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Nujol is a brand of mineral oil by Plough Inc., cas number 8012-95-1, and density 0.

838 g/mL at 25
C, used in infrared spectroscopy. It is a heavy paraffin oil so it is chemically inert and has a
relatively uncomplicated IR spectrum, with major peaks between 2950-2800, 1465-1450, and 1380
1370 cm1[citation needed]. The empirical formula of Nujol is hard to determine exactly because it is a mixture
but it is essentially the alkane formula C
nH
(2n + 2) where n is very large.

To obtain an IR spectrum of a solid, a sample is combined with Nujol in a mortar and pestle or some
other device to make a mull (a very thick suspension), and is usually sandwiched
between potassium- or sodium chloride plates before being placed in the spectrometer. For very
reactive samples, the layer of Nujol can provide a protective coating, preventing sample
decomposition during acquisition of the IR spectrum. When preparing the sample it is important to
keep the sample from being saturated with Nujol, this will result in erroneous spectra since the Nujol
peaks will dominate, silencing the actual sample's peaks.

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