Professional Documents
Culture Documents
Observation
White fumes evolve, white
sublimate on the cooler walls of the
test tube.
Inference
May be NH4+
May be CO32-
May be NH4+
CO32- confirmed.
NH4+ confirmed.
Experiment-2
Aim-To analyse the given salt qualitatively and systematically.
Physical characteristics
1) Colour-White
2) Odour -Ammonical odour
3) State- Amorphous
4) Solubility- Soluble in cold distilled water
Preliminary dry heating test
Experiment
Salt is taken in a dry test tube and
heated.
Analysis of Acidic radical
Observation
White fumes evolve,white sublimate
on the cooler walls of the test tube
Inference
May be NH4+
No reaction.
No change.
PO43- obtained.
PO43- obtained.
May be NH4+
NH4+ confirmed.
Experiment-3
Aim-To analyse the given salt qualitatively and systematically.
Physical characteristics
1) Colour-White
2) Odour Vinegar like odour
3) State- Crystalline
4) Solubility- Soluble in cold distilled water
Preliminary dry heating test
Experiment
Salt is taken in a dry test tube and
heated.
Observation
White fumes evolve with vinegar
like smell.
Inference
May be CH3COO-
No reaction.
May be CH3COO-
CH3COO- confirmed.
CH3COO- confirmed.
CH3COO- confirmed.
NH4+ absent.
Pb2+ confirmed.
Pb2+ confirmed.
Pb2+ confirmed.
Pb2+ confirmed.
Experiment-4
Aim-To analyse the given salt qualitatively and systematically.
Physical characteristics
1) Colour-Blue
2) Odour Odourless
3) State- Crystalline
4) Solubility- Soluble in cold distilled water
Preliminary dry heating test
Experiment
Salt is taken in a dry test tube and
heated.
Observation
White fumes evolve, water droplets
are seen on the inner cooler walls of
the test tube.
Inference
May be Cl-
No reaction.
May be Cl-
Confirmatory test
1) Take salt in a test tube and solid
K2Cr2O7 is added followed by conc.
H2SO4 and the mixture is heated.
To the yellow solution, acetic acid
along with lead acetate solution is
added.
2) To the salt solution few drops of
HNO3 is added followed by silver
nitrate solution.
Cl- confirmed.
Red fumes of chromyl chloride
comes out. On passing through
NaOH solution, it turns yellow.
Yellow precipitate obtained.
Cl- confirmed.
Cl- confirmed.
NH4+ absent.
Group 2 present.
Pb2+ absent.
Group 1 absent
Cu2+ confirmed.
Cu2+ confirmed.
Experiment-5
Aim-To analyse the given salt qualitatively and systematically.
Physical characteristics
1) Colour-White
2) Odour Odourless
3) State- Crystalline
4) Solubility- Soluble in cold distilled water
Preliminary dry heating test
Experiment
Salt is taken in a dry test tube and
heated.
Observation
Brown fumes evolve and colour of
residue is brown.
Inference
May be Br- or NO3-
No reaction.
NO3- confirmed.
NO3- confirmed.
NO3- confirmed.
NH4+ absent.
Group 2 present.
As3+ confirmed.
As3+ confirmed.
Group 1 absent
Experiment-6
Aim-To analyse the given salt qualitatively and systematically.
Physical characteristics
1) Colour-White
2) Odour Odourless
3) State- Amorphous
4) Solubility- Soluble in cold distilled water
Preliminary dry heating test
Experiment
Salt is taken in a dry test tube and
heated.
Observation
White fumes evolve with water
droplets on inner cooler walls of the
test tube.
Inference
May be Cl-
No reaction.
May be Cl-
Confirmatory test
3) Take salt in a test tube and solid
K2Cr2O7 is added followed by conc.
H2SO4 and the mixture is heated.
To the yellow solution, acetic acid
along with lead acetate solution is
added.
4) To the salt solution few drops of
HNO3 is added followed by silver
nitrate solution.
Cl- confirmed.
Cl- confirmed.
Cl- confirmed.
NH4+ absent.
No precipitate obtained.
Group 2 absent.
Group 3 present.
May be Al3+
Group 1 absent
Al3+ confirmed.
Experiment-7
Aim-To analyse the given salt qualitatively and systematically.
Physical characteristics
1) Colour-White
2) Odour Odourless
3) State- Amorphous
4) Solubility- Soluble in cold distilled water
Preliminary dry heating test
Experiment
Salt is taken in a dry test tube and
heated.
Observation
White fumes evolve with water
droplets on inner cooler walls of the
test tube.
Inference
May be Zn2+
No reaction.
No change.
SO42- confirmed.
SO42- confirmed.
NH4+ absent.
No precipitate obtained.
Group 2 absent.
No precipitate obtained.
Group 3 absent.
Group 1 absent
Zn2+ obtained.
Zn2+ obtained.
Experiment-8
Aim-To analyse the given salt qualitatively and systematically.
Physical characteristics
1) Colour-Green
2) Odour Odourless
3) State- Crystalline
4) Solubility- Soluble in cold distilled water
Preliminary dry heating test
Experiment
Salt is taken in a dry test tube and
heated.
Observation
White fumes evolve with water
droplets on inner cooler walls of the
test tube.
Inference
May be SO42-
No reaction.
No change.
SO42- confirmed.
SO42- confirmed.
NH4+ absent.
No precipitate obtained.
Group 2 absent.
No precipitate obtained.
Group 3 absent.
Group 1 absent
Group 4 present.
May be Ni2+ orCo2+
Ni2+ confirmed.
Ni2+ obtained.
Experiment-9
Aim-To analyse the given salt qualitatively and systematically.
Physical characteristics
1) Colour-Pink
2) Odour Odourless
3) State- Crystalline
4) Solubility- Soluble in cold distilled water
Preliminary dry heating test
Experiment
Salt is taken in a dry test tube and
heated.
Observation
White fumes evolve with water
droplets on inner cooler walls of the
test tube.
Inference
May be SO42-
No reaction.
NO3- confirmed.
NO3- confirmed.
NO3- confirmed.
NH4+ absent.
Group 1 absent
No precipitate obtained.
Group 2 absent.
No precipitate obtained.
Group 3 absent.
Group 4 present.
May be Ni2+ orCo2+
Co2+ confirmed.
Co2+ obtained.
Experiment-10
Aim-To analyse the given salt qualitatively and systematically.
Physical characteristics
1) Colour-Pale pink
2) Odour Odourless
3) State- Crystalline
4) Solubility- Soluble in cold distilled water
Preliminary dry heating test
Experiment
Salt is taken in a dry test tube and
heated.
Observation
Colour of fumes is white and yellow
residue obtained.
Inference
May be SO42-
No reaction.
No reaction.
SO42- confirmed.
SO42- confirmed.
NH4+ absent.
No precipitate obtained.
Group 2 absent.
Group 1 absent
No precipitate obtained.
Group 3 absent.
Group 4 present.
May be Mn2+
Mn2+ confirmed.
Mn2+ confirmed.
Experiment-11
Aim-To analyse the given salt qualitatively and systematically.
Physical characteristics
1) Colour-White
2) Odour Odourless
3) State- Crystalline
4) Solubility- Soluble in cold distilled water
Preliminary dry heating test
Experiment
Salt is taken in a dry test tube and
heated.
Observation
White fumes evolved.
Colour of residue
Hot-white
Cold-White
Inference
May be Cl-
No reaction.
May be Cl-
Confirmatory test
1) Take salt in a test tube and solid
K2Cr2O7 is added followed by conc.
H2SO4 and the mixture is heated.
To the yellow solution , acetic acid
along with lead acetate solution is
added.
2) To the salt solution few drops of
HNO3 is added followed by silver
nitrate solution.
Cl- confirmed.
Cl- confirmed.
NH4+ absent.
Group 1 absent
No precipitate obtained.
Group 2 absent.
No precipitate obtained.
Group 3 absent.
No precipitate obtained.
Group 4 absent.
Group 5 present.
Ca2+ confirmed.
Ca2+ confirmed.
Experiment-12
Aim-To analyse the given salt qualitatively and systematically.
Physical characteristics
1) Colour-White
2) Odour Odourless
3) State- Crystalline
4) Solubility- Soluble in cold distilled water
Preliminary dry heating test
Experiment
Salt is taken in a dry test tube and
heated.
Observation
White fumes evolved.
Colour of residue
Hot-white
Cold-White
Inference
May be Cl-
No reaction.
May be Cl-
Confirmatory test
1) Take salt in a test tube and solid
K2Cr2O7 is added followed by conc.
H2SO4 and the mixture is heated.
To the yellow solution , acetic acid
along with lead acetate solution is
added.
2) To the salt solution few drops of
HNO3 is added followed by silver
nitrate solution.
Cl- confirmed.
Cl- confirmed.
NH4+ absent.
No precipitate obtained.
Group 2 absent.
Group 1 absent
No precipitate obtained.
Group 3 absent.
No precipitate obtained.
Group 4 absent.
Group 5 present.
Ba2+ confirmed.
Ba2+ confirmed.
Experiment-13
Aim-To analyse the given salt qualitatively and systematically.
Physical characteristics
1) Colour-White
2) Odour Odourless
3) State- Crystalline
4) Solubility- Soluble in cold distilled water
Preliminary dry heating test
Experiment
Salt is taken in a dry test tube and
heated.
Observation
Reddish brown gas evolves.
Colour of residue
Hot-white
Cold-Yellowish
Inference
May be Br- or NO3-
No reaction.
NO3- confirmed.
NO3- confirmed.
NO3- confirmed.
NH4+ absent.
No precipitate obtained.
Group 2 absent.
No precipitate obtained.
Group 3 absent.
Group 1 absent
excess.
5) Through the above solution H2S
gas is passed.
No precipitate obtained.
Group 4 absent.
Group 5 present.
Sr2+ confirmed.
Sr2+ confirmed.
Experiment-14
Aim-To analyse the given salt qualitatively and systematically.
Physical characteristics
1) Colour-White
2) Odour Odourless
3) State- Crystalline
4) Solubility- Soluble in cold distilled water
Preliminary dry heating test
Experiment
Salt is taken in a dry test tube and
heated.
Observation
Reddish brown gas evolves.
Colour of residue
Hot-white
Cold-Yellowish
Inference
May be Br- or NO3-
No reaction.
NO3- confirmed.
NO3- confirmed.
NO3- confirmed.
NH4+ absent.
No precipitate obtained.
Group 2 absent.
No precipitate obtained.
Group 3 absent.
Group 1 absent
excess.
5) Through the above solution H2S
gas is passed.
No precipitate obtained.
Group 4 absent.
Group 5 absent.
Group 6 present.
Mg2+ confirmed.
Experiment-15
Aim- To analyse the functional group present in the given organic compound. (Alcohol)
Aim- To analyse the functional group present in the given organic compound. (Phenol)
EXPERIMENT
1) Litmus testTo a drop of compound blue litmus
is added.
2) Neutral Ferric chloride testTo the organic compound neutral
FeCl3 solution is added.
3) Libermanns test2-3 crystals of NaNO2 are taken in a
test tube and organic compound is
added to it. Contents are heated
gently on a water bath for 1minute
and allowed to cool. 1ml of conc.
H2SO4 is then added and shaken.
OBSERVATION
INFERENCE
Aim- To analyse the functional group present in the given organic compound. (Aldehyde)
EXPERIMENT
1) 2,4 Dinitrophenyl hydrazine test
To the organic compound dissolved in
thanol, 2 ml of 2,4-DNp solution is
added.Corked the test tube and shake it
and allowed to stand for 5 minutes.
2) Sodium bisulphite testTo the organic compound, NaHSO3
solution is added. Test tube is corked,
shaken and left to stand for 20 minutes.
3) Schiffs testTo the organic compound, 1 ml of
Schiffs reagent is added.
4) Tollens testTo silver nitrate solution, 2-3 ml of
dilute NaOH is added which results in
the formation of a brown precipitate.
NH4OH is then added till brown
precipitate disappears. To the above
OBSERVATION
INFERENCE
Formation of yellow-orange
precipitate.
Aim- To analyse the functional group present in the given organic compound. (Ketone)
EXPERIMENT
1) 2,4 Dinitrophenyl hydrazine
test
To the organic compound dissolved
in thanol, 2 ml of 2,4-DNp solution
is added.Corked the test tube and
shake it and allowed to stand for 5
minutes.
2) Sodium bisulphite testTo the organic compound, NaHSO3
solution is added. Test tube is
corked, shaken and left to stand for
20 minutes.
3) m- Dinitrobenzene testTo the organic compound, finely
powdered m- Dinitrobenzene is
added followed by dilute NaOH and
the test tube is shaken.
4) Sodium nitroprusside testDissolve a crystal of sodium
nitroprusside in water.
Add the organic compound to the
above solution followed by addition
of NaOH dropwise.
OBSERVATION
INFERENCE
Formation of yellow-orange
precipitate.
Aim- To analyse the functional group present in the given organic compound. (Carboxylic acid)
EXPERIMENT
1) Litmus testTo a drop of compound blue litmus
is added.
2) Sodium bicarbonate testTo the organic compound, saturated
solution of NaHCO3 is added.
2)Ester test-
OBSERVATION
INFERENCE
Aim- To analyse the functional group present in the given organic compound. (Amine)
EXPERIMENT
1) Solubility testTo the organic compound, dilute
HCl is added and shaken.
1) Litmus testTo a drop of compound red litmus
solution is added.
3) Carbylamine testTo the solid KOH pellets taken in a
test tube about 1ml of of ethanol is
added and the contents are warmed,
followed by addition of chloroform
and given organic compound.
4) Nitrous acid testDissolve the organic compound in 1
ml of conc. HCl and cooled the
contents in a ice bath. In another test
tube, a solution of sodium nitrite is
made and kept in ice for cooling.
Mixed the contents of both the test
tubes.
5) Azo dye testDissolve organic compound in 1 ml
of conc. HCl and kept for cooling in
ice bath. In 2nd test tube, an aqueous
solution of NaNO2 is prepared and
cooled. In the 3rd test tube naphthol is taken and cooled in ice
bath. Mix all the contents of the
respective solutions.
OBSERVATION
INFERENCE
May be amine.
Experiment-16
Aim- To analyse the food stuff (carbohydrate) present in the given sample.
EXPERIMENT
1) Solubility testFood sample solution is taken in 3
test tubes. To the first test tube water
is added. To the second ethanol is
added and to the third chloroform is
added. Each test tube is shaken
vigorously aand observed carefully.
2) Translucent spot testA drop of given food sample is taken
on the filter paper which is folded
and pressed a little.
3)Acrolein testFood sample is heated with crystals
of KHSO4 in atest tube.
OBSERVATION
INFERENCE
a) Immiscible in water
b) In alcohol it forms lower layer
which dissolves on heating.
c) Miscible in choloroform.
Oil/Fat is confirmed.
Oil/Fat is confirmed.
Oil/Fat is confirmed.
Aim- To analyse the food stuff (proteins) present in the given sample.
EXPERIMENT
1) Biuret testTo the dispersion of food sample, 2
ml of NaOH solution is added
followed by 4-5 drops of 1 % CuSO4
solution.
2) Xanthoproteic testTo 2 ml of dispersion of HNO3 is
added and contents are heated on a
water bath.
3)Millions testTo the dispersion of the given food
sample, Millions reagent is added.
4) Ninhydrin testTo the dispersion of the given
protein, Ninhydrin solution is added
and the contents are boiled.
OBSERVATION
INFERENCE
Protein confirmed.
Protein confirmed.
Protein confirmed.
Protein confirmed.
Experiment-17
Aim- To prepare crystals of Ferrous ammonium sulphate (Mohrs salt)
Theory- Mohrs salt is prepared by dissolving an equimolar mixture of hydrated ferrous sulphate and ammonium
sulphate in water containing a little sulphuric acid and then subjecting the resulting solution to crytallisation when
pale green coloured crystals of ferrous ammonium sulphate having monoclinic shape separates out.
FeSO4.7 H2O + (NH4)2SO4
Materials required- Two beakers (250ml) , China dish, funnel, funnel stand, glass rod, wash bottle , tripod stand,
filter paper, ferrous sulphate crystals, ammonium sulphate crystals, dilute sulphuric acid, distilled water.
Procedure
1) Take a 250 ml beaker and wash it with water. Transfer 7 g of ferrous sulphate and 3.5 g of ammonium sulphate
crystals to it. Add about 2-3 ml of dilute sulphuric acid to prevent the hydrolysis of ferrous sulphate.
2) In another beaker boil about 20 ml of water for about 5 minutes to expel dissolved air.
3) Add the boiling hot water to the contents in the first beaker in small installments at a time. Stir with a glass rod
until the salts have completely dissolved.
4) Filter the solution to remove undissolved impurities and transfer the filtrate to a china dish.
5) Heat the solution in the china dish for some time to concentrate it to the crytallisation point.
6) Place the china dish containing saturated solution over a beaker full of cold water. On cooling crystals of Mohrs
salt separate out.
7) decant off the mother liquor quickly. Wash the crystals in the china dish with a small quantity of alcohol to
remove nay sulphuric acid sticking to the crystals.
8) Dry the crystals by placing them between filter paper pads.
ObservationsWeight of crystal obtainedExpected yield of crystalsColour of the crystals- Light green
Shape of the crystals- Monoclinic
Precautions1) To avoid oxidation of ferrous sulphate boiled water is to be added.
2) Dilute sulphuric acid is added immediately to prevent hydrolyis of FeSO 4
3) Do not heat the solution for a long time as it may oxidize ferrous ions to ferric ions.
Experiment-18
Aim- To prepare a sample of Dibenzal acetone.
Theory- The preparation of dibenzal acetone is an example of Claisen- Schmidt reaction. This reaction takes place
between aromatic aldehyde and aliphatic ketones in presence of sodiumhydroxide. Two moles of benzaldehyde
condense with one mole of acetone to give dibenzal acetone.
2 CHO + CH3COCH3
NaOH
CH=CHCOCH=CH