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AITS-CRT-IV-PCM (Sol)-JEE (Main)/14
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FIITJEE JEE(Main)-2014
ANSWERS, HINTS & SOLUTIONS

CRTIV
(Main)
Q. No. PHYSICS CHEMISTRY MATHEMATICS

ALL INDIA TEST SERIES
1. A D D
2. B B B
3. D C C
4. D A D
5. C B B
6. C B A
7. A D C
8. A A C
9. B B C
10. C D B
11. A A A
12. C C D
13. D C A
14. B A C
15. A A A
16. A A B
17. D C C
18. C B B
19. D B D
20. A B C
21. B A A
22. B D C
23. D B A
24. C C A
25. C A D
26. A D C
27. D A B
28. C D C
29. C A D
30. B B B
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2
Physics PART I
SECTION A
1. For maximum
1N 3N 9N 10N 23N
9N
10N
3N 1N
A triangle is possible with sides 4 unit, 9 unit and 10 unit. Hence minimum
resultant is zero.
2. 2.4 km downstream from the point directly opposite to 0
3. rate of change of speed

= tangential component of acceleration v

(component of acceleration in the direction of velocity) at
3i 3j 6 4
a . v (2i j) . 2m / s2
5 5 a

an
4. Force is always perpendicular to velocity
5. elementary mass = x dy y
x = R cos, y = R sin
dy = R cos d
x
elementary mass = (Rcos) (Rcos d)
= R2cos2 d R
/2
2 2
y
yan

ydm
0
R cos R cos d
x
/2
.dm 0
2 2
R cos d
4
R
3
6. Let the block is in translational equilibrium and ready to N

topple. F
=F
N = mg
Taking torque about C.O.M. = 0
a a a mg
F f N
2 2 2 = F
2F = N
3
N
F
2
N
f
2
but f N
N
N
2
1

2
V Vo
7. f fo .
V Vs
Here, Vo = u + at
Vs = 0
varies linearly with t.
8. As long as cylinder is completely inside, B is constant in magnitude, then its value decreases
linearly with displacement and finally becomes zero.
9. at t = 1sec
2/ms
at t = 0
1/ms 1m/s2
5
1m/s2
1/ms
2
R
V2

5 5 5m
an 1
5
10. Applying work-energy theorem w.r.t wedge
kq0 kq0 kq0 3kq0

19. VP .
2a a a / 2 2a
1.5
20. Pitch = 0.3 mm
5
0.3
Least count = 0.006 mn
50
21. m1v1 m2 v 2
v 2 m1v1 / m2 (1)
1 2 a 1 1
kx m2 g m1v12 m 2 v 2 2 (2) From work energy theorem
2 2 2 2
Substituting (1) in (2) and solving
m2 (ka2 4m2 ga)
v1 = 10 cm/s
4m1(m1 m2 )
22. Mechanical energy loss happens due to viscous/frictional forces without which the liquid will
oscillate. This is released as heat
4
GMm
23. mr2
r3
3 2 2
GM r (GM = gr )
r 3 .2
g
R2
(4nR)3 .2
g
n2 .R 2
g 64 nR2 .
24. Frequencies are in odd ratio hence it is a closed organ pipe.

v
freq (2n 1)
4L
2v
(frequency) 100Hz
4L
L = 1.7 m.
Q
25. For maximum elongation charges on the blocks must be equal to on each block.
2
2
Q
1
2 kx
40 ( 0 x)2
Q 2( 0 x) 40kx .
1012 2 10 4 25
26. Number of emitted electrons = 5 104 electrons
105
q = + ne = 8 1015 C.
36
27. R 2
36
1 1 1 dR dR dR
2 21 22
R R1 R 2 R R1 R2
R
% error = 100%
R
R1 1 R 2 1
= R 100 100 %
R
1 R1 R 2 R 2
1 1
= 2 1 2 %
3 6
4
= %
3
28. As V increases, E increases, min decreases, K remains constant so (K min) increases
29. Increasing the filament current increases the intensity because more electron
now strike the target. Decreasing the potential difference increases the minimum wavelength.
1.6 1 1.8 105

30. = 12
900 109
5
Chemistry PART II
SECTION A
1. OEt
H3C HC
H3 O

CH3CHO : differentiated by Na, Fehling and Tollens test
OEt
(p) (Acetal)

H3 O
CH3 CH2 O CH2 CH3 EtOH; differentiated by Na,Fehling andTollen' s test
q
RT
2. EX / AgX / Ag = EAg / Ag + ln Ksp
F
3. Compounds with more covalent nature, was unable to respond to chromyl chloride test SnCl4,
due to mole polarizing power of Sn+4 the compound is more covalent.
5. Kc
SO3
2
SO2 O2
1
Kc 100
O 2
[O2] = 10 2
n
10 2
10
n = 0.1
P1 2V P2 V P2 V
6. n n1 n2
T1 T1 T2
8. xA = 0.3 , xB = 0.7
PA P
yA , yB B
PT PT
y A 0.6 3 PA x A 7

y B 0.4 2 PB x B 2
9. RbCl and KCl have rock salt structure

aRbCl aKCl 0.5

2 rRb rCl 2 rK rCl 0.5

Hence rK 1.33 A
11. Intramolecular aldol condensation.
12. Perkinss reaction
6
13. Bromination of benzylic carbon followed by hydrolysis
14. Hoffmann elimination, least stable alkene will be the major product.
16. -Hydroxy compound is easily dehydrated.
17.

2AB2 (g)
2AB(g) + B2 (g)
1 0 0
1- x x x/2
Total moles = 1 x + x + x/2 = 1 + x/2.
2
x 2 x p
kp = 2 [ x is small, 1-x = 1 and 1 + x/2 = 1].
1 - x 1 + x/2
1
x3p
kp = x = 2k p P = 2k p P 3
2
19. At constant pressure, the addition of inert gas shifts the equilibrium towards larger no. of moles.
2 2
20. The hybridisation of B in BBr3 is sp that C in CS2 is sp, that of S in SO2 is sp while that of
3
S in SF4 is sp d . Hence CS2 has the maximum bond angle of 180.
27. NaHCO 3 NaOH Na 2CO3 H2O
28. For a bcc lattice

X 0.4 o
0.732 Y 0.546 A
Y 0.732
Now, for fcc lattice,
Z
0.414 Z Y 0.414
Y
= 0.546 0.414
o
= 0.226 A
29. H
H H O H
O O Cl O O O
C
Ph C C C Ph Cl C C H H C H
C
C
O O Cl HO O
H O O
(I) (II) H H
(III) (V)
30. Hint: It is Acyl Cleavage
7
Mathematics PART III
SECTION A
1. f(x) = f(x)
xn = (x)n
loga x ax
2. lim 0 and lim
x xa x log x
a
3. g(x) = cos (x) ||x| 1|, x R
dv rdh 2hdr
4. r
dt dt dt
ax 4 bx3 cx 2
5. f(x) = dx
4 3 2
a b c
f(0) = 0, f(1) = d 0
4 3 2
6. h(x) = f 2(x) + (f(x))2

h(x) = 2x(f(x))2 g(x)
3v 2
7. Let F be the fuel charges. Then, F
16
3v
Let train covers kms. Then, total cost for running the train, C 300
16 v
dc d2 c
For 0 and 0
dv dv 2
v = 40 km/hr
8. For maximum or minimum, f(x) = 0

x2 + 8x (12 + t) = 0
t<4
9. AD divides BC in ratio AB : AC

AB 2i 5j 7k AC 2i 3 j 4k
So, P.V. of D =
AB AC
2
10. Required vector r x1b x2 c and r a a
3

r 2i j x1 2 k 4 x1 , where x1 R

12. r a x 2 a b c , r b x 3 b c a , r c x1 c a b
13. Equation of line x + 2y + z 1 + (x + y 2z 2) = 0
8
x + y 2 + (x + z 2) = 0
(0, 0, 1) lies on it
= 0, = 2
For point of intersection, z = 0
14. Equation of lines, (y mx) + , (z c) = 0

(y + mx) + 2 (z + c) = 0
It meets at xaxis, hence 1 = 2
cy = mzx
3
15. Slope of reflected ray =
4
3
Equation of incident ray is (y + 4) = x 2 i.e., 4y + 3x + 22 = 0
4
1
16. Required area = 4(Area of S2OS4) = 4 ae 8be1
2
r r 1 1 r r 1
17. sin1 tan tan
1
r tan1 r 1
r r 1 1 r r 1
1 1 1 2
18. AG 2b2 2c 2 a2 a ; BG b 4c 2
3 3 3
AG BG AB 5 13
R1
4 GAB 12
19. zn 1 = (z 1)(z z1)(z z2) .. (z zn 1)

Differentiating w.r.t. x
nzn 1 1 1 1
n
.....
z 1 z 1 z 2 z zn1
1 1 1
20. Tr
2 1 3 5 ..... 2r 1 1 3 5 ..... 2r 1
1 cos x cos x
22. sin x 2cos x 0 sin x cos x 0 0
0 0 sin x cos x
tan x = 2 or tan x = 1
2
y (2, 4)
2 2x x dx
x 2
23. Required area =
0 (0, 1)
x x
O (2, 0)
y
26. Combined mean = 16; d1 = 9; d2 = 6
9
n1 12 d12 n2 22 d22
2 67.2
n1 n2
3
27. 1 1 + sin x 2

I
2 2 2
dy
xy
28. xe dx
ln x
ydy x
dx
2
y ln x c
29. Let A(, 0) and B(, 0) be the two points

c
OT2 = OAOB = =
a
1 x18
30. f x
1 x
18
1 x 1
f x 1
x

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AITS-CRT-IV-PCM (Sol)-JEE (Main)/14

ANSWERS, HINTS & SOLUTIONS

Q. No. PHYSICS CHEMISTRY MATHEMATICS

2. 2.4 km downstream from the point directly opposite to 0

3. rate of change of speed

4. Force is always perpendicular to velocity

6. Let the block is in translational equilibrium and ready to N

10. Applying work-energy theorem w.r.t wedge

kq0 kq0 kq0 3kq0

24. Frequencies are in odd ratio hence it is a closed organ pipe.

28. As V increases, E increases, min decreases, K remains constant so (K min) increases

1.6 1 1.8 105

9. RbCl and KCl have rock salt structure

11. Intramolecular aldol condensation.

12. Perkinss reaction

13. Bromination of benzylic carbon followed by hydrolysis

16. -Hydroxy compound is easily dehydrated.

27. NaHCO 3 NaOH Na 2CO3 H2O

28. For a bcc lattice

30. Hint: It is Acyl Cleavage

Mathematics PART III

3. g(x) = cos (x) ||x| 1|, x R

6. h(x) = f 2(x) + (f(x))2

8. For maximum or minimum, f(x) = 0

13. Equation of line x + 2y + z 1 + (x + y 2z 2) = 0

14. Equation of lines, (y mx) + , (z c) = 0

19. zn 1 = (z 1)(z z1)(z z2) .. (z zn 1)

26. Combined mean = 16; d1 = 9; d2 = 6

29. Let A(, 0) and B(, 0) be the two points

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