2007L2006W
  

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 W$%&  1
2

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( 8 ) :

@ABC)?DE K + (aq) + Cl (aq) + ?=1mL 45 6 89):;<) JI

= ;KH@I0.+(J
5KL,2 AgCl(s) 
@A;=+FGD / Ag + (aq) + NO3 (aq)
 E0,25FKNOPNA 
\0 .= : ^K-  V0 = 100 mL  WXG Y@) Z[ C0  UV= + +  ST   & ?JII
1 mL 5
+XG.,Yae N, C = 103 mol.L1 UV= +
@ABC)
_
?G`
a,bcd@)
 WS 4 ` 4N<` /e
8
a,bN<^^HV_
Ofe)
/gcN=,

 
 E1FK& :NW
h X =;C)
+V$ J1
 E0,75FK& UK-NA+
= ;  j WiA i J2
 E2FK& l/+\_C+m
EDb a,Ge _k) J3
 E1,5FK& D8no G 
Oa+A=N J4
 E1F K C0 V=Cq \0Kl/   Veq p@\XP _J5
 E1FWS N4; +l/  nr
O(0 J6
C.Veq
  = ( + K + )
Veq + V0 NO3
 E0,5FK k 
r
,0q  J7
 WBa
  K + = 7,35 mS.m 2 .mol1   NO = 7,14 mS.m 2 .mol 1   Ag + = 6,19 mS.m 2 .mol 1
3

  Cl = 7,63 mS.m 2 .mol1

 

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 !W
 2
2
( 12 ) :
( 7 ) :

_ e
+K 1 = 90,0C Z+ G
_ m1 = 200g Z  =H
W= 0 = 20,0C b+ G
_
 :N8)
 K = 76,5C 
We
  N85 P &  P
 E1FKHp t&eA Q1 & P
W=;
G J1
 E1FK 
p t

 Q0 & P
W=q  J2
 E1FK 0 200J.K 1 WS- 
W
 P


WEi, J3
Z+ G
_  m 2 = 150g Z  = 
 `aE = 76,5C & P
  _
:_H: Wu) J4
 K 2 = 570C
c 76,5C   NT
 H  m1 = 200g
  & 
  G
_ Y/ 
D Q  & P
W= ;
G J1 J4
 E1FK e = 100C
c 570C   Z+ G
_ LAo +   
 `aE p t  &eA Q  & P
W= ;
G J2 J4
 E1FK e = 100C
 E1FK5 P =  o +NT
H
W=i, J3 J4
 E1FK o H _= 
J4 J4
 WSa)
  ce = 4180J.kg 1 .K 1 WHW
  &PG
  cCu = 380J.kg 1.K 1 W & 
 `PG
  L v = 2255.103 J.kg 1 WHIo 
 &PG
 
( 5 ) :
 K W
 + wST, Z=x ?Sa, N<)
 E1FKx ^p t

&ee
De&VZ_Z 
T, Z)
&+n J1
 K I = 25A b+zST, Z=+b/ { U AB = 50V  + x ^Y@y J2
 E1Fx ^p t


T, Z&eS-
 K_AwB+


T, Z&e10% W J3
 E1FKx ^p t
0^&)
e
;G J1 J3
 E1FK t = 15min &bu z x ^: Z}+m Q & P
W=_ J2 J3
 E1FKx ^
4&VX &eB~e )Z a,i+
)+\ J4
 
 
 
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