LESSON PLAN

Course Code / Name: CH 2351 - CHEMICAL ENGINEERING

THERMODYNAMICS II
Branch: Chemical Engineering
Semester : VI
Regulation :2008
AIM
In this course, the students will learn various principles of thermodynamics
from a chemical engineering point of view.
OUTCOME
The Students will be well versed with the behaviour of fluids under PVT
conditions and also apply them for practical purpose. They will be provided a
comprehensive exposition to theory and application of solution thermodynamics.
TEXT BOOKS
1. Smith, J.M., VanNess, H.C., & Abbot M.C, Introduction to Chemical Engineering
Thermodynamics, McGraw Hill VII Edition 2004.
2. Narayanan K.V A Text Book of Chemical Engineering Thermodynamics Prentice
Hall of India Pvt. Ltd. 2001.
REFERENCES
1. Hougen, O.A., Watson, K.M., and Ragatz, R.A., Chemical Process Principles Part II,
Thermodynamics, John Wiley, 1970.
2. Dodge, B.F., Chemical Engineering Thermodynamics, McGraw-Hill, 1960.
3. Sandler, S.I., Chemical and Engineering Thermodynamics, 2nd Edition, Wiley,
1989.
INTERNAL MARKS DETAILS
Internal Assessment Test I
Internal Assessment Test II
Internal Assessment Test III
Attendance
TOTAL
TEST SCHEDULE
Sl. No.
1
2
3
4
5
6

TEST
Unit Test I
Unit Test II
Unit Test III
Unit Test IV
Unit Test V
Model Exam

5
5
5
5
20
DURATION
1.5 Hrs
1.5 Hrs
1.5 Hrs
1.5 Hrs
1.5 Hrs
3 Hrs

LESSON PLAN
Course Code / Name: CH 2351 - CHEMICAL ENGINEERING
THERMODYNAMICS II
Branch: Chemical Engineering
Semester : VI
Regulation :2008

UNIT I PROPERTIES OF SOLUTIONS

Partial molar properties, ideal and non-ideal solutions, standard states
definition and choice, Gibbs-Duhem equation, excess properties of mixtures.
Objective
To understand the various properties of solutions and interpret them;
Teaching
Method

Sl. No.

Date

Hour

02/01/15

Solution Thermodynamics

03/01/15

Basic Laws and Relationships

-do-

05/01/15

Partial Molar Properties

-do-

06/01/15

Determination of PMP

-do-

07/01/15

Ideal Solutions

-do-

-do-

08/01/15

Non-Ideal Solutions

-do-

-do-

09/01/15

Standard States Definition & Choice

-do-

-do-

10/01/15

Gibbs-Duhem Equation

-do-

12/01/15

10

13/01/15

Topics to be covered

Excess Properties of Mixtures

Tutorial

Time
55 min

Chalk & Talk,

Power Point
Presentation
-do-do-do-

-do-

-do-

-do-

-do-

-do-

LESSON PLAN
Course Code / Name: CH 2351 - CHEMICAL ENGINEERING
THERMODYNAMICS II
Branch: Chemical Engineering
Semester : VI
Regulation :2008
UNIT II PHASE EQUILIBRIA
Criteria for equilibrium between phases in multi component non-reacting
systems in terms of chemical potential and fugacity, application of phase rule,
vapour-liquid equilibrium, phase diagrams for homogeneous systems and for
systems with a miscibility gap, effect of temperature and pressure on azeotrope
composition, liquid-liquid equilibrium, ternary liquid-liquid equilibrium.
Objective
To impart knowledge about chemical equilibrium, fugacity, activity and
chemical potential;
Sl. No.

Date

Hour

Topics to be covered

Time

55 min

Teaching
Method
Chalk & Talk,
Power Point
Presentation

14/01/15

Criteria for Phase Equilibria

19/01/15

Multicomponent Systems

-do-

20/01/15

Chemical Potential and Fugacity

-do-

21/01/15

Applications of Phase Rule

-do-

22/01/15

Vapor-Liquid Equilibria

-do-

-do-

23/01/15

Phase Diagrams for Homogeneous Systems

-do-

-do-

24/01/15

Azeotropic Composition

-do-

-do-

27/01/15

Liquid-Liquid Equilibrium

-do-

9
10

28/01/15
29/01/15

3
7

Ternary Liquid-Liquid Equilibrium

Tutorial

-do-do-

-do-do-do-

-do-do-do-

LESSON PLAN
Course Code / Name: CH 2351 - CHEMICAL ENGINEERING
THERMODYNAMICS II
Branch: Chemical Engineering
Semester : VI
Regulation :2008

UNIT III CORRELATION & PREDICTION OF PHASE EQUILIBRIA

Activity coefficient-composition models, thermodynamic consistency of
phase equilibria, application of the correlation and prediction of phase equilibria in
systems of engineering interest particularly to distillation and liquid extraction
processes.
Objective
To impart knowledge about the thermodynamic consistency of VLE data and
various models of vapor-liquid equilibrium;
Teaching
Method

Sl. No.

Date

Hour

30/01/15

Activity & Activity Coefficent

31/01/15

Antoines Equations

-do-

02/02/15

Composition Models

-do-

03/02/15

Analysis of VLE Data

-do-

04/02/15

Thermodynamic Consistency

-do-

-do-

05/02/15

Redlich-Kister Method

-do-

-do-

06/02/15

Correlation & Prediction

-do-

-do-

07/02/15

Distillation Process

-do-

09/02/15

Liquid Extraction Process

-do-

-do-

10

10/02/15

Tutorial

-do-

-do-

Topics to be covered

Time

55 min

Chalk & Talk,

Power Point
Presentation
-do-do-do-

-do-

LESSON PLAN
Course Code / Name: CH 2351 - CHEMICAL ENGINEERING
THERMODYNAMICS II
Branch: Chemical Engineering
Semester : VI
Regulation :2008

UNIT IV CHEMICAL REACTION EQUILIBRIA

Definition of standard state, standard free energy change and reaction
equilibrium constant, evaluation of reaction equilibrium constant, prediction of free
energy data, equilibria in chemical reactors, calculation of equilibrium compositions
for homogeneous chemical reactors, thermodynamic analysis of simultaneous
reactions.
Objective
To impart knowledge about the standard free energy, reaction equilibrium
and thermodynamic analysis of reactions;
Teaching
Method

Sl. No.

Date

Hour

11/02/15

Standard State - Introduction

55 min

12/02/15

Standard Free Energy Change

-do-

13/02/15

Reaction Equilibrium Constant

-do-

14/02/15

Evaluation of Reaction Equilibrium Constant

-do-

17/02/15

Prediction of Free Energy Data

-do-

-do-

18/02/15

Equilibria in Chemical Reactors

-do-

-do-

19/02/15

Calculations of Equilibrium Compositions

-do-

-do-

20/02/15

Homogeneous Chemical Reactors

-do-

21/02/15

10

23/02/15

Topics to be covered

Simulataneous Reactions Thermodynamic

Analysis
Tutorial

Time

Chalk & Talk,

Power Point
Presentation
-do-do-do-

-do-

-do-

-do-

-do-

-do-

LESSON PLAN
Course Code / Name: CH 2351 - CHEMICAL ENGINEERING
THERMODYNAMICS II
Branch: Chemical Engineering
Semester : VI
Regulation :2008

UNIT V REFRIGERATION
Principles of refrigeration, methods of producing refrigeration, liquefaction
process, coefficient of performance, evaluation of the performance of vapour
compression and gas refrigeration cycles.
Objective
To know about various miscellaneous fertilizers;
Teaching
Method

Sl. No.

Date

Hour

24/03/15

Refrigeration - Introduction

25/03/15

Principles of Refrigeration

-do-

26/03/15

Methods of producing Refrigeration

-do-

27/03/15

Choice of Refrigerant

-do-

02/03/15

Liquefaction Process

-do-

-do-

03/03/15

Coefficient of Performance

-do-

-do-

04/03/15

Evaluation of Work, Energy & CoP

-do-

-do-

05/03/15

Vapour Compression Cycle

-do-

9
10

06/03/15
10/03/15

3
7

Gas Refrigeration Cycle

Tutorial

-do-do-

Topics to be covered

Time
55 min

Chalk & Talk,

Power Point
Presentation
-do-do-do-

-do-do-do-

LESSON PLAN
Course Code / Name: CH 2351 - CHEMICAL ENGINEERING
THERMODYNAMICS II
Branch: Chemical Engineering
Semester : VI
Regulation :2008

Course Delivery Plan

Week 1
2
3
Unit
I
I
I
II

4
II

5
II

6
III

Prepared by

7
III

8
IV

9
IV

10
V

11
V

Approved by

Signature
Name of Faculty
Designation

Mr. ANTONY ANGELO

TRINITO
Assistant Professor

Prof. M.D.DURAIMURUGAN
Head (Chemical Engg.)

12
R