as (TS), (S), (C), or (U).
There is no limitation on the length of the abstract. How-

Sb,, &,
8d. PROJECT NUMBER: Enter the appropriate
8
military department identification, such as project number,
rujbproject number, system numbers, !ask number, etc.

ever. the suggested length is from 150 to 225 words.

9a. ORIGINATOR'S REPORT NUMBER(S): Enter the offlcidi report number by which the document will be identified
and tontri.tled by the originating activity. This number must
be uniqre i t is report.
oh OTHER REPORT NUMbER(S):
if the repne
o
. been
.. ',. Vnred inv other report number% (eithe.r by t,
i.riginoator
,-r hi 11,- pon or), also enter this number(s).
It.
AVAILARIILITY/LIMITATION NOTICES: Enter any tims',!= -ri,nfit her :hisSemination of the report, other than those

14. KEY WORDS: Key words are technically meaningful terms

or short phrases that characterize a report and may be used as
index entries for cataloging the report. Key words must be
selected so that no security classification is required. Identifiers, such 'as equipment model designation, trade name, military
project code name, geographic location, may be used as key
words but w,1t be followed by en indication of technical con.
text. The assignment of links, rules, and weights is optional.

UNCLASSIFIED
Security Classification