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1)
k-1
NOBr2 (g)
k2
2NOBr
(fast)
(slow)
The rate law for formation of NOBr based on this mechanism is rate = ________.
A) (k 2 k1 /k-1 )[NO] 2 [Br2 ]
B) k1 [Br2 ]1/2
C) k1 [NO] 1/2
D) (k 1 /k-1 )2 [NO]2
E) (k 2 k1 /k-1 )[NO][Br2 ]2
2) Of the following, ________ will lower the activation energy for a reaction.
A) adding a catalyst for the reaction
B) increasing the concentrations of reactants
C) raising the temperature of the reaction
D) removing products as the reaction proceeds
E) increasing the pressure
2)
3) Calculate rate constant k for a first order reaction with a half-life of 75.0 min.
A) 1.54 10-4 min-1
B) 2.67 10-2 min-1
C) 52.0 min-1
D) 9.24 10-3 min-1
E) 1.33 10-2 min-1
3)
4) Carbon-14 has a half-life of 5720 years and this is a first order reaction. If a piece of wood has
converted 25% of the carbon-14, then how old is it?
A) 1430 years
B) 4750 years
C) 4290 years
D) 11440 years
E) 2375 years
4)
5) A reaction is followed and found to have a rate constant of 3.36 104 M -1 s-1 at 344 K and a rate
constant of 7.69 M-1 s-1 at 219 K. Determine the activation energy for this reaction.
5)
A) 23.8 kJ/mol
B) 12.5 kJ/mol
C) 42.0 kJ/mol
D) 58.2 kJ/mol
E) 11.5 kJ/mol
CHEM 1212
EXAM #3 Chapter 13,14, and 15
6) The equilibrium constant is given for one of the reactions below. Determine the value of the
missing equilibrium constant.
Kc = 3.8 104
4 HBr(g) 2 H2 (g) + 2 Br2 (g) Kc = ?
H2 (g) + Br2 (g) 2 HBr(g)
A) 6.9 10-10
B) 5.1 10-3
C) 2.6 10-5
D) 1.9 104
E) 1.6 103
7) In which of the following reactions will Kc = Kp?
7)
8)
B) 1.9 10-3
C) 1.7 106
D) 3.0 104
E) 3.3 10-5
9) Determine the value of Kc for the following reaction if the equilibrium concentrations are as
follows: [N2 ]eq = 3.6 M, [O2 ]eq = 4.1 M, [N2 O] eq = 3.3 10-18 M.
2 N2 (g) + O2 (g) 2 N2 O(g)
A) 5.0 1036
B) 4.9 10-17
C) 2.2 10-19
D) 2.0 10-37
E) 4.5 1018
9)
CHEM 1212
EXAM #3 Chapter 13,14, and 15
10) Consider the following reaction, equilibrium concentrations, and equilibrium constant at a
particular temperature. Determine the equilibrium concentration of H2 O(g).
C2 H4 (g) + H2 O(g) C2 H5 OH(g)
Kc = 9.0 103
A) 1.68 M
B) 0.013 M
C) 9.9 10-7 M
D) 80. M
E) 1.0 M
11) Consider the following reaction:
11)
D) 2.2 M
E) 1.7 M
12) Consider the following reaction at equilibrium. What effect will increasing the volume of the
reaction mixture have on the system?
12)
13)
H= +35.9 kJ
14)
CHEM 1212
EXAM #3 Chapter 13,14, and 15
15) What is the conjugate base of H2 PO4 ?
A) PO4 3-
B) OH
C) HPO4 2-
D) H3 O+
16) The stronger the acid, then which of the following is TRUE?
A) The weaker the conjugate base.
B) The weaker the conjugate acid.
C) The stronger the conjugate acid.
D) The stronger the conjugate base.
E) None of the above.
16)
17) Which of the following solutions would have the highest pH? Assume that they are all 0.10 M in
acid at 25C. The acid is followed by its Ka value.
17)
18)
Answer Key
Testname: EXAM 3 W2015
1) A
2) A
3) D
4) E
5) C
6) A
7) A
8) A
9) D
10) B
11) B
12) E
13) C
14) C
15) C
16) A
17) E
18) E