11¢ Kanyakumari District Examination Second Mid Term Test, November - 2013 www.tnschools.co.in Standard 11 Time: 1.30 Hrs. CHEMISTRY Marks: 75 Part-I Answer all the questions. Choose and write the correct answer. 1) The most electronegative element of the periodic table is a) iodine b) fluorine —c) chlorine d) oxygen 2) The law of octaves was stated by a) Doberiner b) Mendeleev c) Moseley d) Newland 3) Electron affinity of noble gases are a) zero b) maximum c) minimum d) positive 4) The compound which contains both ionic and covalent nature is a) CH, b) H, c) KCN d) KCé 5). The crystal lattic of electrovalent compound is composed of . a) atom b) molecules c) oppositely charged ions d) both molecules and ions 6) The bond: angle in water molecule is a) 104.5° —b) 109°28' cc) 107° d) 90° 7) Which solution would possess the lowest boiling point a) 1% NaCé solution b) 1% urea solution c) 1% glucose solution d) 1% sucrose solution 8) The Van't Hoff factor of 0.005 M aqueous solution of KCé is 1.95. The degree of ionisation of KCé is a) 0,94 b) 0.95 c) 0.96 d) 0.59 9) Isotonic solutions are the solutions having the same a) Surface tension b) Vapour pressure c) Osmotic pressure d) Viscosity 10) The relative lowering of vapour pressure is equal to a) mole fraction of solvent b) number of moles of solute c) number of moles of solvent d) mole fraction of solute1ic 11) 12) 13) 14) 15) .16) Note: 17) _ 18) 19) 20) 21) 22) 23) 24) 25) 26) 27) www.tnschools.co.in 2 In which process work is maximum a) Reversible b) Irreversible c) Exothermic d) Cyclie Enthalpy H cah be defined as a) H = V-PV b) H = P+U4+V c) H = U+PV d) H = U-TS Which of the following is not a state function ayq b) qt+w c) AH d) V+PV Diels-Alder reaction is the reaction between a) Diene and dienophile b) Electrophile and nucleophile c) Oxidant and reductant d) none Alcohols can be dehydrated to olefins using a) H,SO, b) PCe ¢) Soce, — d) Zn/Hg Which isomerism is present in but-1-ene and 2-methyl prop-1-ene? a) positioin isomerism b) meta merism c) Cheun isomerism d) tauto merism Part-II Answer any eight: 8x3=24 State Hund's rule of maximum multiplicity. Write the electronic configurationi element with Mn and Cu. What is Octet rule. What is meant by hybridisation? Define relative lowering af vopour pressure. What are the advantages of Berkley-Hartley method? State Charle's - Vant Hoff law. Write the difference between an exothermic and an endothermic process. Define Zeroth law of thermodynamics. Write - Sabatier Senderens reduction. What are the uses of ethylene?11C www.tnschools.co.in 4 Part - III Answer any three questions. Choose at least one question from each section: 3x5=15 28) 29) 30) 31) 32) 33) Section-A Explain the various quntem. numbers. Explain the important properties of Ionic compound. Section -B Describe about Beckmann thermo meter. Derives the equivation AH = AV+RT An(g) Section -C Explain the following reaction: (i) Hydroboaration (ii) Arorhatization (iii) Nitration in alkane Describe geometrical isomerism present in alkene. Part-IVv Question number 36 is compulsory and answer any one from the remaining questions: 3x5=15 34) 35) 36) a] Describe the limitation of Bohr theory. b] Calculate the latitue energy of NaCé using Born-Haber cycle, a] Explain the determination of relative lowering of vapour pressure of Ostwlad Walker method. b] Compare the enthalpy changes that occur between the neutralisation of a strong acid and a weak acid by sodium hydroxide. Explain the difference seen. a] A solution containing 2.5 g of a non-volatile solute in 100 gm of benzen boiled at a temperature 0.42 K higher than at the pure solvent boiled. What is the molecular weight of the solute? The molal elevation constant of benzene is 2.67 K.Kg mol‘.11¢c 4 www.tnschools.co.in b] An organic compound A(C,H,O) reacted with H,SO, at c d 160°-170°C to give compound B with molecular formula C,H,. Compound B react with Baeyer's reagent to give compound C(C,H,O,). Identify A, B and C. Explain the reaction. (OR) Calculate the enthalpy of combustion of ethylene at 300 K at constant pressure if its enthalpy of combustion at constant volume is -1406 K) mol". An organic compound A(C,H.,)-is passed into dilute sulphuric acid in the. presence of mercury sulphate give an aldehyde B(C,H,O). Further (A) is passed through red hot iron tube under pressure get polymerised to aromatic compound C(C,H,). Identify A, B and C explain the reaction.