CAREER POINT

MOCK TEST PAPER

CENTRAL BOARD OF
SENIOR SECONDARY EXAMINATION
CHEMISTRY (Theory)
SOLUTIONS
Sol. 1 Negative deviation Sol. 9 (a) p-type, because In has 3 valence
electrons. Holes are produced which can
Sol. 2 Fe3+ is a better coagulating ion due to greater move through the crystal like positive
positive charge on it- charge.
(b) n-type, because P has 5 valence electrons.
Sol. 3 sucrose + H2O Glucose + fructose The fifth electron becomes delocalised
and is free contribute to electrical
Sol. 4 Due to the formation of [PCl4]+ [PCl6] conduction.

Sol. 10
Sol. 5 cresol , aniline
Anode Cathode
() (+)
Sol. 6 H2SO4 cannot be used along with KI in the
conversion of an alcohol to an alkyl iodide as NaOH
it converts KI to corresponding HI and then H2 or O2
oxidieses it to I2. KOH

Sol. 7
CH3 CH3 Porous carbon electrode
impregnated with Pt
CH3CH CH3COOH
O2 At anode at high pressure H2 is supplied and
following chemical reaction takes place

Cumene Cumene At Anode : H2(g) 2OH (aq) 2 H2O(l) + 2e

Hydroperoxide At cathode at pressure oxygen is supplied and
following reaction takes place
OH
1
H+ O 2 ( g ) + H 2 O ( l ) + 2e 2OH(aq)
+CH3COCH3 2
H2O
Cell reaction :
1
Sol. 8 1-Phenyl pentan-1-one H 2 (g ) + O 2 (g ) H2O(l)
2
O
CH3CH2CH2CH2C OR

CPTower,RoadNo.1,IPIA,Kota(Raj.),Ph:07445151200|www.careerpoint.ac.in Page#1
 Conducting can be defined as the tendency of
the solution to conduct electricity and
conductance of all the ions present in 1 cm3
of solution which is present between
electrodes present 1 cm apart and area of
electrode is such that whole solution is
present between them-
Molar conducting can be defined as
conductance of all the ions present in V cm3
of solution containing 1 mol electrolyte and
solution is kept between electrodes present
1 cm apart and area of electrode is such that
it contain whole solution between them units
of specific conductivity
K = S cm1
molar conductivity
m = S cm 2 mol 1
Sol. 11 Given WA = 19.5 g , WB = 500g,
Kf = 1.86 Kgmol1
Tf(obs) = 1C
K f WB 1000
Tf =
MB MA
K f WB 1000
MB =
Tf M A
1.86K kg mol 1 19.5g 1000g
= Calcinations :- Heating of ore in limited
1.0K 500kg
= 72.54 gmol1
Molecular mass of CH2FCOOH
= 12 + 2 + 19 + 32 + 1 = 78 g mol1
i = normal molecular mass/observed molecular
mass = 78/72.54 = 1.0753
Ka = 0.5 (0.0753)2
Ka = 3.07 103
Sol. 12 (a) Due to the formation of chemical bonds
between adsorbate and adsorbent in case
of chemisorptions
(b) Brownian movement and Tyndall effect
(c) The movement of colloidal particles
under an applied electrical potential is
electrophoresis. When electrophoresis of
dispersed particle in a colloidal system is
prevented by some suitable means, it is
observed that dispersion medium itself
begins to move in an electric field. This
phenomenon is known as electro
osmosis.
Sol. 13 No. of moles of ethylene glycol = nB
Molar mass of C2H6O2 = (24 + 6 + 32)g mol1
222g
NB = = 3.58 mol
62mol 1
mass of solution = (250 + 222)g = 472g
Sol. 14 (a) As flux to remove FeO impurities in the
form of slag FeSiO3.
(b) Roasting :- Heating of ore in excess of
air below its melting point
supply of air below its melting point
F F
F
S Xe
Sol. 15 (a) (b)

CH2FCOOH CH2FCOO + H+ F
F F
C mol L1 0 0
C(1 ) C C Sol. 16 (a) Due to strong inter particle force
a = i 1 = 1.074531 = 0.0753 (b) Due to variable oxidation state

[CH 2 FCOO ][H + ] C C 2

ka = = = Sol. 17 In gaseous phase, basic character of amines
[CH 2 FCOOH] C(1 ) 1
increases with increases in number of electron
19.5 1000 releasing groups, due to + I effect, so trend of
C= = 0.5M
78 500 basic character is 3 > 2 > 1.
Ka = C2
CPTower,RoadNo.1,IPIA,Kota(Raj.),Ph:07445151200|www.careerpoint.ac.in Page#2
 But in aqueous phase, salvation of
ammonium cation occurs by water molecules,
greater the size of ion, lesser will be the
salvation, and lesser will be the stability of
ion, so on combining + I effect and salvation
effect, in aqueous phase trend changes to
2 > 3 > 1.
Sol. 18 (a) During Friedel Craft's alkylation,
aluminium chloride acts as a catalyst, as
well as a Lewis acid, if forms salt with
NH2 group of aniline, so thatNH2 group
acquires a positive charge, and acts as a
deactivating group, so aniline does not
undergo FCA.
(b) During nitration in strongly acidic
medium aniline is protonated to form
anilinium ion, which is a meta directing
group, so along with o & p isomers,
meta isomers is also obtained.
E 0cell = (RT / nF) ln K
(ii) When the concentration decreases the
number of ions present in unit volume of
solution decreases, as a result electrical
conductivity decreases.
OR
(a) Galvanic cells, that are designed to
convert the energy of combustion of fuels
like H2, CH4, CH3OH etc. directly into
electrical energy are called fuel cells.
They produce electricity with an
efficiency of about 70% and are pollution
free.
(b) Reactions taking place in Leclanche cell
Anode : Zn(s) Zn2+ (aq) + 2e
Cathode :
2 MnO2(s) + 2 NH +4 (aq) +2e
2MnO(OH) + 2NH3
(c) Zn(s)Zn (aq) | | Ag2O(s) | Ag(s) | OH(aq)
2+

Sol. 19 (a) In the first cell silver is deposited at E 0cell = E0(Ag2O/Ag) E0Zn2+ / Zn
cathode according to the equation E0(Ag2O/Ag) = 0.344V (0.76 V)
(i) Ag+ (aq) + e Ag (s) = 1.104 V
107.8 gAg = 1F electricity Zn(s) + Ag2O(s) + H2O(l)
1. 78gAg = 0.01F Zn2 +(aq)+2Ag(s) + 2OH(aq)
= 965C electricity n=2
(ii) The oxygen gas is liberated at anode of nE 0cell
2.303RT = at 25C
first cell as well as second cell according 0.059
to equation 2 1.104
log k c = = 37.42
+
2 H 2 O (l ) 4 H ( aq ) + 4e + O 2 ( g ) 0.059
4 Electricity = 1 mol O2 in each cell kc = anti log (37.42) = 2.34 1037
4F = 32g O2 in each cell
Sol. 20 (a) Lyophillic colloids-(i) They have strong
32g
0.01F = 0.01g forces of attraction between the dispersed
4g
phase and dispersion medium. (ii) They
= 0.08 g O2 in each cell are reversible in nature
Total weight of O2 liberated Lyobolic colloids (i) They have work
= 2 0.08g = 0.16 g (in both cells) force of attraction between the dispersed
(b) phase and dispersion medium (ii) They
(i) The equilibrium constant are irreversible in nature. (Any one
K and E 0cell are related by the relation difference)

CPTower,RoadNo.1,IPIA,Kota(Raj.),Ph:07445151200|www.careerpoint.ac.in Page#3
 (b) (i) Due to the scattering of light by (iv)
colloidal particles, the path of light
becomes visible. The effect is called CH2= CHCH=CH2+ CH2=CH
Tyndall effect. The illuminated path of Butadiene C6H5
the beam of light is called Tyndall cone. Styrene

(ii) The colloidal particles get precipitated at CH2CH=CHCH2CH2CH

n
one of the electrodes, having charge C6H5
opposite to the charge they have. Buna-S

Sol. 21 (A) Normal Pr otein

Denatured Pr otein Sol. 23 (A)(i) Aspirin
( 2, 3or 4) Factors ( always 1)
OCOCH3
(B) Nucleotide = Nit.Base + Pentose + H 3 PO 4 COOH
sugar

(C) pH at which amino Acids do not Migrate

towards any electrode. (ii) Paracetamol
OH
Sol. 22 (A) Thermoset polymer :
Due to extensive cross bonds shape
cannot be changed by heating &
cooling eg. Bakelite NHCOCH3
Thermoplastic polymer : (iii) Bithionol
Unbranched or less branched Cl OH HO Cl
polymers
S
Shape may be changed by heating &
Cl Cl
cooling
(iv) Chloroxylenol
OH
(B) (i) nCH2= CH CH2CH
n
Cl Cl
PVC
CH3 CH3
(ii) nCH2= CH CH2CH Cl
n
CN CN (B) Antacids Chemicals which reduces
PAN acidity in stomach
(iii) e.g. (1) Omeprazole
HOOC COOH + CH2CH2 (2) Lanso prazole
Terphatlic Acid OH OH (3) Al(OH)3
Ethylene Glycol (4) Mg(OH)2 etc

+4
Sol. 24 (a) Ce (b)
CH2 COOCH2 CH2O
n (i)Cr2 O 72 + 3Sn+2 +14 H+
Terylene
2Cr+3 +3Sn+4 + 7H2O
(ii)Mn O 4 +5Fe+2 + 8H+
Mn+2 + 5Fe+3 +4H2O

CPTower,RoadNo.1,IPIA,Kota(Raj.),Ph:07445151200|www.careerpoint.ac.in Page#4
Sol. 25 (a) Trans CH2OH
(b) [NiCl4]2 [Ni(CO)4] FeCl3
Ni+2 = [Ar] 4S0 3d8 Ni = [Ar] 4s2 3d8 No violet colouration

Benzyl alcohol
3d 4s 4p 3d 4s 4p
(ii) Butan-2-ol when warmed with NaOI
CO is strong field ligand
sp3 (I2/NaOH) gives yellow precipitate
Cl is weak field ligand iodoform while 2-Methylpropan-2-ol
sp3 does not give this test
OH O
Sol. 26 In haloarenes CX bond acquires a partial +NaOI
CH3CH2CHCH3 CH3CH2CCH3
double bond character due to resonance. As a NaO
Butan-2-ol H2O +3NaOI 3NaOH
result the bond cleavage in haloarenes is
difficult than haloalkanes and therefore, they O
+NaOH
are less reactive towards nucleophilic CHI3 CH3CH2CCI3
substitution reaction. Iodoform
(Yellow ppt.)
X X X CH3
+NaOI No yellow ppt.
CH3CCH3
OH
2-methyl propan-2-ol

X X
Sol. 28 (a)
(i) Rate equation
d[C12 H 22 O11 ] d[H 2 O]
Rate = =
OR dt dt
d[C 6 H12 O 6 ] d[C 6 H12 O 6 ]
= =
(i) CH3I reacts faster than CH3Br as dt dt
iodine is a better leaving group because (ii) Rate law equation
of its larger size. Rate = K[C12H22O11]
(ii) CH3Cl (1 halide) reacts faster than (iii) Molecularity 2
(CH3)3CCl (3 halide) since in case (iv) Order first order
tertiary butyl chloride three bulky methyl
group hinder the approaching (b) As the reaction is of first order therefore
nucleophile. 2.303 P0
k= log
t 2P0 Pt
Sol. 27 (i) Phenol gives a violet colouration with
when t = 100s
FeCl3 solution while benzyl alcohol does
(2.303) (0.5)
not. k= log
100 2 0.5 0.6
6C6H5OH + FeCl3
k = (2.303) / 100 log 1.25
[(C 6 H 5 O)6Fe]3 + 3HCl + 3H + = (2.303) / 100 (.0969)
( Violetcolouration )
= 2.2316 103 sec1

CPTower,RoadNo.1,IPIA,Kota(Raj.),Ph:07445151200|www.careerpoint.ac.in Page#5
 When Sol. 29 (a) (i) due to increment in bond length
P0 = 0.65 atm i.e. P0 + P = 0.65 atm (ii) In its structure only one H is attached
P = 0.65 P0 = 0.65 0.50 = 0.15 atm with O
Therefore the pressure of SO2Cl2 at time t O
(PSO 2Cl 2 ) P
H H
= P0 P = (0.50 0.15) atm = 0.35 atm H
Rate at that time = K (PSO Cl )

2 2
(b) (i) 2Pb(NO3)2 2PbO + 4NO2 + O2
3
= 2.2316 10 0.35
(ii) 2XeF2 + 2H2O 2Xe + 4HF + O2
= 7.8 104 atm sec1
(iii) Ca3P2 + 6H2O
3Ca(OH)2 + 2PH3
OR
(a) Sol. 30
In the absence of catalyst (a)
(i)
In the presence of
PCC
catalyst CH3CH2OH CH3CHO
Energy aldol dil.NaOH

CH3CHCH2CHO
Path of reaction OH
Effect of catalyst on activation energy (ii)
(b) Because catalyst catalyses the forwards
as well as backward reaction to the same CHO CH3CHOH
extent. CH3MgBr
(c) Given HOH/H+
K1 = 4.5 103 s1 ; T1 = 283 K
[O]
K2 = 1.5 104s1 ; T2 = ? , Ea = 60 KJ mol1
K2 Ea T2 T1 CH3C= O
log =
K1 2.303R T1 T2
log (1.5 104) / (4.5 103)
T T1 (b)
= 60000 / (2.303 8.314) 2
T1T2 (A) Butyl butanoate (B) Butanoic acid
log 3.333 = 3133.63 [(T2283) / 283T2] (C) Butanol (D) But-1-ene
T2 = 283 / 0.9528
= 297 K = (297 273)C
= 24C

CPTower,RoadNo.1,IPIA,Kota(Raj.),Ph:07445151200|www.careerpoint.ac.in Page#6