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IN-MOD.dot / Rv. 5 du 19.03.2010
IN-42.3-5.1 Std material spec Low alloyed steels for pressure vessels.doc
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Table of content
1.
SCOPE ........................................................................................................................... 4
2.
2.2
3.
WELDING ..................................................................................................................... 11
3.1
3.2
3.3
4.
General ................................................................................................................ 11
Welding processes .............................................................................................. 11
Welding consumables chemical analysis ............................................................ 12
Cladding............................................................................................................... 13
Weld Overlay ....................................................................................................... 13
Ferrite content...................................................................................................... 14
Nozzles and Manways ......................................................................................... 14
5.
6.
This document contains confidential proprietary material belonging to Axens which may only be made
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IN-MOD.dot / Rv. 5 du 19.03.2010
IN-42.3-5.1 Std material spec Low alloyed steels for pressure vessels.doc
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GENERAL COMMENTS
The information given hereafter for "Base Metal Quality" and "Welding" results from
AXENS/IFP wide and significant experience in the low alloyed steels made pressure vessels
specification/operation and mostly in the field of hydro-processing and reforming units.
Specific codes, as well as Client and Engineering Contractor Standards may also influence
the choice in materials and methods. Therefore, the given specifications shall be considered
as minimum requirements and should consequently be used by the Engineering Contractor
during call-for-bid.
The data given here, are defined in the aim at giving an appropriated quality and safety level
for these critical equipments. It should not in any case interfere with Contractors
specification relative to design, manufacturing and inspection of the equipment. In case of
any discrepancy between specifications, and for lack of any official derogating decision
issued by the Owner or the Contractor, then the more stringent requirement shall govern.
PREAMBLE:
The use of V-modified Cr-Mo steels is, for many years, considered as an enhancing
specification compared to corresponding conventional Cr-Mo steels.
Beyond the well-known improvement of design stress intensity resulting in thinner and lighter
reactors, they also offer an increased resistance to hydrogen damages, a lower susceptibility
to temper embrittlement and also a better resistance to weld overlay disbonding and creep
phenomena.
Fine, globular shape, stable and well distributed Vanadium carbides do favorably act in
providing excellent benefits to these steels.
Nevertheless, this steel grade should never be specified without considering its inherent
weakness in term of limited toughness and reduced weldability which require specific and
dedicated manufacturing and heat treatment procedures. Vendor should then be able to
establish its capability and its similar experience by demonstrating how dedicated
carefulness is applied all along fabrication steps.
Moreover, vendor shall typically assure a close cooperation with the steel supplier itself so as
to finally get the fine balance between the different specifications herein given.
This document contains confidential proprietary material belonging to Axens which may only be made
available to personnel or organizations who have signed appropriate secrecy agreements.
IN-MOD.dot / Rv. 5 du 19.03.2010
IN-42.3-5.1 Std material spec Low alloyed steels for pressure vessels.doc
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1. SCOPE
This specification has to be applied to the equipment fabricated with 2.25Cr-1Mo-0.25V low
alloyed steel and 2.25Cr-1Mo-0.25V low alloyed steel weld overlaid or clad with austenitic
stainless steel and built in accordance with the ASME Code as applicable.
This document contains confidential proprietary material belonging to Axens which may only be made
available to personnel or organizations who have signed appropriate secrecy agreements.
IN-MOD.dot / Rv. 5 du 19.03.2010
IN-42.3-5.1 Std material spec Low alloyed steels for pressure vessels.doc
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2. REACTORS MANUFACTURING
2.1 Base Material Plates
The plates to be used for the fabrication of the equipment shall comply with the basic
requirements of the ASME Section II, Part A & D specification SA-542 Type D, Class 4a (or
SA-832 Gr 22 V for thickness < 150 mm) and SA-20 supplemented by following additional
requirements:
This document contains confidential proprietary material belonging to Axens which may only be made
available to personnel or organizations who have signed appropriate secrecy agreements.
IN-MOD.dot / Rv. 5 du 19.03.2010
IN-42.3-5.1 Std material spec Low alloyed steels for pressure vessels.doc
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The specific chemical analysis of the present steel grade, shall be in conformity with ASME
specification SA-542 or SA-832 requirements with the following restrictions:
- The expected level of main impurities shall be as follows (by Heat Analysis):
Acceptable limitations
(*)
(*)
0.15% max
0.010% max
Ni
0.25% max
Cu
0.20% max
O2
30 ppm max
H2
3 ppm max
(by product)
P + Sn
0.015% max
(target 0.012%)
to
propose
(target 0.007%)
such
guaranty
for
thickest
plates
- While the other indications here below, given for information, are corresponding to the
typical chemical compositions which should also be met for such kind of application (by
Heat Analysis):
Typical limitations
Si
0.10% max
Al
0.045% max
0.008% max
Sn
0.010% max
As
0.012% max
Sb
0.004% max
N2
80 ppm max
Nb
0.07% max
Ti
0.03% max
This document contains confidential proprietary material belonging to Axens which may only be made
available to personnel or organizations who have signed appropriate secrecy agreements.
IN-MOD.dot / Rv. 5 du 19.03.2010
IN-42.3-5.1 Std material spec Low alloyed steels for pressure vessels.doc
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In view of minimizing the risk of temper embrittlement, the "J" factor shall verify the relation
hereafter :
All elements mentioned here above, specified in weight percentages, have to be checked on
ladle and on product.
Notes:
- Susceptibility to Temper Embrittlement phenomenon has forced steel producers to restrict
tramp elements contents, mainly P, Sb, Sn, As (in order of decreasing severity in weight
percent basis) which elements can detrimentally diffuse to the grain boundaries while steel is
held within the embrittling temperature range.
This criterion and also the specified impurities level shall uniformly be guarantied for the
whole vessel, including the shell, heads and all other plates made pressure retaining parts as
well (e.g. nozzle parts, elbows, etc.).
This document contains confidential proprietary material belonging to Axens which may only be made
available to personnel or organizations who have signed appropriate secrecy agreements.
IN-MOD.dot / Rv. 5 du 19.03.2010
IN-42.3-5.1 Std material spec Low alloyed steels for pressure vessels.doc
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This document contains confidential proprietary material belonging to Axens which may only be made
available to personnel or organizations who have signed appropriate secrecy agreements.
IN-MOD.dot / Rv. 5 du 19.03.2010
IN-42.3-5.1 Std material spec Low alloyed steels for pressure vessels.doc
AC
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IN-42.3
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This document contains confidential proprietary material belonging to Axens which may only be made
available to personnel or organizations who have signed appropriate secrecy agreements.
IN-MOD.dot / Rv. 5 du 19.03.2010
IN-42.3-5.1 Std material spec Low alloyed steels for pressure vessels.doc
AC
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IN-42.3
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10/17
This document contains confidential proprietary material belonging to Axens which may only be made
available to personnel or organizations who have signed appropriate secrecy agreements.
IN-MOD.dot / Rv. 5 du 19.03.2010
IN-42.3-5.1 Std material spec Low alloyed steels for pressure vessels.doc
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3. WELDING
3.1 General
The vessel Manufacturer shall not subcontract fabrication involving welding to others without
the written approval of the Contractor.
The plate, or forging edge preparation for welding as well as the nozzle openings will be
carried out by machining. Flame cutting may sometimes be allowed by the Contractor
provided the heat affected zone is completely removed by machining or grinding (ex: Nozzles
openings in shell or head).
This document contains confidential proprietary material belonging to Axens which may only be made
available to personnel or organizations who have signed appropriate secrecy agreements.
IN-MOD.dot / Rv. 5 du 19.03.2010
IN-42.3-5.1 Std material spec Low alloyed steels for pressure vessels.doc
AC
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IN-42.3
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This document contains confidential proprietary material belonging to Axens which may only be made
available to personnel or organizations who have signed appropriate secrecy agreements.
IN-MOD.dot / Rv. 5 du 19.03.2010
IN-42.3-5.1 Std material spec Low alloyed steels for pressure vessels.doc
AC
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IN-42.3
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IN-42.3-5.1 Std material spec Low alloyed steels for pressure vessels.doc
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available to personnel or organizations who have signed appropriate secrecy agreements.
IN-MOD.dot / Rv. 5 du 19.03.2010
IN-42.3-5.1 Std material spec Low alloyed steels for pressure vessels.doc
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This document contains confidential proprietary material belonging to Axens which may only be made
available to personnel or organizations who have signed appropriate secrecy agreements.
IN-MOD.dot / Rv. 5 du 19.03.2010
IN-42.3-5.1 Std material spec Low alloyed steels for pressure vessels.doc
AC
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This document contains confidential proprietary material belonging to Axens which may only be made
available to personnel or organizations who have signed appropriate secrecy agreements.
IN-MOD.dot / Rv. 5 du 19.03.2010
IN-42.3-5.1 Std material spec Low alloyed steels for pressure vessels.doc
AC
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17/17
This document contains confidential proprietary material belonging to Axens which may only be made
available to personnel or organizations who have signed appropriate secrecy agreements.
IN-MOD.dot / Rv. 5 du 19.03.2010
IN-42.3-5.1 Std material spec Low alloyed steels for pressure vessels.doc
AC