Chemistry

CHEMISTRY
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CONTENTS
1. Structure of Atom ................................................................................................ 5-8
2. Composition of Matter ..................................................................................... 9-13
3. Gaseous Behaviour .......................................................................................... 14-15
4. Solution ............................................................................................................. 16-20
5. Chemical Thermodynamics ............................................................................ 21-23
6. Chemical Reactions .......................................................................................... 24-26
7. Thermo-Chemistry ........................................................................................... 27-31
8. Electro-Chemistry ............................................................................................. 32-34
9. Radioactivity ..................................................................................................... 35-37
10. Chemical Bonding ........................................................................................... 38-38
11. Periodic Table ................................................................................................... 39-40
12. Non-Metals ........................................................................................................ 41-45
13. Organic Chemistry ........................................................................................... 46-50
14. N, P, C & HALOGENS ................................................................................... 51-54
15. Metallurgy ......................................................................................................... 55-58
16. Environmental Chemistry ............................................................................... 59-69
17. Chemistryat a Alance ....................................................................................... 70-74
IAS ACADEMY
CHRONICLE
A CIVIL SERVICES CHRONICLE INITIATIVE
STRUCTURE OF ATOM
It was John Dalton who first enunciated matter to be
composed of indivisible particles having an independent existence and called them Atoms (meaning uncut).
But towards the end of the 19th century, modern atomic
theory, mostly from the works of Thomson, Rutherford,
Chadwick, Milliken, Bohr, de Broglie proved that atom
is divisible and made up of three fundamental subatomic particles namely electron, proton and neutron.
Atoms are very reactive and do not exist in the free state,
except the atoms of noble gases.
Constituents of Atom
An atom consists of three fundamental particles:
(i)
Electron: The presence of electrons was discovered

by J.J. Thomson. Electrons are negatively charged
particles revolving around the nucleus in orbits of
fixed energy.
(ii) Proton: The proton was observed by Goldstein in

1896. Protons are positively charged particles residing in the nucleus.
(iii) Neutron: Neutron was identified by James
Chadwick in 1932. These are neutral particles (no
charge) residing in the nucleus with protons.
In addition to the above fundamental particles, some uncommon sub-atomic particles have also been postulated:
(i) Positrons: These are the positive counterpart of the
electrons. These were discovered by Anderson in
1932. These are highly unstable and combine with
electrons producing -rays (energy radiations).
(ii) Neutrinos and Antineutrinos: These are the particles of small mass and zero charge. These were
postulated by Fermi in 1934.
Particle
mass
Symbol
Position
Relative
(iii) Pi-mesons (Pions) and -mesons (muones) : These

particles have a mass intermediate between that of the
electron and the proton. The positively and negatively
charged mesons were postulated by Yukawa in 1935.
Neutral mesons () were postulated by Kemmer to
account for the binding forces between the nucleons.
Therefore, an atom, on the whole, is neutral because
the no. of protons is equal to the no. of electrons. Almost
the entire mass of atom is concentrated in a very small
part of its total size. This part is called the nucleus and
character.
The
de-Broglie
wavelengthinofit. Radius
alldual
the protons
and
neutrons
are embedded
particle
is given: by m-13
v
material
of the nucleus is approx. 10 cm and that of the atom is
-8
p
near about 10 cm.
Rutherfords Experiment - Atomic Model

In 1911, Lord Rutherford bombarded a gold foil with
a beam of -particles (an -particle is a positively
2+
charged helium ion - He ).
He observed that:
(i)
Most of the -particles passed straight through

the foil.
(ii) Some were deflected away from the path near the
centre.
(iii) A few were reflected back.
(i)
(ii)
On the basis of the results of alpha -Scattering

experiment, Rutherford proposed that
x. p
4
Atom is spherical.
Most part of the atom is empty.
(iii)
Mass and positive charge of the atom are located

at the centre of the atom i.e. in the nucleus.
(iv) Electrons move around the nucleus in circular paths.
Absolute
charge
Relative mass
charge
1840
nucleus
Proton
Neutron
Nucleus
Electron
e
n
Nucleus
+1
around 0the
+ 1.60 1019 coulomb

1
19
coulomb
0 1.60 10
1
9.1 10
1.67 1024 gm
1
1.68 1024 gm
Chronicle IAS Academy
[5]
(v)
Absolute
w.r.t proton)
The attractive force between the positively charged

nucleus and negatively charged electron is balanced by the centrifugal force.
The diagram of the experiment is shown below:
28
gm
number of electrons in any energy level is 2n where n is

the number of that energy level. The energy levels are
also known as shells.
2
2
K - Shell (n = 1) = 2n = 2 x 1 = 2 electrons
2
L - Shell (n = 2 ) = 2n = 2 x 2 = 8 electrons
2
Bohr model of an atom
M - Shell (n = 3 ) = 2n = 2 x 3 = 18 electrons
2
2
N - Shell (n = 4 ) = 2n = 2 x 4 = 32 electrons
Rutherfords model, however, fails to explain the stability

The electrons firstly occupy the lowest energy shell.
of atoms and the line spectrum of hydrogen. To overcome This systematic distribution of electrons is called electron configuration of the atom.
the drawbacks of Rutherfords model, in 1913 Neil Bohr
proposed a new model of the atom. This can be stated as:
(i)
Atom is spherical.
(ii) Most part of the atom is empty.

(iii) Protons and neutrons are located in the nucleus.
Dual Nature of Electron
de-Broglie pointed out in 1924 that the electron have

photon (lightparticles) like particles, behaving both as a
material particle and as a wave, i.e. the electron has a
(iv) Electrons move around the nucleus in an atom in

orbits known as energy levels having fixed energy.
(v) The energy levels are either designated as K, L, M, N
etc. or numbered as n = 1, 2, 3, 4, etc.
(vi) The absorption or emission of energy can occur
only by transition of electrons from lower to the
higher energy level, or vice-versa.
Thus, as long as electrons continue to revolve in the
same energy level, they neither lose nor gain energy and
the atom remains stable.
hh
= wavelength
h = Planks Constant
m = mass
v = velocity
p = momentum
The wave character of electrons was experimentally
proved by x-ray diffraction studies.
Heisenbergs Uncertainty Principle
Different energy levels in an atom
Distribution of Electrons in Different

Energy Levels
According to the Bohr-Bury scheme, the maximum
It is not possible to determine exactly both position

and velocity (momentum) simultaneously of a particle
having
wave nature. In other words, the product of
For 6C
uncertainty in momentum ( p)and that in position
( x) almost remains constant.
h
The Heisenbergs concept introduces the concept of

probability of locating the electrons in the space about
the nucleus.
Atomic Number
It is defined as the number of unit positive charges
on the nucleus (nuclear charge) of the atom of that
element. It is denoted by z. It is basically the number of
protons and this number is also equal to the number of
electrons in a neutral atom.
Atomic number = number of protons = number of
electrons.
Mass Number
The sum of the protons and neutrons present in the
nucleus of the atom is known as the mass number of the
atom.
[6]
Valence Electron
An electron in one of the outer shells of an atom that
takes part in forming chemical bonds is known as the
valence shell.
Valency (Valence)
It is the combining power of an atom equal to the
number of hydrogen atoms that the atom could combine
with or displace in a chemical compound (hydrogen
has a valency of 1). It is equal to the ionic charge in ionic

compounds, for example, in Na2S, Sodium has a va+
2lency of 1 (Na ) and Sulphur a valency of 2 (S ).
Atomic Mass
Atomic mass of an isotope = mass of neutrons +
mass of protons.
Isotope : The name isotope was first introduced by
Soddy. Different kinds of atoms of the same element
which have the same atomic no. but different mass nos.
or atomic mass (or atomic weights) are called isotopes of

that element. In other words, it can also be defined as
different atoms of the same element which have same
no. of protons but different no. of neutrons in their
respective nuclei. Isotopes have identical chemical properties and differ slightly in their physical properties like
densities, melting and boiling points.
iii.
Tritium 1H3 & T
2.
Isotopes of oxygen- 8O16, 8O17, 8O18
3.
Isotopes of chlorine - 17Cl35, 17Cl37
4.
Isotopes of carbon - 6C12, 6C14
Isobars
The atoms of different elements which have the same

mass no. but different atomic number are called isobars.
In the representation of an isotope of a given eleThese can also be defined as atoms of different elements
ment, the mass number (A) is shown as the superscript
which have the same sum of protons and neutrons in
at the head of the symbol of the element while the atomic the nucleus of each of these atoms but different atomic
no. (Z) is shown as the subscript at its bottom. The
number.
symbolic representation of an isotope of an element X
As for example 18Ar40, 19K40, 20Ca40etc.
has been shown below:
Symbolic Representation of Isotopes
A Mass number (protons + neutrons)
Isotones
X Symbol of the element

Z Atomic number = Protons = electrons
e.g. 8O16
O is symbol of oxygen atom
8 is atomic no. of oxygen atom
Since mass no. = Protons + Neutrons
16 is mass no. of oxygen atom
14
14 = 6 + n
Examples of Isotopes
1. There are three isotopes of hydrogen (atomic no.
Z=1) with mass no. (A) 1, 2, 3. These are:
i. Protium 1H1 - Ordinary hydrogen
ii.
The atoms of different elements which have the same

no. of neutrons but different atomic numbers are called
isotones.
Example 6C14, 7N15, 8O16
Deuterium 1H2 - or D-heavy hydrogen
n = 14 - 6 = 8
for 7N15
15 = 7 + n
n = 15 - 7 = 8
For 8O16
16 = 8 + n
n = 16 - 8 = 8
Hence the no. of neutrons of all 6C14, 7N15, 8O16 is the
same as 8 but their atomic no. is different.
Quantum Numbers
The electronic structure of an atom refers to the way
in which the electrons are arranged about the nucleus
and in particular the energy levels that they occupy.
Each electron can be characterized by a set of four quantum numbers as follows :
(i) Principal Quantum Number: It is denoted by n. It
gives the main energy level and has values 1, 2, 3, etc.
(the higher the number, the further the electron from the
nucleus). Traditionally these levels or the orbits corresponding to them are referred to as shells and are denoted by letters K, L, M etc. Hence it gives information
about the energy of an electron in an orbit, the distance
of the electron from the nucleus (size of an atom) etc.
(ii) Azimuthal Quantum Number: It is denoted by l. It
[7]
gives orbitals and the shape of orbitals. The values

of l depend on the values of n and range from 0 to n
-1 for a particular value of n. Thus for n = 2, the
value of l is 0 and 1, for n = 3, there are three values
of l (0, 1, 2)
l =
orbital
0,
1,
2,
Spherical Dumb-bell Double dumb

-bell
clockwise spin
1
s=
for anticlockwise spin
(iv) Spin Quantum Number: It is denoted by s. It

indicates the spin of the electron around its own axis.
The spin can be either clockwise or anticlockwise. For
Shape of Shape of
s-orbital p-orbital
s=
Shape of
d-orbital
Pauli Exclusion Principle : No two electrons in the

atom can have the same set of quantum numbers.
CHRONICLE
COMPOSITION OF MATTER
(iii) Magnetic Quantum Number: It is denoted by

Aufbau Principle
m. Its value depends on the values of l. For a particular
It gives the order in which orbitals are filled in sucvalues of l, the values of m range from +l to -l including
zero. Thus if l = 3, the value of m are +3, +2, +1, 0, -1, - cessive elements in the periodic table. The order of filling is 1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p,
2,
7s, 5f, 6d. This is according to the increasing order of
-3. This quantum number indicates the orientation of
energy. Maximum capacity of the s-orbital is 2 electrons,
the orbitals in the magnetic field.
of the p-orbital is 6 electrons of the d orbital is 10 elecs-orbital
trons and of the f orbital is 14 electrons i.e.
l = 0, m = 0
s-orbital
p-orbital
p-orbital
d-orbital
px
py
pz
f-orbital
l = 0, m = + 1 0
-1
d-orbital
Hunds Rule
l=2
dxy
dzx
dyz d x2
When electron filling occurs in an orbital, each orientation of the orbital is first singly occupied and only
after this pairing occurs. The filling of two electrons in
the p-orbital can be shown as:
m= +2 +1 0 -1 -2
Orientation of different orbitals are shown in the
figure given below :
+1
0-1+1
0-1
(A)
(B)
In (A), electron pairing occurs leaving empty orientation, hence this distribution is not valid according to
Hunds rule. In B, single occupancy of orientation occurs and this is valid distribution of electrons according
to Hunds rule.
[8]
IAS ACADEMY
Matter and its Nature

Entire universe is made up of only two types of
entities matter and energy. Matter occupies space and
has mass. It can be seen, tested, smelt or felt, but energy
can only be experienced, like light and heat.
Two types of change take place in matter:
(A) Physical Change : It is a temporary change and

does not involve any change in the composition of
matter. For example conversion of
water into ice, stretching a spring,

evaporation of water etc. This change
is reversible, it means that matter can
be brought back to its original form
on removing the factors governing the
change.
(B) Chemical Change : It is a permanent

change in which the composition and
properties are changed. This change
is irreversible (original substance can
not be reobtained , even after remov-
ing the factors governing the change.)

For example, burning i.e. Combustion,
rusting of iron, respiration, cooking
food, etc.
Matter is made up of different kinds of substances. A
substance is a material of which all parts are chemically
identical and of same composition.
Elements, Compounds and Mixtures
5.
Elements are found in all forms of matter i.e. solid,

liquid and gaseous form.
6. Some elements like nitrogen, oxygen, noble gases and
gold occur in the free state or the native state, while
most other elements occur in the combined state.
7. Elements are represented by the symbol e.g. Mercury is represented by Hg, Bromine is represented
by Br. etc.
8. Some elements like Technetium, Promethium, Asta-
1. An element may be defined as the simplest form of

matter which can neither be broken into, nor built
from two or more simple substances by any physical or chemical method.
2. An element is a substance made up of atoms.
3. There are about 109 elements known to man. It is a
remarkable fact that the entire universe consists of
about 100 elements only, of which, 92 are found in
nature and the rest are man made.
4. Some examples of elements are Carbon, Nitrogen,
Helium, Potassium, Iron, Gold, Platinum, etc.
Water Electric
tine, Francium and all the elements with atomic

number above 92 are found either in very slight
traces or not at all in nature.
Compounds
1.
A compound may be defined as a substance formed

by the combination of elements in a fixed proportion by weights.
2. It can be decomposed into two or more elements by
any suitable method.
3. Formation and decomposition of compounds can
be understood by taking an example i.e. Hydrogen
and Oxygen combine to form water and conversely
water is decomposed into Hydrogen and Oxygen
by passing the electric current through it.
Hydrogen + Oxygen
Water
(Elements)
(Compound)
[9]
FORMS OF ELEMENTS
Elements in
liquid form
Elements in
gaseous form
Mercury (Hg)
Bromine (Br)
Hydrogen (H)
Nitrogen (N)
Oxygen (O)
Francium (Fr) Fluorine (F)
Chlorine (Cl)
and noble
gases like
Helium (He)
Neon (Ne),
Argon (Ar)
Current
Elements in
solid form
Rest elements
like Carbon (C)
Sodium (Na)
Potassium (K)
Calcium (Ca)
Barium (Ba)
etc.
Hydrogen + Oxygen
4. Compounds, unlike mixture, cannot be separated

by physical means.
5. The composition of a particular compound does not
depend upon the source. For example, water obtained from rain, wells, oceans, rivers or mountains
has the same composition (H2O).
6. A compound is represented by a chemical formula
indicating the presence of elements and their relative number of atoms. For example, chemical formula of water is represented by H2O which includes
two Hydrogen and one Oxygen atoms.
Mixtures
1. Mixture is obtained by mixing of two or more substances (elements or compounds) in any proportion.
2. Componentsretaintheirindividualchemicalproperties.
3. It can be separated by suitable physical means.
4. Soil, stone, wood, air, water, milk, kerosene, etc. are
examples of mixtures.
5. Its properties depend on the nature and amount of
the constituents.
cooling give back the original substance. This phenomenon is only applicable when the vapour pressure of the solid phase is high. It can be used for
substances which form sublimates in their separation from non-sublimate materials. Naphthalene,
iodine and ammonium chloride are sublimable.
6. Therearetwotypesofmixtures:
Solid
Gas
2.
Distillation: On heating, a liquid is converted into

vapour which converts into the liquid on cooling.
This process is called distillation. In this process
both vapourisation and condensation take place. It
is used to purify liquids and to separate liquid mixtures.
Fractional Distillation: When the boiling points of

various components are far apart, then simple distillation method is used to separate the mixtures.
But if boiling points are closely related with each
other, then fractional distillation is used. In this
process a fractionating column is used to separate
two or more volatile liquids. It is applied extensively in petroleum refining, separation of Oxygen,
N2, inert gases and Carbon dioxide from liquid air,
manufacture of spirits such as whisky, gin, rum
and brandy.
Steam Distillation: It is a method of distilling liquids that are immiscible with water by bubbling
steam through them. It is essential that the vapour
pressure (and hence the boiling point) of the mixture of the two immiscible liquids should be lower
than the vapour pressure of either, pure liquid. This
method gives results, almost equivalent to those
obtained from simple distillation.
3.
Sedimentation and Decantation: This method is

applicable when one component is liquid and another component is an insoluble solid (heavier than
the liquid). If muddy water is kept undisturbed for
some time in a beaker, the particles of earth (clay
and sand) settle at the bottom leaving a clear liquid
Difference Between Mixtures

i.
ii.
Homogeneous Mixture
Homogeneousmixture;and
Heterogeneous mixture.
Separation of Mixtures
Some methods for the separation of mixtures are described as below :
1. Sublimation: A direct change
of state from solid to gas is
called sublimation. In this
process gaseous subtances on
Heterogeneous Mixture
1.
Composition is uniform throughout. Different components are not present

uniformly.
2. Exist in one phase either solid or
Exist in different phases.
liquid or gas.
Examples:
Examples: Smoke (mixture of air and
Air - Oxygen + Nitrogen + other
Carbon particles), Milk, mixture of
gases
iron filings and Sulphur.
Salt Solution - Sodium
Chloride in water
Sugar Solution - Sugar + Water
Carbonated Water - CO2 + Water

at the top. This process is called sedimentation. The
clear liquid (water in this case) can be gently transferred into another beaker. This process is known as
decantation.
4. Filtration: Separating the solid particles through a
filter is called filtration. The filter is made up of a
porous material (such as paper or fine glass wool)
which prevents solid particles from passing through.
There are some applications of this method which
are useful in our daily life such as l
purification of the domestic water supply by filter-
[10]
ing river water through a layer of sand.

removal of solid particles in engine oil in car engines by air filters.
filtration of tea from tea leaves in the preparation of
tea, etc.
Gas filtration involves removal of solids (called
dust) from a gas-solid mixture. Liquid filtration is
used for a liquid-solid separation in the manufacture of chemicals, polymer products, medicines, beverages and foods, in mineral processing, in water
purification, in sewage disposal, in the operation of
machines such as internal combustion engines.

5. Crystallization: This process involves the formation of crystals from a liquid or gas. Separation and
purification of solid substances is done by this
method. During this process, firstly mixture is heated
with a suitable solvent to its boiling point and then
the hot solution is filtered. The filtrate is slowly
cooled down to room temperature. Thus pure solid
crystallizes out. This is separated from the filtrate
by filtration and dried. In fractional crystallization
the components of the mixture crystallize out at
different intervals of time.
6. Chromatography: This is a technique for analysing
or separating mixtures of gases, liquids or dissolved
substances. The components of a mixture move differently on an adsorbent material (filter paper), blotting paper, solid surface of Silica, etc. when the
liquid moves through them. They travel to different
extents through the adsorbent material and thus get
separated. Separation of coloured materials from
green vegetables, ink are common examples.
2.
3.
4.
States of Matter
There are three states (or phases) of matter i.e. solids, 5.
liquids and gases. Sometimes plasma is also considered
a fourth state of matter which is a highly ionisable gas.
1. Solids: It is a state of matter which has a threedimensional regularity of structure, resulting from
the proximity of the component atoms, ions or molecules and the strength of the forces between them .
In this closely packed structure molecules vibrate
about fixed positions, solids are incompressible and

all its atoms are in a state of perpetual motion. True
solids are crystalline. If a crystalline solid is heated,
the kinetic energy increases. At the melting point
the binding forces between the components break
down and the solid becomes a liquid.
Crystalline Solids: It has a regular internal arrangement of atoms, ions or molecules. Crystalline materials need not necessarily exist as crystals, for example, all metals are crystalline although they are
not usually seen as regular geometric crystals.
Amorphous Solids: Some liquids do not solidify on
cooling into true solids. Internal structure of this
solid is haphazard and thus these solids are shapeless or amorphous. Glass is a common example.
Liquids: In a liquid, atomic (or ionic or molecular)
regularity of the solid is absent. There is a short
range structural regularity extending over several
molecular diameters. These bundles of ordered atoms, molecules or ions are free to wonder about,
enabling liquids to have almost fixed volumes which
adopt the shape of their containers.
Gases: It is a fluid of which volume is not fixed.
There are very weak bonds between the molecules
of a gas, so the molecules are free to move.
Change of State
Solid, liquid and gas are converted into each other
through the melting, boiling, condensation and solidifying processes. At melting point any change involves the
loss or gain of a certain amount of heat and this heat is
called latent heat. Some impure and non-crystalline substances like glass, butter, etc. do not have definite melting
points. Volume of substances expand upon melting and
shrinks upon solidifying but water expands on freezing.
An additional amount of heat energy called the heat of
vapourization is required to turn a liquid, such as water
0
at 100 C into steam at that same temperature. Properties
like boiling and melting depend on pressure. At less than
normal pressure, melting and boiling points are generally lower. On increasing the pressure, the boiling point
and melting point generally increase but melting point of
water decreases on increasing of pressure.
Atomic Theory of Matter

1.
Matter is made up of indivisible particles called atoms.
2.
Atoms of a particular element are all alike but differ

from atoms of another element. So different elements
behave differently but different samples of the same
element show the same behaviour.
3. A fixed quantity of an element (which must contain
a fixed no. of atoms) has a fixed mass.
4.
Atoms can neither be created nor destroyed.
[11]
Percentage of ions in Sea-water

Solute
Chloride Cl
Percentage
55.05
Sodium Na+ Sulphate So42

30.61
7.68
Magnesium Mg2+1 Calcium Ca2+ Potassium K+
3.69
1.16
1.10
0.19
% by wt. of Major Elements in the Lithosphere

Symbol of element O
Si
Al
Fe
Ca
Mg
Ti
Mn
Bromide Br
43.6
27.7
8.1 5.0
3.6
2.8
2.6
2.1
But according to the modern atomic concept atoms are

divisiblei.e.madeupofelectrons,protonsandneutrons.
0.44
There are three important laws of chemical combination based on the Daltonian atomic concept as below:
NaCl + H2O NaOH + HCl

We see that the total no. of atoms before and after the
reaction remains the same. Hence mass or matter is
conserved in this reaction.
2. Law of Constant Composition or Law of Definite
Proportion: This law states that the composition of a
pure compound is always the same. Compound is
always made up of the same elements in the same
percentage. This law can also be explained on the
basis of Daltonian theory : The no. and kind of atoms
in a given compound is fixed. H2O molecule always
contains 2 atoms of hydrogen and 1 atom of Oxygen.
3. Law of Multiple Proportion : This law states that when
two elements combine to form two or more than two
compounds, a simple ratio of weight of both elements is
maintained. For example, consider the formation of
Carbon dioxide (CO2. and Carbon monoxide (CO) by
the combination of Carbon andOxygen atoms.
In Carbon dioxide one Carbon atom combines with
two Oxygen atoms. In Carbon monoxide (CO) one
Percentage
(%)
Nitrogen
Oxygen
Argon
78
21
1 (justUnder)
0.1
Kinetic Theory of Matter

1.
All matter is made up of atoms or molecules of

independent existence.
2.
These constituent particles of each substance are distinct and have certain properties which are different
fromthoseofatomsormoleculesofallothersubstances.
3.
Molecules of the same substance are identical in all

respects.
4.
There are empty spaces between molecules, which

increase as in the following order:
solid < liquid < gas
5.
Forces of attraction being exerted between molecules

are in the following decreasing order :
solid > liquid > gas
6.
Molecules possess kinetic energy to move freely

through the bulk or volume of liquid or gas. Increasing order of kinetic energy is as below:
solid < liquid < gas
7.
Themoleculesofagasareincontinuousrandommotion
and exert pressure on the walls of the container.
8.
The kinetic energy increases on increasing the temperature.
Molecules
Gaseous Composition of the Air

Gas
0.2
Carbon atom combines with one Oxygen atom.

Hence the ratio of Oxygen combining with the fixed
amount of Carbon is 2 : 1 between CO2 and CO. This
is also the ratio of their weights.
Laws of Chemical Combination
1. Law of Conservation of Matter (or Mass): According to this law Matter can neither be created nor
destroyed in a chemical reaction. Thus there is no
change in mass in a chemical reaction. For example,
the reaction between Sodium Chloride and water
can be written as :
0.14
Carbon
Xenon, Neon, Krypton,
dioxide
0.04
Water Vapour
Very Small amounts
It is one of the fundamental units

to form a chemical compound that
can take part in a chemical reaction.
Molecules can be classified into two
types:
by how many times an atom is heavier tha

IAS Academy
Chroniclelated
1
[12]
Homoatomic Molecules
l
Made up of similar atoms.
Mostly elementary gases are homoatomic, for example, Hydrogen gas consists of two atoms of hydrogen i.e. H2. Oxygen gas consists of two Oxygen
atoms but they are diatomic. Hence it may be diatomic, etc.
Heteroatomic Molecules
l
l
Made up of different atoms.

Mostly ionic compounds are heteroatomic. It may be
in any state of matter. It also may be diatomic, triatomic, etc. Sulphur dioxide is a triatomic molecule in
which two atoms of Oxygen and one Sulphur atom
are combined together as SO2.
Benzene (C6H6) is 12 (C=6, H=6).
Avogadros Hypothesis
Equal volumes of all gases contain equal numbers
of molecules at the same pressure and temperature.
This statement is called Avogadros hypothesis. It is
true only for ideal gases. The actual no. of molecules in
a gram molecule is known as Avogadros number and
23
its value is 6.023 x 10 molecules.
Atomic Mass
It is the average relative mass of an atom. It is calcu12
Atomicity
The total no. of atoms in a molecule is called atomicity. For example atomicity of hydrogen molecule (H2) is
2, of hydrogen chloride (HCl) is 2 (H=1, Cl=1) and of
th
Mole
weight of Carbon-12 isotope. For example, Atomic mass

of Nitrogen is 14 i.e. Nitrogen is 14 times heavier than
1
Molecular Mass
23
Mole is a unit which represents 6.023 x 10 particles

(atoms, molecules or ions etc) irrespective of their nature.
23
The number 6.023 x 10 is called Avogadros number.
23
It is the mass of a molecule i.e. number of times a

molecule is heavier than
1 mole of atoms = 6.023 x 10 atoms

23
1 mole of molecules = 6.023 x 10 molecules
GASEOUS BEHAVIOUR
Molecular mass = Sum of the masses of all atoms in a

molecule.
For example, molecular mass of CO2 is 12 + 2 x 16 =

12 + 32 = 44. Therefore, molecular mass of CO2 is 44
a.m.u. The molecular mass of the compound is expressed
in grams known as gram molecular weight. Gram molecular weight of Carbon dioxide (CO2) is 44 gm.
CHRONICLE
A mole of any substance is related to :

a)
mass of a substance,
b)
number of particles,
c)
volume of a gaseous substance
One mole of all the gases at STP (Standard Tempera0

ture and Pressure i.e. 0 C and 760 mm of Hg) occupy a
volume of 22.4 litres or 22400 cc.
PV
can be established as
: TP2 V2
[13]
V
at constant T and n
(V-nb) = nRT (for n mole of the

gas.)
IAS ACADEMY
Kinetic Theory of Gases

1. Gaseous particles are in motion. Particles are made
up of molecules and as such molecules are in motion.
The moving molecule theory of gases is known as
the kinetic theory of gases.
2. Actual volume of a gas is negligible as compared to
the empty space between molecules.
3. Molecules experience attractive forces and therefore
these are in rapid, random (Zig-Zag) motion.
4. Molecules collide each other but there is no loss of
kinetic energy.
Boyles Law
Volume of a fixed mass of a gas at constant
temperature is inversely proportional to the pressure of
the gas. It can be shown as:
1
P
P = Pressure, V = Volume, T = Absolute temperature,

n = no. of moles of gas.
Charles Law
The volume of a given mass of gas at constant
pressure varies directly with absolute temperature.
Mathematically it can be seen as:
V T at constant P and n
Avogadros Hypothesis
At constant temperature and pressure, volume of a
gas varies directly with no. of moles of the gas.
Mathematically it can be seen as :
V n at constant T and P.
Equation of State or Ideal Gas Equation

It is a combined gas law and is established with the help
of Boyles law, Charles law and Avogadros hypothesis. i.e.
PV = nRT where R is gas constant and is equal to

-1
-1
8.314 JK mol
Relation between different values of P,V,T for a gas
1
1
1
T2
Real and Ideal Gas

Gases which obey Boyles law, Charles law,
Avogadros law and equation of state are called ideal,
or perfect gases and those which show deviations from
1 r or realgases.
theserlaws arecalled non-ideal
Pp Almost all
diffusion
diffusiondeviation or
gases show
from these
laws and hence almost
all gases are non-ideal, or real gases.
Vander Waal Equation

Since none of the gases is known to behave according
to the ideal gas equation, these gases are called as real
gases. Their behaviour is explainable on the basis of
Vander Waals equation as represented below :
r12
an
2
V
M2
It is the modification of the ideal gas equation PV = nRT

where pressure correction a as well as volume correction
b have been applied; a and b are Vander Waals constants
whose values depend on the nature of the gas.
Liquefaction of Gases
When gases are compressed and cooled (i.e.
subjected to high pressure and low temperature), they
are converted to liquid. The process of gas liquid is
known as liquifaction and the temperature at which a
gas is converted to liquid is known as the liquifaction
temperature. At high pressure and low temperature,
attractive forces between gaseous molecules is high and
molecules are drawn together to form a liquid. The
liquifaction of gases is indicative of the attractive forces
between the gaseous molecules.
Critical Temperature
The temperature at which a gas can be liquified is
[14]
called liquifaction temperature and this liquifaction

temperature is also called critical temperature because
above this temperature, the gas cannot be liquified no
matter how high the pressure is. Thus above the critical
temperature gaseous state exists, at the critical
temperature liquifaction occurs and below critical
temperature liquid state exists. Critical temperature
depends on the attractive forces present in the gaseous
+d
d
molecule. Thus attractive forces in HCl (H Cl ) is
greater than that in CO2 O C

and so
O
critical, temperature of HCl is higher than that of CO2

i.e., HCl is liquified at a higher temperature than CO2.
Deviation from Ideal Gas Behaviour

Gas behaves like ideal gas at high temperature and
low pressure. If gases behave like ideal gas through
obeying PV=nRT gas equation, it means that at high
temperature high pressure, PV = nRT is valid but at
(i) low temperature high pressure and
(ii) low temperature low pressure, there is deviation.
Deviation from ideal gas behaviour is less at high

temperature and greater at low temperature.
Inversion Temperature
It is the temperature at which the gas neither shows
heating effect nor shows cooling effect on expansion.
Diffusion
Inter mixing of gases irrespective of the force of
or their densities or directly proportional, to their

pressures.
1
md
r1 = Rate of diffusion of one gas

r2 = Rate of diffusion of another gas
P1 = Pressure of one gas
P2 = Pressure of another gas
Where r = Rate of diffusion
M1 = Molecular weight of one gas
p = Pressure
M2 = Molecular weight of another gas
CHRONICLE
m = Molecular weight
d = Density
SOLUTION
For two different gases
Different Types of Velocities
The three different types of velocities possessed by

gas molecules are :
P
r2 P 2 M 1
Most Probable Velocity (Cm): It is the velocity

possessed by the maximum fraction of the molecules of
gravity is known as diffusion. It refers to the flow of

molecules from a region of high concentration to a region
of low concentration.
the gas at a particular temperature. Cm
2 RT
M
R = gas constant
T = temperature (273 + tC)
Effusion
The passage of gases through a small aperture under
pressure is known as effusion. Grahams law of diffusion
is also applicable to effusion.
Grahams Law of Diffusion

Under similar conditions of temperature and
pressure, the rates of diffusion of gases are inversely
proportional to the square roots of their molecular masses
M = molecular weight
Average Velocity (Ca): It is the arithmetic mean of
the different velocities of the molecules of the gas at a
8 RT
M
Root Mean Square Velocity ( C): It is the square root

of the average of the squares of the different velocities of
molecules at particular conditions. C =
3RT
M = molecular weight of the gas.
[15]
IAS ACADEMY
particular temperature.Ca
A solution is a homogeneous mixture of two or more
substances whose properties vary continuously with varying proportion of the components. Several types of solutions
are possible because components of a solution can be in any
state of aggregation (i.e. solid, liquid or gas). They are solid
solid, solid gas, liquid liquid, liquid gas and gas gas.
Solvents and Solutes

In a solution, the substance which dissolves is called
the solute. In salt water solution salt is the solute. The
liquid that the solute dissolves in is called the solvent. In
salt water solution water is the solvent. If sugar is dissolved in water, then a solution is obtained in which
sugar is the solute and water is the solvent.
Mostly chemical reactions take place through the solvent system. Water is universal solvent due to its high
dielectric constant, thus it dissolves a large no. of different
substances. Generally solvent is in an excess quantity.

Some alloys are solid solutions of one metal in another. Ionic solids also form solid solution (e.g. NaCl,
and KCl). Gas dissolves in liquids as well as solids. A
solution of ammonia in water is familiar as a cleaning
solution in homes. Oxygen is also sufficiently soluble in
water to permit survival of aquatic life in lakes, rivers
and oceans. Both examples are from the gas-liquid type.

An example of a gas dissolving in solids is the solubility of gaseous Hydrogen in Palladium or Platinum
when water evaporates in the air; the water is the solute
and the air is the solvent, thus it is an example of gasgas solution.
Saturated Solution
possible, the solution is called as saturated solution. At

this point there can be no further addition of solute to
solvent. Supersaturated solutions have a greater proportion of solute than is contained in the saturated
solutions.
Miscible and Immiscible Liquids

Liquids which mix with each other are called miscible, e.g. water and ethanol can mix with each other.
Liquids which do not mix with each other are called
immiscible. e.g. oil, and water do not mix with each
other.
In a dilute solution, a small amount of solute is

dissolved in a large quantity of solvent. In a concentrated solution a large amount of solute is dissolved.
When a solvent has dissolved as much solute as is
Distinctions Between Acid and Base

Acid
Base
It is sour in taste. It turns blue litmus paper into red.
Methyl orange turns red in colour.
It turns red litmus paper blue.
Methyl orange turns yellow in colour.
(hydrogen lions). It contains hydrogen.
lions (OH ) in an aqueous solution.
It donates protons in solution.
It accepts protons.
Hydrochloric acid (HCl), Sulphuric acid
Sodium hydroxide (NaOH), Ammonium
(H2 SO4), Acetic acid (CH3COOH) etc. are the examples. hydroxide (NH4OH), Potassium hydroxide (KOH)
etc.
are the examples.
l
According to the modern concept (Lewis
It donates a lone pair of electrons.
Compounds having a lone pair of electrons
concept), it accepts a lone pair of electrons.

l
Electron deficient compounds such as

ZnCl2, AlCl3, BF3, FeCl3, etc. are acids.
such as HOH, : NH3, HF etc. are bases.
Chemistry [14] Academy
Emulsion
When we add cooking oil to water, the oil floats on
the water. Oil and water are immiscible. But on shaking
vigourously the oil and water, a milky-looking liquid is
obtained, this is called an emulsion. This milky liquid is
due to the presence of tiny droplets of oil. Milk is an
emulsion. It is made up of tiny droplets of fat floating in
water.
[16]
ing temperature. We take an example of gaseous solubility such as in a pond on a cool day there is usually
plenty of Oxygen dissolved in the water because solubility of gas increases at low temperature. But on a hot
day, the hot, fast moving Oxygen molecules can escape from the water into the air. Less Oxygen remains in
solution in the water because solubility of gases de-
Importance of Solution in Human Body

Human body is about 70% water. In water several
It is ionized
aqueous
solution
to give H ions
importantl reactions
whichinare
necessary
for keeping
alive, takehydroxy
place. For instance, respiration is a chemical
reaction which releases energy from food. It happens in
every cell in human body. These chemical reactions will
happen only if the substances taking part in the reaction the reactants are in solution. Cells are jelly like
solutions of many different substances in water. If the
water was not there, the chemical reactions would not
take place. It would then result into death.
Solubility
Solubility is a measure of how much of a substance
will dissolve. At saturation, the amount of solute in a
given solvent at a specified temperature is known as the
solubility of
the solute.
It can also be defined as the no. of
IAS
Chronicle
grams of solute that will dissolve in 100 gms of solvent at
a given temperature. For example, the solubility of table
salt is 35.7 grams in 100 grams of water at solvent
0
0
temperature of 0 C. It is 39.8 grams at 100 Celsius.
Solubility of solids increases with increasing temperature and solubility of gases decreases with increas-
It contains hydroxyl groups and form
creases with increase in the temperature. Fishes then

may get short supply of Oxygen and have to come to the
surface to get air.
weather when its radiator is full of water, an antifreeze

material, ethylene, glycol or alcohol, is added to lower
the freezing point of the liquid in the radiator.
Osmosis
Colligative Properties
Colligative properties of solutions are those properties which depend on the number of solute and solvent
particles (molecules or ions) but not on the nature of the
solute. Examples of such properties are :
i.
lowering of vapour pressure.
ii. elevation of boiling points.
iii. the depression of freezing point.
iv. the osmotic pressure.
Boiling and Freezing Points of Solution

Boiling point of a solution is higher than that of the
pure solvent and freezing point of a solution is lower
than that of the solvent. For running the car in subzero
Osmosis is the phenomenon where solvent molecules

flow from a dilute solution to a more concentrated solution through a semipermeable membrane. There are two
types of osmosis:
i.
Exosmosis: It is the outward flow of water from a

cell containing an aqueous solution through a semipermeable membrane e.g. grape in NaCl solution.
ii. Endosmosis: It is the inward flow of water from a
cell containing an aqueous solution through a semipermeable membrane e.g., grape in water.
Osmotic Pressure
Osmotic pressure is the pressure which just prevents the passage of pure solvent into the solution
powder
[17]
on the solution is more than the osmotic pressure, t

solvent will start flowing from the solution to the pu
he
solvent.
It is called
reverseItosmosis.
It isequiused in
t
re
through a semipermeable
membrane.
may be the
weight
or one mole of a solute, it is called a molar
desalination
of
sea
water
to
obtain
pure
wat
he
librium hydrostatic
pressure of the column set up as a
solution.
er.
result of osmosis
or minimum of excess pressure to be
The gram molecular weight of Nitric acid is HNO3 =
know that
all living
beings
made
applied in ready
the solution
to prevent
the
entryare
of the
sol-up of cell
1 + 14 + (3 X 16) = 15 + 48 = 63 grams
each
cell there
is a semipermeable
membrane arou
vent molecules
s. In into
the solution
through a semipermeOne molar solution (1M) of Nitric acid would thereable membrane.
nd
There are
huge (number
of)inuses
acids,
base
fore contain
63agrams
of the acid
oneof
litre
of solution.
salts
in
our
daily
life.
Sulphuric
acid
is
used
s and
i. Hypotonic Solution : A solution is called hypotonic
One
litre of such solution which contains 1 in
gm.t
he
if its osmotic pressure is lower than that of the soluequivalent
of solute is called a normal solution denoted
tion separating it by a semipermeable membrane. In
by N. A gram equivalent weight is the molecular weight
such a system, the flow of solvent due to osmosis,
divided by the no. of active hydrogen atoms or OH
will be from the hypotonic solution into the other
groups in a molecule of the substance. In the case of
solutionvery
across
the semipermeable
Sulphuric acid, the gram equivalent weight is 98 didelicate
balance in os- membrane.
vided by 2 or 49 grams. A normal solution (1N) of
ii. Hypertonic Solution: A solution is called hyperSulphuric acid would, therefore, contain 49 grams of
tonic if its osmotic pressure is higher than that of the
the acid in one litre of solution.
solution separating it by a semipermeable membrane. In such a system, the flow of solvent due to
Alkalies
osmosis will be from the solution across the semipermeable membrane into the hypertonic solution.
All bases are not soluble in water. Bases which are
iii. Isotonic Solution: Two solutions are called isotonic
soluble in water are called alkalies.
if they exert the same osmotic pressure. In such a
system, no osmosis occurs and hence there will not
Amphoteric
be a flow of solvent from either of the solutions
separated by a semipermeable membrane.
A compound which can act as both an acid and a
Plasmolysis: When a plant cell is placed in a hyperbase is called amphoteric. For instance, Aluminium hydroxide Al(OH)3 and Zinc hydroxide are amphoteric.
tonic solution, the fluid from the plant cell comes out
and the cell shrinks. This phenomenon is called plasmolysis and this is due to osmosis.
Salts
Reverse Osmosis: When external pressure applied
Salt is an ionic compound containing a positive ion
(cation) and a negative ion (anion). It is formed by the
neutralization reaction of an acid with a base. Some
common examples of salts are table salt or Sodium Chlo-
ride, Sodium Sulphate, Ammonium Chloride, etc.

Importance of Osmosis for Living Beings: We al-
Importance of Acids, Bases and Salts

the cellular materials. Cell draws water, oxygen and
nutritive substances from outside the liquid through the
semipermeable membrane. Wastes are taken out through
the semipermeable membrane into the surrounding Property
True solution
Colloidal solution
liquid. These processes Particle size Less than 1 nm.
Between 1 - 100 nm.
take place by osmosis. A
Appearance
motic; pressure must be

maintained in the case of
cells.
Molar and Normal

Solutions
The word molar and
normal indicates the concentration of solution. If
one litre of a solution contains one gram molecular
Clear and transparent

Settling
Suspension
More than 100 nm.
Translucent
Do not settle
Opaque
Do not settle under
gravity, but can be
under gravity
Settle on standing
made to settle under
There are various ways for determining the pH o

solution.
One of the simplest ways is using the indi
fa
Pass through
Not filterable
at into
all
tors.
When filter
an paper
indicator
comes
contact with a
caanon
cidicfilterable
or a basic
though solution, it changes colour at differ
n
points
on membrane
the pH Scale.
ent
parchment
centrifugation
Filterability
Filterable through filter

paper, parchment
membrane
Diffusible
Diffuse quickly
Tyndall effect No Tyndall effect
Someslowly
natural colouring
materials
Diffuse
Do not
diffuse from red cabba
raddish
ge, skin, beet root and rose petals are used
Shows Tyndall Effect
Very little or no Tyndall effect
indicators.
as
Academy
Chronicle IAS
Uses of salts are also well-known. Sodium
[18]
ridechlois used in food, to increase taste, purifyin

water
and in many plastics. Potash alum and Methyl oran
g
+
+
calomel
are medicinally
used.
Hypo
or Sodium
manufacture
dyestuffs,
drugs,
fertilizers
[H ] Phenolphthalein
is molar concentration of H in the solution. A
ge of explosives,
Thiosulphate
5H2O) is usedacid
in photogand also in
oil and sugar(Na
refining.
is pH below
7 indicates
an acid solution, one above 7
2S2O3 . Hydrochloric
Bromophenol
bl
used in the
indicates an alkaline or basic solution. pH value deuemanufacture of glue, gelatin, dextrose, and
(NaHCO3(PVC)
) is used
powder.
Magnesium
Chlon concentration of the hydrogen ion. The range
polyvinyl chloride
andas
it baking
is also used
in cleaning
pends
ride
(MgCl
.
6H
O)
Solution
is
also
used
in
cotton
ometals. Nitric acid is2used2 as a solvent in gold ornament ofinpH is 0 to 14. The PH of blood, milk and saliva is
- a solvent for many other metals. Nitric acid
industry, as
7.35, By
6.6 this
and method
6.3 respectively.
we can determine the amount
is also used for the manufacture of fertilizers and exploacid
or base in a solution or strength of a soluti
of
usedacid
for and
making
surgical bandag
sives such(CaSO
as dynamites,
picric
trinitrotoluene
4 2 H2O) is
on.
and in
plastering
Potassium
nitrate
es
(T.N.T). Acetic
acid
is used of
aswalls.
a solvent
for many
or- (KNO3) i
s
ganic compounds
andproduction
for the formation
of cellulose
used in the
of gunpowder.
Potassium ioacetate. Hydrofluoric
acid is
in making refrigerdide (KI) is used
in used
photography.
ants and certain plastics.
Bases also play a vital role in our day to day life.
Sodium hydroxide is used in the rayon, soap, paper and
petroleum industries. Calcium hydroxide is used to raise
the Ph of soils and to make insecticides.
Indicator
Colour in Strong Acid
Litmus
Red
Red
Colourless
Yellow
raphy as a fixing agent sodium bicarbonate
Colour in
Strong Base
Blue
Yellow
Red
Blue
Titration
dustry for increasing the strength of threads and used
as a cement for joining broken tooth. Plaster of paris
Buffer Solution: Buffer solution is a solution which
resists change in PH when an acid or alkali is added or
when the solution is diluted. There are two types of
buffer solutions : (a) acidic buffer; and (b) basic buffer.
a. Acidic Buffer : These are formed by mixing solupH System
tions of a weak acid and its salt such as CH3COOH and
It is a negative logarithmic scale for expressing the
CH3COONa.
acidity or alkalinity or basicity of a solution. It is
b. Basic Buffer: These are made up by mixing solu+1
expressed as pH = - log [H ]
tions of a weak base and its salt such as NH4OH and
NH4Cl.
Dispersed
Phase
Dispersion
Medium
Designation
Examples
1.
Gas
Liquid
Foam
Whipped cream, soap- suds.
2.
Gas
Solid
Solid foam
Pumice stone, bread, foam

rubber, styrene foam.
3.
Liquid
Gas
Clouds, mists, fogs.
4.
Liquid
Liquid
creams and other emul-
Aerosol
Emulsion
Milk,
sions
5.
Liquid
Solid
Gel
6.
Solid
Gas
Solid foam
7.
Solid
Liquid
Liquid sol
8.
Solid
Solid
Solid sol
Cheese, jellies, curd, boot

polish.
Smoke, volcanic dust, dust
storm.
White of an egg, mud.
Coloured glass, precious
stones, alloys, minerals,
pearls.
There is a great importance of buffers for us. For example, in the laboratory, buffers are used to prepare solutions of known stable PH. Natural
buffers occur in living organisms,
where the biochemical reactions are
very sensitive to change in pH. The
main natural buffers are H2CO3 ,HCO3and H2PO4-HPO42- Buffer solutions are
also used in medicine (e.g. in intravenous injections), in agriculture and in
dyeing, fermentation processes and
the food industry. Buffer solutions are
widely used in electroplating and also
in processed food and drinks to prevent excessive acidity.
[19]
Colloidal Solution
Colloidal solution is a homogeneous system of two
immiscible phases. It means that colloids are now regarded as systems in which there are two or more phases,
with one (is called the dispersed phase) distributed in the
other (the continuous phase).
There are various types of colloidal solutions. Sol is
called a colloidal solution. Sols are of two types:
i.
Lyophobic Sols: In these sols there is no affinity between the dispersed phase and the liquid.
ii.
Lyophilic Sols: These are more like true solutions in

which the solute molecules are large and have an
affinity.
2.
Cleansing of Clothes: Soaps and detergents are

used to clean dirty clothes. They remove dirt by
converting and precipitating them as colloidal
particles.
3.
Use of Gas Masks: Use of gas masks depends on

the absorption property of charcoal.
4.
In making of inks, dyes and paints etc. ink, dyes

and paints are colloidal substances.
5.
Purification of Water: When potash alum isadded

to muddy water, the colloidal muddy particles get
coagulated and they precipitate out and settle down
at the bottom making water clean and pure.
6.
Smoke Precipitation: Smoke is a colloidal solution of carbon in air. They are charged particles
and hence they can be precipitated on charged
metal plates.
7.
Sewage Disposal: Disposal of sewage is based on

the phenomenon of cataphoresis.
Applications of Colloidal Solution:

1. In Medicine: Oral medicines are taken in colloidal
form because they are more effective in this state. Colloidal gold, colloidal silver, colloidal calcium, colloidal manganese, etc. are used to increase the vitality of
our body. Colloidal sulphur is used as a germicide.
[20]
CHRONICLE
CHEMICAL
THERMODYNAMICS
IAS ACADEMY
Introduction
Thermodynamics is the study of the laws that govern the conversion of energy from one form to another,
the direction in which heat will flow and the availability of energy to do work. Chemical thermodynamics is
the branch of thermodynamics which deals with the
study of processes involving chemical energy only.
System: It is a part of the universe which is selected
for thermodynamic investigation.
Surroundings: Except for the system the rest of the
universe is the surrounding. A gas enclosed in a cylinder is the system, cylinder is the surrounding and cylinder + gas is the universe in thermodynamic sense.
On the basis of exchange of mass and energy, the
system may be:
i.
Isolated System: For thermodynamics, system is

defined as quantity of matter enclosed by a boundary surface from the rest of the universe i.e. the
surrounding. If the boundary of the system neither
allows heat flow nor allows matter flow, it is called
an isolated system.
ii. Open System: If boundary of the system allows
heat flow or matter flow through it, the system is
called an open system.
Example of Open System: Evaporation of water kept
in beaker is example of an open system. Water vapour
escapes into surroundings and heat required for evaporation flows from the surroundings to the beaker. Thus,
both matter and energy flow through the system.
Mathematically it can be expressed as :

q = dE + W
where
q = heat absorbed by the system
dE = change in internal energy
q
= S2done
S1 by
=revthe system
WD=Swork
Principles of Conservation of Energy

i.
Different forms of energy are interchangeable, but

when a quantity of one kind of energy disappears
an equivalent amount of energy appears.
ii. Energy cannot be annihilated nor can it be created
from nothing.
iii. Changes and transformations in energy may occur,
but the total energy of the universe is constant.
Isothermal Process
It is one in which temperature of the system remains
constant (
T = 0); change of state (freezing, melting,
evaporation, etc.) is an isothermal process.
Isobaric Process
It is one in which the pressure of the system remains
constant (
P = 0).
Isochoric Process
It is one in which the volume of the system remains
constant (
V = 0).
1
iii. Closed System: If the boundary
1 of the system alAdiabatic Process
lows only=heat flow but not matter flow it is called
closed system.
It is one in which the system does not exchange heat
Example of Isolated System: If water in a sealed
with the surroundings i.e. no heat enters or leaves the
bottle is insulated, heat transfer from the surrounding to
system (
q = 0).
the bottle is prevented. Thus water in a sealed bottle and
bottle covered with insulator is an example of an isoReversible Process
lated system. Water kept in thermos flask represents an
It is one in which direction may be reversed at any
isolated system.
stage. Such a process is carried out extremely slowly
First Law of Thermodynamics
in equilibrium conditions. The reversible process takes
infinite time to occur. For a process to be reversible,
This statement is equivalent to the law of conservafriction, resistance, etc. should be absent and secondly
tion of energy. Heat added to a system is equal to the
there should be thermodynamic equilibrium.
change in internal energy and work done by the system.
[21]
Irreversible Process
This process occurs suddenly or spontaneously with-
out the restriction of occurring in stages. There is no

thermodynamic equilibrium during the change. The system does not change to its initial stage by itself after the
change. The heat change and work in opposite directions are unequal. All natural processes are irreversible.
Heat Capacity at Constant Pressure (Cp)

The amount of heat required to raise the temperature
of one mole of a substance by one degree at constant
pressure is called molar heat capacity at constant pressure and is denoted by (Cp).
predict the direction of the change. This problem is

overcome by the second law of thermodynamics. This is
developed in terms of the entropy criterion:. According
to this law, it is impossible to transfer heat from cold to a
hot reservoir without doing some work. In other words,
it is impossible to convert all the heat taken from source
to work, without losing some of it to the colder reservoir.
Entropy
Entropy can be interpreted as a measure of a systems

disorder or randomness, the higher the entropy the
greater the disorder. The change in entropy during the
Heat Capacity at Constant Volume (Cv)
process is mathematically given by the ratio of heat
Heat required to raise the temperature of one mole of a absorbed by the system (q) in the reversible manner to
the temperature (T) at which it is absorbed.
substance by one degree at constant volume is called heat
capacity at constant volume and is denoted by (Cv).
Relation between Cp and Cv

Cp Cv = R , R = Gas constant
= l, l = Specific heat ratio.
Conversion of Heat into Work (Carnot

Engine)
Heat engine is a machine used for the conversion of
heat into work. Carnot gave an imaginary reversible
cycle which demonstrates the maximum conversion of
heat into work. Here, the system consists of one mole of
an ideal gas enclosed in a cylinder fitted with a frictionless piston. The heat engine takes heat from the reservoir at high temperature (called the source), converts
some heat into work and returns the remaining heat to
another reservoir at low temperature (called the sink).
Steam engine is one common example.
Efficiency of heat engine (h) =
Q2
Q2 Q 1 T2 T1
Q2
T2
T
T2
W = work done
Q2 = Heat absorbed from the source
Q1 = Heat returned to the sink respectively
T2 = Temperature of the source
T1 = Temperature of the sink
Second Law of Thermodynamics

The first law of thermodynamics does not help us to
Spontaneous Process
The physical, or chemical, process which occurs in a
particular set of conditions either of its own or after
proper initiation. All natural processes are spontaneous processes. Spontaneous processes cannot reverse
on their own. In a spontaneous process there is an
increase of entropy.
The conversion of solid into liquid and liquid into
gas (solidliquid gas) is accompanied with increased random distribution of molecules and also increased entropy. Similarly, spontaneous diffusion of
one gas into another involves increase of entropy and
the molecules of the two gases get mixed in a more
random manner.
The concept of entropy as a measure of randomness
or lack of order has a great physical significance. For
0
example, when ice melts to water at 0 C,
S is 5.26
-1
-1
cal.deg mole but when solid benzene melts,
S=
1
-1
8.27 cal. deg mole . This means that there is greater
order in water than in liquid benzene which may be due
to hydrogen bonded structure in water.
Entropy Change for Irreversible process

Entropy change for an irreversible process is positive hence entropy increases. Since all natural processes
are occuring spontaneously i.e. irreversibly, the entropy
of the universe is increasing continuously.
Now-a-days, different types of pollution are occurring
in our atmosphere. Hence, greater disorder is occuring
around our lives, thus entropy is continuously increasing.
The entropy of the universe tends towards a maximum.
Entropy Change in a Reversible Process : The total
entropy change of the system and the surrounding in
the reversible process is equal to zero.
[22]
Entropy Change during Freezing and Condensation: Freezing of a liquid and condensation of gases are
examples for which the entropy is decreased.
Importance of Thermodynamics
Since thermodynamics is concerned with energy
change therefore we assimilate a complete knowledge
of various forms of energy i.e. kinetic energy, potential
energy, electrical, energy, radiant energy, mass energy,
nuclear energy and chemical energy from its study.

These energies play a vital role in our lives.
The concepts of thermodynamics are applied in
studying the phenomena involving light, heat or electric and magnetic fields. It also helps in predicting the
maximum efficiency of various types of heat engines
and maximum work obtainable from a given fuel, i.e. in
the problems of combustion and power. For example,
refrigerator is based on this principle.
CHEMICAL REACTIONS
CHRONICLE
[23]
IAS ACADEMY
Chemical Reactions
Chemical reaction is a process in which one or more
substances (called reactants) react together to form one
or more new substances (called products) or a compound decomposes into two or more new compounds.
In the chemical reaction, bond breaking and bond formation take place. In other words, we can say that there
is a rearrangement of the energy distribution in the
chemical reaction.
Chemical reaction is represented by a chemical equation. A chemical equation includes the chemical formulae of a compound representing the symbols of ele-
ments. Or in other words, a chemical equation is a brief

method of expressing a chemical reaction with the help
of symbols and formulae. For example, sodium (Na) reacts with water (H2O) to form sodium hydroxide (NaOH)
and hydrogen gas (H2). This chemical reaction represented by a chemical equation would be written as :
2Na + 2H2O 2NaOH + H2
Balancing Equations
According to the law of mass conservation, in chemical reactions the amount and constituents of reactants
are accountable in the form of products. Consider the
reaction of nitric oxide (NO) with O2 producing NO2 as

given below :
NO + O2 NO2
This is evidently not a balanced equation as no. of O
atoms on the left hand side of the equation do not equal
those on the right hand side. Simple algebra is used to
balance without disturbing the molecular formula of
the reactants and products. Hence balanced equation
can be written as
2NO + O2 2 NO2
No. of Nitrogen (N) atoms
= 2(L.H.S. = R.H.S)
No. of oxygen (O) atoms
= 4 (L.H.S. = R.H.S.)
Where
L.H.S. = Left hand side
R.H.S. = Right hand side
There are large no. of varieties of chemical reactions.

Some of these may be explained as below:
1.
Combination Reactions: In this type, combining of

an element with a compound and another element
or a compound results to form a new compound.
4Na + O2 2Na2O
2.
Decomposition Reactions: It is just a reverse of the

combination reaction. In this type of reaction, a compound decomposes into simpler substances.
2NaHCO3 HeatNa2CO3 + CO2+ H2O
Explosions are violent decomposition reactions that

release large amounts of energy.
3. Displacement Reactions : It is also known as substitution reaction. In this type of reaction replacement takes place in which a substrate of reactant
replaces another substrate of reactant to form a product. For example,
2Na + 2H2O 2NaOH + H2
In the above reaction, sodium (Na) displaces hydrogen of water molecule and combines with hydroxyl
(OH ) group to form sodium hydroxide.
(NaOH)
Na2CO3 + Ca(OH)2 CaCO3 + 2NaOH
Sodium Carbonate displaces OH- from Ca(OH)2 and
combines to form NaOH and Ca displaces CO3 from
Na2CO3 then combines

to form CaCO3
4.
Isomerisation Reaction : In this type of reaction, a

new compound is formed after rearrangement of
atoms.
NH4CNO H2NCONH2
Ammoniumcyanate (Urea)
Chemical Formula
Chemical formula represents exact figure of the constituents in a compound. It denotes how many atoms
are combined in a molecule. For example, H2O is the
chemical formula for the water molecule, in which two
atoms of hydrogen and one atom of oxygen are present.
Sometimes elements exist as molecules that are combi[24]
nations of like atoms. Thus hydrogen or oxygen gas is

diatomic as H2 or O 2. Some can be polyatomic, for instance, S8or P4.
Oxidation and Reduction

Oxidation is a chemical process which involves :
i.
combination with oxygen or other electronegative

elements (electron attractor elements).
ii. removal of hydrogen or any other electropositive
element (electron donor elements) from a compound.
iii. increase in valency of metal atom in a compound.
iv. increase in the proportion of an electronegative element or group and decrease in the proportion of
electropositive element in a compound.
v. increase in oxidation no. (the no. of charges) of an
element.
vi. loss of electrons.
Electronegative elements S, Cl, Br, I, N, O, etc.
FeCl3 Fe+++ +
3Cl
- 2 Fe++ + 2ClFeCl
Electropositive
elements Fe, Cu, Na, K, etc.
Examples of oxidation :
i.
2Cu + O2 2CuO
ii.
2Mg + O2 2MgO
iii. Mg + Cl2 MgCl2
iv. 4HCl + MnO2 2H2O + MnCl2 + Cl2
v. 2SO2 + O2 2SO3
vi. 2Mg + O2 2MgO
In the above reactions (i) and (ii) Cu, Mg are combined with oxygen. Hence they have undergone oxidation and oxygen is the oxidizing agent. In (iii) reaction
Mg is combined with electronegative element Cl2. Hence
Mg has undergone oxidation. In (vi) reaction H has
been removed from HCl to obtain Cl2 hence HCl has
undergone oxidation and MnO2 is the oxidizing agent.
In (v) reaction oxidation number of S is +4 in SO2 which
has increased to +6 in SO3 . Hence SO2 has undergone
oxidation and O2 is the oxidizing agent. In (vi) reaction
++
each Mg atom has lost 2 electrons to form Mg

++
during the process of oxidation of Mg to Mg O .
ion
Oxidizing Agents: An oxidizing agent oxidizes other

substances. It is a substance which can supply oxygen
or any other electronegative element and can remove
hydrogen or an electropositive element from a compound. Modern definition of an oxidizing agent is a
substance which has the capacity to gain electrons.
i.
F + e F
F is an oxidizing agent
-
ii.
O + 2e O
O is an oxidizing agent
Following types of elements and compounds are
oxidizing agents :
1.
Most of the non-metals except C, H and P.
2.
All ic-salts of metals FeCl3, Fe2(SO4)3, CuSO4 5H2O,

CuCl2, HgCl2, HgSO4
3.
Oxides and higher oxides of metals CuO, Fe2O3,

NaO2
4.
KMnO4, HClO, HClO2, HClO3, HClO4, HNO3,

K2Cr2O7
Reduction: It is a chemical process which involves:

i.
combination of an element with hydrogen or with

any other electropositive element.
ii.
removal of oxygen or any other electronegative element from a compound.
iii. decrease in valency of a metal atom in a compound.

iv. increase in the proportion of an electropositive element and decrease in the proportion of an electronegative element or group in a compound.
v.
decrease in oxidation number of an element.
vi. gain of electrons by a substance.

Examples:
i.
S + 2Na Na2S
S has undergone reduction
ii.
CuO + C Cu + CO
CuO has undergone reduction to Cu
iii.
2Fe+3Cl-13 + S+4O-22 + 2H+12O-2 2Fe+2Cl-12 +

H+12S+6O-24 + 2H+1Cl-1
Oxidation number (no. of charges) of Fe has decreased from +3 in FeCl3to +2 in FeCl2. Hence FeCl3 has
undergone reduction.
ii.
2FeCl3 + H2S FeCl2 + 2HCl + S

H2O
H2O
Fe
+++
+ e Fe
++
Each Fe+++ ion of FeCl3 gains an electron and is reduced to Fe++ which is present in FeCl2
Reduction involves gain of electrons.
Reducing Agents: A substance which has the capacity to supply hydrogen or any other electropositive
element and remove oxygen or any other electro-negative element from a compound is called a reducing agent.
Modern definition of a reducing agent is that it has
the capacity to loose electrons.
[25]
Na Na + e
Na is a reducing agent.
Following substances are reducing agents:
All metals, carbon, hydrogen, phosphorus, FeCl2,
FeSO4, SnCl2, Hg2Cl2, NaH, LiAlH4, CaH2, NH3, H2S,
HBr, HI, HCl, H2S, H2Se and H2Te, Aldehydes, formic
acid, oxalic acid, Na oxalate, sodium formate,
sulphides, bisulphide, sulphite and nitrite are reducing
agents.
Redox Reaction: There is no such reaction known in
which only oxidation or only reduction occurs. In all
oxidation-reduction reactions, which are called redoxreactions if one substance is oxidized, there is another
substance which is reduced. In other words, it can be
said that in redox reactions oxidising agent is reduced
and reducing agent is oxidized.
To find out which substance is oxidized and which
is reduced, oxidation numbers of all atoms on the left
hand side and right hand side of a redox-reaction are
calculated. A reactant whose oxidation number increases as a result of the reaction gets oxidized and a
reactant whose oxidation number decreases as a result
of the reaction gets reduced.
Examples : S+4O-22 + 2+1H2S-2 2+1H2O-2 + 3S0

The oxidation number of all atoms are written at the
top of the reactants and the products in the equation. It
can be seen that oxidation number of S decreases from
+4 in SO2 to zero in elemental sulphur. SO2 is reduced to
S.
SO2 is an oxidizing agent. Oxidation no. of S in H2S
is 2 which increases to zero in elemental S. Hence, H2S
is oxidized and hence it is a reducing agent.
Importance of Oxidation-Reduction: Oxidation-reduction is closely related with our lives. Various reactions taking place in our body are redox reactions. For
examples, digestion, respiration, etc. are related with
redox reactions. Following are important examples:
THERMO CHEMISTRY
i.
Combustion of Fuels: When a fuel burns, it gains

oxygen. It is oxidized. Natural gas is a good example. Natural gas is methane, CH4.
CH4(g) + 2O2(g) CO2(g) + 2H2O(g)
ii.
Respiration: Respiration is the release of energy

from food in living cells. Glucose from food reacts
with oxygen. The carbon in glucose is oxidized.
Glucose + oxygen Carbon dioxide + water

C6H12O6(aq) + 6O2(g) 6CO2(g) + 6H2O (l)
(aq aqueous),
g = gas
l = liquid
So we get energy from our food by a redox reaction.
CHRONICLE
iii. Corrosion of Metals: Many metals corrode or rust in

air. Iron is a good example. The iron combines with
oxygen. It is oxidized.
Iron + oxygen Iron oxide (rust)
4Fe + 3O2(g) 2Fe3+2O2-3(S)
The iron loses electrons, so it is oxidized. The oxygen
gains electrons, so it is reduced. Rusting is a redox
reaction.
iv. Formation of Power Cells of Quartz Watches: By
using the redox reactions, scientists can create tiny
power cells for quartz watches, control the rusting
of iron and explain the role of oxygen in keeping
them alive.
v.
Extraction of Metals from Ores: Iron is extracted

from iron ore in a blast furnace. The iron combines
with hot carbon monoxide gas.
Iron ore + Carbon monoxideIron + Carbon dioxide H2(g) + Cl2(g) HCl(g) + 22KCal
Fe2O3(S) + 3CO(g) 2Fe(S) + 3CO2(g)
The iron ore loses oxygen, so it is reduced. The

carbon monoxide gains oxygen, hence it is oxidized.
Extracting of metal from ore is a redox reaction.
vi. Reaction of Photosynthesis:
Light energy absorbed
6CO2 + 12H2O Light Chlorophyllabsorbed
C6H12O6 + 6H2O
+ 6O2
Oxygen is set free after water molecules are broken
out. The hydrogen from the water molecules combines
with Carbon dioxide to form glucose. Hence, oxidation
and reduction takes place.
vii. Electrolysis : At anode oxidation takes place and at
cathode reduction takes place. Electrolysis plays an
important role By
inenergy
the metal industry. Besides production of many metals, it is also used in the production of heavy water (D2O).
1 mole
Energy
[26]
IAS ACADEMY
It is well known that the system naturally tends

towards greater stability. This stability results from low-
ering the energy because a lower energy state is more

stable than a high energy state. This drives a chemical
reaction in which the products would have lower en-
ergy than the reactants, after going through either evolution or absorption of heat. All these things are dealt
with by thermochemistry.
Exothermic Reaction
Chemical reaction in which heat is evolved is called
an exothermic reaction and is expressed as : A + B C
+ D + Q where Q is heat evolved, A and B = reactants
and C and D = products.
Endothermic Reaction
Chemical reaction in which heat is absorbed is called
an endothermic reaction and is expressed as A + B + Q
C + D or A + B C + D Q where Q is heat absorbed,
A and B = reactants and C and D = products.
pressure and V is its volume. For an exothermic reaction

H is taken to be negative and for an endothermic
reaction
H is taken to be positive. Enthalpy is also
known as heat content.
Heat of Formation
Heat absorbed or released in the formation of one mole
of a substance from its elements is called heat of formation
and
Hf is called enthalpy change of formation.
1
22
Heat of formation Qf = 22KCal

Hf = -22KCal
Heat of Combustion
Bond Dissociation Energy and Bond

Energy
Heat released in complete combustion of one gramatom of an element or one gram-mole of a compound is
called heat of combustion and
H is called enthalpy
Bond dissociation energy is the energy required to break
change of combustion.
a particular type of bond in one mole of gaseous molecules.
C(s) + O2(g) CO2(g) + 94 KCal
The energy released in the formation of one mole of
Heat of combustion of C = Q
bonds is known as bond energy.
= 94 KCal
For example, the bond dissociation energy of hydrogen molecules is 435.6 KJ per mole. This means, 435.6 KJ
H combustion of C = -94 KCal
-1
mol of energy is required to break the H H bonds in one
This is the same reaction that we observe when we
mole of hydrogen molecules. This may be expressed as
burn charcoal in stoves and ovens in the kitchen.
H2
Bond
2H(g)
435 6 KJmol-1
Breaking
of hydrogen absorbed
molecule.
or 435.6 KJ/mol of heat energy is given out during

the formation of one mole of hydrogen gas molecules.
Enthalpy
It is denoted by H. A thermodynamic property of a
system is defined by H = U + PV, where H is the enthalpy. U is the internal energy of the system, P is its
Heat of Fusion
Heat absorbed in the conversion of one mole of a
solid to liquid is called heat of fusion and DH is called
enthalpy change of fusion.
H2O(s) H2O(l) 1.44 KCal
Ice water
Q = -1.44 KCal
Hfusion = + 1.44 KCal
Photochemical Reaction
It is a chemical reaction caused by light or ultraviolet
radiation. The incident photons are absorbed by reactant molecules to give excited molecules or free radicals
[27]
which undergo further reaction. Photosynthesis in presence of sunlight, expands dissociation of I2 molecule
into two iodine atoms upon
absorption of light. Photog.
raphy in which photographic film is coated with silver
bromide which is sensitive to light and is chemically
affected by light and hence the photographic image is
obtained by developing the film in the dark are examples of photochemical reactions. In a photochemical
reaction light is required.
Electrochemistry
The study of chemical properties and reactions involving ions in solution, including electrolysis and electric cells is called electrochemistry.
Chemiluminiscent Reaction: Light is evolved.
Electrolytic Reaction: Electricity is required.
Electrochemical Reaction: Electricity is produced.
Respiration: It is the process of release of energy; it is
an exothermic reaction.
C6H12O6 + 6O2 6CO2 + 6H2O

Glucose Oxygen Carbon Water
dioxide
Metallic Corrosion
Many metals react with air or the environment to
form undesirable compounds on their surfaces. This
process is called corrosion. Mostly metals, except like
least active metals platinum, gold undergo corrosion.
Iron corrosion is called rusting. In contact with air, iron
forms red or orange materials. This material is the hydrated form of ferric oxide (Fe2O3 xH2O).
The reaction may be written as :
8Fe + 6O2 + 6H2O
Iron
Oxygen
(fromair)
Water
2Fe2O3+ 4F3(OH)3
Iron
Oxide
Iron
Hydroxide
Fe2O3 + xH2O Fe2O3xH2O

Rust
Iron rusting is not possible in dry air and vacuum. It
is prevented by coating the iron with Zinc. Zinc forms
zinc compounds with humid air and forms a protective

cover over the iron thus protecting it from rusting. This
coated iron is known as galvanized iron or G.I.
Chemical Reactions
The chemical reactions are primarily classified as :
i. irreversible; and
ii. reversible reactions.
i.
Irreversible Reactions : These are chemical reactions in which the products do not react back to give
the reactants.
For example, 2KClO32KCl + 3O2
AgNO3 + HCl AgCl + HNO3

ii. Reversible Reactions: These are chemical reactions
in which the products also react to give back the
reactants. Such reactions can be made to occur in
either direction by suitable variations in the conditions. If the reaction is carried out in a closed vessel,
it is found that the reaction does not go to completion.
For example,
2SO2(g) + O2(g)
2SO3(g)
3Fe(S) + 4H2O(g)
Fe3O4(S)3 + 4H2(g)
Equilibrium State
When a reversible reaction is carried out in a closed
vessel, then it is observed that a constancy in properties
Haemoglobin
Oxygen
HbO2(s)
like intensity
of colour,
pressure,
concentration, etc., is
achieved under a given set of conditions. Such a state is
referred to as an equilibrium state. A chemical equilibrium is a state at which the composition of the chemical
system becomes constant under a given set of conditions.
It must be noted that at equilibrium, the chemical reaction
does not stop but instead both the forward as well as the
backward reactions take place at the same rate.
Chemical Equilibrium
or,
Kf [A] [B] = kb [C] [D]
C
A
D
B
Kb
Ke
When two reactants are mixed, they react to form the

product as:
A+B C+ D
A and B are reactants and C and D are products. At
time 0, the concentration of the products is 0 and as time
progresses, concentration of the reactants decreases and
the concentration of the products increases. As the concentration of the products increases, they may also react
according to the reaction.
C+D A+B
Thus there is competition between
A+B C+ D
C+D A+B
And backward C + D A + B reactions
At a particular instant (time), the concentration of
the reactants no more decreases and there is no increase
in the concentration of the products i.e. at a particular
instant the concentration of both the reactants and the
products are constant. This state is called equilibrium
state and is represented by
A+B
C+ D
(
sign of equilibrium)
The state of equilibrium continues indefinitely until
it is disturbed by external factors like variation of concentration, temperature, pressure, etc. A catalyst does
not affect the final state of the equilibrium.
[28]
Law of Mass Action

Rate of a reaction is proportional to the product of
the active mass of reactants. Active mass of a substance
is approximately equal to its molar concentration.
This is the law of mass action. For the reaction aA +
bB cC + dD, the rate of reaction is given as : rate =
a
b
K[A] [B]
where K is called rate constant, [A] is molar concentration of A and [B] is molar concentration of B.
Equilibrium Constant : In the equilibrium state the
rate of forward reaction is equal to the rate of backward

reaction and the reaction is given as :
aA + bB
cC + dD
In this aA + bB cC + dD is forward reaction and
cC + dD aA + bB is backward reaction
rf = Rate for the forward reaction = Kf[A]a[B]b
rl = Rate for the backward reaction = Kb[C]c[D]d
at equilibrium rf= rb
a
Applications of Le Chateliers Principle

in Everyday Life
Kf
[A], [B], [C] and [D] is the molar concentration of A, B,

C, and D respectively.
Le Chatelier's Principle
If any kind of stress (such as change in concentration, temperature or pressure) is applied on equilibrium, it shifts in a direction that tends to undo the effect
of the stress. For example:
i.
Transport of Oxygen by Haemoglobin in Blood :

The haemoglobin of RBCs of our blood combines
with oxygen to form oxyhaemoglobin as below:
Hb(s)
+ O2(g)
Oxyhaemoglobin
Cl
CH3 Cl OH
When oxyhaemoglobin
reaches
the tissues, the
CH3OH into
partial pressure of oxygen becomes low so equilibrium
shifts towards the left, giving up oxygen. When the
i. Decrease in the concentration of any of the products or blood returns to the lungs, the partial pressure of oxy1
increase in
concentration
of any
of the reactants
(a)the
(CH
O becomes higher and the equilibrium favours the
3)2 CHCl + OH-
Slow(CH3)2 CH+ + Cl- +gen
pushes the
equilibrium
in
the
forward
direction.
Hformation of more oxyhaemoglobin.
(CH3)2 CH+
Cl- + OHan
CHOH
- 1
ii. In an endothermic
reaction,
increase
temperaSlow(CH3)2in
+ + C ii. Removal of Carbon Dioxide by Blood : Blood gives up
l
ture favours
- the forward reaction, while a decrease
CO2 fromthetissuesaccordingtotheequilibrium
in temperature
favours
(CH3)2CHOH
+ Clthe backward reaction. In an
CO2(g)+H2O(l)
H2CO3(aq)
H+(aq)+HCO3(aq)
exothermic reaction, low temperature favours the
forward reaction and a high temperature favours
Due to the high partial pressure of CO2, CO2 is disthe backward reaction.
solved
in the blood(CH
in 3)the
tissues
2CH
+ Cl and due to low
(CH3)2CHCl
iii. Increase of pressure pushes the equilibrium towards
partial pressure of CO2in the lungs, CO2 is released
the side in which number of gaseous moles decreases.
from the blood.
iv. Effect of Inert Gas : For a reaction at constant vol- iii. Sweet
(CH3)2CHSubstances
+ OH
(CH3)2CHOH
Cause
Tooth Decay : Tooth
ume i.e., when the no. of moles of the reactants are
enamel is made up of an insoluble substance called
equal to the no. of moles of the products the addition
hydroxyapatite Ca5(PO4)3OH. Its dissolution is
of inert gas has no effect. When an inert gas is added
called dimineralization and its formation as
to the equilibrium system at constant pressure, the
remineralization. It exists in equilibrium as :
equilibrium will shift in a direction in which there
Ca5(PO4)3OH(S)
is an increase in the no. of moles of gases.
v. A catalyst increases the rate of forward and

backward reactions to the same extent.
Demineralization
Remineralization
5Ca+2(aq) + 3PO43-(aq) + OH-(aq)

Remineralization
When we eat sweets, sugar present in the sweets gets
+
fermented to give H ions which combine with the OH
ions shifting the equilibrium in the forward reaction.
Therefore, Ca5(PO4)3OH dissolves causing tooth decay.
Chemical Kinetics
Rate of Reaction : It is the speed with which the
reactants are converted into products. In other words,
rate of reaction is the rate of disappearance of a reactant
or the rate of appearance of a product.
This can be expressed as :
A B
Rate = K[A]
A + B Products
Rate = K[A][B]
K is called rate constant. As rate constant is specific
for a reaction, it is also called specific rate constant.
[29]
A reaction may occur in more than one step, the

slowest step determining the rate of the reaction and
hence is known as the rate determining step. The formation of (CH3)2CHOH from (CH3)2CHCl by the reaction
with OH can be expressed as :
K
-1
Rate of reaction in this case
= K1[(CH3)2CHCl][OH-]
Order of Reaction: The sum of the exponents in the
rate expression of a reaction is called order of the reaction.
A B
Rate = K[A]
2. Thus the reaction is a second order bimolecular

reaction. Let us consider the reaction of (CH3)2CHCl
and NaOH
K2
ii.
i.
Fast
Is slow and is the rate determining step. In the

transition state of this step, two moles (one each of
CH3Cl and OH-) are involved. Hence molecularity
of the reaction is 2. The order of the reaction is also
Order of Reaction
Order = 1
A + B Products
Rate = K[A][B]
Order = 1 + 1 = 2
2A Products
2
Rate = K[A]
Order = 2
Slow
+
Fast
Molecularity of Reaction
(i)
Sum of the exponents in rate

(i) No. of moles of reactants involved
expression is called order of
in the transition state of rate deterreaction. If rate expression is K
mining step is called molecularity
[A]2, order or reaction is 2 and
of the reaction.
Haber process
if rate expression is K [A], order
of reaction is l.
(ii) It may be a whole no. or fraction
(ii) It is always a whole no.
(iii) It is determined by actual
(iii) It is determined by reaction
experimental data.
mechanism.
Order of reaction is determined

by experimental measurements and
it can be a whole number or even a
fraction.
Molecularity of Reaction: Before
the discussion about molecularity we must study activated state or transition state. Before the reaction occurs,
reactants collide and form the activated or the transition
state
govern the rate of a reaction.

i. Concentration of reactants :
A B
Rate = K[A]
A + B AB*
If concentration of the reactant increases, rate of
A and B are reactants, AB* is the transition state or the reaction increases. When concentration of reactant inactivated state. Product is formed from the activated state. creases, number of molecules increases. If there is an
increase in the number of molecules, no. of collisions
AB* Products
and consequently effective number of collisions inThus the reaction can be given as A + B AB*
creases. With increase in the effective number of colliProducts
sions, rate of reaction increases.
The energy of activated or transition state is higher
ii. Temperature: Rate of reaction increases with inthan both the of reactants and products. The number of
crease in temperature. With increase in temperature
moles of reactants involved in the transition state or
kinetic energy of the reactant molecules increases.
activated state or the rate determining step of a reaction
With increase in kinetic energy velocity of the molis called molecularity of reaction. Let us consider the
ecules increases. Due to increase in velocity of the
reaction of CH3Cl (methyl chloride) and NaOH (Sodium
molecule, number of collision and hence effective
hydroxide):
number of collision increase. Due to increase in
K1
effective number of collision, rate of reaction increases.
i.
Slow

iii. Chemical Nature of Reactants and Rate of Reaction : Due to difference in chemical nature of reactant activation energy of the reaction is different
and consequently rate is different. Activation energy is the minimum energy required for a chemical
reaction to take place. The reaction of FeSO4 with
KMNO4 in acidic medium is fast, but that of oxalic
acid with KMNO4 in acidic medium is slow. The
difference in rate is due to difference in the chemical
nature of FeSO4and H2C2O4 (oxalic acid).
iv. Physical State of Reactants : This effect is pronounced for heterogeneous reactions. In homoge CHare
Cl
CHreactants
3Cl
3+ in
neous reaction,
adifferent phase.
A reaction between FeSO4 solution + KMNO4 solution is homogeneous, but a reaction between CaCO3
(solid) and dilute HCL(l) is heterogeneous. The reaction of one gram solid piece of CaCO3 with dilute HCL is
slower than that of 1 gram powder of CaCO3. This is due
to increased surface area in the powdered form. Thus
greater the surface area of the reactant, greater is the rate
of reaction.
[30]
v. Catalyst and its Effect on the Rate of Reaction:

Substances which change the rate of chemical reactions by their presence are called catalysts and the
phenomenon is called catalysis. The catalyst takes
part in the reaction and is regenerated at the end of
the reaction. Thus the catalyst is not consumed in
the chemical reaction and is recovered chemically
unchanged at the end of the reaction.
There are four types of catalysts: (a) positive catalyst;
(b) negative catalyst; (c) auto-catalyst; and (d) induced
catalyst.
Positive catalyst increases the rate of reaction and
negative catalyst decreases the rate of reaction. Thus in
the decomposition of KClO3 to O2, MNO2 acts as a posi-
Manufacturing
1.
Catalysts Used
To convert vegetable edible oil

into vanaspati
In manufacturing of
ammonia gas by
2.
3.
Nickel
Fe
iron powder
In the formation of Nitric

acid by Ostwalds process
Production of Sulphuric acid
by the Contact process
Lead Chamber process of
production of sulphuric acid
Process of Ether formation
from alcohol
Deacon process for the
production of chlorine gas
Platinum wire-gauge
ELECTRO CHEMISTRY
4.
5..
6.
7.
platinum powder
oride of nitrogen
Hot alumina
cupric chloride
tive catalyst. The airy oxidation of chloroform is prevented in the presence of a few drops of alcohol. This is
an example of negative catalysis. Autocatalyst is the
product of the reaction. No catalyst is added from outside. The reaction of KMNO4 and Oxalic acid in acidic
+2
medium is slow, but as soon as MN is produced in the
+2
reaction, rate of reaction increases. Thus MN acts as a
catalyst for the reaction. Na2SO3 is oxidized by air, but
Na2ASO3 (arsenite) is not. However, when Na2ASO3 is
mixed, both are oxidized. The oxidation of Na2SO3 induces oxidation of Na3ASO4 and the catalyst is an induced catalyst.
Catalysts change the rate of reaction by changing the
activation energy and the mechanism of the reaction.
Positive catalysts decrease the activation energy and so
the reaction is faster. Negative catalysts increase the
activation energy and so the reaction is slower.
CHRONICLE
[31]
IAS ACADEMY
It is the branch that deals with the study of the

following two types of reactions :
i.
Reactions in which chemical energy is converted to

electrical- energy (electrochemical cell or Galvanic
cell or voltaic cell); and
ii.
Reactions in which chemical energy is required to

bring about a chemical reaction (electrolytic cell).
Electrolysis
The production of a chemical reaction by passing an
electric current through an electrolyte. In electrolysis,
positive ions migrate to the
cathode (negative electrode)
and negative ions to the anode. (positive electrode)
Hence the passage of electricity; through an electrolyte is
called electrolysis.
The reactions occurring
depend on electron transfer
at the electrodes and are

therefore redox reactions. At
the anode, negative ions in
solution may lose electrons
to form neutral species. Alternatively, atoms of the electrode can lose electrons and
go into solution as positive
ions. In either case, the reaction is an oxidation. At the
cathode, positive ions in solution can gain electrons to
form neutral species. Thus cathode reactions are reductions.
Electrolyte and Non-electrolyte

In liquid state or in the form of solutions in some
solvent (mostly water) substances allows electricity to
pass through are called electrolytes and those substances which do not allow the passage of electricity are
called as non-electrolytes. Water, Sodium Chloride and
Molten Salts are electrolytes. Sugar, wax and naphthalene etc. are non-electrolytes.
Cations and Anions: During electrolysis, positively

charged ions and negatively charged ions are formed.
Positively charged ions are called cations and negatively charged ions are called anions.
Electrolytic Cell
A cell in which electrolysis occurs i.e. one is which
current is passed through the electrolyte from an external source.
In an electrolytic cell, usually two metallic or graphite rods or plates are used for allowing the electric current to pass through the electrolyte these are called
electrodes. The one electrode which allow the electric
current to enter into the electrolyte is called anode and
the other electrode which allow the current to leave the
electrolyte is called cathode. During electrolysis the electrodes may or may not take part in the chemical change.
Electrolytic Cell Reactions

In electrolysis reactions the nature of reaction is oxidation-reduction. Oxidation takes place at anode and
reduction takes place at cathode.
Example : Electrolysis of NaCl in molten state
+
NaCl
Na + Cl
+
at cathode Na + e
Na
at anode Cl
Cl2 + eSodium is deposited at the cathode and Cl2 is liberated at the anode.
Characteristics of Electrolysis
i.
ii.
iii.
iv.
v.
The process of electrolysis starts when power is

supplied and stops when power is cut.
The primary products are discharged ions and these
are liberated only at electrodes.
Electropositive elements like hydrogen and metals
are liberated at the cathode.
Electronegative elements like non-metals are liberated at the anode.
The weight of a substance produced on an electrode
during electrolysis is proportional to the quantity of
electricity passed through the electrolyte.
Uses of Electrolysis
i.
Electroplating: A method
of plating one metal with
+2
Zn + Cu
Zn + Cu
another at the electrodes (the process of depositing
ore metal on another by electrolysis).
[32]
The articles to be plated are made the cathode of an

electrolytic cell and a rod or bar of the plating metal
is made the anode. Electroplating is used for covering a metal with a decorative, more expensive or
corrosion resistant layer of another metal.
ii. Electrorefining: Metals can be refined (purified) by
the electrolytic method. Anode is made up of an
impure metal and Cathode is made up of a pure
metal in the solution of a suitable salt of the metal to
be purified. Passage of electricity results in the dissolving of the anode and deposition of metal at the
cathode. The
impurities fall
down in the
form of anode
mud. Copper is
industrially
purified by this
method.
iii.
Electrometallurgy: Metal is
extracted from its ore by electrolysis this process is
called electrometallurgy. For example sodium and
Aluminium are extracted from its ore by this process.
iv. Electroprinting: Type-page impression is made on wax
plate or plaster of paris. By sprinkling graphite on
wax, the plate is made conductor and thus made cathode in a copper plating bath. On the passage of electricity copper deposits on the wax plate. It is removed
and strengthened by filling its back with type-metal.
The mould is obtained which is an exact copy of the
printers page and is used in large scale printing.
v. Industrial Applications: There are a large no. of
compounds formed electrolytically such as caustic
soda, washing soda, chlorine and so on are obtained by electrolysis of Sodium Chloride.
Strong and Weak Electrolytes
An electrolyte which dissociates to a greater extent is

called a strong electrolyte. Whereas an electrolyte which
is feebly ionized is a weak electrolyte. Strong acids like
HCL (Hydrochloric acid), strong bases like Sodium Hydroxide (NaOH) and almost all salts like NaCl are strong
electrolytes and weak acids such as acetic acid
(CH3COOH) and weak bases like (NH4OH) ammonium
Hydroxide are weak electrolytes. A strong electrolyte in
dilute solution is supposed to be completely ionised.
Electrochemical Cell
An electro chemical cell can be created by placing
metallic electrodes into an electrolyte where a chemical
reaction either uses or generates an electric current. This
is also called Galvanic or Voltaic cell.

Electrochemical cell
Cathode
Anode
i. Reduction ocurs Oxidation ocurs
at cathode.
at anode.
2+
2+
Cu + 2e
Cu
Zn Zn +2e
ii is positive.
is negative.
Electrons flow in the external circuit from anode to
cathode while conventional current flows from cathode
to anode.
In an electrochemical cell, there are two electrodes
dipped into solutions of their salts, as for example,
many metallic compounds generate electricity in many
displacement reactions. Zn electrode is dipped into solution ZnSo4 and Cu electrode into solution of CuSo4.
Two solutions are separated by a partition A. When two

electrodes are joined, electrical energy is produced. Zn
+2
forms Zn and 2e electrons moves from Zn to Cu elecWeight
trode.or
E
E
E Since Equivalent Weight is no. of
The following reactions occur :
+2
Zn
Zn
+2
Cu
+ 2e
+ 2e (Oxidation)
Cu (Reduction)
+2
Electricity is produced at Zn electrode and moves to

the Cu electrode.
At Zn electrode where oxidation occurs is the Anode. At Cu electrode where reduction occurs is the Cathode. At Zn electrode negatively charged electrons are
produced and then move from it to the Cu electrode.
Hence Zn electron i.e. anode is negatively charged and
as electrode moves to Cu electrode i.e. Cathode, it is
positively charged.
Dry Cell
This is also called a flash light battery. Dry cell was
invented by G. Le Clanche in 1868. A common dry cell has
a solution of ammonium chloride and a carbon rod (surrounded by a paste of manganese oxide) at the center and
the whole cell is covered by zinc. During the chemical
reaction, zinc produces zinc ions and electrons.
[33]
These electrons are then used by reactions involving

manganese dioxide. This reaction may be represented
as below :
i.
2MnO2 + 2NH4Cl + 2eMn2O3 + 2NH3 + H2O + 2Cl

This is Cathode reaction
ii.
2MnO2 + 2NH4Cl + Zn
[Zn(NH3)2Cl2.+ Mn2O3 +H2O
The voltage of the dry cell is 1.5V. Silver cells and the
lithium cells are the examples of a dry cell.
Storage Cells
Storage cells are recharged but other electrochemical
cells are not recharged. Lead storage cells are used in
cars and other vehicles. These are the most common
examples.
Car battery has concentrated H2SO4 (density = 1.15
(in which Pb (lead) rod (negative electrode) and pb rod
coated with PbO2 (positive electrode) are dipped. When
two electrodes are joined, chemical reaction occurs and

electricity is produced.
There are other examples of storage cells like nickeliron and nickel cadmium cells.
Faradays Law of Electrolysis

Faraday in 1833 established a certain relationship
between the quantity of electricity passed and the amount
of substance electrolysed, which is called Faradays
law of electrolysis.
RADIOACTIVITY
First Law: The amount of a substance obtained in

electrolysis is proportional to the quantity of electrolysis passed through its electrolyte.
W Q
W it (Q Q = it)
W = amount of a substance deposited at cathode by
using Q quantity of electricity
W = Z it
CHRONICLE
Z = Electrochemical equivalent of the substance

i = current in amperes
t = time in seconds
Second law: When the same quantity of electricity is
passed through different electrolytes the amount of substances liberated is proportional to the chemical equivalents of different substances. Chemical equivalent means
gm equivalent weight or 1gm eq. If W1 gm W2gm, W3
gm of different substances are obtained when Q coulombs of charge0.693
is passed through their respective elect 1 orT =
trolytes
and if E1, E2, E3 are the chemical equivalents
respectively
from the second law of electrolysis: W E
t1
or
T
period l = decay
W1
W2= half-life
W3
constant
123
gram-equivalent. Therefore, the same quantity of electricity will deposit the equal no. of gram equivalents of
all substances in electrolysis.
It can also be inferred from this that quantity of
electricity required for deposition of one gram equivalent of any substance must be the same and this quantity is called one faraday. It is denoted by F and is
numerically equal to 96500 coulombs, approx.
[34]
2.0141 2
0.0141
IAS ACADEMY
0.00705 10 70
The phenomenon of radioactivity was discovered

accidentally by the French scientist, Henri Becquerel in
1896. The term radioactivity was first used by Marie
Curie.
Radioactivity is essentially a nuclear phenomenon
and a drastic process because the element changes in
kind. It is spontaneous and an irreversible self-disintegrating activity because the element breaks itself up for
good. Certain substances like Uranium, Thorium, Radium, etc. spontaneously emit radiation like a, b, g rays
15 days and so on.

Mathematically it can be shown as
2
Characteristics of , , Radiations
Radiation
Charge
+2
Mass
Mass Defect
Nucleus
90Thby
U238 is formed
2 the combination of protons
and neutrons.
The mass of P = 1.00783 and the mass of
34
(n/p) ratio in the
n = 1.00866 amu. The mass of 1H2 formed from one
PenetratingLess than less than greater
Proton than
Th234 91Pa23
power
and
but more and
proton and
one neutron is 2.01410 amu.
4
than
H
+ 0n1 1H2
1 1
Velocity
1/10th of
less than
light velocity
8
light velocity light velocity (310 m/s)
Ionizing
power
more than more than less than

and
and less and
than
and are converted into new elements. The property of

emission of radiations from a substance is known as
radioactivity. Spontaneous emission of radiations from
a substance is called natural radioactivity. The substance which emits radiation is called radioactive substance. The process in which an element is converted
into a new radioactive isotope (i.e. unstable isotope) by
artificial means (i.e. by bombarding the element with
fast moving particles like proton, deutron, helium, etc. )
is called artificial or induced radioactivity.
Half-life Period
Half-life period of a radioactive substance is the time
required to disintegrate one-half of the original amount
of the substance. In other words, the half-life period of a
radioactive substance is the time in which half of the
radioactive substance will disintegrate. For example,
any substance which has a half- life period of 5 days
that means this substance disintegrates 50% in 5 days.
In other words after reduction of 50% in five days, the
radioactive substance is 25% after 10 days 12.5% after
1.00783 + 1.00866 2.01410

= 2.01649
Thus there is loss in mass when a nucleide is formed
from the nucleus.
m = 2.01649 2.01410
= .00239 amu
This loss in mass is called mass defect. The loss in
mass is released as energy according to the relation
2
E = mc
1 atomic mass unit = 931.5 Mev
(Mev = million electron volt)
Thus in the formation of 1H2from a proton and neutron 0.03 x 931.5 Mev of energy is released.
U235 +Packing
0n192U
Ba
Fraction
141
In the formation of heavy nucleide from the nucleus,

there is decrease in mass due to loss of energy. The
decrease in mass has been expressed by packing fraction defined as:3
4
f = 10
Isotopic atomic weight mass no.

Mass Number
The isotopic weight of 1H2 is 2.0141 and mass no. is 2

and so f for 1H2 is
22
10
10
[35]
Nuclear Stability
Some nucleides or elements are stable and some are
unstable. It is determined by
Neutron
nucleus. If n/p = 1 the nucleide is stable, if n/p > 1 and n/

p < 1, the nucleide is unstable and shows radioactivity.
Nuclear Binding Energy

Energy released when neutrons and protons combine
to form the nucleus is called Nuclear binding energy. The
energy required to separate the neutrons and protons
from the nucleus is also called nuclear binding energy.
Radioactive Decay (Disintegration)

The main radiations in radioactivity are (i) a (ii) b.
Emission of a -particles produces an element which has
a mass of four units less and charge two units less than
that of the parent element.
AX Y-2BX-4 + 2He4
A = Radioactive element
X = Atomic number
y
Y = Atomic mass
place towards the right in the periodic table. This is

group displacement law. It can be shown as below:
92
VI B IV B
90
IV B V B
Nuclear Fission
The nuclear reaction in which one heavier nucleus
is split up into two lighter nuclei of releasing a, b and g
radiation along with the release of a huge amount of
92U235
90Th231 + 2He4
energy is called nuclear fission or atomic fission.

In 1939, German Chemists Otto-Hahn and his associates Meitner and Strassman bombarded92U235 with slow
235
moving neutrons and observed that U nucleus, after
236
capturing a neutron, gave U nucleus which was radioactive called (compound nucleus) and hence had broken
up to form ultimately a pair of stable products (called
fission products) consisting of 56Ba141 and 36Kr92 and liberated three neutrons (called secondary neutrons) in addition to a huge amount of energy called fission energy.
236
92 56
Compound
Nucleus
+ 3 Kr
+ 30n1 + Energy
92
U = Uranium
Chain Reaction
Th = Thorium
He = Helium
Emission of -particle produces an element having
same mass but charge one unit greater than the parent
element.
Y+1BX + -1 0
YAX
Tl206
81
Pb206 +
82
-1
The process of radioactive disintegration continues

till a non-radioactive element is produced. In case of
92U238, and particles are emitted and the final product is 82Pb206
U238
92
82Pb208
Thus the mass difference is 238 206 = 32 units and

this corresponds to emission of 8 particles (mass of
= 0). The charge difference is 92 82 = 10. Emission of
8 particles decreases the charge by 16 units and emission of each b increases the charge by one unit. Thus 16
10=6 particles are emitted.
Group Displacement Law

When an a - particle is emitted, the new element is
displaced 2 places left in the periodic table, and when a
b -particle is emitted, the new element is displaced one
Moderators
,
The explosive effect of the nuclear fission chain reaction can be reduced by using some substances called
moderators which slow down the fast moving neutrons. The secondary neutrons (which are formed after
the first nuclear fission reaction) pass through the moderator and lose some of their kinetic energy and their
speed is reduced. Thus the use of a moderator controls
the explosive effect of the nuclear fission chain reaction.
When graphite is used as a moderator, the reactor is
called Atomic Pile and when D2O (heavy water) is used
it is called Swimming Pool reactor.
Nuclear Fusion
Such a nuclear reaction in which two lighter nuclei are
combined or fused together to form a heavier (and hence
stabler) nucleus is called nuclear fusion. Nuclear fusion
occurs at reasonable rates only at very high temperatures. It
is because of this that the nuclear fusion reactions are also
called thermonuclear reactions i.e. temperature depen-
During a nuclear fission a large number of chain

235
reactions take place. If we initiate fission of one U
nucleus by one neutron obtained either by cosmic rays or
by some radioactive source. In this fission process each
235
U nucleus suffering fission will liberate three neutrons.
These three neutrons will in turn cause the fission of
235
three other U nuclei and will liberate three more neu235
trons in the fission of each U nucleus. Thus nine neutrons will be obtained and so on. Consequently, a self
propagating or self sustaining chain reaction (also called
auto catalytic reaction) starts in which the number of
neutrons keeps on multiplying rapidly (in geometrical
progression). This chain reaction is also accompanied by
the liberation of a huge amount of energy which is called
fission energy. This energy can either be very fast resulting in a violent explosion (as in an atom bomb) or it can be
controlled and maintained at a steady rate (as in chain
reacting nuclear piles or nuclear reactors).
Nuclear Reactor
A nuclear reactor is a mechanism by which nuclear
fission is produced in the form of a controlled selfsustaining chain reaction. In other words, it is a controlled chain-reacting system supplying nuclear energy.
[36]
dent reactions. Nuclear fusion adequately explains the:I.
energy of the sun and other stars which is called

Stellar energy.
II. thebasicprincipleofthehydrogenbomb(Fusionbomb).
i.
Stellar energy :
41H1 2He4 + 21e0 +

Energy
Proton Helium Positron
Above nuclear reaction indicates that four H-atoms
(or protons) are fused together to produce one helium
nucleus and two positrons. On the sun the fusion of four
H-nuclei into helium nucleus does not take place through
a single step but takes place through deuterium 1H2.
ii.
Hydrogen Bomb: Nuclear fusion reaction depends

on high temperature. This is provided by the fission
235
of U nucleus which is an explosive chain reaction.
This forms the principle of the hydrogen bomb. In the
preparation of hydrogen bomb a suitable quantity of
all the isotopes of hydrogen ( 1H1; 1H2 and 1H3 ) is
combined with an atomic bomb. The function of
atomic bomb is to provide the high temperature which
is necessary for bringing about the nuclear fusion

reactions in hydrogen bomb. In the hydrogen bomb
the following nuclear fusion reactions take place:
1H1 + 1H2 2He3 + Energy H2 + 1H2
CHEMICAL BONDING
6CO2 + 6H2O C6H12O6 + 6O2

Here a very important question arises whether the oxygen evolved in this process comes from CO2 or from H2Oor
from both. This question has been answered by the use of
radioactive O18 isotope H2O is made to react with Carbon
dioxide containing O18 (i.e. CO218) and it is found that the
oxygen evolved does not contain O18 i.e. O18 presentinCO218
goes to sugar and water while that of water is evolved as free
oxygen.Thusoxygenevolvedintheprocessofphotosynthesis comes from H2O and not from carbon dioxide and consequently, the reaction shown above could be shown as :
6CO218 + 12H2O C6H12O618 + 6H2O18 + 6O2
CHRONICLE
ii.
2He3 + 0n1 + Energy

1H3 + 1H2 2He4 + 0n1 + Energy
Uses of Radioisotopes
l
l
l
Uses of tracers in the diagnosis of diseases : Radio

iodine (1-131) has been used to locate and detect the
presence of tumour.
24
iii. Circulation of blood : Radioactive sodium (Na )
has been used to study cases of restricted circulation of blood.
iv. Pumping action of heart has been studied by using
radioactive sodium or radio iodine.
131
v. Radioactive iodine (I ) is given to a patient with
thyroid disorders.
vi. Tracer iron has been used in studying the disorders
associated with pregnancy.
60
vii. Co emits high energy g (gamma) rays which are
used for testing deeply seated cancer growth.
viii.The wear of piston rings and of gears in engines
and its prevention by means of suitable lubricants
have been studied by radioactivity.
ix. Radioactive uptake of phosphorus by plants from
soil and fertilizer is determined by adding radio
phosphorus to the fertilizer.
x. Irradiation of maize with radioactive Cobalt produces
15% increase in the quantity of green parts over those
plants growing in the same field, but not irradiated.
2. Uses of radioisotopes in the treatment of diseases
(Radiotherapy) :
131
l
Radioactive iodine I
has been used for the
treatment of certain thyroid complaints. Actually
131
I is utilized in the treatment of hyperthyroidism
and cancer of the thyroid.
l
Radioactive phosphorus in the form of phosphate is
widely used in the treatment of certain blood disorders.
60
l
Radio Cobalt (Co ) is used in the treatment of cancer.
60
Co has been called Poor Mans radium.
Radioisotope of phosphorus is being used for the
treatment of leukaemia.
30
Radio phosphorus (P ) is found good for skin diseases.
238
U
isotope is used for the determination of the
earth by rock dating method.
1. Uses of radioisotopes as radioactive tracers:

14
i. Uses of tracers in studying reaction mecha-by using the radio carbon (C ) dating method.
nisms like photosynthesis as :
[37]
The age of animal and plant fossil is is

determined
l
IAS ACADEMY
Except noble gases atoms of all other elements have

a tendency to combine either with each other or with the
atoms of other elements to form clusters or aggregates of

atoms with a definite composition. Thus, a chemical
bond is defined as the attractive force that holds two or

more atoms together in a molecule or an ion. Atoms
combine chemically for the following reasons:
1. When two atoms come closer to combine together to
form a bond between them, the attractive and repulsive
forces begin to operate them. Attractive force is due to
attraction between one atomic nucleus and electrons of
another atom. Repulsive force is due to repulsion between electrons of different atoms. If attractive force is
dominant over repulsive force then bond formation
occurs and if the repulsive force is dominant over the
attractive force there is no bond formation.
PERIODIC TABLE
Molecule
BaCl2
Co2
Bcl3
CH4
NH3
H2o
PF5
Xef2
SF6
[Cu(NH3)2]2+
Shape
Linear shape
Linear shape
Trigonal planar shape
Tetrahedral shape
Trigonal pyramidal shape
V shaped (angular or bent
Trigonal bipyramidal
Linear shape
Octahedral shape
Square planar
2. Chemical bond is formed for getting stability. This

stability occurs by acquiring a stable outer-shell of
eight electrons.
In the formation of a chemical bond atoms interact
with each other by losing, gaining or sharing of
electrons so as to acquire stable octet electrons.
3. The process of chemical bonding between the atoms
decreases the energy of the combining atoms and
gives rise to the formation of a system which has
lower energy and hence greater stability.
Generally metals have the tendency to donate electrons and non metals have tendency to gain electrons.
So in this stage an electrovalent bond forms. For example, in the formation of NaCl (Sodium Chloride), Na
(Sodium) donates an electron to chlorine to get an octet.
+
Na Na + e (2,8,1 2,8)
-
Cl + e Cl (2,8,7 2,8,8)
Donors are Cations and Gainers are Anions.
ii.
CHRONICLE
Covalent Bond : The chemical bond between two

atoms in which the electrons (in pairs) are shared
by both the participating atoms is called Covalent
bond. The covalent bond formed by the sharing of
one, two or three electron pairs between the participating atoms is called single, double and triple covalent bond respectively. Single bond is represented
by a single dash (-) in which one pair of electrons is
involved as in H H (H2) and H Cl (HCl). Double
Covalent bond is represented by double dash (=) in
which 2 pairs of electrons are involved as in O = O
(O2). Triple Covalent bond is represented by Triple
dash ( ) in which 3 pairs of electrons are involved
as in N N (N2). H2, HCl, NH3, CH4, CCl4, BF3, CO2
are examples of covalent compounds.
iii. Co-ordinate Bond:Acovalentbondwhichisformedby
the mutual sharing of two electrons both of which are
provided entirely by one of the linked atoms (or ions) is
called a co-ordinate bond. For example in O3 molecule,
one lone pair of one oxygen atom of O2 is donated to the
other oxygen atom to form O3 molecule as in
O = O O2
denotes co-ordinate bond.
Shapes of Molecules
In ionic compounds, the bond exists due to electrostatic attraction between oppositely charged species
There are mainly two types of chemical bonds as below which are non-directional. So the structure is determined almost entirely by the relative sizes of the ions.
:
Covalent bonds are however directional and the shape
i. Electrovalent Bond : It is also known as ionic or
of a covalently bonded molecule is decided by the direcpolar bond. The chemical bond formed between two
tion of the covalent bonds.
atoms by the transfer of one or more valence elecMany physical and chemical properties are decided by
trons from one atom to the other is called an ionic
the shape of molecules. Specific properties of H2O are
bond. This bond is also called Electrovalent bond.
decided by its angular shape. Similarly, the biologically
important DNA molecule which has special
physiochemical behaviour, is due to its double spiral shape.
Types of Chemical Bonds
[38]
IAS ACADEMY
It would be difficult to study individually the chemistry of all the elements and their numerous compounds.
Classification of elements into various sets or groups
make it easy to study the characters of all these elements. In this regard, numerous scientists worked and
gave ideas and subsequenty Mendeleev's periodic table
came forth.
In 1869, J. Lothar Meyer, a German, and Dmitri I.
Mendeleev, a Russian, independently constructed tables
of elements. In these tables, the elements were arranged
in the order of their increasing atomic weights. Thus

Mendeleev's law may be stated as, The properties of
elements are a periodic function of their atomic weights,
i.e. if the elements are arranged in the increasing order
of their atomic weights the properties of the elements (
i.e. similar elements are repeated after definite regular
intervals) or periods. Hence Mendeleev's table gave a
strong base to further work on this field. His prediction
about coming up of new elements like gallium, scandium and germanium has been proved.
Due to some anomalous findings in Mendeleevs

periodic table such as position of hydrogen, position of
lanthanides and actinides, etc the modern periodic table
was put forward by Mosley to overcome the defects of
Mendeleevs periodic table. Mosley in 1911, proposed
that the physical and chemical properties of an element
depend on the no. of electrons and their arrangement in
different orbitals of the atom, and so the classification of
the elements should be based on the number of these
electrons (i.e. atomic number) and their arrangement in
different orbitals. This idea led by Mosley made most of
the defects of Mendeleevs periodic table disappear.
According to the Modern periodic table ''the properties
of elements are a periodic function of their atomic numbers, i.e. if the elements are arranged in the increasing
order of their atomic numbers, the properties of the
elements (i.e. similar elements) are repeated after definite regular intervals or periods.
columns of group VIII.
Modern periodic table includes groups or periods.

The vertical columns are called groups. The total number of groups are 18 which are I A, II A, III A, IV A, V A,
VII A, Zero, I B, II B, III B, IV B, V B, VI B, VII B and three
The horizontal rows shown in the periodic table are

called periods or simply rows. There are seven periods
in the table.
General Characteristics of Groups

1.
Valency Electrons : On moving down a given group

the number of valency electrons does not change,
i.e. remains the same.
2.
Valency : The valencies of all the elements of the

same group are the same.
3.
Physical and Chemical Properties: All the elements

of a given group possess very similar physical and
chemical properties.
4.
Size of Atoms : Size of atoms increases on descending a group.
5.
Metallic Character : The metallic character of the

elements increases in moving from top to bottom in
a group.
General Characteristics of Periods

1.
Valency Electrons : Number of valency electrons

increases from 1 to 8 when we proceed from left to
right in a period.
2.
Valency : The valency of the elements with respect

to hydrogen in each short period increases from 1 to
4 and then falls to one while the same with respect
to oxygen increases from 1 to 7.
3.
Size of Atoms : Size of atoms decreases from left to

right in a period.
4.
Metallic Character : On moving from left to right in

a period the metallic character of the elements decreases.
5.
No. of Shells : In going from left to right in a period

the number of electron shells remains the same and
the number of a period corresponds to the number
of the shells found in the elements of that period.
12
Atomic Masses of Elements referred to C = 12.0000

[39]
NON-METALS
CHRONICLE
[40]
IAS ACADEMY
Generally, non-metals have a tendency to gain electrons to complete their octets and thus they form negative ions. Hence they are called electronegative elements.
For example, Nitrogen, Oxygen, Phosphorus, Bromine,
etc. are non-metals. Non-metallic elements are placed
on the right-hand side of the periodic table. Out of approximately 22 non-metallic elements, 11 are gases (oxygen, nitrogen and chlorine), one is liquid like bromine
and rest are solids (e.g. Carbon, Sulphur, Phosphorus
and Iodine).
Hydrogen
There is great importance of hydrogen in our life. It is
found in water, acids, carbohydrates (sugars, starch,
cellulose), plants, animals, proteins, vitamins, wood,
coal tar, oil, natural gas, etc. The atomic number and
atomic weight is one and 1.00797 respectively. It is the
first chemical element in the periodic system. Hydrogen
is manufactured by Lanes process (By the action of
steam on hot iron) and Bosch Process (from water gas).
Under normal conditions hydrogen is a colourless,
odourless, tasteless gas composed of diatomic molecules,
H2. It is the lightest substance known. At normal tem-
peratures, hydrogen is comparatively unreactive but at

higher temperature, it becomes highly reactive.
Uses of Hydrogen
1. In Chemical Industries: Hydrogen has a great importance in the formation of ammonia by Habers
process, formation of hydrochloric acid and methanol, vanaspati ghee from vegetable oils such as coconut oil, cotton seed oil, etc. by the action of hydrogen in the presence of finely divided Nickel under 5
atmospheric pressure and at 150 - 200C. Petrol
substituents by the action of hydrogen, under pressure on finely powdered coat suspended in oil
(Bergins process) or by the hydrogenation of CO
(Fischer Tropsch process).
2. In Engineering : Hydrogen is used as a valuable
fuel, because its heat of combustion is very high.
Heat of combustion is the amount of heat produced
when one gram of a substance is completely burnt.
It is a constituent of many fuel gases like coal gas,
water gas which contain 50% and 45% by volume of
hydrogen respectively. When hydrogen is burnt with

pure oxygen in oxyhydrogen blow torch, it gives a very
hot flame (2800C) which is employed for welding purposes and for melting platinum and quartz. Hydrogen
is also used as a fuel in rockets and guided missiles.
For Filling Air-Ships and Balloons: Due to its lowest density, hydrogen is used as a gas for inflating
meteorological balloons and in air-ships. As it is
combustible and has a tendency to leak, a noninflammable mixture of 85% He and 15% H2 is used
for the purpose.
4. In Metallurgy : Hydrogen is used in producing
pure metals from their oxides.It is also used in producing a reducing atmosphere within the furnaces
in the heat treatment of metals.
react with normal hydrogen. It was once thought

that the hydrogen was present as atoms in the atmosphere but this is not the case.
2.
Adsorbed or Occluded Hydrogen: Some metals like

Pd, Pt, Au, Fe, Ni etc. can absorb under, certain
conditions relatively large volumes of hydrogen.
The gas thus adsorbed by metals is given off when
the metal is heated especially under reduced pressure. The phenomenon was termed occlusion or
adsorption. The gas so adsorbed by the metal is
termed occluded or adsorbed hydrogen. Occluded
hydrogen is more active and a stronger reducing
agent than ordinary hydrogen.
3.
Active Hydrogen :When ordinary hydrogen at room

temperature is subjected to the action of silent electric discharge at an electrical pressure of more than
30,000 volts, it changes into an active variety of
hydrogen. This is called active hydrogen.
4.
Atomic Hydrogen :When molecular hydrogen in contact with a tungsten or platinum wire was heated by
an electric current at low pressure, it dissociates into
atomic hydrogen. This is an endothermic reaction.
3.
Various Forms of Hydrogen

1.
Nascent Hydrogen : It is a reactive form of hydrogen generated in situ in the reaction mixture (e.g. by
the action of acid on zinc). Nascent hydrogen can
reduce elements and compounds that do not readily
[41]
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
Properties
Metals
Non-Metals
PHYSICAL
Metallic Lustre
Yes
No lusture with the exception of iodine which

possesses metallic lustre.
Not Malleable
Not Ductile
No Conductivity
Non-Conductors (Exception graphite)
Low
Low
Generally low
Cannot be welded
They are solids, and
gases, Bromine (Br2) is a liquid.
Malleability
Malleable
Ductility
Ductile
Thermal conductivity
Good Conductivity
Electrical properties
Good Conductors
Tenacity and Toughness High
Melting and Boiling points High
Density
Generally high
Welding
Can be welded
State of existence at
Generally solid only
room temperature
Mercury (Hg) and
11. Metallic sound
1.
2.
3.
CHEMICAL
Oxides
Hydroxides
Action of HCl or H2So4
4.
Electrolysis
5.
6.
Electropositive nature
Mechanism of reaction
7.
Oxidising or Reducing
Francium (Fr) are liquids.

They produce a
Do not produce any metallic
metallic sound
sound when struck.
when struck.
Basic
Basic
H2 gas is liberated
Acidic
Acidic
Do not liberate H2
They are liberated

at cathode.
They form positive ions
They react by losing
electrons.
Metals are reducing
agents.
They are liberated at anode.

They form negative ions.
They react by sharing,
gaining or losing electrons.
Non- metals are generally good oxidising agents.
The atomic hydrogen so produced was found to be

more reactive than ordinary, nascent and adsorbed
hydrogen. Atomic hydrogen is used for the production of atomic hydrogen welding torch which is
employed for welding and cutting metals.
5. Ortho and Para Hydrogen Molecules : We already
know that a hydrogen molecule is composed of two
hydrogen atoms. Each of these two H-atoms of H2
molecule has one proton in its nucleus and one
electron revolving round the nucleus. Thus H2 molecule which is formed from two H-atoms has two
protons and two electrons in it. The two electrons in
these two H-atoms always spin in opposite directions.
H H H H
or H - H or H2
However, the two protons present in the nucleus of
both the H atoms may spin either in the same direction

(i.e. parallel direction) or in opposite direction(i.e. anti-
parallel direction).
i.
Ortho Hydrogen Molecule : Hydrogen molecule in

which both the protons in the nuclei of both H
atoms spin in the same direction (i.e. parallel direction) is an ortho hydrogen molecule.
ii.
Para Hydrogen Molecule : Hydrogen molecule in

which both the protons in the nuclei of both H
atoms spin in opposite direction (i.e. anti-parallel
direction) is called a para hydrogen molecule.
The two electrons in ortho as well as in para hydrogen
molecule always spin in the opposite direction, otherwise
it will not be possible to get stable hydrogen molecule.
Water
It is an essential part of our life. It is the most abundant compound in the atmosphere. In the second half of
the eighteenth century, Cavendish proposed the composition of water i.e. two volumes of hydrogen and one
volume of oxygen (H2O).
[42]
of the high electronegativity of oxygen, water molecule

is highly polar, the oxygen atom having partial negative
charge and the hydrogen atoms having partial positive
charge.
In liquid water, water molecules are held together by
hydrogen bonding. The density of ice is less than that of
liquid water. When ice melts some of the hydrogen
bonds are broken and the water molecules become more
closely packed. As a result, there is an increase in density above the melting point 0C. As the temperature
increases, the density increases gradually reaching a
maximum at 4C. Thereafter, increasing thermal motion
of the molecules becomes more prominent and density
decreases with temperature as found for most liquids.
Because of its lower density compared with liquid water, ice floats on water. This floating block of ice prevents
or delays the freezing of the underlying water enabling
aquatic life to survive during the winter months.
Physical Properties : Hydrogen bonding plays a vital role in deciding the physical properties of water,
such as its abnormally high freezing point, boiling point,
heat
andD heat of H
fusion
H orofHvaporization
H or
or D(compared to the
hydrides of other elements of the same group of the
periodic table e.g. H2S, H2Se) which arise from the presence of hydrogen bonds. Water has a higher specific
heat, thermal conductivity and surface tension than
most other liquids. These properties are responsible for
water to play a vital role in the biosphere. The high heat
of vaporization and the high heat capacity of water are
responsible for the moderating influence of water on the
climate and body temperature of living organisms. Water is also an excellent solvent for transporting ions and
Water is nearly about 70-80% of the total constituent

of a living body. Of the total estimated global water
9
3
supply of ~1.4 x 10 Km , the oceans and inland saline
water bodies hold 97.3% and fresh water amounts to
only 2.7%. Unfortunately most of the fresh water is not
readily accessible being locked up in frozen lakes, glaciers or under the ground. The fraction of water available for human use is only 0.003% of the total global
water supply.
Naturally, water exists in three phases solid, liquid and gas. Water is known as a universal solvent
because it dissolves almost every substance to some
extent except non-polar substances. Due to these properties it is widely used in agriculture, industry and
chemical laboratories. Rain water is the purest form of
natural water.
A molecule of water consists of two hydrogen atoms
joined to an oxygen atom by covalent bonds. There are
two lone pairs of electrons on the oxygen atom. Because
Some Properties of Three Isotopes of Hydrogen

Property
Ordinary hydrogen
Heavy
or protium
hydrogen or
Tritium
deuterium
Symbol
Atomic number
Mass number (i.e. atomic mass
or atomic weight)
Atomicity
Molecular formula
1
1
2
1
2
1
3
1
1
1.0081
1
2.0147
1
3.0170
2
H2
2
D2
2
T2
3
1
No. of protons in the nucleus

No. of neutrons in the nucleus
No. of electrons
Relative abundance of their diatomic
molecules in ordinary hydrogen
Stability
1
Nil
1
99.984%
1
1
1
.0156%
1
2
1
10.15%
Stable
Stable
Radioactive and
hence unstable
Electronic configuration
molecules needed by plants and animals for their metabolism. Even covalent organic compounds such as
alcohols and carbohydrates have a high solubility in
water because of their ability to form hydrogen bonds
with water molecules.
Chemical Properties : Water displays a versatile
range of chemical behaviour. It acts as an acid, a base,
an oxidant, a reductant and as a ligand to metal ions.
Water molecules exhibit a high thermal stability as
would be anticipated from its high negative heat of
formation. Appreciable decomposition of water to the
respective elements requires high temperatures. The extent of dissociation at 1500K is < 0.02%.
Pure water has a small but measurable electrical
conductivity because of the following equilibrium:
H2O(l) + H2O(l)
H3O+(aq) + OH-(aq)
(Hydronium
(Hydroxylion)
Thus water can act both as an acid and a base and is
said to be Amphoteric. Water acts as a base towards
acids stronger than itself and as an acid in the presence
of a base stronger than itself, as shown below :
H2O(l) + HCl
H3O+(aq) + Cl-(aq)
base
acid
H2O(l) + NH3(aq)
acid base
acid base
NH4+(aq) + OH-(aq) acid base

The autoprotolysis of water is thus of great importance in acid-base chemistry. Certain compounds without the presence of water, do not react. For example,
Structure of water molecule
chemical reactions in plant or animal tissues take place

only in the presence of water. Iron combines with the
oxygen of the air to form iron oxide, or rust, only because
water is present in the air in the form of water vapour.
Isotopes of Hydrogen
Naturally, hydrogen has three isotopes as below :
ii.
[43]
i.
Hydrogen or Protium (1H1)

Heavy Hydrogen or Deuterium (1H2)
iii. Tritium (1H3)

A bond to a protium atom can be added as much as
18 times faster than that to a deuterium atom. Thus
protium reacts with Cl2, 13.4 times faster than deute-
rium does. The addition of H2 to ethylenic compounds

takes place two times faster than with deuterium at the
same temperature. Protium is more rapidly adsorbed on
the surface than deuterium.
Uses of Deuterium and Tritium

Deuterium is used in the preparation of hydrogen
bomb. Heavy water (D2O) is used as a moderator in
nuclear reactors to slow down the speed of fast moving
neutrons. Dueterium and its compounds are used as a
tracer in the study of the mechanisms of various chemical and metabolic reactions taking place in the body, e.g.
with the help of deuterium it has been shown that butyric acid (a component of butter) is never stored in the
body and is an immediate source of energy which at
once gets consumed while Stearic acid (a component of
lard) is not used up at once and hence is useful in
building up reverse stock in the body.
Tritium has the possibility of use as an artificial
radioactive tracer in chemistry, medicine and biology.
Hard Water and Soft Water

In water, some elements like calcium, magnesium
and iron are present at an appreciable level, that why
water does not form lather with soaps easily. The effectiveness of water for washing purposes is then reduced.
This type of water is called hard water. Soaps are sodium salts of fatty acids (RCOOH) where R is usually a
higher alkyl chain. Calcium or magnesium ions present
in hard water form insoluble salts with soap and prevent the formation of lather.
M2+ + 2RCOO (RCOO)2M
M = Mg or Ca
A large amount of soap will be used up, for the
complete removal of calcium or magnesium salts and
thus lather will be formed. Hard water poses problems
when used in industrial boilers for producing steam,
because it causes the formation of scales or deposits on
the wall of boilers. The process of removal of calcium or
magnesium salts is known as water softening.
There are two types of hardness Temporary and
Permanent.
Temporary Hardness : Temporary hardness is
caused by the presence of Bicarbonate of Calcium and
Magnesium. This type of hardness is removed by boilS1 and addition of
ing,S1addition of limeS1(Clark method)
NaOH (Sodium hydroxide) or NH4OH (ammonium hydroxide).
Permanent Hardness: Permanent hardness is
caused by chlorides and sulphates of Calcium and Magnesium. This type of hardness is removed by the following methods:
[44]
i.
By the addition of calculated amounts of washing

soda (Na2CO3.10H2O)
ii.
Ion-Exchange method : Permanent hardness may

be replaced by sodium ions and is known as the
ion-exchange process. Naturally occurring zeolites
or similar synthetic complex sodium aluminium
silicates are used for this purpose. When hard wa2+
2+
ter is passed through such a zeolite, the Ca or Mg
ions are exchanged by equivalent amounts of sodium ions in the zeolite.
Besides these methods, Calgon Process (calgon is
sodium hexameta-phosphate) and Filtration is also used
to remove the permanent hardness.
ORGANIC CHEMISTRY
Oxygen
Oxygen is a colourless, tasteless and odourless gas.
3
Its solubility in one litre of water at 293 K is ~30 cm gas
at STP. This small amount of dissolved oxygen is sufficient to sustain marine and aquatic life and for the
destruction of organic wastes in water bodies.
Oxygen is the most abundant element on the earth.
Oxygen constitutes nearly 50% by weight of the crust of
the earth, bodies of water and the atmosphere. In the
earths crust, oxygen is found in combined form as
silicates, carbonates and oxides of metals. Water consists of 88.8% oxygen by weight. Oxygen gas makes up
about 23.2% by weight of the atmosphere. Almost all of
the oxygen gas in the atmosphere is believed to be the
result of photosynthesis by green plants.
Oxygen has an atomic number of 8, atomic weight
15.9994 and electron configuration as 2, 6. Oxygen gas
(O2) molecule has two of 16 electrons which are unpaired. So, O2 is paramagnetic.
Uses of Oxygen : Oxygen molecule is used in making steel and in metal fabrication as an aid to combustion. It is essential for life support systems (e.g. in hospitals, in underwater diving) Liquid oxygen is used as an
oxidizer in rockets for space exploration and in the
launching of satellites.
Air
The earth is surrounded by an ocean of the atmosphere. Atmosphere is divided into three layers such as
lithosphere, stratosphere and ionosphere. Air is a mixture of different gases as is explained below:
Nitrogen (N2)
78.1%
Oxygen (O2)
20.29%
Carbon dioxide (CO2)
0.03%
Water vapour
0.4%
Inert gases
0.95%
Dust particles, sulphur oxides, nitrogen oxides, etc.
variable
Air is a very important factor in our life. Due to its
pressure, the various objects (living as well as nonliving retain their existence on the earths surface. We
take oxygen from air which is responsible for respiration and combustion. Nitrogen is used in diluting the
oxygen to moderate the process of burning and respiration. Nitrogen also takes part in the plant growth and
protein formation in animals. Photosynthesis requires
carbon dioxide which is available from the air. The
importance of water vapour is revealed from its controlling the evaporation of water from the bodies of plants
and animals and thus is essential for our health and
body comfort. Dust particles provide a medium for the
condensation of water vapour to cause rain.
CHRONICLE
Atomic number of oxygen is 8, atomic weight is

15.994 and electronic configuration is 2, 6.
Sulphur and its Compounds

Sulphur has atomic number 16, atomic weight 32.1
and a molecular formula of S8. Sulphur is found in both
combined and free state form. It is a constituent of many
important metallic minerals like cinnabar (HgS), Zinc
blende (ZnS), Copper pyrites (CuFeS2), etc.
There are several allotropic forms of Sulphur. Sulphur is used for vulcanizing rubber, in the manufacture
of dyes, explosives e.g. gun powder and various chemicals for killing moulds and pests and in medicine as
blood purifiers. Flower of sulphur is a yellow powder
obtained by subliming the vapour. It is used as a plant
fungicide.
Sulphuric acid (H2SO4). Molecular weight = 98
H = Hydrogen
S = Sulphur
O = Oxygen
Sulphuric acid is known as oil of vitriol. It is a very
important chemical. The industrial progress of a country is measured in terms of the consumption of sulphuric
acid. It is manufactured by the lead Chamber process
and the Contact process. In Contact process, platinum
asbestos or vanadium pentoxide is used as a catalyst
and in contact process, NO2 acts like a catalyst.
Sulphuric acid is a colourless, viscous and oily liquid, highly soluble in water. Concentrated H2SO4 acts
as a dibasic acid. It is a powerful oxidizing agent as well
as dehydrating agent.
[45]
IAS ACADEMY
Study of Carbon compounds is known as organic

chemistry. But some exceptions like Carbon monoxide,
Carbonates (Na2CO3), Thiocynates, e.g. NaSCN, Carbon
dioxide (CO2), Bircarbonates, e.g. NaHCO3, Cyanates
e.g. KOCN, Carbon dislphides CS2, Cyanides, e.g. KCN,
Carbides, e.g. CaC2 are inorganic compounds.
Originally, it was thought that such compounds
could only be obtained from living matter (natural
sources) hence the name organic. However, this theory
was disproved in 1828 when Friedrich Wholer obtained
urea by heating the inorganic salt ammonium cyanate.
Organic Compounds
6.
C NH2
urea (organic)
7.
Generally organic compounds are very large because

carbon has the ability to form strong covalent bonds with
other carbon atoms to form chains and rings of varying
sizes. This property of carbon is called Catenation.
Other characters of organic compounds : Carbon
has the ability to form single, double and triple bonds.
Carbon has the ability to form strong covalent bonds
with many other atoms such as H, O, S, N, Cl, Br and I.
Chemical reactions
are rapid.
Exhibit isomerism.
Isomers are limited to

a few exceptions
(e.g. the transition
elements).
8.
Exhibit covalent bonding.
Exhibit ionic bonding.
Sources of organic compounds :

There are four sources of organic compounds:
1.
Catenation
Chemical reactions
are usually slow.
NH oCN
Ammonium cyanate heat
(inorganic salt)
Inorganic Compounds
Coal It is about 80% free carbon.
2.
Crude oil It is a complex mixture of organic compounds. Probably the most important source at
present.
3.
Natural gas It is a mixture of low molecular weight

organic compounds.
4.
Water and other plant materials.
Importance of Organic Chemistry
Importance of organic chemistry is great because

approximately
every activity around us is related with
Difference between organic and inorganic comit. Thus it is the chemistry associated with all living
4
pounds:
matter in both plants and animals. Carbohydrates, fats,
H2N
Organic Compounds
Inorganic Compounds
proteins, vitamins, hormones, enzymes and many drugs
1. Low melting
High melting points.
are organic compounds. Wool, silk, cotton, linen and
points.
such synthetic fibres as nylon, rayon and Dacron con2. Low boiling
High boiling points.
tain organic compounds. So do perfumes, dyes, flavors,
points.
.....+H .....
soaps, detergents,
plastics,
gasoline and oils.
3.
Low solubility in
water, high solubility in
water, high
4. Flammable.
5. Solutions are nonconductors of electricity.
High solubility in water,

low solubility
in non Polar solvents.
Non-flammable.
Solutions are conductors
of electricity.
H
H
Classification
Compounds
H ..... .....
H of
Organic
Hydrogen
bond ...
+H compounds
......
Organic
are divided into four categories:
1.
Aliphatic Compounds : These are open chain compounds. Examples are Methane, Ethane, n-Hexane,
Ethyl alcohol and Ethylamine. It means that or

ganic compounds of alkanes, alkenes or alkynes or
their derivatives are aliphatic compounds.
2. Alicyclic Compounds : These compounds are cyclic
compounds which resemble aliphatic compounds
in properties. Examples are cyclopropane and cyclohexane.
in-polarsolvents.: These unsaturated cyclic
3. Aromatic Compounds
compounds are ringed structures which have special stability and properties. Examples are Benzene,
Toluene and Naphthalene.
4. Heterocyclic Compounds: These are cyclic compounds in which the ring contains elements other
than carbon. Examples are Pyridine, Pyrole and
Furan.
Functional Group
A functional group is the reactive part of an organic
molecule. A functional group may be a single atom or
[46]
group of atoms. Double and triple bonds are functional

groups. Other examples include Cl, -Br, -OH, -NH2
groups. The functional group is the action group and
the hydrocarbon portion of the molecule remains inert.
As for example, Propyl alcohol is as given below:
CH3CH2CH2
OH
Hydrocarbon Portion
-CHO (Aldehydic), -COOH (Carboxylic acid group),

-COO (Esters), - (Ketones), -NH2 (amines) are functional
group.
Functional group serves as a basis of nomenclature
(naming) of organic compounds. It serves to classify
organic compounds into classes/families. Functional
groups give organic compounds their chemical personalities. A functional group is a site of chemical reactivity
in a molecule.
Homologous Series
A homologous series is a series of compounds in
which adjacent members differ by a CH2 unit. The individual members of such a series are called homologs.
Hybridization
The process of mixing of pure orbitals to give a set of
new equivalent orbitals (same energy and same shape)
is called hybridization. Obtained orbitals are called hybrid orbitals.
Three types of hybridization generally are found in

organic compounds as below:
3 __
i.sp
In this, three p orbitals and one s-orbital takes
part to form four hybrid orbitals. It contains tetrahedral
structure. As for example in ethane, methane and pro3
pane molecule sp hybridization is found.
2 __
ii.
sp
In this hybridisation two p-orbitals and one s
orbital take part to form three hybrid orbitals. As for
2
example, Ethylene and Benzene have sp
hybridisation orbital which is similar to that of an
3
sp orbital.
__
iii. sp In this hybridisation, one s-orbital and one porbital take part to form two hybrid orbitals. Acetylene is an important example. Its structure is linear.
Hydrogen Bonding
Hydrogen bonding is an attractive force which occurs in any compound whose molecules contain O-H or
N-H bonds (as in water, alcohols, acids, amines and
amides). The O-H bond, for example, is a highly polar
bond. Oxygen is more electronegative than hydrogen
and pulls the bonding electrons closer to it. As a result
of this displacement, the oxygen atom acquires a small
negative charge (-d) and the hydrogen atom a small
positive charge (+d).

OOO
.....
C12H22O11 + H2 O
C12H22O11 + H2 O
Hydrogen bonded compounds have higher boiling

points and higher melting points. A hydrogen-bonded
substance is usually soluble in another hydrogenbonded substance.
Isomerism
Isomers are compounds with same molecular
formulaes but different physical and chemical properties. The phenomenon is called isomerism. Since isomers have the same molecular formulae, the difference
in their properties must be due to different arrangement
of atoms within the molecule.
There are two main classes of isomerism known as
structural isomerism and stereo-isomerism.
Structural isomerism: These isomers have the same
molecular formula but differ in structural formula, that
is, in the order in which the different atoms are linked in
[47]
the molecule. Structural isomerism is of five types: chain

isomerism, position isomerism, functional isomerism,
metamerism and tautomerism.
Stereo isomerism: These isomers have the same molecular formula, same structural formula, but differ in
the special arrangement of the groups. Stereo isomerism
is of two types: geometrical isomerism and optical isomerism.
Hydrocarbons
The compounds must have carbon and hydrogen.

These are classified into Alkanes, Alkenes and Alkynes.
Alkanes : Alkanes are saturated hydrocarbons that
contain only single bonds. They can be represented by
the general formula CnH2n+2, where n is the number of
carbon atoms in the molecule, C is the symbol of Carbon
and H is the symbol of Hydrogen. Examples are methane (CH4), ethane (C2H6), propane (C3H8) etc. Alkanes
are also called paraffins. Methane, ethane, propane and
butane are all part of the refinery gas. Hexane comes out
in the diesel oil fraction. Alkanes with around 25 carbon atoms per molecule come out in the lubricating oil
fraction. The bitumen fraction contains alkanes with
over 50 carbon atoms per molecule.
Alkenes : Hydrocarbons that contain a carbon-carbon double bond are called alkenes. Their general formula is CnH2n where n is the number of carbon atoms,
C is the symbol of carbon and H is the symbol of hydrogen. Alkenes are also called olefins. These are unsaturated hydrocarbons. Ethylene, Propylene, etc. are examples. Ethylene is used in the making of Polythene.
Alkynes : Alkynes are unsaturated hydrocarbons
that contain a carbon-carbon triple bond. The general
formula of alkynes is CnH2n-2, where n is the number of
carbon atoms. Acetylene, Propyne, Pentyne are examples
of Alkynes. Acetylene is used in oxyacetylene torch
used for welding and cutting metals. Acetylene is also
used for the manufacture of PVC, Polyvinyl acetate,
Orlon, Neoprene Rubber and for the preparation of Acetaldehyde, Acetic acid and Ethyl alcohol.
Important Organic Compounds

Chloroform: Molecular formula of chloroform is
CHCl3, Where C is carbon, H is hydrogen and Cl is
chlorine. Chloroform is used as a solvent for fats, waxes
and rubber, and in the preparation of chloropicrin (Cl3CNO2) which is used as an insecticide.
manufacture of Freon-12 which is a widely used refrigerant and propellant in aerosol sprays.
Organometallic Compounds: Compounds which
contain a carbon-metal bond are called organometallic
compounds. Examples are Methyl magnesium iodide
(CH3MgI), ethyl lithium (C2H5Li).
Grignard Reagents: Compounds which contain a
carbon-magnesium bond are called Grignard reagents.
Examples are ethyl magnesium bromide (C2H5MgBr).
Alcohols: Alcohols are compounds in which a hydroxyl group (-OH) is attached to a saturated carbon.
Methyl alcohol (CH3OH) and Ethyl alcohol are suitable
examples.
Pyroligneous Acid: Water + Methyl alcohol + Acetone + Acetic acid
Molasses: Molasses is the mother liquor left after the
crystallization of cane sugar from concentrated juice. It
is a dark coloured thick syrupy mass. Molasses contain
about 60% fermentable sugars, mostly sucrose, glucose
and fructose. Molasses is converted into ethyl alcohol
by several steps with fermentation.
Invertase
C6H12O6 C6H12O6
Glu cose Fructose
Maltase
2C6H12O6
Glucose
C6H12O6 Zymase2C2H5OH + 2Co2
Absolute Alcohol: Absolute alcohol is 100% pure ethyl

alcohol. Commercial alcohol is a mixture of 95% ethyl
Carbon Tetrachloride: Its molecular formula is CCl4.
alcohol + 5% water. This mixture can not be separated by
It is used as a solvent for oils, waxes, fats and greases, as further distillation. Such a solution is called an azeotrope.
a fire-extinguisher under the name Pyrene and in the
Denatured alcohol is commerDenatured Alcohol:
Chronicle
IAS
Academy
cial ethyl alcohol to which

small amounts of poisonous
substances (such
as
methyl
alcohol or pyridine) have

been added. This is done to make it unfit for human
consumption.
Proof Spirit: The alcoholic content of a beverage is
indicated by a measure known as proof spirit. The proof
value is twice the alcoholic content by volume. Thus
whiskey which is 50% alcohol is said to be 100 proof.
Methyl Alcohol: It is poisonous and used as a solvent and as a raw material for making urea formaldehyde. It is known as wood alcohol, wood naphtha or
wood spirit.
Power Alcohol: Benzene + Petrol + ethyl alcohol
Wine: It contains 12% ethyl alcohol
Beer: It contains 4% ethyl alcohol
Whiskey and Brandy: It contains 40-50% ethyl alcohol.
Ethyl Alcohol: Its molecular formula is C2H5OH. It is
used as an antifreeze for car radiators, as a de-icing
[48]
fluid for aeroplane wings and in the manufacturing of

Dacron, dioxane and ethylene oxide.
Glycerols: Its molecular formula is C3H8O3. It is used
as a moisture-retaining agent in both tobacco, cosmetic
industries, in plastic industry and in the manufacturing of nitroglycerine and dynamite.
Diethyl Ether: Its molecular formula is C4H10O. It is
used as a solvent in the preparation of Grignards reagents. It is also an excellent solvent for fats, waxes, oils,
plastics and liquars. Diethyl ether has been used as a
general anaesthetic.
Ethyl Cellosolve (2- ethoxyethanol): It is used as a
solvent for quick-drying enamels and varnishes.
Formaldehyde: Its chemical formula is CH2O. It is
sold as 40% aqueous solution under the name formalin
and is used in this form for most purposes. Formalin is
used in the preservation of biological specimens, as an
antiseptic and in the manufacture of synthetic plastics
such as bakelite and Melmac.
soluble in water, but soluble in non polar organic solvents such as ether, chloroform or carbon tetrachloride.
Examples are : Oils, Fats, Terpenes and Steroids. Lipids
are important to humans for three reasons:
ii.
i.
iii. Lipids also serve as the basic structural components of all Cell Membranes.
Aromatic Compounds: Benzene and all compounds
that have structures and chemical properties resembling benzene are classified as aromatic compounds.
Examples are:
Lipids serve as Source of Energy: Excess carbohydrates and other energy giving foods are converted
and stored in the body as lipids and fats. These fat
reservoirs constitute one of the main storage forms
of chemical energy and carbon in the body.
Lipids surround and insulate Some Vital Body

Organs: In this capacity, they provide protection
from mechanical shock and help to maintain the
correct body temperature.
ture CH2=CH-
Br
CH3
H. It is used as a tear gas, in the
preparation of resins and in the manufacture of insecticides.

Vinegar: Vinegar is 4-6% acetic acid and is obtained
from fermented liquors containing 12-15% ethanol.
Fermentation: A form of anaerobic respiration occurring in certain microorganisms, e.g. yeasts. It comprises a series of biochemical reactions by which sugar
is converted to ethanol and carbon dioxide. Fermentation is the basis of the baking, wine and beer industries.
Benzene Toluene
Bromobenzene
Gammexane: It is also known as Benzene hexachloride (BHC). It is a powerful insecticide. Its molecular
formula is C6H6Cl6.
(TNT) Trinitrotoluene: Its molecular formula is C7H3
NO2 C7H3 (NO2)3 and is used as an explosive. It is mixed
with ammonium nitrate to form the blasting material
which is used for blasting buildings and rocks.
Soaps: Soaps are sodium or potassium salts of long

H
chain fatty acids, chiefly oleic,
stearic, palmitic and
myristic acids. Soaps are products of hydrolysis of fats
with NaOH (Saponification). Fats are mixed triglycerides and thus soaps are mixtures of long-chain fatty
acids containing
12 to 18
atoms.
Acrolein:
Its carbon
molecular
formula is C3H4O and
|| Synthetic detergents called
Syntheticc-Detergents:
Syndets are composed of several different types of compounds. Link soaps, one end of the detergent is polar
H2O
2Cnon-polar.
12H22
11 +molecule
6H12O6 + 2C
6H12O6
and the other Cend
ofOthe
is
Deter
gents differ from ordinary soaps in that they do not form
2+
2+
3+
insoluble salts (precipitates) with Ca , Mg , Fe ions.
Thus detergents are superior to ordinary soaps. They
can be used in either soft water or hard water, while
soaps are precipitated in hard water and go waste.
Sodium alkyl sulphonate and Benzene Sulphonate are
detergents.
stru Saccharin: Its molecular formula is C7H5 O4SN. It is

widely used as a calorie-free sugar substitute for diabetics.
It is 500 times sweeter than table sugar. It is sold in markets
as soluble sodium salt (sodium saccharin). Saccharin is
also used as a sweetening agent in tooth pastes, mouth
washes and aerated drinks like Cola and Thums up.
Lipids: Lipids are a group of compounds with widely

+ 2H2 o
different compositions
They are defined
Raffinose and structures.
H
as naturally occurring organic compounds +
that are in+
Aspirin: It is also known as acetylsalicyclic acid. Its

molecular formula is C9H8O4. It is used as an analgesic.
Glucose Fruclose
C6H1
DDT: It is known as dichlorodi phenyltri-chlorethane.

Its molecular formula is C14H9Cl5. DDT is an effective
insecticide for mosquitoes, flees and crop pests.
Chloramine-T: C7H7O2.NClNa is the molecular formula of chloramines-T. It is an effective antiseptic for

treatment of wounds.
Picric Acid: Its molecular formula is C6H3(NO2)3. It
is used for making explosives liks Lyddite and Melinite.
It is a valuable dye for wool.
C6H1
[49]
LSD: It is also known as Lysergic acid diethylamide. It is an example

a hallucinogenic
drug.
(C6H10O5)of
nH2O H
n +
-naphthol:
It is used as an insecticide.
2. Diasaccharides: They yield two monosaccharide

molecules on hydrolysis. Examples are sucrose
and maltose
-naphthol: It is used as a tanning agent.
Carbohydrates: The term, carbohydrate literally

means hydrate of carbon. This name arose from the fact
that many carbohydrates have the molecular formula
Cx(H2 O)y. For example, glucose has the formula of
C6H12O6 or C6(H2O)6
Carbohydrates are classified into three groups :
Monosaccharides: The Monosaccharides are carbohydrates which cannot be decomposed by hydrolysis
to give simpler carbohydrates.
Examples are glucose and fructose.
C6H12O6 + H2O
No reaction
1. Oligosaccharides:TheOligosaccharidesarecarbohydrates
whichyieldadefinitenumber(usually2to10)ofmonosaccharidemoleculesonhydrolysis.Theyinclude:
Maltose
Glucose Fructose
C12H22O11 + H2O 2C6H12O6+ 216H12O6

Maltose
Glucose
Glucose
Trisaccharides: Which yield three monosaccharide

molecules on hydrolysis.
Example is raffinose.
C18H32o16
Glactose
3. Polysaccharides: The polysaccharides are high molecular weight carbohydrates which yield many
monosaccharide molecules on hydrolysis. Examples
are starch and cellulose.
nC6H12O6

glu cos e
Cellulose: It is a polysaccharide. It is mainly obtained from trees and other plants. Cotton wool is 90-95%
cellulose. Wood is 50% wool. Cellulose nitrates are called
gun cotton or cordite which are highly explosive. It is
used in the manufacture of smokeless gun powder. Collodion is used as a covering over cuts and skin abrasion.
HALOGENS & CARBON
ture. As enzymes they catalyse biochemical reactions;

as hormones they regulate metabolic processes. Proteins are classified in two ways;
Compositional Classification: It classifies proteins
as below:
a) Simple Proteins: It contains only amino acids.
Albumins: egg albumin, serum albumin, lactalbumin.
CHRONICLE
Globulins: tissue globulin, serum globulin

Glutenins: glutenin in wheat, coryzenin in rice.
b)
Conjugated Proteins : It contains a non peptide

group in addition to the amino acids in the structure. The non-peptide portion is called the prosthetic group. Examples are:
Glycoproteins: Mucin in saliva, prosthetic group,
carbohydrates.
Phosphoproteins: Casein in milk, prosthetic group,
phosphoric acid.
Chromoproteins: Haemoglobin in red blood cells,
prosthetic group, coloured iron pigment.
Structural Classification: It classifies proteins as
either fibrous or globular.
1. Fibrous Proteins: Examples are below:
Keratin: Present in skin, hair and nails.
Myosin: Present in muscles.
Collagen: Present in tendons, cartilages and bones.
Globular Proteins: Examples are below:
Enzymes: Pepsin from stomach helps in digestion.
Insulin: Secreted by pancreas, regulates glucose metabolism.
Haemoglobin: Present in blood, transports O2 from
lungs to all cellular tissues.
Antibodies: Protect the body from outside infection
e.g. gamma globulins in blood.
Cytochromes:Presentinblood,actaselectroncarri ers.
2.
Alkaloids: Alkaloids are plant produced basic compounds which contain one or more nitrogen heterocyclic rings. Examples are Conine and Nicotine.
The alkaloids are valuable because they find important applications in medicine. They may cause such
physical effects as below :
Nicotine: Raising the blood pressure.
Caffeine: Stimulating nerves, stimulating production of urine.
Atropine: Dilating the pupils of the eyes.
Proteins: Proteins are polymers of -amino acids

bonded by peptide linkages. They occur in all living
cells. Proteins are present in muscle, skin, hair and
other tissues that make up the bodys non bony struc-
Ergonovine: Causing the blood to clot.

Morphine: Relieving pain.
Quinine: Cure/prevention of malaria
NITROGEN, PHOSPHORUS,
ACADEMY
IAS
Nitrogen
Atomic number = 7
[50]
Atomic weight = 14.008

Nitrogen occurs free gaseous state in atmosphere. It
is present in air to the extent of 78.03% by volume and
75.51% by weight of dry air. It is also found in nature in
the combined state as nitrates (Nitre KNO3, Chile Salt
Petre NaNO3) or ammonium salt. It is also present in
living animals or plants in the form of proteins. Nitrogen is obtained for industrial purposes by fractional
distillation of liquid air.
Fixation of Nitrogen: The conversion of atmospheric
nitrogen into useful nitrogenous compounds by natural or artificial methods is called fixation of nitrogen.
Nitrogen present in these nitrogenous compounds is
called fixed or combined nitrogen.
Nitrogen is fixed in nature by the following methods:
By lightning Discharge: Under the influence of lightning discharges the nitrogen and oxygen in air form
nitric acid. This acid is washed down by rain into the

soil, where it reacts with limestone and alkalies of the
soil to form nitrogen and is stored there as plant food.
By Symbiotic Bacteria: The atmospheric nitrogen is
being constantly transferred to the soil through the
agency of certain bacteria called symbiotic bacteria.
These grow in small nodules in the roots of plants
belonging to the family of leguminacea (pea, gram, etc.)
and directly assimilate atmospheric nitrogen and convert it into products useful for plant growth.
Nitrogen Cycle: Nitrates in the soil are taken up by
plant roots and may then pass along food chains into
animals. Decomposing bacteria convert nitrogen-containing compounds (especially ammonia) in plant and
animal wastes and dead remains back into nitrates,
which are released into the soil and can again be taken
up by plants. Though nitrogen is essential for all forms
of life, the huge amount present in the atmosphere is not
directly available to most organisms. It can however be
assimilated by some specialized bacteria and algae and
is thus made available to other organisms indirectly.
Lightning flashes also make some nitrogen available to
plants by causing the combination
of atmospheric nitrogen and oxygen to form oxides of nitrogen,
which enter the soil and form nitrates. Some nitrogen is returned
from the soil to the atmosphere by
denitrifying bacteria.
Ammonia Gas: It is present in
atmospheric air in traces being produced by the purification of animal
or vegetable matter or from the decomposition of urine.
Ammonia is manufactured on a
large scale by the following process :1. Habers process for the manufacture of ammonia on a large scale
includes the following catalysts :
i. Finely divided iron with traces
of molybdenum and calcium metals; or
ii. Ferric oxide with traces of SiO2
[51]
& K2O; or
iii. Finely divided nickel and sodamide deposited over
pumice stone support; or
iv. Finely divided osmium or uranium metal.

trinitrotoluene and for etching names on copper, brass
or bronze articles.
Phosphorus
2. From destructive distillation of coal
Atomic Number is 15.
3. Cyanamide process
Atomic Weight is 31.
Daily uses of NH3:

i.
It is used in refrigeration because it gets easily condensed and is called volatile alkali.
ii.
For the production of ammonia fertilizers such as

(NH4)2SO4, (NH4)3PO4, NH4NO2, and urea.
iii. In medicines
Nitrous Gas (N2O): It is laughing gas.
Nitric Acid (HNO3): Nitric acid is manufactured by
Birkland and Eyde process from air and by Ostwald
process from ammonia. Nitric acid is used as a solvent
in gold ornament industry and it is used for the manufacture of explosives such as dynamites, picric acid,
Phosphorus is a very reactive non-metal. It catches

fire in air. Hence it is not found as phosphorus in nature. It occurs in nature in the form of stable phosphate.
Animal bones contain about 58% calcium phosphate. It
is also present in blood and urine of animals.
White or Yellow Phosphorus: White phosphorus
produces light yellowish green light when kept in dark.
This phenomenon is called phosphorescence, white
phosphorus is poisonous. It turns yellow after sometime hence it is also called yellow phosphorus. It catches
fire at room temperature because its ignition temperatureis30C.
Red Phosphorus: It is less reactive than white phos-
phorus. It does not catch fire in air at room temperature.

It is used in safety matches.
Scarlet Phosphorus: It is non-poisonous, insoluble
in CS2 (carbon disulphide) and more reactive than red
phosphorus.
Black Phosphorus: It is a black solid, insoluble in
carbon disulphide (CS2), inactive like red phosphorus.
It is a conductor of electricity.
Phosphine: Its molecular formula is PH3 and shape
is triangular pyramidal. It is a colourless gas with a
smell of rotten fish and neutral to litmus paper. It is a
poisonous gas. It is used in making home signals and
producing smoke screen in battle-fields.

Silicon: Its symbol is Si. Its atomic number is 14 and
relative atomic mass is 28.086. Silicon is the second
most abundant element in the earths crust (25.7% by
weight) occurring in various forms of silicon (IV. o x ide (e.g. quartz) and in silicate materials. It is used as a
semiconductor. It has a diamond like crystal structure,
an amorphous form also exists. Chemically silicon is
less reactive than carbon.
Silicon Carbide (Carborundum): It is also known as
carborundum which is hard like diamond. Its molecular formula is SiC. It is used as an abrasive for cutting
and grinding glasses. It has a very high melting point
and therefore used in furnace lining. It is also used as
carbon rods in resistant heaters.
Halogens
It is a group of elements in the periodic table (group
VII B). These elements are Fluorine (F), Chlorine (Cl),
Bromine (Br), Iodine (I), and Astatine (At). The halogens
are typical non-metals, they have high electronegativities, high electron affinities and high ionization energies. They form compounds by gaining an electron to
complete the stable configuration, i.e. they are good
0
oxidizing agents. At 20 C, fluorine and chlorine are
gases, bromine is liquid, and iodine is a sublimable
solid. All exist as diatomic molecules. Fluorine reacts
with all non metals except nitrogen and the noble gases
helium, neon and argon, iodine does not react with any
noble gas, nor with carbon, nitrogen, oxygen or sulphur. The elements fluorine to iodine, all react with
hydrogen to give the acid, with the activity being the
greatest for fluorine, which reacts explosively.
Chlorine and hydrogen react slowly at room temperature in the dark (sunlight causes a free radical chain
reaction) Bromine and hydrogen react if heated in the
soft catalyst. Iodine and hydrogen react only slowly
and the reaction is not complete.
Noble Gases (Inert Gases): These are also known as
rare gases or group elements. They include Helium,
Neon, Argon, Krypton, Xenon and Radon. There is small
amount of noble gases on the earth and they are chemically inert. The valence shells of noble gases are fully
satisfied. Thus these elements represent the termination
of a period and have closed-shell configuration and are
associated with high ionization energies. Except radon
all noble gases are present in atmosphere. These are
colourless and odourless gases. In liquid form these
gases provide very low temperatures.
Argon is used for the making of inert atmospheres in
welding and special-metal manufacture (Ti and Zr) and
(when mixed with 20% nitrogen) in gas filled electric
light bulbs. Due to inertness, Argon is filled in light
[52]
bulbs to prevent the filaments from burning out.

Neon is used in discharge tubes and neon lamps, in
which it has a characteristic red glow. Helium has a
variety of uses, including the provision of inert atmospheres for welding and semiconductor manufacture
as a refrigerant for superconductors and as a dilutant in
breathing apparatus. It is also used for inflating balloons. Helium is also used to dilute the oxygen which
deep sea divers use because both pure oxygen and nitrogen are dangerous to breathe at the high pressures
which exist under water. Xenon is used in fluorescent
lamps and bubble chambers.
Carbon
Symbol C
Atomic number =6
Relative atomic mass = 12.011
Group = IVA
Period=2nd
Carbon occurs in nature as element carbon (coal) as
well as in the form of its compounds such as CO2 in air.
Carbon is approximately 0.032% of the earths crust.
Carbon has a peculiar characteristic to form C-C covalent bonds. This property of carbon to link with another
carbon atom is called the catenation property of carbon.
Carbon also form stable C-H bond. Carbon is also capable of forming bonds with N, O, S and other C- atoms.
Because of these properties of carbon, it forms millions
of important compounds which are the subject matter of
organic chemistry.
Allotropic Forms of Carbon: It exists in several allotropic forms such as diamond, graphite, coal, lamp black
etc. Diamond and graphite forms are more interesting

forms of carbon because of their unique structures and
properties.
Diamond: Diamond is a precious gem. It is the
hardest substance known. In diamond, carbon atoms
3
are tetrahedrally Sp hybridised and each carbon is
linked very closely to four other carbon atoms. Thus, CC linking is in three dimensions and all the four valence
electrons are involved in bond formation. The close
linking of C-atom results in its great hardness and involvement of its valence electrons in bond formation
results in its non-conductivity to electricity. Diamond is
deadly poisonous. Diamond is chemically inactive. Diamond is used as a gem. Because of its hardness, it is
used in rock-drills, glass-cutting, instruments and gemcutters.
Graphite: It is a soft crystalline substance with a
greasy feel and metallic lustre. It is a conductor of electricity. Graphite has a a layered structure in which each
2
C-atom is Sp hybridised and is linked with three other
carbon atoms in the same plane. In this way hexagons
of six-carbon atoms are formed in one layer.
Uses:
i.
Graphite marks paper and hence it is used in making lead pencils.
ii.
It is a good conductor of electricity hence, it is used

in making graphite electrodes, arcs and battery
plates.
C6H12O6 +
absorbed by chlorophyll
iii. It is used as a lubricant in machines to prevent

rusting and friction.
Charcoal: Wood charcoal and animal charcoal are
prepared by burning wood and distilling bones, when
residue of bone charcoal is obtained in the retort.
Animal charcoal has a great capacity to absorb
colouring matter. Hence it is used in the sugar industry
for decolouring molasses. Activated wood charcoal is
used for making gas-mask.
Compounds of Carbon
Carbon Monoxide (CO): It is a colourless, natural
gas, insoluble in water but soluble in ammonical cuprous chloride solution. It is a deadly poisonous gas
because it has no smell. Carbon monoxide is poisonous
because it reacts with the haemoglobin in blood and
prevents the blood form acting as an oxygen carrier. It is
largely liberated from car engines. It is used as a reducing agent. It reduces the oxides of copper, lead and iron
to the metals. CO is the main reducing agent in a blast
furnace.
Carbon Dioxide: It is a colourless, odourless gas. It
occurs in the atmosphere (0.03% by volume) but has a
[53]
short residence time in this phase as it is both consumed

by plants during photosynthesis and produced by respiration and by combustion. Carbon dioxide has a small
liquid range and liquid carbon dioxide is produced
only at high pressures. Chemically, it is unreactive and
does not support combustion. It dissolves in water to
give carbonic acid.
Large quantities of solid carbon dioxide (dry ice) are
used in processes requiring large-scale refrigeration. It
is also used in fire extinguishers as a desirable alternative to water for most fires, and as a constituent of

medical gases as it promotes exhalation. It is also used
in carbonated drinks. The level of carbon dioxide in the
atmosphere has been the subject of much environmental controversy as it is argued that extensive burning of
fossil fuels will increase the overall CO2 concentration
and then by the greenhouse effect, increase atmospheric
temperatures and cause climatic modification.
Carbon Cycle: One of the major cycles of chemical
elements in the environment. Carbon (as carbon dioxide) is taken up from the atmosphere and incorporated
into the tissues of plants in photosynthesis. It may then
pass into the bodies of animals as the plants are eaten.

During the respiration of plants, animals and organisms that bring about decomposition, carbon dioxide is
returned to the atmosphere. The combustion of fossil
fuels (e.g. coal and peat) also releases carbon dioxide
into the atmosphere
METALLURGY
Carbon Dating (Radiocarbon Dating): It is a method

of estimating the ages of archaeological specimens of
biological origin. The isotope 6C14 of carbon is used in
carbon dating.
Photosynthesis: It is the chemical process by which
green plants synthesize organic compounds from carbon dioxide and water in the presence of sunlight. It
occurs in the chloroplasts (most of which are in the
leaves) and there are two principal series of reactions. In
the light reactions, which require the presence of light,
energy from sunlight is absorbed by photosynthetic pigments (chiefly the green pigment chlorophyll) and converted into chemical energy. In the ensuing dark reactions, which can take place either in light or darkness,
this chemical energy is used in the production of simple
organic compounds from carbon dioxide and water.
Further chemical reactions convert these compounds
into chemicals useful to the plant. Photosynthesis can
be summarized by the equation:
CHRONICLE
light energy
6CO2 + 12H2O
6H2O + 6O2
Photosynthesis is the basis for all life on earth. Furthermore virtually all the atmospheric oxygen has originated from oxygen released during photosynthesis.
[54]
IAS ACADEMY
Metallurgy is the branch of applied science concerned with the production of metals from their ores, the
purification of metals, the manufacture of alloys and the
use and performance of metals in engineering practice.
Process metallurgy is concerned with the extraction

and production of metals, while physical metallurgy
concerns the mechanical behaviour of metals.
Hence, except a few metals such as Cu, Ag, Au, Pt
etc., most of the metals are found in nature in the form of

Hence, gangue + flux = slag
minerals. Metals are extracted from the minerals by
An example is the use of SiO2 flux to remove basic
several methods.
FeO gangue during the extraction of copper (Cu) from
Copper Pyrite (CuFeS2).
Important Terms
FeO
Ore: An ore is a mineral from which a metal can be

extracted economically. As for example, iron pyrites are
the ores of iron.
Gangue: The impurities present in an ore is called
gangue.
Flux: A material which is added from outside in the
ore during the process of smelting to remove gangue is
called flux.
Slag: Slag is a light fusible waste material obtained
during the extraction of metals. Slag, being lighter and
fusible, floats on the surface of the molten metal.
Gangue
SiO FeSiO3
Flux
Slag
Calcination: It is the process of heating an ore below

its melting point to remove volatile impurities from the
ore.
Fe2O3 H2O Calcination
Fe CO3 Calcination
Fe2O3 + H2O -
FeO + CO2-
Roasting: It is the process of heating an ore below its

melting
point in presence
of air
in order to oxidize it.
Manganese:
Pyrolusite
MnO
2
Examples : 2ZnS + 3O2 Roasting 2ZnO + 2SO2 Smelting: Smelting is the process of heating an ore
above its melting point with coke and flux in order to
reduce the ore to metal.
Amalgam: An amalgam is a mixture of two metals,
one of which is mercury.
Extraction Principles of Metals: Metals are generally
extractedfromtheiroresbymeansofthefollowingmethods:
Alloy: An Alloy is Mixture of Two or More Metals

No.Some Important Alloys Compositions
Uses
1.
Brass
Cu(60-80%), Zn(40-20%)
For making household untensils.
2.
Bronze
Cu(75-90%), Sn(25-10%)
For making coins, idols, bells, utensils, etc.
3.
German Silver
Cu(60%), Zn(25%), Ni(15%)
For making utensils.
4.
Magnelium
Mg (98%), Al(2%)
For making Aeroplane frames, can be worked on lathes.
5.
Rolled gold
Cu(90%), Al(10%)
For making cheap ornament.
6.
Monel metal
Cu(70%),Ni(30%)
Alkali resistant containers.
Bell metal
Cu(72-80%), Sn(28-20%)
For making, bells, utensils, idols, coins etc.
8.
Gun metal
Cu(85%), Zn(10%), Sn(5%)
Used for engineering purposes.
9.
Constantan
Cu(60%), Ni(40%)
For making electrical apparatus.
10. Munz metal
Cu(60%) and Zn(40%)
For making coins, tubes and castings.
11. Solder
Sn(50-14%), Pb(50-30%)
Soldering of metals.
[55]
A.
B.
C.
Carbon-Reduction Process: This process is for those

metals which can be obtained by the reduction of
their oxides. Examples of such metals are Zn(zinc),
Cd(cadmium), Mercury(Hg), Tin(Sn), Copper(Cu),
Lead(Pb) and Iron(Fe).
Electrolytic Process: This process is used for the
extraction of reactive metals such as Na, K, Mg, Ca
and Al.
Goldschmidt Alumino Thermic Process: This process is used for the extraction of metals such as
chromium which can neither be obtained by Carbon-Reduction Process, nor by electrolytic process.
Magnesium: Magnesite MgCO3
Carnallite KCl.MgCl2.6H2O
Dolomite MgCO3.CaCO3
Epsom Salt MgSO4.7H2O
Asbestos CaSiO3.2MgSiO3
Caesserite MgSO4.H2O
l
Magnite Mn2O3.H2O
l
Mercury: Cinnabar HgS
Potassium: Felspar KAlSi3O8
Important Ores
l
l
Nitrite (Shora) KNO3

l
Potash Alum K2SO4.Al2(SO4)3.24H2O
Alu Bauxite Al2O3.2H2O

Diaspore Al2O3.H2O
mini
Cryollite Na3AlF6
um: Barium: Heavy Spar or Barites BaSO
4
Corr Witherite BaCO3
Barytocalcite BaCa(CO3)2
und
Calcium: Calcite CaCO3
um,
Dolomite CaCO3.MgCO3
Rochelle Salt CHOH COONa

|
CHOH COOK
l
Horn Silver AgCl

Pyragyrite Ag3SbS3
l
Rub Limestone and Marble CaCO3

y
Al2O
Gypsum CaSO4.2H2O
Chile Salt Petre NaNO3
Anhydrite CaSO4
Washing Soda Na2CO3.10H20
Fluorspar CaF2
Trona Na2CO3.2NaHCO3.3H2O
Phosphorite Ca3(PO4)2
Copper(Cu): Chalchopyrite or Copper pyrites
CuFeS2
Borax Na2B4O7.10H2O
Tin: Cassiterite SnO2
Tin Pyrites SnS2.Cu2S.FeS
Zinc: Zincite ZnO

Zinc blende ZnS
Ruby Copper or Cuprite Cu2O
Franklinite ZnO.Fe2O3
Azurite (CuCO3)3.Cu(OH)2
Chalcocite or Copper glance Cu2S

Malachite CuCO3.Cu(OH)2
l
Sodium: Brine NaCl

Glauber Salt Na2SO4.10H2O
Silver: Silver glance or Argentite Ag2S
Iron: Haematite Fe2O3
Calamine ZnCO3
Important Compounds
Magnetite Fe3O4
Common Table Salt : NaCl
Cidderite FeCO3
Iron Pyrite FeS2
Caustic Soda : NaOH

Washing Soda : Na2CO3.10H2O (Sodium Carbonate)
Spathose ore FeCO3
Baking Soda : NaHCO3 (Sodium bicarbonate)
Lead: Galena PbS

Anglesite PbSO4
Cerussite PbCO3
Tincture Iodine : It is a solution of I2 and KI in ethyl

alcohol
Potash Alum : K2SO4Al2(SO4)3 24H2O
Cupric Sulphate or Blue vitriol (CuSO4.5H2O): It is
used as a germicide, in electroplating, in electric cells. A

mixture of CuSO4..5H2O and Ca(OH)2 is called Bordeaux
mixture and is used as a fungicide.
Fehling Solution: It is a deep blue solution obtained
by dissolving CuSO4.5H2O in water and adding NaOH
solution and sodium potassium tartarate solution to it.
It is used for the test of an aldehyde.
Benedicts Solution: When NaOH and sodium citrate is added to a solution of copper sulphate, a deep
blue solution is formed which is called Benedicts Solution. It is used for testing the presence of sugar in urine.
When Benedict solution is shaken with a few c.c. of
urine in a test tube, a red ppt. of Cu2O is obtained
indicating the presence of sugar in urine.
Lunar Caustic: It is also known as AgNO3 (silver
nitrate). It is used in photography to prepare AgBr (Silver Bromide). It is used for making hair dyes.
Epsom Salt (MgSO4.7H2O): It is used in cotton industry for soaking cotton threads before final spinning.
Plaster of Paris : It is used for making moulds, idols,
surgical bandages and plastering of walls.
Bleaching Powder Ca(OC)Cl: It is used as a bleaching agent in paper and textile industry, as a germicide
for spraying in drain, disinfecting drinking water.
Soda Lime: CaO + NaOH
Nesslers Reagent: It is a colourless solution of
[56]
K2[HgI4] made alkaline with NaOH solution.

White Vitriol [ZnSO4.7H2O]: It is used in the textile
industry for soaking cotton threads before spinning
and in dyeing industry.
Calomel: Its molecular formula is HgCl2 (Mercurous
Chloride). It is used in medicines in the form of blue
pills.
Lithopone: It is a mixture of ZnS and BaSO4 and
used to prepare white paint.
BoricAcid:H3BO3isthemolecularformula.Itisananticeptic
andisalsousedinglass,enamelandpotteryindustry.
Borax [Na2B4O7.10H2O]: It is used in cleaning household utensils and increasing its shine.
Alumina or Aluminium Oxide (Al2O3) : It is found
in the form of gems. Some important aluminium oxide
gems are:
(a) Topaz yellow (b) Sapphire blue
(c) Ruby red
(d) Amethyst violet
(e) Emerald green

Lead Acetate [Pb(CH3COO)2]: It is also called sugar
of lead.
Lead Tetra-ethyl: Its molecular formula is Pb(C2H5)4.
It is soluble in petrol, and is a great anti-knock agent.
When a very small quantity of it is added to petrol the
knock given by petrol in internal combustion engines is

suppressed. Petrol mixed with lead tetraethyl is coloured
red with an organic dye to distinguish it.
Ammonium Chloride: Its molecular formula is
NH4Cl and is known as Sal Ammoniac.
Nitrous Oxide: It is known as laughing gas. Its molecular formula is N2O.
Plastic Sulphur: When sulphur is heated to a temperature above 160C so that a viscous brown liquid
sulphur is formed and when this molten sulphur is
slowly poured in water contained in a beaker, an elastic
form of sulphur is formed. This is called Plastic Sulphur.
Polywater: Its molecular structure is the same as that
of general water but it has freezing point of 40C and
its boiling point is 500C.
Mustard gas: a class of chemical warfare agent,
can form blisters on skin and lungs.
H2C___S___CH2___CH2___Cl
|
H2C___Cl
White Lead [2PbCO3.Pb(OH)2]: It is used in the making of white paint.
Red Lead [Pb3O4]: It is a red coloured compound
used as anti-corrosion pigment.
[57]
Baryta Water: Ba(OH)2

Blue Vitriol: CuSO4.5H2O
Green Vitriol: FeSO4.7H2O
White Vitriol: ZnSO4.7H2O
Gun-Powder: 75% KNO3, 12% S and 13% charcoal
Lithopone: ZnS + BaSO4
Philosopher Wool: Zinc oxide (ZnO)
Nitrolium Fertilizer: CaCN2
Silver Chloride: It is used to make Photochromic
glass.
Calcium Sulphide: It causes Phosphorescence.
Osmium: It is the heaviest metal.
Tear Gas: Chloroacetophenol, acrolin and
Chloroacetophenone are tear gas.
Calgen: Na(PO3)6 : Used to remove water-hardness.
SnS2: Mosaic gold.
Ammonium Carbonate: It is called Smelting Salt.
Calcium Phosphate : It is used in the making of
toothpaste.
Nichrome: It is made up of Cr, Ni and Fe. It is used in
the making of heater-coil.
Hydrogen Peroxide (H2O2): It is used for adding
brightness of old oil pictures.
AgNO3 Silver nitrate: It is used to make identification on the finger of voters.
Zinc Sulphide: It is used to make Phosphorescence
Screen.
Aluminium hydroxide Al(OH)3: It is used as a fire
retardant.
Aldehydes: Give Tollens reagent Ag(NH3)2OH test
and Fehlings solution (Cu(OH)2 + NaOH test but these
tests are not shown by Ketones and aromatic aldehydes.
Aldehydes also give Benedicts Solution (an alkaline
Water Glass: It is sodium silicate, soluble in water.

Soda Water: Water + solution of CO2.
Liquid Natural Gas: It is liquid like LPG. Its main
component is methane.
Copper: It is mixed with gold to make ornaments.
Iron Sulphide or Iron Pyrites: It is called as Fools
gold.
Soda Ash or Sal Soda: It is sodium carbonate.
Fluorine: It is the highest electronegative element.
Frantium: It is the highest electropositive element.
Platinum: It is the called white gold.
Liquid Gold: It is Petrol.
Lithium: It is the lightest metallic element and strongest reducing agent.
Radon: It is the heaviest among gaseous elements.
Astatin: It is the heaviest among solid non metals.
Polonium: It has the maximum number of isotopes.
Oil of Vitriol: It is sulphuric acid.
Bath Salt: Na2CO3. NaHCO3. 2H2O
Hair Salt: Al2(SO4).18H2O
Oxy-acetylene Flame: It is used in making and cutting of metals.

solution of cupric ions complexed with sodium potassium citrate ions) test. Ketones do not give this test.
Schiffs Test: Dilute Solution of aldehydes when
added to Schiffs reagent (rosaniline hydrochloride dissolved in water and its red colour decolourised by passing Sulphur dioxide) restores its red colour. This is
known as Schiffs test for aldehydes.
Formalin: Formaldehyde is called as formalin.

Hard Soap for Washing Clothes: Sodium salt of
fatty acid is used as hard soap.
Soft Soap for Bathing: Potassium salt of fatty acids
is used as Soft Soap for bathing.
Stainless Steel: Constituents are Iron, Nickel and
Chromium.
Dichloro Difluoro Carbon: Its molecular formula
is CF2Cl2 and is known as Freon. It is used as refrigerant.
CHEMISTRY
The Cast Iron or Pig Iron: The pig iron obtained

from the blast furnace is the impurest form of iron. It
contains the following impurities
C = 1%
Si = 1.4%
Wrought Iron: Wrought iron is the purest form of

iron. It contains very little quantity of impurities. The
total impurities of C, Si, P, Mn, etc. is not more than
0.25% in wrought iron.
Wrought iron is:
1.
Soft
2.
Malleable
3.
Ductile
CHRONICLE
4.
It has less physical strength as compared to pig
iron. It is used for making steel by the Puddling Process.
Steel: Steel is an alloy of Fe, C, and Mn. It contains
the following in small quantities.
Carbon = 0.2%
Silicon = 0.004%
P = 2.5%
Mn = 0.4%
S = 0.1%
P = 0.02%
Mn = 1.8%
Pig Iron is brittle: It is used for the manufacture of
steel, wrought iron and in foundry work. It is also used
for making utensils, type-writer-cover, etc.
S = 0.04%
Thus the impurities in steel are less than that present
in Pig iron and more than that present in wrought iron.
ENVIRONMENTAL
[58]
IAS ACADEMY
The chemistry which deals with the chemical relations among various factors like atmosphere, earth, water, plants and animals is called environmental chemistry. Thus, an environmental chemical balance exists for
the easy survival of living things, but some human
activities such as rapid population growth, industrialization, modern technology are hampering our lives.
Hence, Air, land and water are increasingly becoming
more polluted and the survival of livingbeings is threatened.
There are two main classes of pollutants those that
are biodegradable (e.g. sewage), i.e. can be rendered
harmless by natural processes and, therefore, cause no
permanent harm if adequately disposed off or treated
and those that are non bio-degradable (e.g. heavy metals (such as lead and DDT), which eventually accumulate in the environment and may be concentrated in
food chains.
Air Pollution
Air is essential for living things. Waste substances
like smoke and gases from chimneys escape into the air
and pollute it. Air so changed is said to be polluted and
the substances causing pollution are called pollutants.
The main air pollutants are carbon dioxide, ammonia,

sulphur dioxide, smoke, carbon monoxide and other
waste gases let out through the chimneys of industry,
automobiles (motor, buses) and others (like fuels). Since
plants take in carbon dioxide and release oxygen during photosynthesis, therefore growing trees and plants
in big cities and industrial towns is one way of controlling of air pollution.
Water Pollution
Like air, water is also an essential factor for living
beings. Various types of wastes such as sewage, industrial wastages are liberated into rivers, lakes, etc. Thus
water becomes toxic for fish and other living beings.
The extent of pollution of river water (or any other
type of water) is usually measured by oxygen standards. One is dissolved oxygen (DO) which should not
be less than 4 mg per litre of water. The other is the
biological oxygen demand (BOD) and is a measure of
organic matter present in water. It should not exceed

3mg per litre of water.
The different values of DO and BOD for Ganga water
at different cities are given below:
City
DO (mg/l)
Rishikesh
Haridwar
Kanpur
Varanasi
Patna
Kolkata
8.3
8.1
8.1
7
8.9
7.8
BOD(7 mg/l)
1.4
1.9
20.4
9.4
2.1
3.5
Radioactive Pollution
Nowadays, nuclear tests are occurring in different
parts of the world and atomic reactors are also being
established for peaceful purposes. Due to careless activities exposure to radiations (from radioactive materials) causes death or genetic defects in man.
Ozone Layer
of the atmospheres ozone is concentrated. It occurs 1550 km above the earths surface. In this layer most of the
suns ultraviolet radiation is absorbed by the ozone
molecules, a rise in the temperature of the stratosphere
and preventing vertical mixing so that the stratosphere
forms a stable layer. By absorbing most of the solar
ultraviolet radiation the ozone layer protects living organisms on earth. The fact that the ozone layer is thinnest at the equator is believed to account for the high
equatorial incidence of Skin Cancer as a result of exposure to unabsorbed Solar ultraviolet radiation. The existence of the ozone layer is maintained with creation
and destruction of O3. Oxygen molecules are destroyed
by high energy ultraviolet radiation and form ozone
(O3). This ozone has an appreciable lifetime in the atmosphere until, it is effected from ultraviolet radiation and
once again forms common oxygen gas. Ozone molecules
are stable, however ozone can be broken down by stable
organic chlorine compounds mainly Chlorofluoro carbons, where an active chlorine atom can catalytically
destroy ozone. Due to this destruction ozone hole is
developing.
It is a layer of the earths atmosphere in which most
[59]
iii.
by ingestion
iv.
by inhalation as a lethal vapour.
2. Herbicides: These are used to discourage weed

growth without damaging the crop.
3. Fungicides: It controls parasitic and saprophytic
fungi which are responsible for damaging the crops.
It prevents further attack of fungi on plants.
4. Nematicides: It kills the parasitic worms residing
in soil which feed on growing crops. Nematicides
ACETYL COENZYME-A
Agricultural Chemistry
Chemistry plays a vital role in agriculture particularly of fertilizers and pesticides. By the use of fertilizers
we improve the quantity of nutrients in soil for plants.
Pesticides are such chemicals which are used to destroy
the harmful insects, fungi and others which are harmful
to crops.
Pesticides
Pesticides are chemicals which are subdivided into
the following:
1. Insecticides: Insecticides kill those harmful insects,
which attack growing and harvested crops, livestock, buildings and man himself. There are four
ways in which insecticides may act:
i.
directly
ii.
by passage
act by spreading their vapour through the soil to

reach the invading eelworms.
5.
Molluscicides: It kills slugs, snails, etc. which are

harmful for crops. Hence the use of pesticides depends upon climate and the crop. In tropical and
subtropical areas, insecticides predominate. In temperate regions herbicides are more important. Besides these pesticides some other chemicals are also
used to destroy the harmful factors such as sodium
monochloroacetate, sodium fluoroacetate, zinc phosphide, thalium sulphate and alpha naphthyl thio
urea are used for killing rats or rodents which do
not only destroy stocks of food, they also spread
diseases. Insect control is also done by sex attractants (Pheromones or antifeedants). One example of
such chemical is disparlure which has been used
against gypsy moth.
are the examples of nitrogenous fertilizers.

2.
Phosphatic Fertilizers: It provides phosphorus to

the soil. Superphosphate of lime, triple superphosphate and phosphate slag are examples.
3.
Potash Fertilizers: It supplys potassium to the plant.

These are useful to the plants especially to meadows, tobacco, cotton, coffee, potatoes and corn. All
these fertilizers occur in nature. Potassium chloride
(KCl), Potassium nitrate (KNO3) Potassium Sulphate
(K2SO4. are examples.
4.
NP Fertilizers: It provides two elements namely,

nitrogen and phosphorus. These are obtained by
mixing together nitrogenous and phosphatic fertilizers in suitable proportions. Examples are
dihydrogen ammoniated phosphate (NH4H2PO4),
Calcium superphosphate nitrate Ca (H2PO4)2.
2Ca(NO3)2 and ammoniated phosphate sulphate
Fertilizers
Fertilizers are the substances which are added to
the soil in order to make up the deficiency of essential
elements like nitrogen, phosphorous and potassium
required for the growth of the plants.
1. Nitrogenous Fertilizers: These fertilizers mainly
supply nitrogen to the plants or soil. Ammonium
sulphate (NH4)2SO4, calcium ammonium nitrate,
basic calcium nitrate, calcium cyanamide, urea, etc.
Medicinal Chemistry
In this branch of Chemistry we study chemical structures, synthesis, toxicity, pharmaceutical effects and
activites of medicines which are used for the treatment
of diseases.
Drugs: Chemical substances used for treatment of
diseases and for reducing the suffering from pain are
called medicines or drugs.
Chemotherapy: It is the science in which chemicals
are used for the treatment of diseases. It has developed
into a vast subject today and efforts are being continuously made to search for new drugs for cancer, hypertension and mental illness among others.
Replacement Drugs: Substances used to replace or
supplement a normal hormone or other compounds
that are in short supply in a particular Patients System.
These are called replacement drugs. Example of a replacement drug is insulin which is used when persons
are suffering from diabetes mellitus.
Antipyretics: Antipyretics are substances used to
bring down body temperature in high fever. Their administration often leads to perspiration. Common examples are aspirin, phenacetin and paracetamol. Calcium and sodium salts of aspirin are more soluble and
less harmful.
Analgesics: These are drugs used for relieving pain.
Aspirin and some other antipyretics act as analgesics
also. Certain narcotics (which produce sleep and unconsciousness) are also used as analgesics. Typical exComponents
1.
Blood particles
(a) Red Blood
cells (RBC)
(b) White blood
cells (WBC)
(c) Blood Platelets
Function
Transport of molecular
oxygen from lungs to tissues
Defence against infection,
Blood Clotting
NH4H2PO4. (NH4)2SO4.
5.
NKP or Complete Fertilizer: These fertilizers supply

all the three essential elements namely, nitrogen, phosphorus and potassium to the soil and are produced
by mixing nitrogeneous phosphatic and potash fertilizers in suitable proportions. It is observed that
these fertilizers produce much better results.
[60]
2.
Plasma Solutes
(a) Electrolytes
(ions) Na+
and ClHCO3-
Maintenance of osmotic
pressure and fluid balance
principal buffer in blood,
transport of CO2 from
cells to the lungs
(b) Protein Albumins Maintain osmotic pressure of
blood plasma, transport of
water insoluble substance
Globulins alpha, beta,
gamma, transport of lipids
as lipols, immunological
(protective)
(c) Carbohydrates
Source of energy
amples of narcotics are morphine, Marijuana, cocaine

and heroin. They are known to be habit-forming.
Antiseptics and Disinfectants: Antiseptics are the
chemicals which kill or prevent the growth of micro
organisms. These are applied to living tissues. They can
be applied to wounds, cuts, ulcers and diseased skin
surfaces. Antiseptics reduce odours resulting from bacterial decomposition in the body or in the mouth. For
such use, they are incorporated into deodorants, face
powders and breath purifiers.
Disinfectants kill micro-organisms but are not safe
for contact with living tissues. These are applied to
inanimate objects such as floor, instruments, etc.
Antiseptics can act as disinfectants by varying the
concentration of the solution used. Thus a 0.2 percent
solution of phenol acts as an antiseptic and 1% solution
of it as a disinfectant.
Chlorine is used for making water fit for drinking at
a concentration of 0.2 to 0.4 parts per million. Low
concentration of sulphur dioxide is used for sterilizing
squashes for preservation. Commonly used as antiseptic, dettol is a mixture of chloro-xylenol and terpeneol in
a suitable solvent. Bithional is added to soap to impart
antiseptic properties. It reduces undesirable odours resulting from bacterial decomposition of organic matter
on the skin. Iodine is a powerful antiseptic. It is em-
ployed as tincture of iodine, an alcohol-water solution

containing 2-3% iodine. Iodoform (CHI3) is widely used
as an antiseptic wound powder. Gentian violet and
methylene blue are simple examples of antiseptic dyes.
Tranquilizers: These are substances used for treatment of mental diseases. They act on higher centres of
the central nervous system. They are the constituents of
sleeping pills. These are also called psychotherapeutic
drugs. They help the individuals to enhance capacities
they already have, by alleviating symptoms to emotional distress when these are severe and interfere with
their functions. Derivatives of barbituric acid (viz, luminal and seconal) have been known for their tranquilising
activity for a long time. Equanil possesses a good tranquilizing effect and is used in depression and hypertension.
Antibiotics: Antibiotics are defined as chemical substances produced by micro-organisms (bacteria, fungi
and molds) that can inhibit growth or even destroy
other micro-organisms. Antibiotic therapy is a case of
setting one thief against another because antibiotics
themselves are products of microbial growth. The first
antibiotic penicillin was discovered by Alexander
Flemming in 1929. It is an effective drug for pneumonia,
bronchitis, sore throat and abcesses. Streptomycin is
used for tuberculosis and chloramphenicol for typhoid.
Tetracyclines like chloramphenicol are also antibiotics.
[61]
Ampicillin and amoxicillin are examples of antibiotics.

Sulphur Drugs: Sulphur drugs like Sulphanilamide,
Sulphadiazine and Sulphaguanidine act against micro-organisms like antibiotics and have been used in
place of them.
Food Chemistry
All human activities either physical or mental, need
energy. These energies are supplies by food. It helps in
the replacement of dead cells and create new cells and
its growth. Human body requires carbohydrates and
fats for energy, proteins for body building and water,
minerals, vitamins, hormones for regulating the different functions of life. Human body suffers from diseases
due to lack of any of the nutrients.
Hence in this branch we concentrate on food-chemicals and its digestion. It means All biological processes are chemical transformations.
Chemistry of Biological Processes

A living system is a complex array of chemical reactions. Both small and macromolecules that compose a
cell are synthesized by the cell itself from simple precursor molecules. The set of chemical reactions by which
synthesis of various molecules of cells are achieved is
called anabolism. Other reactions, including complex
organic molecules which are degraded into smaller ones
and into carbon dioxide and water with the liberation of

energy are called Catabolism. The Catabolic reactions
serve to provide both energy for various cellular functions as well as the starting materials for anabolism.
The process of synthesis and degradation are not simply reverse of each other and may occur by different
chemical paths. Together, the synthesis and degradation constitute metabolism.
Photosynthesis
In this process conversion of solar energy into chemical energy takes place. Photosynthesis takes place in
regions of the plant cells called chloroplasts. The reactions can be divided into two categories: the light reactions and dark reactions. In light reactions, the Solar
radiation is absorbed by the pigment Chlorophyll and
this energy is utilized to synthesize energy rich molecules (ATP Adenosine triphosphate) and liberate
oxygen. The dark reactions then use these energy-rich
molecules to convert atmospheric carbon dioxide into
glucose and storage molecules such as starch. The overall process can be represented as follows:
6Co2 + 6H2o
C6
H12 O6 + 6O2
Glucose
Chronicle
IAS
Academy
Adenosine Triphosphate (ATP): ATP is an energyrich compound. It contains two oxygen-to-phosphorous bonds that are called High energy Phosphate bonds.
Proteins and Lipids Digestion: Protein digestion

starts in the stomach where the environment is acidic
(PH = 2). This helps in denaturation of proteins prior to
digestion. Enzymes of protein digestion are called ProDigestion
teases (breaking large protein molecules to smaller peptides) and Peptidases (Convert peptides into amino acDigestion is the process by which complex foods are
ids). The enzymes pepsin, trypsin, chymotrypsin and
broken into simple molecules.
other peptidases are involved in protein digestion.
Carbohydrate Digestion: In the Carbohydrate-digesThe main digestion of lipids takes place in the small
tion process, firstly, starch is hydrolysed into maltose
intestine. Here the food gets mixed with bile fluid. This
with the action of amylase enzyme in mouth. Carbohyemulsifies fats and allows enzymes such as lipases to
drate digestion stops in the stomach where the Ph is
hydrolyse fat into glycerol and fatty acids which then
acidic and the amylases are inactive. Food in intestine is
pass into the bloodstream.
mixed with amylases produced by the pancreas and
Carbohydrate Metabolism: Glucose is oxidized in
small intestine walls. These hydrolyse the polysacchacells into carbon dioxide and water. Thus glucose oxirides completely into monosaccharides such as gludation is one of the most important reactions in a living
cose, fructose and galactose. These pass through intesticell which leads to useful cellular energy. For each molnal walls into the bloodstream and to the liver. A numecule of glucose broken down, 38 molecules of ATP are
ber of Polysaccharides like celluloses in our diet are not
produced. Since two molecules of ATP are also connourishing because there are no enzymes to digest them.
sumed during the initial step of glycolysis, the net prooxidation
hydrolysis
The glucose
absorbed
into blood
is the
major Acetyl
source CoA duction of ATP per molecule of glucose is 36.
Lipids
Fatty
Glycerol
of energy of cells. Though most
tissues can also use fatty
Glucose + 36 ADP (Adenosine diphosphate) + 36 Pi
acids for their
energy needs, cells of brain and nervous
acids
+ 6O2 6CO2 + 36 ATP + 44H2O.
system depend entirely on blood glucose for their funcVarious Steps in Breakdown of Glucose: Glucolytion. The normal required level of glucose in blood is
3
sis
occurs in cytosol. Citric acid cycle and oxidative
about 60 to 100 mg/100 cm of blood. The excess glucose is stored as glycogen which is broken down by
cells in time of need.
[62]
phosphorylation takes place in mitochondria in the

presence of oxygen. In the absence of oxygen, bacteria
fermentation produces ethanol and in muscles, lactic
acid is formed.
Lipid Metabolism: Most of the energy in fats is
contained in the long chain hydrocarbons of fatty acids.
They are the main energy reserves of the body producing 43.62 K J per gram on oxidation, much more than
that generated by oxidation of carbohydrates or proteins (16.8 KJ/gm). On oxidation, Palmitic acid, a C-16
fatty acid produces 130 molecules of ATP.
+
citric acid
cycle ATP
Amino Acid Metabolism: Amino acids provide dietary source of nitrogen and are used in the formation of
new cells or repair of old cells, synthesis of other amino
acids, enzymes, hormones, antibodies and non-protein
molecules such as nucleic acids. Unlike carbohydrates
and lipids which can be stored (as glycogen in muscles
and as fats in adipose tissues, respectively) there are no
storage molecules for amino acids. Some amino acids
are metabolized to pyruvate, some to acetyl CoA and
others to various intermediates in glucose metabolism
and energy is obtained by their breakdown into carbon
dioxide and water.
Water
It is an ideal physiological fluid in living organisms
because of the following characters:
i.
Water has a high boiling point (100C) which is

well above the physiological temperature (37C).
ii.
Due to the smaller molecular size of water and extensive intermolecular hydrogen bonding it dissolves not only other ionic compounds, but also a
large number of polar organic compounds.

iii. Water provides a medium for transport of chemicals to and from cells. Metabolic reactions take place
in water.
iv. It is a common participant in many biochemical
reactions.
v. 70% of total body weight is due to water: A normal
healthy adult will ingest and excrete about 1.5 to 3.0
litres of water per day.
vi. The control of water balance is performed primarily
by kidneys which regulate the amount of water and
electrolytes excreted via urine in conjunction with
thirst mechanism.
Blood
The blood is a vehicle for metabolic communication
among the organs of the body. It is the transporting
medium for nutrients, waste products, oxygen and CO2.
Blood consists of an aqueous solution of ions and organic molecules in which are suspended particles called
the red blood cells (erythrocytes), white blood cells
(leucocytes) and blood platelets.
The Ph of blood must be maintained within the range
of 7.36 to 7.42.
Haemoglobin is the key participant in the process by
which gases CO2 and O2 interchange between the body
and the environment. Haemoglobin is a globular protein consisting of four polypeptide chains arranged in a
tetrahedral configuration. It contains a non-protein constituent called heme which is an iron prophyrin and is
responsible for the red colour of blood. In lungs, haemoglobin combines with oxygen to form oxyhaemoglobin.
Here the oxygen is bound to the iron atom of heme. In
tissues where oxygen content is low, oxyhaemoglobin
dissociates and releases oxygen for utilization. A related protein myoglobin, serves to store oxygen in the
muscle tissues.
Antibodies: These are protectors from foreign invaders like bacteria, virus, etc. The presence of invaders in
the body triggers the production of specialized protein

molecules known as antibodies or immunoglobulins.
Antibodies are Y-shaped protein molecules composed
of four smaller polypeptides linked together. The invader which triggers the antibody formation is designated as antigen. Thus in response to the entry of antigen or infection the level of the corresponding antibody
rises in blood. New born babies do not have a functioning system for antibody synthesis for several months.
During this period, they are protected by antibodies
from the mothers milk.
Allergy
Some persons are sensitive to specific substances
such as pollen, penicillin or cat fur because, he or she
produces an antibody against this substance. The antigen may be airborne, producing a response in the eyes,
respiratory tract or ingested with food-producing gastrointestinal or skin reactions. The binding of antigens
and antibodies results in the cells releasing a variety of
chemicals such as histamine, seratonin, etc. which in
turn generate allergic response. The drugs used to combat the effects of allergy are antihistamines which block
the production of histamines.
Hormone
Hormones, are a class of chemical messengers pro[63]
duced in ductless glands, and transported by blood

circulation to target tissues for producing an inhibitory
or a stimulatory effect. Hormones are very potent and so
are produced in small quantities only.
Hormones are classified into three classes on the
basis of their Chemical Structure :
1. Steroid Hormones
2. Peptide Hormones
3. Amine Hormones
1. Steroid Hormones: Steroids are compounds whose
structure is based on a four-ring network, consisting of
3 cyclohexane rings and 1 cyclopentane ring. Sex hormones like testosterone, dihydrotestosterone, androgens and estrogens are examples of steroid hormones.
There are other steroids such as cortisone, corticosterone and aldosterone which affect metabolism, mineral
and water balance. The deficiency of these leads to loss
of fluids and excess results in an increase in blood
pressure.
Androgens and estrogens also have significant effects on the anabolic system. So they are used by athletes, weight-lifters and other sports-persons to increase
the muscle mass and strength. Such uses of anabolic
steroids are banned in competitive sports.
Besides sterols and ergosterol, digitoxigenin is a Steroid extracted from plant digital and is used as a drug to
regulate heart function. It is also the raw material for
manufacture of several Steroid drugs.
2. Peptide Hormones: Oxytocin and vasopressin
are two hormones of this class. Oxytocin causes contraction of the uterus during child birth. Vasopressin
controls the reabsorption of water in the kidneys.
3. Amine Hormones: These are the water-soluble
amine compounds. Examples are adrenaline (epinephrine) and thyroid hormones. Adrenaline is needed to
prepare animals (humans) for emergency in several

ways. It increases the heart beat rate, heart output and
the blood pressure, preparing the cardio vascular system for emergency action, it stimulates the breakdown
of liver glycogen into blood glucose, the fuel for anaerobic muscular work.
Vitamins
Vitamins are a group of organic compounds which
are required in very small amounts for the healthy growth
and functioning of animal organisms. They cannot be
made by organisms and so have to be supplied in the
diet. They are chemically different from the main nutrients-fats, carbohydrates and proteins. Vitamins A, D, E
and K are fat-soluble substances whereas Vitamin Bcomplex and Vitamin C are water soluble.
Biochemistry and Life Processes

There are a large number of living organisms around
us. Among these, man is the most adaptable species on
the earth.
Cells are the smallest unit of living organisms with
their independent existence. Cell needs food and energy
to work. Besides other parts cells have chromosomes
and genetic code are encoded on the chromosomes.
These genetic codes are responsible for all characters of
living organisms. One of the most important factors for
deciding the natural selection to take place is mutation
that is due to spontaneous changes in an organisms
genes encoded in cells. These genetic codes are made up
of deoxy-ribonucleic acid (DNA). It controls the manufacturing and functioning of proteins in animal systems. Ribonucleic acids (RNA) are the replicas of DNA
and pass into the cytoplasm where proteins are formed.
The genetic code transmits inherited characteristics from
generation to generation.
Mutation or Genetic Engineering: These are the processes in which the sequence of bases in the chemical
constitution of the DNA in the chromosomes is changed.
This results in the synthesis of different proteins which
are more useful and stable. This principle gives a basic
foundation for biotechnology. Biotechnology helps us
to use natural resources and our environment in a better, healthier, more efficient and economic way by the
feron. Interferon causes the synthesis of several enzymes like protein Kinase and phosphodiesterase
which inhibit viral replication by destroying mRNA
and protein synthesis. There are no side effects of
interferon. It is used for treatment of common cold,
influenza, hepatitis, etc. It shows promise as a cure
for bone cancer, skin cancer, breast cancer and leukaemia.
iii. Hormonal Production: Two hormones-somatostatin (hypothalamic hormone) and Somatotropin (human growth hormone) have been successfully
synthesised using biotechnological techniques like
recombinant DNA technology and gene cloning. By
this production we can do the treatment of abnormal growth related diseases.
iv. Tissue Plasminogen Factor: Biotechnology provides
tissue plasminogen factor which is used to dissolve
unwanted blood clots.
v. Blood Clotting Factor VIII: It is an important biotechnology product which is used for the treatment
of haemophilia.
vi. Vaccines: There are many productions of vaccines
from biotechnology method which are used in curing various infective diseases.
Polymers
'Poly' means many and 'mer' means unit. Thus a
polymer is a large but single chain-like molecule in
which the repeating units derived from small molecules
called monomers are covalently linked. The process by
which monomers are transferred into a polymer is called
Polymerization. For example, Polyethylene is obtained
from its monomer ethylene as a result of Polymerization. Here the repeat unit is derived from the monomer
ethylene.
n CH2 = CH2 (-CH2-CH2-)n
ethylene
Polyethylene
applications of organic chemistry, biology and industrial engineering. From biotechnology we get medicines,
hormones and several other useful things. As for example Bacteria and other microorganisms can be genetically engineered to carry out intricate steps in important processes in chemicals and food industry. In
the field of agriculture, genetic engineering holds a great
promise for increasing the crop field and quality by
making them resistant to certain diseases.
Applications of Biotechnology
i.
Insulin Production: Insulin is an important hormone which regulates the amount of glucose. So it is
an animal protein. It is used as an antidiabetic drug.
This hormone is secreted by Pancreas. By biotechnological method it is possible to prepare and link a
synthetic gene, responsible for synthesis of insulin,
to a plasmid of E. Coli. After genetic expression and
translation of mRNA into proteins, insulin is obtained.
ii.
Interferon Production: Interferon is an antiviral

agent. It inhibits viruses. Interferons are glycoproteins. They may be classified into three types (on the
basis of Physiochemical and antigenic properties)
designed as a -interferon, b - interferon andg -inter[64]
In certain polymers repeat units can be different like

nylon-66, carbohydrates and proteins.
Monomer
Ethylene
Propylene
Butadiene
Tetrafluoro
Teflon
Vinyl chloride
=
Adipic acid and CH3
Hexamethylene Diamine
Phenol and formaldehyde
Terephthalic acid
and ethylene glycol
Polymer
Polyethylene
Polypropylene
Polybutadiene
Polytetrafluoroethylene
(Teffon)
Polyvinyl chloride (PVC)
CH CH2)
Nylon-66
Bakelite
Polyester (Terylene)
Polymers may be made from both inorganic and

organic molecules. Examples of inorganic polymers are
metaphosphoric acid (HPO3)n, silicates and silicones.
Examples of organic polymers are mostly synthetic polymers which contain thousands of monomer units having very high molecular mass and thus are often called
macromolecules.
Classification of Polymers
Polymers can be broadly divided into two classes
Natural Polymers and Synthetic Polymers.
Natural Polymers: Polymers derived from nature
mostly from plants and animals are natural polymers.
Starch, cellulose and other polysaccharides, proteins,
nucleic acids and natural rubber are examples of this
type.
Starches are Polymers of glucose, i.e. Starch molecules consist of many hundreds of glucose molecules
joined together. Cellulose is also a polymer of glucose.
Protein is a polymer of amino-acids. Natural rubber is
polymer which consists of repeat units of hydrocarbons
2-methyl 1-1, 3-butadiene (isoprene)
C
n CH2 = | CH = CH2
CH3
Isoprene
condensation polyerization. Polymers have been classified into two main groups based on these modes of
synthesis as
i. Addition Polymers
Condensation Polymers
Addition Polymerization: It involves the repeated

addition of monomers to the polymer chain. Addition
polymers have the same empirical formula as their monomers. Examples are polythene, natural rubber and synthetic rubber neoprene.
Condensation Polymerization: It involves condensation reaction between two monomers which have two
functional groups following the removal of water. Examples are nylon, terylene, alkyne resins, bakelite.
Plastics: Most plastics are made from polymeric synthetic resins, although a few are based on natural substances (e.g. cellulose derivatives or shellac). Plastics
can be shaped by applying heat or pressure. They fall
into two main classes:
i.
Polyisoprene
(naturalrubber)
Natural rubber is a thermoplastic but when mixed

with sulphur and then heated gives a certain shape. This
is known as Vulcanisation. Vulcanisation makes the
rubber hard, strong, more elastic, causes it to lose its
sticky qualities and greatly increases the abrasion resistance of natural rubber. Rubber is a soft material which
can be hardened by adding carbon black to it. Hardened
rubber is used for making tubes, tyres and conveyor belts.
Synthetic Polymers
These polymers are synthesized by man in laboratory or factory. Most of the synthetic polymers are longchain organic molecules containing thousands of monomer units. The names of many of these polymers are
known to most of us. Some of them are polyethylene,
polystyrene, polyvinyl chloride, bakelite, nylon, dacron,
neoprene and thiokol.
Classification based on Synthesis:There are two
modes of polymerization addition polymerization and
[65]
ii.
(CH2 |
Thermoplastic Materials: These materials can be

repeatedly softened by heating and hardened again
on cooling. Polyethylene and Polystyrene, Polyvinyl Chloride, nylon and terylene are examples.
ii.
Thermosetting Materials: These are initially soft,

but change irreversibly to a hard rigid form on heating. Bakelite and melamine are examples.
Different Polymers and their monomers are described
as here:
Uses of Some Polymers

i.
Polyethylene is used as packing films, containers

and bottles, for moulding articles and as electrical
insulators.
ii.
Polypropylene is used in packing of textiles and

foods, liners for bags and heat shrinkable wraps for
records and other articles.

iii. Polystyrene is used for hot-drink cups, toys, household articles, etc.
iv. Polymethylmethacrylate is useful for lenses, transport domes and skylights, dentures, aircraft windows and protective coatings.
v. Teflon is used as a material resistant against heat
and chemical attacks. It is also used for coating
articles and cookware to make them non-sticky.
vi. Polyvinyl chloride is used in the manufacturing of
raincoats, hand bags, plastic dolls, curtain clothes
and vinyl flooring. It is also used as a good insulating material in wires and other electrical goods.
vii. Soft bakelites are used as bonding glue for lami-
nated wooden plants and in varnishes and lacquers. Hard bakelite is used for making combs, fountain-pen barrels, phonograph records, electrical
goods, formica table-tops and many other products.
Sulphonated bakelites are used as ion-exchange resins.
Natural Fibres: These type of fibres are used in making fibres. Cotton, wool and silk are examples; in which
cotton is a cellulose fibre, wool and silk are protein
fibres.
Synthetic Fibres: These are man-made fibres. Synthetic fibres are found in two types
i.
made from natural raw material, e.g. rayon.
ii.
not requiring any natural raw materials which are

pure synthetic. Examples- nylon and terylene.
Rayon: It is a textile made from cellulose. It is made

from wood pulp. Two types of rayons are found
i.viscose rayon
ii.
i.nylon 6
nylons and polyesters. Aniline yellow and malachite green belong to this class of dyes.
c. Direct Dyes: These dyes are thus useful for cotton,
rayon, wool, silk and nylon. The examples are
Martius yellow and Congo red.
d.
Disperse Dyes: This class of dyes is used for polyesters, nylon and polyacrylonitrile. Martius yellow,
Naphthol yellow, Congo red are examples.
e.
Fibre reactive Dyes: These dyes are useful for cotton wool or silk.
f.
Azodyes: These dyes are derived by coupling of a

phenol or naphthol adsorbed on the surface of a
fabric with a diazonium salt. Cotton, silk, polyster
and nylon can be dyed by this method.
g. Vat Dyes: They can be applied to the fabrics. Indigo

is a typical example of a vat dye.
h. Mordant Dyes: These dyes are used primarily for
wool and are applied to the fabrics after treating it
with a metal ion. Depending upon the metal ion
used, the same dye can give different colours. Thus,
alizarin gives a rose red colour with aluminium
and a blue colour with barium.
Petroleum and its Products

Petroleum word is formed from two words (Petrarock, oleum-oil), which means Petroleum is rock oil. It is
a mixture of hydrocarbons. Petroleum is formed from
the fossils of marine animals and plants which were
piled up on the sea bottom a long time ago. With the
passage of time sand and mud covered them. Under
high pressure these together were converted into rocks,
whereas animal and plant fossils were converted into a
dark liquid trapped in the pores of the rocks. Petroleum
gas is found in the same rocks as coal and oil. It, too, was
formed from the half-decayed remains of plants, animals and bacteria. Gas is often only found in small
amounts, because it can easily leak away through tiny
nylon 6, 6
iii.
nylon 6, 10
Nylon is used in the making of high strength fibres

like fishing nets, ropes, parachute fabrics and tyre-cord.
Dyes
Dyes are coloured compounds used to impart colour
to the textiles like silk, wool, food stuffs, etc.
India has a rich tradition in dyes and coloured fabrics. Probably the earliest known dyes were indigo (a
blue dye) and alizarin (a red dye). These were obtained
from plants. Indigo was primarily produced in India
and exported all over the world.
Nowadays, a large number of synthetic dyes are
being manufactured.
Classification
acetate rayon.
Rayon is used for making textiles, tyre-cord, carpets

and surgical dressings.
Nylon: It is a synthetic polyamide fibre having a
protein-like structure formed by the condensation between an amino group of one molecule and a carboxylic
acid group of another. There are three main nylon fibres
ii.
Dyes may be classified on the basis of their applications:

a.
Acid Dyes: Orange-I is example of acid dyes. Acid

dyes can be applied to wool, silk and nylon but not
to cotton.
b.
Basic Dyes: These dyes are used to dye modified

[66]
spaces in rocks.
Mineral crude oil is a mixture of liquids, solids and
gases dissolved in the liquid. The mixture of chemicals
is separated or refined using fractional distillation. The
different components separate because they have different boiling points.
Use of Petroleum Products: In modern technology
various substances like plastics (Polythene, Polyvinyl
chloride, Polystyrene, all the synthetic fibres like nylon,
terylene) acetate, glues, paints, dyes, drugs, cosmetics
are manufactured from oil in the petrochemical industry.
a. Gaseous Hydrocarbons: Molecular composition of
these hydrocarbons is C1 to C4. It is used as industrial or domestic fuel.
[67]
b.
Petroleum Ether: It is used in perfumes and dry

cleaning clothes
c.
Diesel oil or Gas Oil: Molecular composition of

Diesel oil is C15 to C18. It is used as furnace fuel and
diesel engine fuel.
d. Gasoline or Petrol: Its molecular composition is C5
to C12. It is used as a motor fuel, as a solvent, for dry
cleaning and for making Petrol gas.
e. Kerosene: Its molecular composition is C12 to C16. It
is used in lamps, burners (Stoves) and also turbojet
aircraft.
f.
Lubricating oils, Greases, Vaseline and Paraffin

Wax: The molecular composition of these products
is C16 to C50. Lubricating oil is used for lubrication.
Vaseline is used for making toilet goods, grease and
different cosmetic goods. Paraffin wax is used for
making candles and Paraffin wax is a major constituent of many ointments and cosmetics.
g.
Asphalt and Coke: These are semisolid or solid

residues. These are used for roofing, road building,
making underground cables, battery boxes, electrodes and fuels.
Octane Numbers: Quality of petrol is determined by
their anti-knock properties. The anti-knock properties
are measured by the values of their octane numbers.
Higher the octane number, higher the quality of petrol.
i.
ii.
Liquefied petroleum gas (L.P.G): It is mainly a mixture of propane and butane and is used in homes for
cooking.
Water gas: CO + H2
iii. Producer gas (N2 + CO)

iv. Semi-water gas
v. Coal gas: Mixture of hydrogen, methane, ethylene,
carbon monoxide, nitrogen, oxygen and carbon dioxide.
vi. Natural gas: CH4-methane (~75%) + ethane(~10%)
Propane (~7%) and butane (~2%)
Rocket Fuels: Rocket propulsion requires fuels that
are known as Rocket fuels. Some important rocket
fuels are liquid ammonia, alcohol, hydrazine, paraffin,
liquid hydrogen and kerosene oil. It is a combination of
oxidising agents like liquid oxygen, liquid fluorine, hydrogen peroxide or nitric acid. These fuels liberate a
huge amount of hot gases which pass through the nozzle
of the rocket motor and provide the necessary thrust for
the rocket to move forward according to Newtons Third
law of motion.
Rocket propellants are classified on the basis of their
physical state into three types:
1. Solid propellants: These are a mixture of a solid
hydrocarbon and an oxidising agent. A mixture of
paraffin with potassium nitrate is a suitable example in which paraffin is the solid hydrocarbon
and potassium nitrate is the oxidizing agent.
There are two types of solid propellants:
i.
Composite Propellants: Polybutadiene and acrylic

acid are solid fuels in which aluminium perchlorate, nitrate or chlorate are used as oxidising agents.
In composite propellants magnesium or aluminium
is used to burn solid propellants.
Tetraethyl lead is mixed with Petrol to increase the

octane number. The highest octane number is 100.
Fuels: Fuels are those substances which produce
heat energy on combustion without producing undesirable wastes. Quality of fuels depends upon the carbon
or hydrogen content (or both) of the fuel. Calorific values measure the amount of heat generated. Higher the
calorific value the better is the quality of the fuel. Calorific value is the amount of heat produced by burning
one gram of that fuel.
1 calorie = 4.1868 Joules
There are three types of fuels:
Solid Fuels: These fuels contain carbon having solid
form. On combustion it forms carbon dioxide and carbon monoxide with a large amount of heat. Wood, coal
and coke, charcoal, wax, etc. are examples.
Liquid Fuels: These fuels are obtained by fractional
distillation of Petroleum. It produces a huge amount of
heat evolving carbon dioxide and water. Kerosene oil,
Petrol, Diesel, Alcohol and liquefied hydrogen are the
examples of liquid fuels.
Gaseous Fuels: These fuels produce a huge amount
of energy and do not leave ash on burning. The examples of gaseous fuels are given below:

ii.
Double base Propellant: These types of solid propellants consist of nitroglycerine and nitrocellulose.
2. Liquid Propellants: Alcohol, liquid hydrogen, liquid ammonia, kerosene oil, hydrozines, hydrides of
boron, methyl nitrate, nitromethane, hydrogen peroxide, etc. are liquid propellants. Liquid oxygen,
liquid fluorine hydrogen peroxide and nitric acid
are used as oxidising agents.
3. Hybrid Propellants: These type of propellants consist of a solid fuel and a liquid oxidising agent. N2O4
and acrylic rubber are common examples in the use
of rocket propellants.
i.
Saturn booster rocket used in the American Space

Programme derives its thrust from a combination of
kerosene and liquid oxygen as the propellant for the

initial stage and liquid oxygen and liquid hydrogen
for the upper stages.
ii.
The Titan Ballistic Missiles uses hydrazine (fuel)

and nitrogen tetroxide (oxidising agent).
iii. The space shuttle uses liquid hydrogen, liquid oxygen along with solid boosters in the lower stages.
iv. The Russian rockets such as PROTON generally
use a liquid propellant consisting of kerosene and
liquid oxygen.
v.
In the Indian scenario, the SLV-3 and ASLV rocket

use composite solid propellants. The PSLV- rocket
which is still in the experimental stage, will use a
solid propellant in the first and third stages while
the second and fourth stages will use liquid propellants consisting of N2O4 and unsymmetrical dimethyl-hydrazine (UDMH) and N2O4 and
monomethyl-hydrazine (MMH), respectively.
Fire Extinguishers
Any combustible substance catches fire if some required conditions are made available to it. Such conditions are ignition temperature (i.e. lowest temperature at
which a substance catches fire), heat, supporter of combustion and combustible substance. If any of these con-
Some Important Matters

LPG: It is liquefied petroleum gas. It is used as domestic fuel for cooking. It is supplied through cylinder
by filling LPG at high pressure and low temperature in
liquid form.
Thus fuel supplied in gas cylinders contains a mixture of liquified butane and iso-butane under pressure.
The fuel in LPG is highly combustible and forms an
explosive mixture with air so any type of carelessness
can damage it. Ethyl mercaptan is added to LPG for
detecting strong smell on leakage of gas.
Glass: Glasses are often regarded as supercooled
liquids. It is a mixture of sodium silicate (Na2SiO3),
calcium silicate (CaSiO3. and silica (SiO2).
Soda Glass: It is made by heating a mixture of lime
(calcium oxide), Soda (Sodium carbonate) and sand
(silicon oxide). It is a form of calcium silicate. This glass
is used in windows, bottles, etc.
Pyrex: It is a borosilicate glass. It is made by incorporating some boron oxide, so that silicon atoms are replaced by boron atoms. They are tougher than soda
glass and more resistant to temperature changes, hence
their use in cooking utensils and laboratory apparatus.
Glasses for special purposes (e.g. optical glass) have
other elements added e.g. (barium, lead).
ditions is removed burning stops. Hence to extinguish

the fire a device is used that is known as the fire extinguisher. For an extinguisher it must be one that uses
carbon dioxide.
Electrical Fire Extinguisher: In extinguishing the
fire caused by electricity, carbon tetrachloride is used,
because vapours of carbon tetrachloride are heavier
than air, so they settle down on the burning material
and cut off the air supply. Here carbon dioxide and dry
sand may also be used.
Soda-acid Extinguisher: Here water is the main extinguishing agent but carbon dioxide is also used because it is denser than air and does not support combustion. Soda-acid extinguishers principle is based on
cooling down the temperature of the burning substance
below the ignition temperature.
Foam Extinguisher: Water is not used in extinguishing the burning oil because water is heavier than oil or
petrol so oil floats on water and burns fire but if carbon
dioxide, sand or soil are used then foam-type fire is
stopped by cutting off air supply.
Water as Fire Extinguisher: Water is used as a fire
extinguisher except fire caused by burning oil or by
electricity. It extinguishes the fire by cooling down the
burning substance below the ignition temperature.
[68]
Cement: It is used for bonding or setting to a hard

material. Portland cement is a mixture of calcium silicates and aluminates made by heating limestone
(CaCO3) with clay (containing aluminosilicates) in a
kiln. The product is ground to a fine powder. When
mixed with water it solidify in a few hours and then
hardens over a longer period of time due to the formation of hydrated aluminates and silicates. Cement is
used in various forms such as mortar, concrete or reinforced cement concrete.
Soap: It is made by boiling natural oils and fats with
caustic soda (NaOH) or caustic potash (KOH) or Na2CO3
by saponification. Potassium hydroxide gives a more
liquid product (soft soap).
Soaps produce sufficient lather with soft water. This
lather emulsifies oily or greasy material and absorbs
dirt particles which are removed along with water.
Detergents: Detergents are synthetic organic chemical substances. Their cleansing properties are better
than those of soaps. Detergents are compounds that
cause non-polar substances like grease and natural oils,
to go into solution in water. Detergents are made from
hydrocarbons obtained from coal or petroleum. There
are 15-30% detergents in washing powders by weight.
The rest is made of other chemicals.
CHRONICLE
CHEMISTRY AT A GLANCE
[69]
NH4NO3
SiO2 3C
N2O 2H2O
IAS ACADEMY
SiC 2CO
Solid CO2 is called dry ice. It is soft, white snow like

substance. It is used as a refrigerant under the name
drikold.
SiC is known as carborundum. It is manufactured as :
2000 2500C
It is extermely hard, as hard as diamond.

l
l
Butter of tin, SnCl4, 5H2O and pink salt, (NH4)2 SnCl6

are used as mordant in dyeing.
Portland cement got its name because of its resemblance with the famous Portland rock of England.
Its main constituent is calcium oxide and other
constitutents are SiO2, Al2O3, MgO, Fe2O3, SO3,
Na2O, etc.
CO2 is used with ether or acetone as refrigerant.
A mixture of 95% of oxygen and 5% carbon dioxide

(called Carbogen) helps in the artificial respiration.
Kr also forms KrF2.
Noble gases form a number of compounds in which

the gases are trapped within the crystal latties of
certain organic or inorganic substances. These substance are called clathrates. For example clathrates of
Ar, Xe, Kr in -quinol.
He and Ne do not form clathrate compounds.
Neon lamps are used in botanical gardens and in

green houses because it stimulates growth and is
effective in the formation of chlorophyll.
A mixture of 20% oxygen and 80%. It is used by

divers for respiration.
Neil Bartlett prepared the first noble gas compound,

XePtF6.
HF dissolves XeF6 forming highly conducting solution :
XeF6 HF XeF HF2

l
Kr and Xe are used in filling incandescent metal

filament electric bulbs.
Radon is used in treatment of cancer (radiotherapy).
N2O is called laughing gas. When inhaled in small

quantities, it causes hysterical laughter. In small
amounts, it acts as an anaesthetic for minor operations. It can be prepared by heating ammonium nitrate.
milk of lime.
Lime water is clear solution of calcium hydroxide.
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Sodium metal can be easily cut with a knife. Its surface when freshly cut is very shining.
A mixture of Na2CO3 and K2CO3 is called fusion

mixture.
28% NaCl solution is called brine solution.
NaOH + CaO is called soda lime.
K-40 is radioactive and emits rays.
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Sodium hydroxide is used in textile industry for

mercerising cotton fabrics.
Sylvinite is a mixture of NaCl and KCl.
We cannot store sodium in water.
Mg(OH)2 is called milk of magnesia.
MgCl2. 5MgO. xH2O is called magnesia cement or

Sorel cement.
Magnesium is present in chlorophyll, which is

widely distributed in plants.
Heat
HN3 is called hydrazoic acid.
HNO3 attacks proteins giving a yellow nitro compound called xanthro protein. Therefore, HNO3 stains
the skin and renders wood yellow.
Radioactive Phosphorus (P-32) is used for treatment
of leukemia (blood cancer).
Phosphine is used for preparing Holmes signals for
ships to know about the position of the rocks in the
sea.
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Phosphine is used to prepare smoke screens in warfare. Calcium phosphide reacts with water to form
phosphine which burns to give smoke.
Mixture of CaCN2 and coke is called nitrolium and is

used as a nitrogenous fertilizer.
BiClO (Bismuth oxychloride) is called Pearl white.
Suspension of calcium hydroxide in water is called
[70]
A suspension of hydroxide of magnesium is called

milk of magnesia and is used as stomach antacid.
Dolomite is an ore which contains both Ca and Mg.
Colloidal solution of gold is called purple of Cassuis.
Copper, silver and gold are called coinage metals.
Bordeaux mixture is CuSO4 solution + lime. It is used
100 75%
as fungicide.
Nesslers Reagent: K2HgI4- used for detecting NH4+

ions.
Nitrolim: Calcium cyanamide + graphite- used as

fertilizer.
Superphosphate: Calcium dihydrogen phosphate +
FeSO4 is used in the manufacture of blue black ink.
AgNO3 is called lunar caustic.
Silver is best conductor of heat and electricity.
CuSO4.5H2O is called blue vitriol or Nila thotha
FeS2 is called fools gold.
Pure gold is very soft and cannot be used as such for

jewellery. Therefore, it is generally alloyed with other
metals commonly copper or silver to make it harder
and modify its colour. The purity of gold is expressed
as carats. Pure gold is of 24 carat. A 18 carat gold
means that it contains 18 parts of gold in 24 parts by
weight of alloy.
Therefore percentage of gold in 18 carat gold.
18
24
Most of the jewellery is made of 22 carat gold.
Reagents or Mixtures
l
Schweizer Reagent: It is tetraamminediacquacopper dihydroxide which is used for production of cellulose products like rayon and cellophane.
Bordeaux Mixture: CuSO4 solution + lime - used to

kill moulds and fungi on wines.
Soda Bleach: A mixture of Na2O2 and dil. HCl- used

for bleaching of delicate fibres like wool, silk, etc.
Soda Lime: A mixture of Ca(OH)2 + NaOH - used as

an absorbent for a number of gases, and in decarboxylation of sodium salts of fatty acids.
Fusion Mixture: A mixture of Na2CO3 + K2CO3- used

as laboratory reagent.
Lithopone: A mixture of ZnS + BaSO4 - used as white

paint.
Carbogen: A mixture of O2 and 5 -10% CO2 - used for

artificial respiration.
Physical Properties of Some Gases
CaSO4- used as fertilizer.

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Thomas Slag: Tricalcium phosphate + cal. silicate fertilizer.
Baeyers Reagent: Cold alkaline KMnO4 solution used for detecting olefinic and acetylenic linkages.
Molisch Reagent: -Naphthol dissolved in alcoholused for detecting carbohydrates.
Lindlar Catalyst: Palladised charcoal deactivated

with sulphur compounds- partial hydrogenation of
tripe bond to double bond.
Hydrogen, H2: Colourless, odourless, tasteless, lightest gas, sparingly soluble is water, combustible and
burns in air or oxygen with nearly invisible pale
blue flame, neutral, can be liquefied and solidified.
Carbon Monoxide, CO: Colourless, faint odour,

tasteless, as heavy as air, very sparingly soluble in
water, burns in air with blue flame, neutral, poisonous.
Carbon Dioxide, CO2: Colourless, faint, pungent

smell, heavier than air (1.5 times) and can be poured
downward like water, fairly soluble in water. Acidic,
non-poisonous, can be liquefied and solidified.
Milk of Magnesia: Suspension of Mg(OH)2 in waterused as antacid.
Gun Powder: A mixture of S, charcoal and KNO3used as explosive.
Purple of Cassius: Colloidal particles of gold absorbed by colloidal precipitate of stannic acid-used
for colouring glass (rubby red) and pottery.
Nitrogen N2: Colourless, odourless, tasteless,

slightly lighter than air, slightly soluble in water,
non-posionous, can be liquefied.
Nitrogen Oxide, N2O (laughing gas): Colourless,

faint pungent smell, fairly soluble in cold water but
not in hot water, heavier than air, poisonous.
Nitric Oxide, NO: Colourless, slightly heavier than

air, sparingly soluble in water, paramagnetic, neutral, can be liquefied with great difficulty.
Dinitrogen Trioxide:Nitrousanhydride;N2O3.Reddish
brown gas which on cooling gives a deep blue liquid.
Lucas Reagent: A mixture of conc. HCl and anhy.

ZnCl2- used for distinguishing three types of alcohols.
Rectified Spirit: 93-95% ethanol.
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Methylated Spirit: (Denatured alcohol). Rectified

spirit + CH3OH, pyridine, acetone, etc.
Power Alcohol: 4 parts petrol + 1 part alcohol.
[71]
Nitrogen Dioxide, NO2: Reddish brown gas, paramagnetic.
Nitrogen Tetroxide, N2O4: Colourless solid (exists

below 10C), diamagnetic.
Ammonia, NH3: Colourless, characteristic pungent

smell, lighter than air, extremely soluble in water,
brings tears in eyes, basic in nature, can be liquefied
and solidified.
Permutit, Ion Exchange Resins and Calgon: For

removing permanent hardness of H2O.
Oxygen, O2: Colourless, odourless, tasteless, slightly

heavierthanair,slightlysolubleinwater,canbeliquefied
andsolidified,non-inflammable,paramagnetic.
Heavy Water (D2O): A moderator in nuclear reactor.
Hydrogen Peroxide: Bleaching agent, restoring

colour of lead painting blackened by H2S, antiseptic, germicide, propellant or fuel in rockets, etc.
Sodium Metal: Preparation of TEL, sodium amalgam, in sodium vapour lamp, heat transfer medium
in nuclear reactors, Na-K alloy (liquid at room tem-
Ozone, O3: Pale-blue fishy smell, heavier than air,

slightly soluble in water, poisonous due to its destructive action on tissues, can be liquefied, turns
starch iodide paper blue, Hg loses its meniscus in
contact with O3.
Hydrogen Sulphide, H2S: Colourless, smell of rotten eggs, soluble in water, poisonous.
Sulphur Dioxide, SO2: Colourless pungent and suffocating odour, heavier than air, soluble in water,
pisonous, can be liquefied and solidified.
Chlorine, Cl2: Greenish-yellow, suffocating smell,

heavier (2.5 times) than air, fairly soluble in water,
poisonous, can be liquefied.
Bromine, Br2: Reddish brown, heavier than air,

highly soluble in water, poisonous, turns starch
paper yellow.
Iodine, I2: Violet, sparingly soluble in water.
Hydrogen Halides, HX: Colourless, pungent smelling, acidic taste, fairly soluble in water, heavier than
air, can be liquefied.
Some Important Mixture of Gases: Water gas (CO

+ H2)- used for the production of H2 and as a fuel.
Producer gas (CO + N2 + little CO2) used as fuel gas.
Some Gases used in Warfare: Phosgene (COCl2),

mustard gas (ClC2H4-S-C2H4Cl), tear gas (CCl3 NO2),
lewisite (CHCl = CHAsCl2).
Important Compounds
(RMgX) used in organic chemistry, as a fuse in

aluminothermic process, a source of light in photography.
perature) is used in high temperature thermometers

used for finding temperature above the b.p. of mercury.
l
Sodium Peroxide, Na2O2: Oxidising agent, source

of oxygen under the name of oxone, purification of
air, bleaching agent (soda bleach- Na2O2 + dil. HCl)
Sodium Hydroxide, NaOH: For mercerizing cotton
to make cloth unshrinkable.
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Sodium Carbonate, Washing Soda Na2CO3: In

laundries, manufacture of glass, fusion mixture
(Na2CO3 + K2CO3)
Sodium Bicarbonate, Baking Soda, NaHCO3:

Preparation of baking powder, sieditz powder, effervescent drinks and furit salts, in fire extinguishers, as antacid.
Sodium Sulphate, Glaubers Salt. Na2SO4: 10H2O.

Craft paper, window glass, mild laxative.
Potassium Metal. Used in photoelectric cells.
Potassium Carbonate. K2CO3: Soft soap, hard glass,

fusion mixture, washing wool.
Potassium Bicarbonate, KHCO3: Used in medicine

and baking powder.
Potassium Sulphate, K2SO4: As fertilizer, in potash alum and glass, as a purgative in medicines.
Magnesium Metal: Preparation of Grignard reagent
chalk in paints and distempers and in the production of CO2; as precipitated chalk in tooth pastes
and powders, in medicines for indigestion.
l
Calcium Sulphate, CaSO4: Plaster of paris, cement,

ammonia, black board chalks, H2SO4 and ammonium sulphate.
Copper Metal: Electrical wires, cables, calorimeters.

For electroplating and electrotyping, coinage metal,
in ornaments and jewellery.
Copper Sulphate, CuSO4.5H2O: in Bordeaux mixture, electroplating, electrotyping, dyeing,

calicoprinting, detecting moisture, preparing
Fehling solution, as insecticide.
Silver Metal: In coins ornaments, filling teeth (silver-alloy), medicines, silver plating.
Lunar Caustic, AgNO3: In making inks and hair

dyes, silvering of mirrors, as a caustic in surgery.
AgX (except Agl) are used in photography.
Zinc Metal: In galvinisation, desilverisation of lead,
precipitation of Ag and Au (cyanide process) reducing agent (Zn dust).
Zinc White, ZnO: As white pigment under the name
of zinc white or chinese white, as zinc ointment as
filler in rubber industry, white shoe polish.
Zinc Sulphide, ZnS: In lithopone, X-ray screens
and in luminous paint of the dials of watches.
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Alumina, Al2O3: As a refractory material, cement

(bauxite + lime), abrasive, for preparing artificial
gems, in chromatography.
Aluminium Chloride, AlCl3: In Friedel-Craft reaction to prepare synthetic polymers like polythene.
Alum, K2SO4.Al2 (SO4)3.24H2O: In purification of

water, tanning of leather, as mordant in dyeing, as a
styptic to arrest bleeding, for sizing of paper.
Carbon Monoxide, CO: Production of water gas
and producer gas, in extraction of iron and nickel,
Magnesia, MgO: As antacid, as refractory lining, as

basic lining, as insulator, rubber, filler, Sorels cement (MgCl2. 5MgOxH2O) used in filling teeth and
as a substitute for tiles.
Magnesia Alba (MgCO3)x [mg(OH)z]y.ZH2O: In

medicines as an antacid, laxative and in teeth powders and pastes and in silver polishes.
Magnesium Carbonate: Refractory material, filler

for rubber and paper.
Magnesium Sulphate: Purgative, fire-proof fabrics,

filler in paper.
Quick Lime, CaO: Bleaching powder, slaked lime,

lime colours, cement and calcium carbide, purification of sugar and coal gas, softening of water, as
basic lining.
Slaked Lime, Ca (OH)2: Bleaching powder, caustic

soda and soda lime, white washing, softening of
water.
Calcium Carbonate, CaCO3: Used as limestone for

the manufacture of lime and as a flux : as marble for
building purposes and in the production of CO2; as
[72]
reducing agent.
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Carbon Dioxide, CO2: As a fire extinguisher, refrigerant (as dry ice), for artificial respiration (as
carbogen), manufacture of aerated water, white lead
and Na2CO3 (Solvay process).
Tin Metal: Tin foil is used for wrapping cigarettes,
confectionery and for making tooth paste tubes.
Stannous Chloride: Mordant in dyeing (under the

name of tin salt), for preparing purple of cassius, as
a reducing agent.
Butter of Tin (Oxymuriate of tin), SnCl4.5H2O: Mordant
Pink Salt, (NH4)2SnCl6: Mordant
Litharge, PbO: (buff coloured crystalline variety).

For making lead glass, paints and varnishes; in
glazing pottery.
ticles.
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Ammonia, NH3: In making HNO3, NaHCO3,

(NH4)2SO4 and amm. calcium sulphate (both fertilizers), NH4NO3 (explosive), artificial silk; as a cleaning agent for removing grease in dry cleaning.
Massicot, PbO (yellow powder): When mixed with

glycerine, it is used as a cement for glass and stone.
Lead Peroxide, PbO2: In storage batteries, in match

industry, oxidising agent in laboratory.
Phosphrous: Red P in match industry, white as rat

poison.
Trilead, Minium, Red Lead, Pb3O4: In paint, silver

mirrors, lead glass (flint glass), matches and
oxidising agent.
Basic Lead Carbonate, White Lead, 2PbCO3. Pb
(OH)2: White paint.
Phosphorus Pentoxide, P2O5: Dehydrating agent.
Calcium Ammonium Nitrate (CAN): Nitrogenous

fertilizer.
Oxygen, O2: Oxygen + CO2 or O2 + He for artificial

respiration; liquid O2 + finely divided C as a substitute of dynamite; liquid O2 as rocket fuel; oxy-hydrogen and oxy-acetylene flames are used for cutting
and welding purposes.
Ozone, O3: As sterilising agent for water, for improving the atmosphere of crowded places, mild
bleaching agent, for detecting the position of double
bond, for preparing KMnO4 from K2MnO4, artificial
silk and synthetic camphor.
Sulphur: In match industry and fireworks, vulcanization of rubber, disinfectant for houses, skin medicines and in preparing sulphur dyes.
Hydrogen Sulphide, H2S: Reducing agent, laboratory reagent.
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Nitrous Oxide, Laughing Gas, N2O: As propellent

gas, anaesthetic.
Nitric Oxide, NO: Intermediate in HNO3 manufacture, catalyst in lead chamber, in detection of oxygen.
Nitrous Acid, HNO2: Used in preparation of azo

dyes.
Nitric Acid, HNO3: In making explosives (T.N.T.,

picric acid, nitroglycerine, dynamite and gun cotton), fertilizers (ammonium nitrate, calcium nitrate),
artificial silk, dyes, drugs, perfumes; in the purification of silver and gold; as a solvent for etching designs or names upon copper, brass and bronze ar-
[73]
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Sulphur Dioxide, SO2: Bleaching agent, antichlor,

solvent (liquid SO2).
Sulphur Trioxide, SO3: Manufacture of H2SO4,
oleum; for drying gases.
Carbon Black: In black paints, printers ink, as filler

in rubber.
Ethylene Bromide: Increase the efficiency of TEL.
Ethylene: General anaesthetic.
Acetylene: Illumination of hawkers lamps, artificial ripening of fruits.
Oil of Vitriol, H2SO4: In preparing dyes, fertilizers,

detergents, explosives, lead storage batteries, dehydrating agent, pickling agent.
Hypo, Na2S2O3.5H2O: Fixing agent in photography,

as an antichlor in volumetric analysis, in the extraction of Au and Ag from ores.
Westron and Westrosol: Solvents.
Chloroprene: In preparing polymerneoprene (a synthetic rubber).
Chlorine, Cl2: Bleaching agent, purification of drinking water, as germicide, as disinfectant in swimming pools, preparation of domestic antiseptic solution (NaOCl), bleaching powder, chlorates, DDT,
poisonous gases like COCl2, tear gas and mustard
gas.
Acrylonitrile, CH2 = CHCN: In preparing buna N

(synthetic rubber) and orlon (synthetic fibre).
Sodium and Potassium Bromides: Sedatives, AgBr

is used in photography.
Iodine, I2 and Kl are used in treating goitre; for

increasing production of eggs.
Bleaching Powder, CaOCl2: Bleaching agent,

sterilising drinking water, for making wool
unshrinkable.
Green Vitriol (Hara Kasis), FeSO4. 7H2O: Preparation of blue-black (writing) ink, as mordant in dyeing and tanning industries, as insecticide in organic analysis.
Ferric Oxide, Fe2O3: As a red pigment, as a polishing powder in jewellery, as a catalyst for the oxidation of CO to CO2.
2, 2, 4-Trimethlpentane (iso-octane), Increases the

anti-knock quality of petrol (gasoline).
Tetratethyl Lead (TEL), (C2H5)4Pb: Anti-knocking

agent.
solvent; for preparing Grignard reagent, in Wurtz

reaction.
Vinly Acetate, CH2 = CHOCOCH3: In plastic industry.
Vinly Chloride, CH2 = CHCl: In preparing polyvinyl chloride (PVC).
Phenacyl chloride, C6H5.CO.CH2Cl: Lachrymator

to disperse mobs.
Urotropine (Hexamethylene Tetramine): Urinary

antiseptic.
Gammexene, g-B.H.C: (g-benzene hexachloride).

Insecticide.
Chloroform: Anaesthetic, preparing chloropieren (insecticide) and chloretone (hypnotic), preservative for
anatomical specimens.
Iodoform: Antiseptic.
Formaldehyde: (40% solution is known as formalin). As a preservative for biological and anatomical
specimens, in preparation of urotropine, bakelite, in
silvering of mirror.
Freon-12, CCl2F2: As refrigerant and propellent.
Acetaldehyde Ammonia: A rubber accelerator.
Carbon tetrachloride, CCl4: Fire extinguisher

(pyrene), solvent, anthelmentic (elimination of hookworms), fumigant.
Paraldehyde, (CH2O)n: A hypnotic and sporofic.
Metaldehyde, (CH2O)3: Solid fuel in spirit lamp.
Acetone: For storing acetylene.
Chloretone: Hypnotic and sedative.
Formic Acid: In tanning for removing lime from

hides, as a reducing agent.
Acetic Anhydride: Acetylating agent; preparation

of dyes, acetate rayon, aspiring.
Ethyl Acetate: In perfumes, in skin diseases.
Aniline: In preparation of dyes and dye intermediates, accelerators, antioxidants, sulpha drugs.
Acetanilide: Antipyretic under the name of antifebrin.
Ethyl alcohol, C2H5OH: Beverages, solvent, antifreeze for automobile radiators, in apparatuses like
spirit levels, power alchol.
Phenol, C6H5OH: Antiseptic, preparing, salol

(intenstinal antiseptic,) aspirin (antipyretic and antiseptic). picric acid (explosive), phenolphthalein
(indicator), bakelite (a synthetic plastic, used in buttons, electric switches, etc.)
Ether: General anaesthetic, refrigerant, perfumes,
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CHEMISTRY
(SAMPLE QUESTIONS
)
1.
[74]
4.
Which of the following types of clothes is manu
factured by using petroleum products?

(a) Rayon Silk
2.
e-
(b)
Terelyne
(c)
Silk
(d)
Cotton
(b)
Sulphonation
(c)
Hydration
(d)
None of the above
3. Temporary hardness of water is due to t

he
presence of
(a) Chlorides of calcium and magnesium
(b)
Sulphates of calcium and sodium
Hydroxides of calcium and sodium
(d)
Bicarbonates of calcium and magnesium
The coil of an electric heater is made of

(a) Zinc
(b)
Brass
(c)
Copper
(d)
Nichrome
5. If water contracts on freezing which of t

he
following would happen?
(a) Icebergs will completely float on the su
rface of water.
Which chemical weathering process affects lim

stone the most?
(a) Oxidation
(c)
(b)
Ice would become more dense.
(c)
Lakes would freeze from top to bottom.
(d)
Rocks will crack due to freezing of intern
al
water.
6.
c
Mercury is commonly used as thermometri
fluid rather than water. This is because

(a) The specific heat of mercury is smaller tha
n
that of water.
CHRONICLE
potash feldspar?
(a) Bauxite
IAS ACADEMY
(b)
Calcite
(c)
Kaolin
(d)
Muscovite
LE Y
EM
IC
N AD
RO
AC
CH
S
IA
(b)
The density of mercury is greater than tha
9.
Lead pencils
(a) Contain lead
of water.
(c)
(b)
The specific heat of mercury is greater tha
(c)
that of water.
(d)
10.
-
water.
7.
(d)
Mecrury has greater visibility than that o
Calcium sulphate
(d)
Calcium chloride
8.
e
None of the above
phy is
(a) Silver chloride
(b)
Silver sulphide
(c)
Silver bromide
(d)
Silver oxide
Calcium carbonate and magnesium carbonate
(c)
Do not contain lead but graphite mixed

with a little of plastic clay
A light sensitive compound used in photogra
Chemical composition of pearls is

(a) Calcium carbonate
(b)
Contain copper
11.
Which one of the following is likely to be th
Alloys used in making airplane parts contain

(a) Zinc and aluminium
(b)
end product of the chemical weathering of
(d)
Copper and zinc
(c) Magnesium and zinc

Magnesium and aluminium
Chemistry
12.
Match the following:

(A) Lead
1.
Pitchblende
(B)
Aluminium
2.
Monazite
(C)
Thorium
3.
Bauxite
(D)
Uranium
4.
Galena
13.
ap
15.
lly
Silver bromide
(b)
Silver iodide
(c)
Silver nitrate
(d)
None of the above
Ripening of green fruits is hastened artificia
(a)
(b)
by using
(a) Acetylene
(c)
(b)
Methane
(d)
(c)
Sulphur dioxide
(d)
Carbon dioxide
Why does hard water not lather with the so
16.
profusely?
n
(a) Hard water contains sulphates and chl
o-
rides of magnesium and calcium which

form insoluble compounds with soap?
14.
a-
(a)
(b)
Hard water does not contain calcium
(c)
hard water does not contain chlorides
(d)
Hard water does not contain sulphates
Which of the following is used in photogr

phy?
17.
The heads of safety matches do not contai
(a)
Phosphrous
(b)
Sulphur
(c)
Antimony trisulphide
(d)
Potassium Chlorate
HCI is a stronger acid than CH 3 COOH b
ecause
(a) It contains less number of H atoms
(b)
It ionises completely to yield H+ions
(c)
(d)
It contains chlorine
18.
It does not contain oxygen
'Epsom Salt', a well known laxative, is che
mically named as
(a) Sodium chloride
19.
20.
21.
22.
23.
-
(b)
Sodium sulphate
(c)
Magnesium chloride
(d)
Magnesium sulphate
An alcohol will always contain

(a)
Oxygen, carbon and nitrogen
(b)
Carbon, hydrogen and oxygen
(c)
Nitrogen, hydrogen and oxygen
(d)
Hydrogen, oxygen and chlorine
Reduction is a reaction in which

(a)
There is loss of electrons
(b)
An atoms gains electrons
(c)
Transfer of negative valency takes place
(d)
Gain of negative valency takes place
An oil can be made fat by the process of

(a)
Hydrogenation
(b)
Hydrolysis
(c)
Oxidation
(d)
Saponification
The nucleus of deuterium contains

(a) One proton and one neutron
(b)
One proton and one electron
(c)
One neutron and one electron
(d)
Two protons
Which one of the following statements is incor

rect?
(a) A catalyst is highly specific in action
(b)
A catalyst alters the rates of the forwar
d
and backward reactions equally, in a reversible reaction
(c)
A catalyst is used in the course of the rea
ction
(d)
A catalyst remains unchanged at the en
d
of the chemical reaction
24.
m-
The element which has the same atomic nu

ber and atomic weight is
(a)
Hydrogen
(b)
Helium
25.
(c)
Oxygen
(d)
Nitrogen
Chemistry
I
Match the following :

I. Washing soda A. Sodium hydroxide
II.
Caustic soda
B.
Copper sulphate
III.
Blue vitriol
C.
Sodium thiosulphate
IV.
Hypo
D.
Sodium carbonate
II
III
IV
(a)
(b)
(c)
(d)
Chemistry
CHEMISTRY SAMPLE QUESTIONS

( ANSWERS)
CHRONICLE
IAS ACADEMY
Y
EEM
LC
NIA
C DA
RO
HC
S
AI
1 (b)
14 (a)
2 (c)
15 (a)
3 (d)
16 (a)
4 (d)
17 (b)
5 (b)
18 (d)
6 (d)
19 (b)
7 (a)
20 (b)
8 (c)
21 (a)
9 (c)
22 (a)
10 (c)
23 (d)
11 (d)
24 (a)
12 (d)
25 (a)
13 (a)
Chemistry

Chemistry

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CHEMISTRY

Add : D-108, Sec-2, Noida (U.P.), Pin - 201 301

A CIVIL SERVICES CHRONICLE INITIATIVE

Electron: The presence of electrons was discovered

(ii) Proton: The proton was observed by Goldstein in

(iii) Pi-mesons (Pions) and -mesons (muones) : These

Rutherfords Experiment - Atomic Model

Most of the -particles passed straight through

On the basis of the results of alpha -Scattering

Mass and positive charge of the atom are located

+ 1.60 1019 coulomb

Chronicle IAS Academy

The attractive force between the positively charged

The diagram of the experiment is shown below:

number of electrons in any energy level is 2n where n is

Bohr model of an atom

Rutherfords model, however, fails to explain the stability

(ii) Most part of the atom is empty.

Dual Nature of Electron

de-Broglie pointed out in 1924 that the electron have

(iv) Electrons move around the nucleus in an atom in

Heisenbergs Uncertainty Principle

Different energy levels in an atom

Distribution of Electrons in Different

Chronicle IAS Academy

It is not possible to determine exactly both position

The Heisenbergs concept introduces the concept of

has a valency of 1). It is equal to the ionic charge in ionic

or atomic mass (or atomic weights) are called isotopes of

Tritium 1H3 & T

Isotopes of oxygen- 8O16, 8O17, 8O18

Isotopes of chlorine - 17Cl35, 17Cl37

Isotopes of carbon - 6C12, 6C14

The atoms of different elements which have the same

Symbolic Representation of Isotopes

A Mass number (protons + neutrons)

X Symbol of the element

Since mass no. = Protons + Neutrons

16 is mass no. of oxygen atom

The atoms of different elements which have the same

Deuterium 1H2 - or D-heavy hydrogen

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gives orbitals and the shape of orbitals. The values

Spherical Dumb-bell Double dumb

for anticlockwise spin

(iv) Spin Quantum Number: It is denoted by s. It

Pauli Exclusion Principle : No two electrons in the

(iii) Magnetic Quantum Number: It is denoted by

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A CIVIL SERVICES CHRONICLE INITIATIVE

Matter and its Nature

(A) Physical Change : It is a temporary change and

water into ice, stretching a spring,

(B) Chemical Change : It is a permanent

ing the factors governing the change.)

Elements, Compounds and Mixtures

Elements are found in all forms of matter i.e. solid,

1. An element may be defined as the simplest form of

tine, Francium and all the elements with atomic

A compound may be defined as a substance formed

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4. Compounds, unlike mixture, cannot be separated

Distillation: On heating, a liquid is converted into

Fractional Distillation: When the boiling points of