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Unit I
CEMENT PRODUCTION PLANT
Cement
Cement is a crystalline pulverized compound of calcium silicates
and other calcium bearing compounds with impressive hydraulic
properties.
Important components
Respective Sources
Lime ( CaO)
Silica (SiO2)
Alumina (Al2O3)
Gypsum
2.
3.
4.
5.
The combustion gasses and the raw material flow in countercurrent mode and the firebrick acts as insulator for protecting the
heat losses to the ambient.
Chemistry in kiln
Water
(100 0C)
(100 -600)0C
Clay
Calcium Silicates
CaO +
C3A+C4AF
SiO2
Al2O3
Fe2O3
(800 -900)0C
10000C
~13500C
Evaporation
SiO2
Al2O3
Fe2O3
CaO + CO2
2Cao.SiO2=C2S
3CaO.Al2O3=C3A
4CaO.Al2O3.Fe2O3=C4AF
Energy flows
The cement making process is highly energy intensive accounting
for nearly 40 50 % of the production costs.
Energy flows:
Energy flow-details
Assignment 1
The following table is a typical ultimate analysis data for dry ash free premier coal. The
calorific value is 20MJ/kg and was burned under exact amount of air . Calculate the value
of adiabatic flame temperature? What will be the value if 30% excess air is used for
combustion?
Ultimate Analysis
(DAF Basis)
Range
Typical
Carbon
73-78%
74%
Hydrogen
4-5%
4.3%
Nitrogen
1.2-1.4%
1.3%
Oxygen
16-21%
19.8%
Sulphur
0.3-0.8%
0.6%
Flame Temperature
21
22
23
24
26
27
HP = (t f - 25) (mcP )P
where tf is the flame temperature. This relationship cannot be
solved explicitly for tf as there will be a considerable difference
between tf and the reference temperature 25, hence the value
of tf is required to evaluate the specific heats of the combustion
products.
28
29
Site selection
The Site of cement processing pant is usually near to the
location of the main raw materiallime.
Waste water
No pronounced effect for dry processing.
But for processing plants that use coal mines as energy
source there may exist contamination of ground water.
Air pollution
Carbon dioxide emissions can be grouped as energyrelated, referring to emissions that result from the
combustion of fossil fuel, and process- related, referring to
the emissions from the decomposition of calcium carbonate.
Studies have shown that one ton of carbon dioxide gas is
released into the atmosphere for every ton of Portland
cement which is made anywhere in the world.
The only exceptions are so-called 'blended cements', using
such ingredients as coal fly ash, where the CO2 emissions are
slightly suppressed, by a maximum of 10%-15%.
Air pollution
Cement, (Portland cement), results from the calcination of
UNIT II
ALCOHOL PRODUCTION
What is alcohol ?
A class of molecules withOH(hydroxyl) functional
group.
methanol- 1 carbon
ethanol- 2 carbons
propanol- 3 carbons
butanol- 4 carbons
pentanol- 5 carbons
aerobic respiration
anaerobic respiration
- requires oxygen
- 36 ATP per glucose
molecule
alcoholic fermentation
- low energy waste
products, H2O and CO2
lactic acid
fermentation
Sources
Ethanol can be derived from agricultural sources or from
petrochemicals.
1. sugar
2. starch
ethanol
sugar
ethanol
ethanol
Manufacturing Process
ENZYMES
Feedstock
Handling
PRE-TREATMENT
HYDROLYSIS
50% EtOH
95% EtOH
AZEOPTROPIC
DEHYDRATOR
6
5
4
6
5
4
3
2
1
3
2
1
RECTIFIER
99.6% FUEL
GRADE
ETHANOL
WATER
ENZYMES
YEAST
10% EtOH
STRIPPER
FERMENTATION
SOLIDS
Classification of Feedstock
SACHHARINE
Fruits Molasses
STARCH
Grains
Potatoes
PRE TREATMENT
MILLING
MASHING
CELLULOSE
DRY
Green
SHREDDING
MASHING
DILUTION
DILUTION
DILUTION
LIQUEFACTION
HYDROLYSIS
HYDROLYSIS
FERMENTATION
DISTILLATION
DEHYDRATION
DENATURING
STORAGE
Process description
Feedstock Handling. Biomass goes through a size-reduction step to make
it easier to handle and to make the ethanol production process more
efficient. For example, agricultural residues go through a grinding process
and wood goes through a chipping process to achieve a uniform particle
size.
Biomass Pretreatment. In this step, the hemicellulose fraction of the
biomass is broken down into simple sugars.
Enzyme Production. The cellulase enzymes that are used to hydrolyze the
cellulose fraction of the biomass are grown in this step. Alternatively the
enzymes might be purchased from commercial enzyme companies.
Cellulose Hydrolysis. In this step, the remaining cellulose is hydrolyzed to
glucose. In this enzymatic hydrolysis reaction, cellulase enzymes are used to
break the chains of sugars that make up the cellulose, releasing glucose.
Cellulose hydrolysis is also called cellulose saccharification because it
produces sugars.
Continued..
Enzyme Production. The cellulase enzymes that are used to hydrolyze
the cellulose fraction of the biomass are grown in this step. Alternatively
the enzymes might be purchased from commercial enzyme companies.
Distillation
Distillation is a kind of seperation technique of two or more
volatile liquid compunds by using the difference in boiling points
and relative volatility.
The process takes place in a column, and two heat exchangers.
Distillation of Alcohol
Under 1 athmosphere pressure
boiling points of water and alcohol
are 100C and 78.3C.
Water and ethyl alcohol mixture
forms an azeotrope in athmospheric
pressure at a mole fraction of %89.4
of ethyl alcohol which means that by
simple distillation of ethyl alcohol, it
cannot be purified more than %95.6
w.
As distillation equipments, bubble
cap trays and tray columns are mostly
used in alcohol distillation.(Figure on
left)
Starch-to-Ethanol Process
Starch-to-Ethanol Process
Corn-to-Ethanol Process
Materials
Liquefaction
Liquefaction
Liquefaction
Saccharification
Saccharification
Saccharification
Fermentation
Energy balance
Cellulose to Ethanol
Major composition
Pretreatment
Pretreatment
Pretreatment process
Physical pretreatment process.
Physico-chemical pretreatment
process.
Chemical pretreatment process.
Biological pretreatment process.
Pretreatment technology
Pretreatment technology
Steam explosion
Steam explosion
Physico-chemical Pretreatment
Physico-chemical Pretreatment
Chemical Pretreatment
Chemical Pretreatment
Chemical pretreatment
Chemical pretreatment
Biological Pretreatment
By-products
By-products
usage
Alcoholic beverages
Medicine
Fuel
Alcoholic beverages
Alcoholic beverages are divided into three groups:
malt liquors, fermented wines and distilled liquors.
Fuel
Ethanol can be used as fuel in cars alone as power alcohol
or as a blend with benzene.
Characteristics
Generally the effluents from molasses based
distilleries contain large amounts of dark brown
coloured molasses spent wash (MSW).
Because of its acidic pH, dark brown colour, high ash
content, high percentage of dissolved organic and
inorganic matter, it is one of the most difficult waste
products to dispose.
The biochemical Oxygen demand (BOD) and chemical
oxygen demand (COD) of MSW range between 35,000
50,000 and 100,000150,000 mg L-1, respectively.
Continued
Distillery
wastewaters
contain
phenolics
compounds, mainly gallic acid, p-coumaric acid and
gentisic acid, which impart high Antibacterial
activity.
Organic acids such as lactic acid (29% v/v), tartaric
acid (27% v/v), succinic acid (26% v/v), acetic acid
(10% v/v) and malic acid (8% v/v) also documented
in distillery wastewater.
Apart from the above listed cpds distillery waste
water also contains soluble proteins.
Example of Wastewater
distillery characteristics
Parameters such as the pH, alkalinity,
electrical conductivity (EC), total chemical
oxygen demand (COD), soluble chemical
oxygen demand (COD), five-day biochemical
oxygen demand (BOD), total organic carbon
(TOC), phenol, volatile fatty acids (VFA),
volatile solids (VS), volatile suspended solids
(VSS), total solids (TS), total suspended solids
(TSS), mixed solids (MS), mixed suspended
solids (MSS), total nitrogen (TN), ammonia
(NH4+), nitrates (NO3-), total phosphorus (TP)
and phosphates (PO43-) must be reported for
effective water treatment.
Treatment Methods Of
Distillery Waste Water
There are several different methods for treatment
of distillery effluent. They are as follows:
Physico-Chemical Treatment Methods.
Biological Treatment Methods.
Aerobic Treatment.
Anaerobic Treatment.
Enzymatic Treatment.
Physico-Chemical Treatment
Methods
Coagulation: Reduction of repulsive forces through
addition of coagulant.
Continued
Membrane Technology: The effluent collected
from the distillery industry is highly acidic with PH
range of around 3. Hence, it is neutralized using
sodium hydroxide. The neutralized solution has a
lot of suspended solids, so the filtration is carried
out to remove the suspended solids with fine-pore
thin cloth or by using some membranes.
Continued
AnaerobicTreatment : Application of anaerobic digestion to
distillery effluents is a preferable primary treatment option. Since
aerobic processes have higher nutrient requirements and cause
operational difficulties in treating high organic strength
wastewaters, employing these methods in primary treatment of
stillage would result in lower cost-efficiency.
Aerobic Treatment: The post anaerobic treatment stage still has
high organic loading and is high dark brown in colour, hence it is
generally followed by a secondary, aerobic treatment. These are
some aerobic treatment methods:
Biocomposting: Biocomposting is an aerobic, thermophilic
process resulting in a product rich in humus which is thus used as
a fertilizer.
Enzymatic Treatment
Is