B48BA Process Industries C : Spreadsheet Solution

ISKENDEROV NURLAN
Date: 23.10.2016

Dimensions of Tank Donations

Outer diameter of base D 4m
Height of outside H 4m
Wall thickness t 15 mm
Density of tank PVC 1350 kg/m3

Find
Maximum volume inside tank 49.143 m3
Mass of PVC used 1515.392 kg
Outside surface area 75.398 m2

Working
49.143
V(inside)

50.265
V(outside)
1.123
V
1515.392
m(PVC)
75.398
Area outside
Converted values Conversion

0.015 m 1 mm= 0.001 m

Working
V(inside) 49.143
V(outside) 50.265
V 1.123
m(PVC) 1515.392
Area outside 75.398
 The equations for calculations

V = the volume of PVC which is used

B48BA Process Industries C : Spreadsheet Solution
ISKENDEROV NURLAN
Date: 23.10.2016

Dimensions (Outside) of Cylindical Drum Donations

Diameter of Drum D 36
Length of Drum (cylindical shell) H 36
Wall thickness t 0.25
Density of liquid contents 900
Filling level 75%
Type of material used 304 SS
Density of material 0.284

Results
Dry mass of drum 1691.859
Total mass of drum and liquid 6680.690

Conversions
1 lbm/in3= 27679.9 kg/m3
1 inch= 0.0254 m
1 ft= 0.3048 m

Working
7.606 m3
V(outer)
7.391 m3
V(inside)
0.215 m3
V
1691.859411 kg
m(dry)
6680.690 kg
m(total)
 Converted Density Table lbm/in3 The
inches 0.914 Stainless Steels
ft 10.973 302 SS 0.291
inches 0.006 304 SS 0.284
kg/m3 316 SS 0.298
347 SS 0.288
Carbon Steels
lbm/in3 7861.092 Plain Carbon Steel 0.284
Carbon-Silicon 0.282 V = the volum
Chromium Steels 0.283
kg Plastics
kg PVC 0.051
PolyPropylene 0.900
Polycarbonate 1.200
 The equations for calculations

V = the volume of steel which is used.

B48BA Process Industries C : Spreadsheet Solution
ISKENDEROV NURLAN
Date: 23.10.2016

Tank Dimensions Donations Converted

Width w 2m
Length L 3m
Filling depth D 1m
Mass of KCl added 1500 kg
Tank temperature 2 C 275.15
Density of Solution 1000 kg/m3
Results
Will the KCl dissolve??? Yes
Final concentration 0% wt %

Conversions
0 C= 273.15 K

Calculations

The volume of the solution filled= 6000 kg/m3

Solubility was founded from the graph 23.670

From the equation of solubility
m(solute)= m(solution)*solubilty/100%
m(solute)= 1420.1772
It means that 1420.177 kg of KCl is dissolved in the tank at 2 C of temperature
The mass of the solid at 2C = m(KCl added)-m(solute)
m(solid which is present)= 79.8228 kg

Now we are able to calculate the value of solubility (mass % of a solution)

if the all of KCl which is added dissolves in the solution.
Solubility= 25

From the equation which is achieved from the graph

Solubility=0.1308T-12.32
From here,

T= 285.32110092
So, at this temperature all of KCl can dissolve and there will not be any solid that present after this temperature
The final concentration= 25 %
 The equations for calculations

The volume of the solution filled=w*D*L*

This equation was achieved from

Solubility
40

35

30

25

20

15

10

0
290 300 310 320 330 340 350 360

esent after this temperature

s equation was achieved from the graph which is shown below:

T (K) Solubility
298 26.476
313 28.728
323 30.094
343 32.582
353 33.709

The equation is like that:

Solubility=0.1308T-12.32
As there is 275.15K of temperature in the tank,
then the solubility is like that:
Solubility = 23.66962

360
B48BA Process Industries C : Spreadsheet Solution
ISKENDEROV NURLAN
Date: 23.10.2016

Dimensions (Outside) of Cylindical Tank Donations

Diameter of Tank D 36
Length of Tank (cylindrical shell) H 36
Wall thickness t 0.25

Tank pressure p(Gauge) 20

Atmospheric pressure p(Atm) 101.325
Temperature T 23.6

Results
Average molar mass of gas 58.08 kg/kmol
Mass of the gas inside tank 41.62 kg
Partial Pressure n-Butane 227.56 kPa
Vapour pressure of n-Pentane 0.65 bar
Condensation??? yes

Base= 100
Let us take a base of 100 kg of the gas mixture Mass of Gasses
Propane 0.5 kg
n-Butane 95 kg
iso-Butane 3 kg
n-Pentane 1.5 kg
Total 100 kg

Pabs=Pgauge+Patm

Absolute Pressure= 239.220 kPa

Vapour pressure can be defined from the Antoine equation

P (pressure) in bars , T (temperature) in Kelvins

Temperature 268.8K-341.37K
A 3.9892
B 1070.617
C -40.454
it is taken from: Osborn and Douslin, 1974

Vapor pressure of normal pentane = 0.649 bar

 Converted values Commercial Butane Compostion
inches 0.914 m wt %
ft 10.973 m Propane 0.5
inches 0.006 m n-Butane 95
iso-Butane 3
psi 137.895 kPa n-Pentane 1.5
kPa Sum 100
C 296.75 K

64.853 kPa

kg
Molar Mass kmoles of Gasses
44 kg/kmol 0.01 kmol
58 kg/kmol 1.64 kmol
58 kg/kmol 0.05 kmol
72 kg/kmol 0.02 kmol
1.72 kmol

7.39

41.62 kg R=

227.56 kPa

P(n-pentane)= 2.894 kPa

64.853 kPa
ne Compostion Conversions
1 inch= 0.0254
1 ft= 0.3048
1 psi= 6.89476
0 C= 273.15
1 mm Hg= 0.133
1 bar= 100

58.1 kg/kmol

8.314 kJ/kmol K
ions
m
m
kPa
K
kPa
kPa
B48BA Process Industries C : Spreadsheet Solution
ISKENDEROV NURLAN
Date: 23.10.2016

Feed Conditions

Mass and strength of caustic and peroxide solution

Caustic 100 kg 47 wt%
Peroxide 200 kg 35 wt%
Mass of chlorine dioxide used 67.4 kg
Conversion of ClO2

Calculations

Total mass of ClO2 100 kg

Conversion of ClO2 67.4 wt% For the first reaction

 MATERIAL BALANCE
Component Mol.Mass Feed Mass Reacting
kg/kmol kg kmols

ClO2 67.5 100 1.481 -1.481

H2O2 34 70 2.059 -2.059
NaOH 40 47 1.175 -0.999
NaClO2 90.5 0 0.000 0.000
H2O 18 183 10.167 0.000
O2 32 0 0.000 0.000
Cl2 71 0 0.000 0.000
Total 400 14.882
MATERIAL BALANCE
After Composition Without O2 and Cl2
kmols kg Molar % Mass % kg %

0.000 0.00 0.0 0.0 0.00 0.0

0.000 0.00 0.0 0.0 0.00 0.0
0.176 7.06 1.1 1.8 7.06 2.2
0.999 90.37 6.3 22.6 90.37 27.7
12.725 229.05 80.0 57.3 229.05 70.2
1.762 56.38 11.1 14.1 0.00 0
0.241 17.15 1.5 4.3 0.00 0
15.903 400.0 100.0 100.0 326.47 100.0