I.

MATERIAL SAFETY DATA SHEET

Raw Material: ETHYLENE OXIDE

1. Raw Material Identification

Product Name Ethylene Oxide
Synonyms EO, EtO, Epoxyethane, Dimethylene Oxide, Oxane,
Oxirane, Alkene Oxide, Alpha/Beta- Oxidoethane,
Oxacyclopropane
Chemical Family Epoxide
Intended Use Chemical intermediate for production of antifreeze,
polyester resins, non-ionic surfactants and specialty
solvents; sterilizing agent; fumigant; cosmetics
A. Precautionary Labeling
Hazard Symbol

Signal Word Danger

B. Precautionary Statements
EFFECTS OF OVEREXPOSURE: May be fatal if inhaled in high concentrations. May cause
irritation of the respiratory tract, chest tightness, headache, nausea, vomiting, diarrhea, light-headed
feeling, dizziness, weakness, drowsiness, cyanosis, loss of coordination, convulsions, coma,
delayed lung injury (fluid in the lungs), immediate or delayed skin irritation or blisters, allergic skin
reaction.
OTHER POSSIBLE DELAYED HEALTH EFFECTS: May cause nervous system injury, cataracts,
adverse reproductive effects, chromosomal and mutagenic changes, and cancer. PEL: 1 PPM TWA
(as per the Ethylene Oxide Standard 29 CFR . EL: 5 PPM - excursion limit 15 minutes. ODOR:
Ether-like at high concentrations. Exposure to toxic levels may occur without warning to or detection
by the user.
PRECAUTIONS: Do not breathe vapor. Do not swallow. Do not get in eyes, on skin, or on clothing.
Store and use with adequate ventilation in accordance with the Ethylene Oxide Standard.
C. Laboratory Protective Equipment Required
A material that is chemical-resistant to this product is butyl rubber.

All handlers must wear at a minimum: Long-sleeved shirt and long plants, Shoes plus socks,
Chemical-resistant gloves, and
The employer should provide a respirator that is adequate to protect the health of the
employee and ensure compliance with all other OSHA statutory and regulatory requirements. When
handlers could have eye or skin contact with ETO or ETO solutions, such as during maintenance
and repair, vessel cleaning, or cleaning up spills, they must wear:
Chemical-resistant attire, such as an apron, protective suit, or footwear that protects the
area of the body that might contact ETO or ETO solutions, and
face-sealing goggles, a full face shield, or a full-face respirator.

When wearing respirators:

 1. Follow the respirator manufacturers users instructions for changing canisters.
2. Respirators must be fit-tested and fit-checked using a program that conforms to OSHAs
requirements.
3. Respirator users must be trained using a program that conforms to OSHAs requirements.
4. Respirator users must be examined by a qualified medical practitioner to ensure physical ability to
safely wear the style of respirator to be worn. A qualified medical practitioner is a physician or other
licensed health care professional (PLHCP) who will evaluate the ability of a worker to wear a
respirator. The initial evaluation consists of a questionnaire that asks about medical conditions (such
as a heart condition) that would be problematic for respirator use. If concerns are identified, then
additional evaluations, such as a physical exam, might be necessary. The initial evaluation must be
done before respirator use begins. It does not need to be repeated unless the health status of
respirator use conditions change

2. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Concentration ACGIH OSHA NIOSH

Components (%) Exposure Limits Exposure Limits Exposure Limits
Name/CAS No.
0.1 ppm; 5 ppm/10
Ethylene Oxide 100 1 ppm 1 ppm min

3. PHYSICAL AND CHEMICAL PROPERTIES

VAPOR DENSITY: 1.261 kg/m3 (0.078 lb/ft3) pH: Not applicable.

SPECIFIC GRAVITY (air = 1): 0.98 FREEZING POINT: -169C (-272F)
SOLUBILITY IN WATER: Soluble. BOILING POINT: -104C (-155 F)
EVAPORATION RATE (nBuAc = 1): Not applicable. EXPANSION RATIO: 489
ODOR THRESHOLD (detection): 270 ppm VAPOR PRESSURE: Not applicable.
COEFFICIENT WATER/OIL DISTRIBUTION: Not applicable. SPECIFIC VOLUME (ft3/lb): 13.8
APPEARANCE, ODOR AND COLOR: Colorless gas with a sweet odor. The cryogenic liquid is also colorless
and has a sweet odor.
HOW TO DETECT THIS SUBSTANCE (warning properties): There are no distinct warning properties. In terms
of leak detection, fittings and joints can be painted with a soap solution to detect leaks, which will be indicated
by a bubble formation.

4. FIRE AND EXPLOSION HAZARD DATA

Fire extinguishing media Use water spray, Carbon Dioxide, dry chemical,
alcohol-type or universal foams applied by
manufacturers recommended technique. Use fire
extinguishers with class B extinguishing agent.
Evacuate all personnel from danger area.
Special fire-fighting procedures Evacuate all personnel from danger area.
Immediately cool containers with water spray from
maximum distance taking care of not to extinguish

Unusual fire and explosion hazards
Toxic gases produced
5. HEALTH AND HAZARD DATA
Effects of overexposure
flames. Vapors formed from the product may travel
or be moved by air currents and be ignited by pilot
lights, other flames, smoking, sparks, heaters,
electrical equipment, static discharges or other
ignition sources at locations distant from product
handling point. Remove ignition sources if without
risk. If flames are accidently, explosive, re-ignition
may occur.. Stop flow of gas if without risk, while
continuing cooling water spray. Remove all
containers from area of fire if without risk. Allow fire
to burn out. Dilution of ETO with 23 volumes of water
renders it nonflammable, per OSHA29 CFR
1910.1047 appendix B. Union Carbide recommends
dilution with 100 volumes of water as an additional
safe practice. On site fire brigades should comply
with OSHA 29 CFR 1910.156.
Extremely flammable. It may form explosive mixtures
with air and oxidizing agents. Do not extinguish
flames due to possibility of explosive re-ignition.
Flammable vapors may spread from spill. Explosive
atmosphere may linger. Before entering area,
specially confined areas, check atmosphere with
appropriate device. No part of a container should be
subjected to a temperature higher than 52C
(Approximately 125F). Containers are provided with
pressure relief devices that are designed to vent the
contents when they are exposed to elevated
temperatures. Vapors can burn without the presence
of air or oxidizing agents. ETO can decompose
violently under certain conditions. Refer to DOT
EMERGENCY RESPONSE GUIDEBOOK for
isolation end evacuation distances. Vapor in air has
very low ignition energy (0,6mJ) and is prone to
static or other low energy ignition sources.
Carbon monoxide and carbon dioxide
Effects include skin, eye and respiratory tract
irritation or burns. Central nervous system effects
initially cause headache, dizziness and nausea and
in extreme cases, unconsciousness and death.
Peripheral nerve damage may result in muscular
weakness, giddiness, irrational behavior and loss of
sensation in the extremities. Dulling of the sense of

Target Organs
Medical conditions generally aggravated by
exposure
Emergency and first aid procedures
smell may occur.
Overexposure to this product may effect the skin,
eyes, respiratory system, liver, kidneys, brain, blood,
reproductive system and central nervous system.
cause damage to the kidneys or liver.
Preexisting skin, eye and respiratory disorders; lung,
blood, nervous system and peripheral nerve
disorders.
Eye Contact
Immediately flush eyes, including the entire surface
of the eyes and under the eyelids, gently but
thoroughly with plenty of running water for at least 15
minutes. Obtain medical attention immediately.
NOTE: Never wear contact lenses when working
with ethylene oxide. SKIN

Contact
Immediately flush skin thoroughly with water for at
least 15 minutes while removing contaminated
clothing and shoes. Obtain medical attention
immediately. Treat for possible cryogenic injury, if
needed by warming affected areas with warm water
(wrap with a blanket if warm water is not available).
Wash clothing before reuse and discard
contaminated leather articles such as shoes and
belts.
Inhalation
Remove exposed person to fresh air. If breathing has
stopped, give artificial respiration then have qualified
personnel administer oxygen, if needed. Get
immediate medical attention.
Ingestion
If patient is conscious give plenty of water (minimum
of two glasses) but DO NOT INDUCE VOMITING.
This material is corrosive. Keep head lower than hips
to avoid aspiration, should vomiting occur. Get
medical attention immediately.
Note To Physicians
Respiratory symptoms include nausea, vomiting and
irritation of the nose and throat. Pulmonary edema
may occur. Respiratory effects may be delayed.
Consider oxygen administration. If a chemical burn is
present, - decontaminate skin and treat as any
thermal burn. No specific antidote is known, however
 consider gastric lavage and administration of a
charcoal slurry.

6. REACTIVITY DATA
Conditions to avoid Avoid storage at warm temperatures. Do not store at
100F or greater in order to prevent polymerization.
Avoid storage at temperatures above 125F under
any circumstances. Avoid contact of ethylene oxide
with incompatible chemicals to avoid highly
exothermic polymerization reaction. Prevent
exposure to all sources of ignition such as heat,
flame, lighted tobacco products or electrical or
mechanical sparks.
Materials to avoid Ethylene may react violently with the following
materials: Strong oxidizers (e.g., chlorine, bromine
pentafluoride, oxygen, oxygen difluoride, and
nitrogen trifluoride); aluminum chloride, organic
peroxides, copper, nitrogen dioxide, ozone,
halocarbons, halogen acids, and hydrochloric acid.

Hazardous Polymerization May occur at elevated temperatures and in the

presence of oxidizers

7. Spill and disposal procedures

Steps to be followed in the event of a spill or Treat any ethylene oxide leak as an emergency. All
discharge cleanup personnel must wear full protective
equipment. Evacuate all personnel from the area
except those directly engaged in stopping the leak or
in cleaning up. Eliminate all ignition sources if this
can be done safely. Ethylene oxide/air mixtures
ignite readily and may detonate. Use water fog or
spray to disperse vapors. Flood spill with water spray
to dilute and render non-flammable.
Disposal procedure When disposed, ethylene oxide is a RCRA
hazardous waste with waste code U115
(Commercial chemical product - listed for toxicity and
ignitability). Waste ethylene oxide may be incinerated
in an approved hazardous waste incinerator or can
be biologically treated in an approved facility. Do not
incinerate any ethylene oxide containers. Ethylene
oxide is banned from land disposal. Dispose of
waste materials in accordance with all applicable
Federal, State and local laws and regulations.
 8. Protective Equipment
Personal Protective Equipment If engineering controls or work practices are not
adequate to prevent exposure to harmful levels of
this material, personal protective equipment (PPE) is
recommended. A hazard assessment of the work
should be conducted by a qualified professional to
determine what PPE is required.
Respiratory Protection Use a properly fitted, air-purifying or air-fed respirator
complying with an approved standard if a risk
assessment indicates this is necessary. Respirator
selection must be based on known or anticipated
exposure levels, the hazards of the product and the
safe working limits of the selected respirator.
Recommended: organic vapour filter (Type A)
Hand Protection Avoid skin contact. Use impervious gloves (e.g.,
PVC, neoprene, nitrile rubber). Wash hands with
plenty of mild soap and water before eating, drinking,
smoking, using toilet facilities or leaving work.
Eye Protection Safety glasses equipped with side shields are
recommended as minimum protection in industrial
settings. Chemical goggles should be worn during
transfer operations or when there is a likelihood of
misting, splashing or spraying of this material
Skin and Body Protection Avoid skin contact. Wear long-sleeved fire-retardant
garments while working with flammable and
combustible liquids. Additional chemical-resistant
protective gear may be required if splashing or
spraying conditions exist. This may include an apron,
arm covers, impervious gloves, boots and additional
facial protection.

9. Storage and Handling Precautions

Storage and Handling Precautions Wear all recommended protective clothing and
devices when handling this material. Have
established handling and emergency response
procedures in place prior to use. Ground and bond
shipping container, transfer line, and receiving
container. Protect containers from physical damage
and regularly inspect them for cracks, leaks or faulty
valves.
Engineering Controls Ethylene oxide, a major fire hazard, can burn in the
absence of oxygen. All electrical devices used in
areas processing or handling ethylene oxide must be
engineered and designed to the applicable local
electrical/fire codes. Safeguards can include
designing electrical devices as explosion-proof

Storage Segregation
Shipping and Storage Containers
10. Transportation data and other information
United States Department of Transportation (U.S.
DOT 49 CFR 172.101)
Canadian Transportation Of Dangerous Goods
Other transport information
and/or intrinsically safe. When considering
engineering controls, users of ethylene oxide should
consult the current edition of NFPA 55 (Storage,
Handling, and Use of Compressed Gases).
Sterilization facilities should consult NFPA 560
(Storage, Handling, and Use of Ethylene Oxide for
Sterilization and Fumigation) and NIOSH Publication
NO. 2000- 119 (Alert: Preventing Worker Injuries and
Deaths from Explosions in Industrial Ethylene Oxide
Sterilization Facilities).
Store ethylene oxide in a cool, dry, well-ventilated
area away from incompatible chemicals and sources
of ignition. Store cylinders and drums upright; secure
containers tightly; do not drag or slide; and move in a
carefully supervised manner with a suitable hand
truck. DO NOT STORE IN DIRECT SUNLIGHT.
Ethylene oxide is shipped and stored in UN 1A1
specification drums, DOT specification drums and
cylinders. Nitrogen must be charged into the
container after filling with ethylene oxide, bringing
the total container pressure up to 50 psig. Before
returning container to supplier, pressurize container
with nitrogen to 50 psig total pressure; replace valve
plugs tightly in outlets. Check container valves and
plugs for leaks prior to shipment. In addition, please
refer to the most current edition of NFPA Publication
560, "Standard for the Storage, Handling and Use of
Ethylene Oxide for Sterilization and Fumigation".
Proper Shipping Name: Ethylene Oxide
Id Number: UN1040
Hazard Class Or Division: 2.3
Labeling Requirements: 2.3; 2.1
Quantity Limitations:
Passenger Aircraft Or Railcar: Forbidden
Cargo Aircraft Only: Forbidden
Additional Shipping Description: Toxic-Inhalation
Hazard Zone D Canadian
Shipping Name: Ethylene Oxide
Un Number: UN1040
Class: 2.3; 2.1
TDG Classification: Regulated Material.
Proper Shipping Name: Ethylene Oxide
Class/Division: 2.3 (2.1)
Subsidiary Risk: 2.1
 Identification Number IMDG: UN 1040
Packing Group: I
Packing Instructions: 200.
ADR Class: 2
ADR Label Item Nr: 2.3 (Toxic Gas) + 2.1
(Flammable gas)
ADR/RID Hazard Nr: 236 CEFIC
Treamcard Nr: 16
CEFIC Groupcard Nr: 20g43
EMS: F-D; S-U Marine
Pollutant: Not Listed
Other transport Information: Only transport on
vehicles where the load space is separated from the
drivers compartment. Ensure vehicle driver is aware
of the potential hazards of the load and knows what
to do in case of an accident or an emergency.

By-Product: CARBON DIOXIDE

1. Product Identification
Product Name Carbon dioxide
Synonyms Carbon dioxide, Carbonic Anhydride, Carbonic Acid
Gas, Carbon Anhydride
Chemical Family Inorganic Gases
Intended Use Industrial and professional. Perform risk
assessment prior to use. Aerosol propellant.
Balance gas for mixtures. Beverage applications.
Biocidal uses. Blanketing gas. Blast cleaning.
Calibration gas. Carrier gas. Chemical synthesis.
Combustion, melting and cutting processes.
Cooling applications. Fire suppressant gas. Food
freezing. Food packaging gas. Freezing, Cooling
and heat transfer. Inerting gas. Inflation systems.
Laboratory use. Laser gas. Plant growth promoter.
Pressure head gas, operational assist gas in
pressure systems. Process gas. Purge gas.
Refrigerant. Solvent for extraction. Special effects
(entertainment). Test gas.
A. Precautionary Labeling
Hazard Symbol

Signal Word Warning

B. Precautionary Statements
Prevention: None.
Response: None.
 Storage: P403: Store in a well-ventilated place.
Disposal: None.
C. Laboratory Protective Equipment Required
Safety goggles, glasses or mask
Safety leather gloves
Safety shoes

2. COMPOSITION / INFORMATION ON INGREDIENTS

Concentratio
Hazardous n ACGIH OSHA OSHA
Exposure Limits Exposure Limits
Components (%) Exposure Limits (PEL) (STEL)
Name/CAS No.
Ethylene Oxide 100 5000 ppm 5000 ppm 30000 ppm

3. PHYSICAL AND CHEMICAL PROPERTIES

Gas Form: Liquefied gas

Colour: Colourless
Odour: Odourless
Odour Threshold: Odour threshold is subjective and is inadequate to warn of over exposure.
pH: 3.2 - 3.7 The pH of saturated CO2 solutions varies from 3.7 at 101 kPa (1 atm) to 3.2 at
2370 kPa (23.4 atm)
Melting Point: -56.6 C
Boiling Point: -78.5 C
Sublimation Point: -78.5 C
Critical Temp. (C): 31.0 C
Flammability (solid, gas): Nonflammable Gas
Vapour pressure: 45.1 bar ( 10 C)
Vapour density (air=1): 1.522 ( 21 C)
Relative density: 1.512 ( -56.6 C )
Solubility(ies):
Solubility in Water: 2.900 mg/l ( 25 C)
Partition coefficient (n-octanol/water): 0.83
Dynamic viscosity: 0.07 mPa.s ( 20 C) 0.02 mPa.s ( 20 C)

4. FIRE AND EXPLOSION HAZARD DATA

Fire extinguishing media Carbon dioxide is nonflammable and does not
support combustion. Carbon dioxide is an
extinguishing agent for class B and C fires. Use
extinguishing media appropriate for the surrounding
fire..
Special fire-fighting procedures
Unusual fire and explosion hazards
Toxic gases produced
5. HEALTH AND HAZARD DATA
Effects of overexposure
Target Organs
Medical conditions generally aggravated by
exposure
Emergency and first aid procedures
Evacuate personnel from danger area. Carbon
dioxide is nonflammable. If possible, without risk,
remove cylinders from fire area or cool with water.
Self-contained breathing apparatus (SCBA) may be
required for rescue workers.
Upon exposure to intense heat or flame, cylinder will
vent rapidly and or rupture violently. Most cylinders
are designed to vent contents when exposed to
elevated temperatures. Pressure in a container can
build up due to heat and it may rupture if pressure
relief devices should fail to function.
None
Carbon dioxide is a nonflammable liquefied
compressed gas packaged in cylinders under its own
vapor pressure of 838 psig at 70 F (21.1 C). High
concentrations can cause rapid suffocation and can
also increase respiration and heart rate. Contact with
liquid may cause frostbite. Avoid breathing gas. Self
contained breathing apparatus (SCBA) may be
required by rescue workers.
Central Nervous System
None
Inhalation
Persons suffering from overexposure should be
moved to fresh air. If victim is not breathing,
administer artificial respiration. If breathing is difficult,
administer oxygen. Obtain prompt medical attention.
Eye
Contact with liquid or cold vapor can cause freezing
of tissue. Gently flush eyes with lukewarm water.
Obtain medical attention immediately.
Skin
Contact with liquid or cold vapor can cause frostbite.
Immediately warm affected area with lukewarm water
not to exceed 107 F.
Notes To Physician
There is no specific antidote. Treatment for
overexposure should be directed at the control of
 symptoms and the clinical condition.

6. Reactivity Data
Conditions to avoid None
Materials to avoid None
Hazardous Polymerization Will not occur

7. Spill and disposal procedures

Steps to be followed in the event of a leak or Evacuate personnel to safe areas. Wear self-
discharge contained breathing apparatus when entering area
unless atmosphere is proved to be safe. Ventilate the
area. Monitor oxygen level. If the leak is in the user's
system, close the cylinder valve, safely vent the
pressure, and purge with an inert gas before
attempting repairs.
Disposal procedure For emergency disposal, secure the cylinder and
slowly discharge gas to the atmosphere in a well
ventilated area or outdoors. Small amounts may be
disposed of by reacting with a mild base.

8. Protective Equipment
Engineering Controls Provide ventilation and/or local exhaust to prevent
accumulation of carbon dioxide concentrations
above 5000 ppm.
Respiratory Protection Self-contained breathing apparatus (SCBA) or
positive pressure airline with mask are to be used in
oxygen-deficient atmosphere. Air purifying
respirators will not provide protection. Users of
breathing apparatus must be trained.
Hand Protection Sturdy work gloves are recommended for handling
cylinders. The breakthrough time of the selected
glove(s) must be greater than the intended use
period.
Eye Protection Safety glasses recommended when handling
cylinders.
Skin and Body Protection Safety shoes are recommended when handling
cylinders.

9. Storage and Handling Precautions

Handling Precautions Use a suitable hand truck for cylinder movement.
Never attempt to lift a cylinder by its valve protection
valve cap. Never apply flame or localized heat
directly to any part of the cylinder. Do not MSDS #
1005 Carbon Dioxide Page 3 of 6 Pub # 310-408
allow any part of the cylinder to exceed 125 F (52
C). High temperature may cause damage to
cylinder and/or premature failure of pressure relief
device which will result in venting of cylinder
contents. If user experiences any difficulty operating
cylinder valve discontinue use and contact supplier.
Never insert an object (e.g., wrench, screwdriver, pry
bar, etc.) into valve cap openings. Doing so may
damage valve causing a leak to occur. Use an
adjustable strap wrench to remove over-tight or
rusted caps. Only the proper CGA connections
should be used, never use adapters. Use piping and
equipment adequately designed to withstand
pressures to be encountered. If liquid product is
being used ensure steps have been taken to prevent
entrapment of liquid in closed systems. The use of
pressure relief devices may be necessary. Use a
check valve or other protective apparatus in any line
or piping from the cylinder to prevent reverse flow.
Carbon dioxide is compatible with all common
materials of construction. Pressure requirements
should be considered when selecting materials and
designing systems. Use a FULL, IN USE, and
EMPTY tag system on cylinders. This will reduce
the chances of inadvertently connecting or operating
the wrong cylinder.
Storage Precautions Cylinders should be stored upright in a well-
ventilated, secure area, protected from the weather.
Storage area temperatures should not exceed 125
F (52 C). Storage should be away from heavily
traveled areas and emergency exits. Avoid areas
where salt or other corrosive materials are present.
Valve protection caps and valve outlet seals should
remain on cylinders not connected for use. Separate
full from empty cylinders. Avoid excessive inventory
and storage time. Use a first-in first-out system.
Keep good inventory records.
Special Requirements Always store and handle compressed gases in
accordance with Compressed Gas Association, Inc.
(ph. 703-979-0900) pamphlet CGA P-1, Safe
Handling of Compressed Gases in Containers. Local
regulations may require specific equipment for
storage or use. CAUTION: Compressed gas
cylinders shall not be refilled except by qualified
producers of compressed gases. Shipment of a
compressed gas cylinder which has not been filled
by the owner or with the owners written consent is a
violation of federal law.

10. Transportation data and other information

United States Department of Transportation (US Dot Shipping Name: Carbon Dioxide
DOT) Hazard Class: 2.2 (Nonflammable Gas)
Identification Number: UN1013
Transportation of Dangerous Goods (TGD) Product RQ: None
Canada Shipping Label(S): Nonflammable Gas
Placard (When Required): Nonflammable Gas
Special Shipping Information: Cylinders should be
transported in a secure upright position in a well
ventilated truck. Never transport in passenger
compartment of a vehicle.

By-Product: DIETHYLENE GLYCOL

1. Product Identification
Product Name Diethylene Glycol
Synonyms
Bis(2-Hydroxyethyl) Ether; Dihydroxydiethyl Ether;
Beta,Beta'-Dihydroxydiethyl Ether; 2,2'-
Dihydroxyethyl Ether; 2,2'-Oxydiethanol; Ethylene
Diglycol; Diglycol; Glycol Ether; Glycol Ethyl Ether; 2-
Hydroxyethyl Ether; 3-Oxapentane-1,5-Diol; 3-Oxa-
1,5-Pentanediol; 2,2-Oxybisethanol; Brecolane NDG;
Carbitol; Deactivator E; Deactivator H; DEG; Dicol;
Dissolvant APV; TL4N
Chemical Family Glycols
Intended Use
This compound is used in the production of
polyurethane, unsaturated polyester resins and
triethylene glycol. It is also used as a textile
 softener, in petroleum solvent extraction, in the
dehydration of natural gas, as a plasticizer, in
surfactants and as a solvent for nitrocellulose,
resins, dyes, oils and many other organic
compounds. It is used as a humectant for tobacco,
cork, printing ink and glue. It is also used in casein,
in synthetic sponges and paper products, in
bookbinding adhesives, as a dyeing assistant, in
cosmetics, in antifreeze solutions, in lacquers, in
lubricants and in brake fluids.
A. Precautionary Labeling
Hazard Symbol

Signal Word Warning

B. Precautionary Statements
Prevention: Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Wash hands thoroughly after
handling.
Response: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse
mouth. Get medical advice/ attention if you feel unwell. Storage: Store locked up. Disposal:
Dispose of contents and container to licensed, permitted incinerator, or other thermal destruction
device.
C. Laboratory Protective Equipment Required
Protective clothing should be worn to prevent skin contact with diethylene glycol
Safety glasses, googles or face shields
Eyewash fountains and emergency showers

2. COMPOSITION / INFORMATION ON INGREDIENTS

Concentratio
Hazardous n AIHA WEEL OSHA NIOSH
Components (%) TWA Exposure Limits Exposure Limits
Name/CAS No.
Ethylene Glycol 0 0.2 100 mg/m3 -
107-21-1
Diethylene Glycol 99 100 10 mg/m3 - -
111-46-5

3. PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid.

 Color: Colorless
Odor: Odourless
Freezing Point: -6.5 C (20.3 F) Literature
Boiling Point: (760 mmHg) 244.9 C (472.8 F) Literature
Flash Point - Closed Cup: 138 C (280 F) Literature
Vapor Pressure: 0.002 mmHg @ 20 C Literature
Vapor Density (air = 1): 3.65 Literature
Specific Gravity (H2O = 1): 1.118 Literature
Solubility in water (by weight): 100 % @ 20 C Literature
Partition coefficient, noctanol/water (log Pow): -1.98 Estimated.
Autoignition Temperature: 229 C (444 F) Literature
Dynamic Viscosity: 35.7 mPa.s @ 20 C Literature
Explosive properties: Not explosive
Oxidizing properties: The substance or mixture is not classified as oxidizing.
Liquid Density: 1.18 g/cm3 @ 20 C Literature
Henrys Law Constant (H): 7.96E-10 atm*m3/mole; 25 C Estimated.

4. FIRE AND EXPLOSION HAZARD DATA

Fire extinguishing media Water fog or fine spray. Dry chemical fire
extinguishers. Carbon dioxide fire extinguishers.
Foam. Alcohol resistant foams (ATC type) are
preferred. General purpose synthetic foams
(including AFFF) or protein foams may function, but
will be less effective.
Special fire-fighting procedures Keep people away. Isolate fire and deny
unnecessary entry. Use water spray to cool fire
exposed containers and fire affected zone until fire is
out and danger of reignition has passed. Fight fire
from protected location or safe distance. Consider
the use of unmanned hose holders or monitor
nozzles. Immediately withdraw all personnel from the
area in case of rising sound from venting safety
device or discoloration of the container. Burning
liquids may be extinguished by dilution with water.
Do not use direct water stream. May spread fire.
Move container from fire area if this is possible
without hazard. Burning liquids may be moved by
flushing with water to protect personnel and minimize
property damage.
Unusual fire and explosion hazards Container may rupture from gas generation in a fire
situation. Violent steam generation or eruption may
occur upon application of direct water stream to hot
liquids
Toxic gases produced Carbon monoxide and carbon dioxide
 5. HEALTH AND HAZARD DATA
Effects of overexposure Hazardous in case of skin contact (irritant,
permeator), of ingestion. Slightly hazardous in case
of eye contact (irritant).
The substance is toxic to blood, kidneys, the nervous
system, liver. Repeated or prolonged exposure to the
substance can produce target organs damage.
Target Organs Nervous system, blood, kidneys
Medical conditions generally aggravated by Persons with pre-existing skin disorders or eye
exposure problems, or impaired liver, kidney or respiratory
function may be more susceptible to the effects of
the substance.
Emergency and first aid procedures Inhalation
Remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen.
Obtain medical attention immediately.

Eye
Immediately flush eyes with gentle but large stream
of water for at least 15 minutes, lifting lower and
upper eyelids occasionally. If persistent irritation
occurs, obtain medical attention.

Skin
Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated
clothing and shoes. If persistent irritation occurs,
obtain medical attention. Wash clothing before
reuse.

Ingestion
Obtain medical attention immediately. Do not induce
vomiting unless directed to do so by a medical
personnel. Never give anything by mouth to an
unconscious person.

6. Reactivity Data
Conditions to avoid Exposure to elevated temperatures can cause
product to decompose. Generation of gas during
decomposition can cause pressure in closed
systems.
Materials to avoid Avoid contact with: Strong acids. Strong bases.
 Strong oxidizers.
Hazardous Polymerization Will not occur

7. Spill and disposal procedures

Steps to be followed in the event of a spill or Small spills: Absorb with materials such as: Cat litter.
discharge Sand. Sawdust. Vermiculite. Zorb-all. Hazorb.
Large spills: Dike area to contain spill. Pump into
suitable and properly labeled containers.
Disposal procedure Do not dump into any sewers, on the ground, or into
any body of water. All disposal practices must be in
compliance with all federal, state/provincial and local
laws and regulations. Regulations may vary in
different locations. Waste characterizations and
compliance with applicable laws are the
responsibility solely of the waste generator. We have
no control over the management practices or
manufacturing processes of parties handling or
using this material. The information presented here
pertains only to the product as shipped in its
intended condition as described in msds section:
composition information. For unused &
uncontaminated product, the preferred options
include sending to a licensed, permitted: recycler.
Reclaimer. Incinerator or other thermal destruction
device.

8. Protective Equipment
Engineering controls A system of local and/or general exhaust is
recommended to keep employee exposures below
the Airborne Exposure Limits. Local exhaust
ventilation is generally preferred because it can
control the emissions of the contaminant at its
source, preventing dispersion of it into the general
work area.
Respiratory Protection Respiratory protection should be worn when there is
a potential to exceed the exposure limit requirements
or guidelines. If there are no applicable exposure
limit requirements or guidelines, wear respiratory
protection when adverse effects, such as respiratory
irritation or discomfort have been experienced, or
where indicated by your risk assessment process.
For most conditions, no respiratory protection should
be needed; however, if material is heated or sprayed,
use an approved air-purifying respirator. The
following should be effective types of air-purifying
 respirators: Organic vapor cartridge with a
particulate pre-filter.
Eye Protection Use safety glasses (with side shields).
Hand Protection PVC gloves, chemical resistant gloves or nitrile
gloves.
Skin and Body Protection When prolonged or frequently repeated contact
could occur, use protective clothing chemically
resistant to this material. Selection of specific items
such as faceshield, boots, apron, or full-body suit will
depend on the task. When handling hot material,
protect skin from thermal burns as well as from skin
absorption.

9. Storage and Handling Precautions

Handling Protect self against physical damage. Avoid contact
with skin, eyes and clothing. Do not breathe vapor.
Use only in well ventilated areas.
Storage Must be stored in a well-ventilated area and keep
away from ignition and heat sources. Keep away
from aerosols, oxidizing agents and corrosives. The
vapor is heavier than air. Beware of accumulation in
pits and confined spaces. Breathing losses during
storage should be controlled by a suitable vapor
treatment system. Store in a segregated and
approved area. Keep container in a cool, well-
ventilated area. Keep container tightly closed and
sealed until ready for use.

10. Transportation data and other information

Transport information UN Number: Not regulated.
Hazard Class: Not classified as hazardous material.
Packing Group: Not applicable.
Proper shipping name: Diethylene Glycol

By-Product: TRIETHYLENE GLYCOL

1. Product Identification
Product Name Triethylene glycol
Synonyms TEG, 2,2'-Ethylenedioxydiethanol, Glycol-
bis(hydroxyethyl) ether, Triglycol, Ethanol 2,2-(1,2-
ethanediylbis(oxy))bis-, AC-9430T, 94392
Chemical Family Glycol
Intended Use Triethylene glycol is used as a dehydrating agent
for natural gas; a solvent and lubricant in textile
dyeing and printing; a plasticizer; a raw material for
 the production of polyester resins and polyols; a
humectant; a constituent of hydraulic fluids; a
selective solvent for aromatics.
A. Precautionary Labeling
Hazard Symbol

Signal Word Warning

B. Precautionary Statements
Avoid breathing dust/fumes/gas/mist/vapors.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. Seek medical attention.
C. Laboratory Protective Equipment Required
Protective clothing should be worn to prevent skin contact with ethylene glycol
Safety glasses, googles or face shields
Eyewash fountains and emergency showers

2. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Concentration ACGIH OSHA NIOSH

Components (%) Exposure Limits Exposure Limits Exposure Limits
Name/CAS No.
Ethylene Glycol 0.1 100 mg/m3 - -
107-21-1
Triethylene Glycol 99.5 100 mg/m3 - -
112-27-6

3. PHYSICAL AND CHEMICAL PROPERTIES

Physical state and appearance: Liquid. (Hygroscopic liquid.)

Molecular Weight: 150.18 g/mole
Color: Colorless.
Boiling Point: 285C (545F)
Melting Point: -5C (23F)
Specific Gravity: 1.1274 (Water = 1)
Solubility: Easily soluble in cold water.

4. FIRE AND EXPLOSION HAZARD DATA

Fire extinguishing media SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. Do not

Special fire-fighting procedures
Unusual fire and explosion hazards
Toxic gases produced
5. HEALTH AND HAZARD DATA
Effects of overexposure
Target Organs
Medical conditions generally aggravated by
exposure
Emergency and first aid procedures
use water jet.
Use alcohol-type or all-purpose type foam by
manufacturer's recommended techniques for large
fires. Use carbon dioxide or dry chemical media for
small fires. Do not direct a solid stream of water or
foam into hot, burning pools; this may cause frothing
and increase fire intensity. Wear adequate personal
protection to prevent contact with material or its
combustion products.
Self-contained breathing apparatus with a full
facepiece operated in a pressure demand or other
positive pressure mode
Contact with oxidizers may cause fire and/or
explosion. The sensitivity to static discharge is not
available. The sensitivity to impact is not available.
Emits toxic fumes under fire conditions.
Carbon monoxide and carbon dioxide
Exposure to high concentrations of aerosol
generated at room temperature may cause lung
injury and liver dysfunction. Exposure to vapor
generated at high temperatures may result in eye
and respiratory tract irritation, dizziness and nausea
May cause damage to the kidneys and nervous
system
None
Inhalation
Allow the victim to rest in a well ventilated area. Seek
immediate medical attention.
Eye
Check for and remove any contact lenses.
Immediately flush eyes with running water for at least
15 minutes, keeping eyelids open. Cold water may
be used. Do not use an eye ointment. Seek medical
attention.
Skin
No known effect on skin contact, rinse with water for
a few minutes.
Ingestion
 Do not induce vomiting. Loosen tight clothing such
as a collar, tie, belt or waistband. If the victim is not
breathing, perform mouth-to-mouth resuscitation.
Seek immediate medical attention.

6. REACTIVITY DATA
Conditions to avoid Incompatible materials, exposure to moist air or water
Materials to avoid Strong oxidizing agents, strong acids
Hazardous Polymerization Will not occur

7. Spill and disposal procedures

Steps to be followed in the event of a spill or
discharge
Small Spill: Dilute with water and mop up, or absorb
with an inert dry material and place in an appropriate
waste disposal container. Finish cleaning by
spreading water on the contaminated surface and
dispose of according to local and regional authority
requirements.

Large Spill: Absorb with an inert material and put

the spilled material in an appropriate waste disposal.
Finish cleaning by spreading water on the
contaminated surface and allow to evacuate through
the sanitary system.
Disposal procedure Whatever cannot be saved for recovery or recycling
should be managed in an appropriate and approved
waste disposal facility. Processing, use or
contamination of this product may change the waste
management options. State and local disposal
regulations may differ from federal disposal
regulations. Dispose of container and unused
contents in accordance with federal, state and local
requirements.

8. Protective Equipment
Engineering Controls Use adequate ventilation to keep airborne
concentrations low.
Respiratory Protection Follow the OSHA respirator regulations found in 29 C
FR 1910.134 or European Standard EN
149. Use a NIOSH/MSHA or European Standard EN
149 approved respirator if exposure
limits are exceeded or if irritation or other symptoms
are
experienced.
Eye Protection Wear appropriate protective eyeglasses or chemical s
afety goggles as described by OSHA's
eye and face protection regulations in 29 CFR 1910.1
33 or European Standard EN166.
Skin and Body Protection Wear appropriate protective gloves to prevent
skin exposure.
Wear appropriate protective clothing to prevent skin e
xposure.

9. Storage and Handling Precautions

Special precautions Keep away from heat. Keep away from sources of
ignition. Empty containers pose a fire risk, evaporate
the residue under a fume hood. Ground all
equipment containing material. Do not ingest. Do not
breathe gas/fumes/ vapour/spray. Avoid contact with
eyes If ingested, seek medical advice immediately
and show the container or the label.
Storage Keep container dry. Keep in a cool place. Ground all
equipment containing material. Keep container
tightly closed. Keep in a cool, well-ventilated place.
Combustible materials should be stored away from
extreme heat and away from strong oxidizing agents.

10. Transportation data and other information

United States Department of Transportation (US DOT Classification: Not a DOT controlled material
DOT) (United States).
Identification: Not applicable.
Special Provisions for Transport: Not applicable.

Product: MONOETHYLENE GLYCOL

1. Product Identification
Product Name Monoethylene glycol
Synonyms MEG, Ethylene Glycol, 1,2-Ethanediol, 1,2-
Dihydroxyethane, EG, Glycol, Ethylene
Glycol Polyester Grade, High Purity Grade,
Industrial Grade and Antifreeze Grade
Chemical Family Ethylene Glycol
Intended Use Multiple Uses Including Chemical Feedstock,
Chemical Intermediate, Chemical
Component, Chemical Constituent
A. Precautionary Labeling
 Hazard Symbol

Signal Word Warning

B. Precautionary Statements
Prevention: Do not eat, drink or smoke when using this product. Do not breathe dust/ fume/ gas/
mist/ vapours/ spray. Wash hands thoroughly after handling.
Response: IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Get medical advice/ attention
if you feel unwell.
Disposal: Dispose of contents and container to licensed, permitted incinerator, or other thermal
destruction device.
C. Laboratory Protective Equipment Required
Protective clothing should be worn to prevent skin contact with ethylene glycol
Good Materials for Personal Protective Equipment (Against Ethylene Glycol):
Natural Rubber
Butyl Rubber
Neoprene
Polyvinyl chloride
Nitrile Rubber
Polyethhylene
Teflon, Viton, Saranex, Barricade
Safety glasses, googles or face shields
Eyewash fountains and emergency showers

2. COMPOSITION / INFORMATION ON INGREDIENTS

Hazardous Concentration ACGIH OSHA NIOSH

Components (%) Exposure Limits Exposure Limits Exposure Limits
Name/CAS No.
Ethylene Glycol 95 - > 99.9 100 mg/m3 Ceiling 50 ppm Ceiling 50 ppm Ceiling
107-21-1 Aerosol
Diethylene Glycol < 0.5 - 5
111-46-5

3. PHYSICAL AND CHEMICAL PROPERTIES

 Appearance Clear, colorless Physical Form Liquid
Odor Slightly sweet Odor Threshold Not established
pH Neutral Vapor Pressure <0.1 psi 100oF, 38oC
Vapor Density > 2 (air = 1) Boiling Point/Range 388oF/1989oC
Percent Volatile 100% Partition Coefficient <3
Specific Gravity 1.15 @ 60oF Density 9.3 lb/gal @ 60oF
Molecular
Weight 62 Evaporation Rate Not established
Flash Point 240oF/116oC Test Method ASTM 56
Explosive
Limits 3.2% LEL, 15.3% UEL Autoignition 748oF/398oC
Temperature
Solubility in
Water Essentially 100%

4. FIRE AND EXPLOSION HAZARD DATA

Fire extinguishing media
Special fire-fighting procedures
Unusual fire and explosion hazards
Dry chemical, carbon dioxide, water spray or alcohol
resistant foam is recommended. Media Water spray
is recommended to cool or protect exposed materials
or structures. Carbon dioxide can displace oxygen.
Use caution when applying carbon dioxide in
confined spaces. Water may be ineffective for
extinguishment, unless used under favorable
conditions by experienced fire fighters. Water or
foam may cause violent frothing.
Use water spray to cool fire-exposed containers and
to protect personnel. Isolate Instructions immediate
hazard area and keep unauthorized personnel out.
Water spray may be useful in minimizing or
dispersing vapors and to protect personnel. Cool
equipment exposed to fire with water. Avoid
spreading burning liquid with water used for cooling.
For fires beyond the incipient stage, emergency
responders in the immediate hazard area should
wear bunker gear. When the potential chemical
hazard is unknown, in enclosed or confined spaces,
or when explicitly required by regulations, a self-
contained breathing apparatus should be worn.
Wear other appropriate protective equipment as
conditions warrant.
This material has a slight to moderate exposure
hazard when exposed to heat and Explosion flame.
Above the flash point, vapor-air mixtures are
explosive within the flammable Hazards limits. A
 product container, if not properly cooled, can rupture
in the heat of a fire.
Toxic gases produced Carbon monoxide and carbon dioxide

5. HEALTH AND HAZARD DATA

Effects of overexposure
Target Organs
Medical conditions generally aggravated by
exposure
Emergency and first aid procedures
Repeated or prolonged exposure may result in
kidney damage. May produce Symptoms symptoms
of central nervous system depression including
headache, dizziness, nausea, euphoria, loss of
equilibrium, drowsiness, visual disturbances, fatigue,
unconsciousness and respiratory arrest.
May cause damage to the kidneys or liver.
Individuals with lung disorders like asthma, kidney or
liver disease may have Aggravated by increased
susceptibility to exposure. Skin contact may
aggravate an existing Overexposure dermatitis. May
cause central nervous system depression.
Inhalation
Move the exposed person to fresh air. If not
breathing, clear airways and give artificial
respiration. If breathing is difficult, humidified oxygen
should be administered by qualified personnel. Seek
medical attention if breathing difficulties continue.

Eye
Flush eyes with water for at least 15 minutes. Hold
eyelids apart to ensure complete irrigation of the eye.
Remove contact lenses, if worn, after initial flushing.
Do not use eye ointment. Seek medical attention.

Skin
Remove contaminated shoes and clothing, and flush
affected areas with large amounts of water. If skin
surface is damaged, apply a clean dressing and
seek medical attention. If skin surface is not
damaged, clean affected area thoroughly with mild
soap and water. Seek medical attention if tissue
appears damaged or if pain or irritation persists.
Launder or discard contaminated clothing.

Ingestion
Immediately give two glasses of water and induce
vomiting. Never give anything by mouth to an
unconscious person.. Seek medical attention.
 6. Reactivity Data
Conditions to avoid Avoid all possible sources of ignition.
Materials to avoid Avoid contact with strong oxidizing agents such as
strong acids, alkalies, chlorine and (Materials to
other halogens, dichromates or permanganates,
which can cause fire or explosion.
Hazardous Polymerization Will not occur

7. Spill and disposal procedures

Steps to be followed in the event of a spill or Stop the leak if it can be done without risk
discharge Entering waterways, sewers, basements or
confined areas should be prevented
Contain release to prevent further
contamination of soils, surface water or
groundwater.
Clean up spill as soon as possible using
appropriate techniques such as applying
non-combustible absorbent materials or
pumping.
All equipment used when handling the
product must be grounded.
A vapor suppressing foam may be used to
reduce vapors.
Use clean non- sparking tools to collect
absorbed material.
Dispose of contaminated materials in a
manner consistent with applicable
regulations.
Disposal procedure The generation of waste should be avoided or
minimized wherever possible. Significant quantities
of waste product residues should not be disposed of
via the foul sewer but processed in a suitable
effluent treatment plant. Dispose of surplus and non-
recyclable products via a licensed waste disposal
contractor. Disposal of this product, solutions and
any by-products should at all times comply with the
requirements of environmental protection and waste
disposal legislation and any regional local authority
requirements.

8. Protective Equipment
Personal Protective Equipment If engineering controls or work practices are not
adequate to prevent exposure to harmful levels of
this material, personal protective equipment (PPE) is
 recommended. A hazard assessment of the work
should be conducted by a qualified professional to
determine what PPE is required.
Respiratory Protection Wear a NIOSH-approved full facepiece respirator for
routine use situations where atmosphere is at or
above OSHA's Action Level. Do not exceed the
maximum use conditions of the respirator. For
emergency or non-routine uses where
concentrations are unknown, wear an SCBA with a
full facepiece operated in the pressure-demand or
positive pressure mode.
Eye Protection Always wear chemical safety glasses. If splashing
may occur, wear a full face shield as a
supplementary protective measure over safety
glasses. NEVER WEAR CONTACT LENSES when
working with ethylene oxide.
Skin and Body Protection Wear impervious gloves (see
www.ethyleneoxide.com for permeation data); boots;
aprons; head cover; and clean impervious body-
covering clothing to prevent any possibility of skin
contact. Launder contaminated clothing and discard
contaminated leather shoes, belts, etc.

9. Storage and Handling Precautions

Special precautions This material and its container must be disposed of
in a safe way. Care should be taken when handling
emptied containers that have not been cleaned or
rinsed out. Empty containers or liners may retain
some product residues. Avoid dispersal of spilt
material and runoff and contact with soil, waterways,
drains and sewers.

10. Transportation data and other information

United States Department of Transportation (US Shipping Description: Environmentally hazardous
DOT) substance, liquid n.o.s. (Ethylene Glycol), 9,
UN3082, III
Transportation of Dangerous Goods (TGD) Shipping Name: Environmentally hazardous
Canada substance, liquid, n.o.s. (Ethylene Glycol)
Hazard Class and Division: 9
ID Number: UN3082
Packing Group: PGIII
Label: Class 9
Placard: Class 9
Reportable Quantity: 5000 lb
Emergency Response Guide: 171
MARPOL III Status: Not a DOT Marine Pollutant per
49 CFR 171.8
International Maritime Organization
International Maritime Dangerous Goods Code
(IMO/IMDG)
European Agreements Concerning the International
Carriage by Rail (RID) and by Road (ADR)
International Civil Aviation Organization /
International Air Transportation Association
(ICAO/IATA)
Shipping Description: UN3082, Environmentally
hazardous substance, liquid, n.o.s. (Ethylene
Glycol), 9, III
Shipping Name: Environmentally hazardous
substance, liquid, n.o.s. (Ethylene Glycol)
Hazard Class and Division: 9
UN Number: 3082
Label: Class 9
Shipping Name: Environmentally hazardous
substance, liquid, n.o.s. (Ethylene Glycol)
Hazard Class: 9
Packing Group: III
Shipping Name: Environmentally hazardous
substance, liquid, n.o.s. (Ethylene Glycol)
UN/ID Number: UN3082
Hazard Class and Division: 9
Packing Group: III

II. LOSS PREVENTION/ HAZARD IDENTIFICATION AND ASSESSMENT

Title Ingestion of Hazard Life Safety/ Chemical

ethylene glycol
Who is at risk? Workers
Risk Evaluation
Fire Smoke Bomb Earthquake Protest Tsunami Typhoon
Threat
High Hig Hig High Hig Hig High
Med h h Med h h Med
Low Med Med Low Med Med Low
N.A. Low Low N.A. Low Low N.A.
N.A N.A N.A. N.A.
Title High Hazard Life Safety/ Chemical
Aerosol
Concentrati
. .
on
Possible Consequences:
Who may include inebriation, nausea andWorkers
is at risk?
- Ingestion vomiting, metabolic acidosis and CNS
depression. Cardiopulmonary effects Risk Evaluation
include tachycardia, hypertension, severe metabolic
Fire with hyperventilation,
acidosis Smoke Bomb
hypoxia,Earthquak Protest
congestive heart failure andTsunami Typhoon
adult respiratory distress
syndrome as well as renal failure.
Threat May alsoe produce a local irritation effect on the digestive
system
Hig and causepain
Higand bleeding.
Hig High Hig Hig Hig
h h h Med h h h
Med Med Med Low Med Med Med
Low
Control: Low Low N.A. Low Low Low
- N.A N.A
Immediately give two glasses
N.A of water and induce vomiting.
N.A N.Agive
Never N.A
anything by
. mouth to an .unconscious person.
. Seek medical attention.
. . .
Possible Consequences:
- Have a proper training in materials handling
-High aerosol concentrations may cause respiratory irritation.

Control:
- Use proper PPE
- Use a full-face positive-pressure supplied air respirator in circumstances where air-
purifying respirators may not provide adequate protection.

Title Skin contact of Hazard Physical

MEG
Who is at risk? Workers
Risk Evaluation
Fire Smoke Bomb Earthquak Protest Tsunami Typhoon
Threat e
High High High High High High High
Med Med Med Med Med Med Med
Low Low Low Low Low Low Low
N.A. N.A. N.A. N.A. N.A. N.A. N.A.
Possible Consequences:
-May be mildly irritating to the skin. Not a sensitizer. Not expected to be a skin absorption
hazard.
Control:
- Avoid skin contact. Wear long-sleeved fire-retardant garments while working with Body
flammable and combustible liquids. Additional chemical-resistant protective gear may
Protection be required if splashing or spraying conditions exist. This may include an
apron, arm covers, impervious gloves, boots and additional facial protection.
Workplace Risk Management
When using MEG, make sure that there is limited exposure to the liquid, and also avoid
the generation of vapor mists. Always use chemical resistant gloves to protect your hands and
skin and always wear eye protection such as chemical goggles. Do not eat, drink, or smoke
where this chemical is handled, processed, or stored. Wash hands and skin following contact. If
this chemical gets into your eyes, rinse eyes thoroughly for at least 15 minutes with tap water and
seek medical attention.

III. ENVIRONMENTAL PROTECTION

Air pollution abatement

o Carbon capture and storage (CCS) is the process of capturing waste
carbon dioxide from large point sources transporting it to a storage site,
and depositing it where it will not enter the atmosphere, normally an
underground geological formation.
o Ethylene glycol released to the atmosphere will be degraded by reaction
with hydroxyl radicals; the half-life for the compound in this reaction has
been estimated at between 0.3 and 3.5 days.
Water pollution abatement
o Ethylene glycol has generally low toxicity to aquatic organisms. Toxic
thresholds for microorganisms are above 1000 mg/litre. EC50s for growth
in microalgae are 6500 mg/litre or higher. Acute toxicity tests with aquatic
invertebrates where a value could be determined show LC50s above 20
000 mg/litre, and those with fish show LC50s above 17 800 mg/litre. An
amphibian test showed an LC50 for tadpoles at 17 000 mg/litre. A
noobserved-effect concentration (NOEC) for chronic tests on daphnids of
8590 mg/litre (for reproductive endpoints) has been reported. A NOEC
following short-term exposure of fish has been reported at 15 380 mg/litre
for growth.
 o No hydrolysis of ethylene glycol is expected in surface waters.
Solid waste management
o The generation of waste should be avoided or minimized wherever
possible. Significant quantities of waste product residues should not be
disposed of via the foul sewer but processed in a suitable effluent
treatment plant. Dispose of surplus and non-recyclable products via a
licensed waste disposal contractor. Disposal of this product, solutions and
any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional
local authority requirements.
o Ethylene glycol is readily biodegradable in standard tests using sewage
sludge. Many studies show biodegradation under both aerobic and
anaerobic conditions. Some studies suggest a lag phase before
degradation, but many do not. Degradation occurs in both adapted and
unadapted sludges. Rapid degradation has been reported in surface waters
(less in salt water than in fresh water), groundwater, and soil inocula.
Several strains of microorganisms capable of utilizing ethylene glycol as a
carbon source have been identified.
IV. PLANT LOCATION

Mariveles, Bataan
The proposed plant location for the production of Monoethylene Glycol (MEG) is in
Mariveles Bataan, where most of the existing industrial establishments of Bataan is located. The
plant site is situated near a port (Freeport Area of Bataan) which is considered to be the center of
trade in the Philippines. It also gives a strategic point for the transportation of both the raw
materials and product into and out of the plant. Aside from port, the plant is near industrial
facilities like a power plant (Mariveles Power Plant) which can provide a power supply to the
plant. Other facilities near the plant site includes a refinery, dam and water treatment facility
which will all be beneficial to the plant. A plastic plant is also located at the vicinity of Mariveles
which can be considered as the major consumer of the plant. Aside from that, industrial parks in
Hermosa, Bataan and Limay, Bataan can also open to possible collaborations and partnerships
which can increase the economic capability of both the plant and the MEG industry.

Olongapo City and Subic, Zambales

V. PLANT LAYOUT
New site development or addition to previously developed site
o Bataan
Type and quality of products to be produces
o Fiber-Grade Ethylene Glycol
Color, Pt-Co, max 5
Suspended matter Free
Diethylene Glycol, wt% max 0.008
Acidity, as acetic acid, wt% max 0.005
Ash, wt% max 0.005
Water, wt% max 0.08
Iron, ppm wt max 0.07
Chlorides, ppm wt max <0.2
Distillation Range, ASTM at 760 mmHg, , max 200
Odor Mild
UV Transmittance, %min at:
220 nm 70
250 nm 90
275 nm 95
350 nm 99
Specific Gravity , 20/20 1.1151-1.1156
Water solubility Complete
Type of process and product control
o Hydrolysis of Ethylene Oxide
This method is most widely used for production of ethylene glycol.
It involves the reaction of Ethylene Oxide with Water Producing
Monoethylene Glycol. This chemical reaction leads to secondary
and tertiary reaction producing Diethylene Glycol and Triethylene
Glycol, respectively.
Operational convenience and accessibility
o The plant layout is designed that the location of each unit operators with
respect to the employers are operational convenient and accessible.
Economic distribution of utilities and services
o The allotment of capital for the plants utilities and the employers services
should be well analyzed.
 Heat and safety considerations
o The plant layout is designed that considers the safety of the employers.
Personal protective equipment (PPE) is recommended. A hazard
assessment of the work should be conducted by a qualified professional to
determine what PPE is required.
Waste disposal requirements
o Waste disposal is abide by the Ecological Solid Waste Management Act of
2000 (RA9003), Philippine Environmental Policy (PD 1151), and DENR
Administrative Order 24 and 25 Water Classification and The Effluent
Standards.
Space available and space required
Roads and railroads
o The plant is located near the road to be accessible.
Possible future expansion
o As the industry progresses exponentially, the industry will have a
possibility to have another branch for expansion. Having two lines of
manufacture of Monoethylene Glycol in the Philippines increases the rate
of competitiveness.

VI. PLANT OPERATION AND CONTROL

Instrumentation
o Tubular Reactor
The operating pressure of the reaction is controlled at a level,
which limits or avoids the vaporization of ethylene oxide from the
aqueous solution. Literature shows that commercial reactors operating at
190-200 C will be at pressures 14-22 atm depending on the initial
concentration of the oxide.

o Evaporator
Temperature, production and vacuum are controlled by regulating
the system valves. To control these parameters, a closed loop control is
needed which can be obtained by a controller. Proportional-Integral-
Derivative (PID) control, feed forward controller and internal model
 controller are some of the algorithms that may use to attain the desired
conditions.

o Vacuum Distillation
To provide vacuum control, place a throttling valve between the
column and the vacuum source, introduce an external load into the suction
line to the vacuum source, or recycle from the discharge of the vacuum
source to the suction side.

Maintenance
o Maintenance will be conducted every month for all the equipment to
prevent machine failure.
Utilities
o Water and electricity are the utilities used in manufacturing Monoethylene
glycol.
Storage
o Ethylene Oxide
Ethylene oxide must be stored in approved pressure vessels in a cool, well
ventilated area or in properly designed storage systems. Sprinkler systems in
storage areas are highly desirable for fire control and to cool containers exposed
to intense heat from fires.

o Mono-, di- and triethylene glycol

Use and store this material in cool, dry, well-ventilated areas away from
sources of ignition. Keep away from incompatible material.

Materials Handling
Before handling, it is important that all engineering controls are operating
and that protective equipment requirements and personal hygiene measures are
being followed. Prevent uncontrolled release of product. Eliminate heat and
ignition sources such as sparks, open flames, hot surfaces and static discharge.
Post "No Smoking" signs. Immediately report leaks, spills or failures of the safety
equipment (e.g. ventilation system). Do not use at elevated temperatures without a
thorough safety assessment. Prevent accidental contact with incompatible
chemicals. Use non-sparking ventilation systems, approved explosion-proof
equipment and intrinsically safe electrical systems. Do not weld, cut or perform
hot work on empty container until all traces of product have been removed. Use
the pressure regulator appropriate for cylinder pressure and contents. Secure
cylinder in an up-right position. Protect cylinders from damage. Use a suitable
hand truck to move cylinders; do not drag, roll, slide, or drop