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ENERGY
What is this topic about?
To keep it as simple as possible, (K.I.S.S.) this topic involves the study of:
1. HIGH ENERGY COMPOUNDS & FUELS
2. CARBON & CARBON COMPOUNDS
3. THE CHEMISTRY OF COMBUSTION
4. RATE OF CHEMICAL REACTIONS
...all in the context of societys use of fuels.
Combustion
Photo by Alex M
Exothermic &
From the humble match to a
rocket launch, Combustion is Endothermic
the chemical reaction that chemical changes,
releases the energy of the
and then extend your chemical
Photo www.broken-arts.com
The Variety
Origin of
of Allotropes Possible Carbon
Fossil Fuels of Compounds
Carbon
Natural Gas
Alkanes & Alkenes
Significance
of Names
Photosynthesis Formulas
Structures
Carbon Properties
High Energy Compounds of
& & Alkanes & Alkenes
Fuels Carbon Compounds
Safety Issues
Refining
of Petroleum
ENERGY The
Combustion
Reaction
Chemistry
of Bond Breaking,
Rate of Bond Making
Combustion
Chemical
Reactions
Activation
Slow, Fast Energy
&
Explosive
Factors Combustions.
that Effect
Safety Issues
Reaction Rate
Exothermic
Pollution from &
Temperature Fuel Combustion Endothermic
Concentration Temperature
Size of solid &
particles Kinetic Energy
Catalysts of Particles
Incomplete
Combustion
Models of
Catalysts Catalyst
& Action
Activation Energy
green pigment
Composition of Natural Gas
in chloroplasts As an example of just which high-energy compounds are
of plant cells
ligh
t en
present in a fossil fuel, the following table summarizes the
ergy composition of Natural Gas which is chemically the
simplest of the fossil fuels. (K.I.S.S. Principle!)
chlorophyll
WATER + CARBON GLUCOSE + OXYGEN
DIOXIDE Compound Formula Typical % in
Name Natural Gas
to
high-energy air
from from sugar (food) Methane CH4 90%
soil air Ethane C2H6 5%
Propane C3H8 2%
Butane C4H10 1%
6H2O + 6CO2 C6H12O6 + 6O2 Other gases CO2, SO2, H2 2%
The Element Carbon Diamond is also a covalent lattice of carbon atoms, but
Carbon is element number 6 in the Periodic Table. the atoms are arranged in a tetrahedral pattern, forming a
huge 3-D crystal lattice.
C
Carbon
Configuration = 2.4 hardest natural
substance known.
Some other elements that have allotropes include sulfur, The best known has the formula C60, in which the carbon
phosphorus, oxygen and tin. atoms are arranged to form a sphere resembling a soccer ball.
C
Allotropes of Carbon
In Graphite, the atoms are arranged in hexagonal rings
60
which connect to form flat sheets.
The atoms in
each sheet are
strongly bonded,
(m.p. & b.p. are
high) but the
bonds between
the sheets are
very weak. They
can easily slide
past each other,
so graphite is
slippery.
The Bucky Balls have not yet found a practical use, but
Because of its slipperiness, graphite is an excellent they have potential for use as high temperature lubricants,
lubricant, used for example, in door locks. Its most familiar for making super-conducting polymers or even as
use is the lead in a lead pencil. specialized capsules for administering medicines.
Unusually for a non-metal and covalent lattice, graphite is a ALLOTROPES:
good conductor of electricity and is used in electric motors Same element, same atoms.
in the rotating contacts called brushes; in this role it both Different atomic arrangements,
conducts electricity and helps lubricate the rotating axle. different physical properties.
C C Ethane Molecular
Model
Molecular Formula C2H6
Single Bond
Structural Formula
A single C-C bond involves sharing one pair of electrons.
Each carbon atom has 3 other bond positions available, H H
allowing the formation of chains, rings and networks.
H C C H
Condensed
C C
H H Structural Formula CH3CH3
Propane Molecular
Double Bonds (sharing 2 pairs of electrons) Model
and Molecular Formula
Triple Bonds (sharing 3 pairs) create even more possibilities. C3H8
C C Structural Formula
H H H
H C C C H
The result is that carbon can form more possible
compounds than all the other elements put together. H H H Condensed
Structural Formula CH3CH2CH3
The ALKANES
are HYDROCARBONS
containing only SINGLE C-C Bonds.
CnH2n+2
where n = number of carbon atoms
1 Meth-
2 Eth- Structural Formula
3 Prop- H H
4 But- C C Condensed
Structural Formula CH2CH2
5 Pent- H H
6 Hex-
7 Hept- Propene Double C=C Bond
}
Obviously, the alkanes and alkenes with 4 or less carbon
Single C-C bonds all atoms are already gases at room temperature, but even
Double C=C bonds non-polar those which are liquids are highly volatile.
C-H bonds covalent
Consider octane, a component of petrol. Its boiling point
Therefore, you would expect these compounds to: is a little above that of water, but it is much more volatile.
At room temperature, octane (petrol) in an open container
have relatively low m.p. & b.p.s and youd vaporizes rapidly compared to water under the same
be insoluble in water be correct ! conditions.
be non-conductors of electricity
The explanation is, again, all about bonding. Water
To keep it simple, (K.I.S.S. principle) consider just the molecules tend to cling together because of the dipole-
boiling points: dipole attractions of hydrogen bonding. Octane molecules
have only the weak Dispersion Forces holding them, and
Alkane b.p. State Alkene b.p. State many molecules have enough energy to escape into the gas
(oC) 25oC (oC) 25oC state, even at temperatures well below the boiling point.
Methane -162 gas
Ethane -89 gas Ethene -104 gas The volatility of the alkanes and alkene has important...
Propane -42 gas Propene -48 gas
Butane -1 gas Butene -6 gas Safety Consequences.
Pentane 36 liquid Pentene 30 liquid We havent yet looked at the Chemical Properties of
Hexane 69 liquid Hexene 64 liquid alkanes and alkenes, but dont forget that these are fuel
Heptane 98 liquid Heptene 94 liquid compounds... they contain a lot of energy, are highly
Octane 126 liquid Octene 121 liquid inflammable, and now we find out they are highly volatile
as well! DANGER, DANGER!
When these values are graphed the pattern becomes
obvious, and also the great similarity between the alkanes
and alkenes (at least for this property). Natural Gas
is mostly methane.
100
It must be stored in
high pressure cylinders,
es es outdoors and kept
en
Boiling Point (oC)
lkan Alk
A cool.
0
stored as pressurized
liquids in pressure
200
1 2 3 4 5 6 7 8 outdoors, or in well-
No. of Carbon Atoms ventilated areas only.
Inter-molecular Forces? Small amounts of smelly chemicals are added to gas fuels
Inside each molecule are strong, non-polar, covalent bonds. so that leaks are easily detected by smell.
However, the only forces between the molecules are the
Petrol, Kerosene & Diesel
very weak Dispersion Forces, so m.p. & b.p. are
generally low. are highly volatile liquid fuels. They must be stored in sealed
drums or tanks, and all sparks or flames (even mobile
Dispersion forces become stronger as the size and mass of phones) kept well away. All transfer of fuel from tank to
the molecule increases, which explains the pattern of the tank (e.g. filling the car) must be done outdoors.
graph. SAFETY IS CHEMICAL COMMON SENSE
Heat
er
Photo by Diana
The next step is to separate the petroleum mixture into Ethanols b.p. = 78oC. Waters b.p. = 100oC.
more useful fractions. This is achieved by...
The mixture is heated gently until the vapour temperature
Fractional Distillation is about 80oC. At this temperature the distillate collected
which separates the mixture according to differences in from the condenser is relatively pure ethanol, perhaps
boiling point. about 90%. Once all the ethanol has evaporated from the
mixture, the vapour temperature will rise to around 100oC,
indicating that now water is being collected.
Fractionating Tower in a Refinery
Simplified By watching the thermometer, and changing collection
Schematic beakers at the right time, it is possible to collect 2 separate
Diagram fractions from the original mixture.
Gas fraction
L.P.G.
Oil Refinery
Fractionating Towers
Petrol
Vapours condense on
collection trays...
Temperature decreases
Diesel &
at different levels... Kerosene
up the tower
Carbon is element No.6 and therefore has electron Another property of alkanes and alkenes is that they are
configuration a)...................... Carbon has 3 allotropes; highly volatile. This means that they tend to ai).......................
b)......................................., ........................................... and the readily. This has important safety consequences for these
so-called buckyballs. Allotropes are different physical highly inflammable, aj)......................-energy compounds.
forms of the same element. Allotropes are composed of
c).............................. atoms, but they are d)................................ Crude petroleum is a complex ak)............................ of many
differently, giving each allotrope different e).......................... compounds. At a refinery, it is separated into useful
..................................... al)............................. by the process of am)............................
................................................... The crude mixture is
Carbons 2 main allotropes have different properties which vaporized and as the vapours rise and the temperature
determine their uses: an)............................., each fraction ao)...................................
In Graphite, the atoms are arranged in f).............................. at a different level in the tower.
which can slide easily, so it is used as a g)...............................
It is also a good electrical h)..........................................., it is Part B Practice Questions
used in the rotating contacts in i)............................................. 1. There are other Homologous Series which have different
Its soft, slipperiness and black colour make it suitable for name endings, but the prefixes follow the same rules.
its major use, as the j)......................... in a pencil. How many carbon atoms in:
a) pentanone? b) butanal?
In k).................................. the atoms are arranged in a 3-D c) propanal? d) octanone?
l)......................................... (shape) pattern, producing a hard e) methanoic acid? f) hexanol?
crystal which has been prized for m).................................
throughout history. Its extreme hardness makes it useful 2. What is the molecular formula, structural formula and
for n).............................................................................................. condensed structural formula for nonene and decane,
given that the prefixes non = 9 and dec = 10.
The huge variety of carbon compounds is due to the ability
of carbon atoms to each form o)................. (number) of
Energy Content
must be chemicals
negative
during
broken... reaction
Energy
needed
Products have
LESS energy
Energy must be supplied to break these bonds.
Once the atoms are freed from the reactant molecules, they Now we must add the idea of Activation Energy:
can begin combining into new molecules to form the
products.
Ea Ea = Activation
Reactants Energy
The making of these new bonds always releases energy.
Energy Content
Products
New bonds
are made.
Energy
released
The Activation Energy is like a hill or energy barrier
which must be overcome before the chemicals can turn
Activation Energy into products. The Ea is the energy needed to break some
The reaction cannot begin until some energy is supplied to bonds in reactant molecules so the atoms can begin to
break some bonds in reactant molecules. This energy rearrange themselves. Remember, that this is connected to
requirement is called the Activation Energy. the value of the Ignition Temperature of a fuel.
Once a combustion reaction gets started, the energy
released by the exothermic reaction provides the activation
energy for other molecules, so the reaction continues. Ea
may be incomplete:
H less
octane + oxygen carbon monoxide + water
positive C8H18(g) + 17 O2(g) 8CO(g) + 9H2O(g)
Reactants
2
In this topic, you have seen combustions, while back in In this case, the solid carbon formed is soot, often
topic 2 you saw active metals react with observed from diesel exhausts, burning candles, and
water or acids. In topic 3 you measured bunsen burners set to a yellow flame.
the heat released
during dissolving
Incomplete Combustion
of carbon-based fuels
results in the formation of
Carbon Monoxide and/or soot
Endothermic
Reactions Try the Worksheet at the end of this section
Carbon Dioxide
However, the release of billions of tonnes of CO2 from
fossil fuel combustion is believed to be leading to a
Greenhouse Effect, and causing global warming. This
may be leading to (is leading to?) major environmental
changes, such as alterations to climates and weather
patterns.
Emission of SO2 is minimized by In 2005, the world economies were shocked by a sudden
removing sulfur impurities during the refining of liquid spike in the price of petroleum. It is highly probable that
and gas fuels. such events will continue to happen (for both political and
economic reasons). This is certain to encourage research
scrubbing the exhaust emissions from coal-burning
and development of alternative, sustainable fuels. Its
power stations and sulfide-ore metal smelters. The SO2 already happening...
can be collected and used to make sulfuric acid for
industry. Now theres a career idea
for todays Chemistry students!
Preliminary Chemistry Topic 4
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keep it simple science
Incomplete Combustion occurs when there is a) an exothermic reaction with large H and
insufficient t)............................................ available, small Ea.
or when the fuel and air are not b) an exothermic reaction with small H and
u)............................................. thoroughly. In large Ea.
hydrocarbon fuels, incomplete combustion leads c) an endothermic reaction.
to the production of v)............................................. d) Which diagram (a, b or c) could describe a fuel
gas, or even particles of solid with a high ignition temperature? Explain your
w)..................................... answer.
Fast Combustions
In a gas stove or bunsen burner,
the fuel is mixed with air before
ignition. The fuel and oxygen
molecules are intimately mixed
together, then ignited as they
reach the burner nozzle.
CO2 H2O
TEMPERATURE
is a measure of the average
At higher concentration, the chances of reactants colliding
KINETIC ENERGY
is increased, so reaction rate is higher.
of the particles
Reactant Collision
CaCO3(s) + 2HCl(aq) CO2(g) + H2O(l) + CaCl2(aq) &
molecule(s)
adsorb to Reaction
You would have found that the reaction occurs faster with surface
the powdered solid than with larger lumps. This is because Bond placed under
the smaller solid pieces in the powder add up to a larger
strain by adsorption CATALYST
to catalyst
total surface area for the acid to react with. Collisions
between reactants occur more often, so the reaction
Many Industrial processes rely on catalysts of this type:
proceeds faster.
In the manufacture of Ammonia
Catalysts N2(g) + 3H2(g)
Fe catalyst
2NH3(g)
A Catalyst is a chemical substance which increases the
rate of a reaction, without being consumed or permanently
the reaction rate is speeded up using an iron catalyst, finely
changed by the reaction.
divided to provide greater surface area.
Catalysts are widely used in Industrial Chemistry (examples In the Catalytic Cracking of petroleum compounds at
at right) but perhaps the most notable example of catalysts an oil refinery (to be studied in a later topic) larger
is in Biology. All living cells carry out thousands of hydrocarbon molecules are broken up to increase the yield
chemical reactions which would occur far too slowly for life of the valuable petrol fraction. The reaction is speeded up
to function if not for catalysts. In every cell, every reaction by a catalyst of Zeolite; a natural clay mineral with a large
is made possible by protein catalysts called Enzymes. surface area, and an affinity for hydrocarbon molecules.
H With Catalyst.
Activation Energy is very slow, but if a small amount of NO2(g) is added to the
reduced mixture, 2 faster reactions occur in sequence:
Products
Reaction 1: SO2(g) + NO2(g) SO3(g) + NO(g)
Note that H is NOT affected
Reaction 2: 2NO(g) + O2(g) 2NO2(g)
If the Activation Energy requirement is lower, then at any The NO2 is regenerated at the end, and has not been
given temperature there will be more reactant molecules consumed... it is a catalyst for the reaction, and each NO2
having the energy to react... so the reaction goes faster. molecule can be recycled over and over.
Preliminary Chemistry Topic 4
Copyright 2005-2007 keep it simple science
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Emmaus Catholic College SL#802440
keep it simple science
Practical Work: Catalysts Another Example
You may have carried out a practical experiment to see the of an experiment on catalysts uses the following reaction:
effect of a catalyst on a reaction rate.
hydrogen + iodide + hydrogen iodine + water
A popular experiment is to use the familar reaction peroxide ions ions
H2O2(aq) + 2I-(aq) + 2H+(aq) I2(aq) + 2H2O(l)
Mg(s) + 2HCl(aq) H2(g) + MgCl2(aq)
The reaction is quite slow, but can be followed visually over
with, and without a catalyst. several minutes because while the reactants are colourless,
the iodine product is a yellow-brown colour.
The catalyst used is a small
piece of copper metal, which a
strip of magnesium ribbon is Solution
wrapped around. (The metals darkens as
must be in contact.) Product I2
Colourless forms
In contact with the copper, it Reactants
will be found that the
magnesium reacts much faster
than an identical experiment
without the copper.
At the end of the reaction, the copper is totally If a few drops of a dilute solution of sodium molybdate
unchanged... it speeds the reaction up, but is not (NaMoO4) is added to another identical mixture, the
consumed or changed itself; it is a catalyst. reaction proceeds to completion much faster... a few
seconds compared to many minutes.
The method by which the copper catalyses the reaction -
does not fit either of the models described on the The molybdate ion (MoO4 , a polyatomic ion) acts as a
previous page. catalyst and remains in the solution unchanged at the end.
Worksheet 4
Fill in the Blank Spaces
The rate of a combustion reaction depends on If solid substances are involved, then reaction
the reactant molecules a)................................. with rate can be increased by increasing the
each other. In a slow combustion, such as the u).................................................... of the solid, such
burning of b)............................... .............................., as by v).......................................................... .............
the reaction only occurs at the surface where
c)..................................... can reach the fuel. In a A catalyst is a substance which
gas stove or bunsen burner the fuel and air are w)..................................... the rate of a reaction,
mixed before d)......................................... The rate without x)............................................... or
of reaction is limited only by the flow of ............................................ by the reaction. In
e).................... & ................................ to the burner living things, all chemical reactions are controlled
nozzle. by catalytic proteins called y).....................................
Catalysts effect the energy profile of a reaction;
If a fuel-air mixture is allowed to build up, a spark they have no effect on the value of
or flame can result in an z)......................, but reduce the
f).......................................... Any combustible gas aa).............................. .................................. This
or even g)............................ can become an means that, at any given temperature, there are
explosive mixture if allowed to mix with air. This more reactant molecules with enough
has important h)........................................... ab)............................................ to commence the
implications for workplaces which produce dust reaction, so the ac).................................................
or fibres, such as i)................................., increases.
.................................., etc. (examples)
Some catalysts work by ad).......................................
According to the j)................................. Theory of reactant molecules to their surface in such a way
Matter, all substances contain particles which that collisions become more
are constantly k)................................... Adding heat ae)..................................... Chemical bonds may
energy causes the particles to l)................ also be placed under af)......................................
......................................... Temperature is a measure which makes it more likely that they can be
of the average m).................................................. of ag)................................... to begin the reaction.
the particles. This type of catalyst is common in industry, such
as the use of ah).................................. catalyst in
An increase in temperature causes all chemical the production of ammonia, and the use of the
reactions to n)............................................................. clay mineral ai)......................................... in the
This is because the particles will move aj).......................... Cracking in petroleum
o)......................................, and the chances of refining.
p)........................................... increases. Also, the
reactant molecules are more likely to have the Other catalysts work by providing an
necessary q).................................. energy at higher ak)................................ ......................................
temperatures. pathway from reactants to products. In these
cases, the catalyst actually takes part in the
Higher r)......................................... also increases reactions, but is al).......................................
reaction rates, by making it more likely that unchanged at the end.
s)...................................... will occur. In gases, the
t)............................................. of the gas is
equivalent to the concentration. WHEN COMPLETED, WORKSHEETS
BECOME SECTION SUMMARIES
ENERGY
Practice Questions 8.
These are not intended to be "HSC style" questions, but to If the compound hydrogen sulfide (H2S) underwent
challenge your basic knowledge and understanding of the combustion, you would expect the products to be:
topic, and remind you of what you NEED to know at the A. carbon dioxide and water
K.I.S.S. Principle level. B. water and oxygen
C. sulfur dioxide and water
When you have confidently mastered this level, it is
strongly recommended you work on questions from past D. hydrogen and sulfur dioxide
exam papers.
9.
Part A Multiple Choice The correctly balanced combustion equation is:
A. CH4(g) + 3O2(g) CO2(g) + H2O(g)
1. 2
The chemical raw materials for photosynthesis are B. CH4(g) + 3O2(g) CO2(g) + 2H2O(g)
A. water & oxygen
B. glucose & oxygen
C. carbon dioxide & glucose C. CH4(g) + 2O2(g) CO2(g) + 2H2O(g)
D. water & carbon dioxide
D. CH4(g) + 3O2(g) 2CO2(g) + 2H2O(g)
2.
When a fuel such as coal is burned, large amounts of 10.
energy are released. This energy was previously in the form During a chemical reaction, some chemical bonds are
of broken and others are formed. The correct statement is:
A. low energy compounds such as CO2 and water.
B. chemical energy stored in carbohydrates. A. energy is released by both making & breaking of bonds.
C. geothermal energy from mineral formation. B. energy is released when bonds are made, and absorbed
D. chlorophyll used in photosynthesis in ancient plants. when bonds are broken.
C. energy is released when bonds are broken, and absorbed
3. when bonds are made.
Allotropes of an element: D. energy is absorbed by both making & breaking bonds.
A. contain identical atoms in different arrangements.
B. are different atoms arranged in the same way.
C. have the same physical properties as each other. 11.
40
D. have the same appearance and uses. The diagram shows an energy
profile for a chemical
4. reaction. It would be true to Energy Content (kJ/mol)
The molecular model say that the reaction is: 30
shown is A. exothermic,
20
D. endothermic,
A. be a member of the alkene homologous series. and H = -10kJ/mol.
B. contain a triple carbon-carbon bond.
C. have a name ending in -ANE.
D. have polar molecules. 12.
A major problem associated with large scale use of fossil
6. fuels is:
Which of the following is NOT a property of the alkanes? A. the toxic effects of CO2 gas.
A. soluble in water B. SO2 gas release which causes petrochemical smog.
B. relatively low melting & boiling points C. carbon monoxide destruction of the ozone layer.
C. non-conductors of electricity D. global climate change due to CO2 gas release.
D. hydrophobic
7. 13.
In petroleum refining, Fractional Distillation separates the The risk of an explosive combustion is increased by:
mixture according to differences in: A. increasing the particle size of solid fuels.
A. melting point B. decreasing the collision rate of reactant molecules.
B. density C. storing liquid fuel in larger tanks or drums.
C. solubility D. allowing build-up of dust or fibres in the air.
D. boiling point
24. (4 marks)
During the combustion of petrol and diesel fuels both
release approximately the same amount of energy (per unit
Boiling Point (oC)
temperature.
1 2 3 4 5 6 7 8
Energy Content
Products
i) Describe this reaction
as endo- or exo-
thermic, and state the sign
of the value for H. Reactants