elt JA Resonance MAJOR TEST (MT) Educating for better tomorrow TARGET : IIT-JEE 2012 DATE : 11-03-2012 CLASS-XIl / XIII COURSE : ALL INDIA TEST SERIES (VIKALP) HINTS & SOLUTION E PAPER-1 oon Heh -coot PARTI (Chemistry 1 neo TH 4. The increasing onder of cis nature of Li. I Sol. On moving let to rat in pro table acidic nature of once inreose. 80, metalic oxides are bas, non metalic vidoe ae 00K cox tiie ond Be i amphotee. 4 cook | eH sol = meso isomer 2. The freezing point depression of 0.1 M ag, ne PH Ho—j—# Sol ATaieem ‘ boon o2mixtexos > isin = aso 18, Fora zero oder chemical 9600. 7 7 sol 2NH, == Ny * 3H, _ ca? _ 000.19 Pressueatt=0 dam~ 00 uF (0.17) Pressure at (2am xatm 3xatm #1354102 Ans. 1 : 4 MOE gy = =800) 2 lcacve sample had an inti acy. teed acon nae aA an 2 10-2 N 5 Ne 1000 a = 0 SN Deane e836 20 Salm How many of he flowing reaction reaut 4. Conect option regarding @ container contaning Hees seek eenat (b) HCl, + KI ——> Sol. snc, (@nec'+N0; + c5" —> $0, i12> 1 then, fort mole of gas a 279K, volume wi be 22.4 Hey ot it Wen Pw greater nan tam (OIE Oe Ky oy NON 5. Blister coppers refined by sing motion impure tocage ag nt ‘Sol. Poling is a purification process which is used for metals which (K,Cr40, + conc.H,SO, + Cl —>A Kacey 8 ——+? Eons ther own onde as mpurty. one, eh {Among celuiose oly vinyl che, nyon and (Hg + cot + sc” ——> Sol. nermoleulerfoass ae H-bonding, iplecpowe svacion, _-() BP" +OH- + SOH)> ——> ander woal fore of atracson, Nyon has H-bonding 20. NO, dissociates ntoNO & NO, ALequlioum 8 0)(C,H,C1BCOOH) are adhaioadbststed Sot No, == w+ NO, In tvesslatequioum + atm faim tam « hence y= am In vbsel ina im % Sol. {ue to otro eft) Secale ae oer G-x? Gey! 11. tH iquis A and 8 form an ideal sluton the entropy hence x= 4 Sol, On beng entropy wi increases, Ties NOy = 2atm Ang 12, 1upACname otIAIC 0918 ‘Sol. Refer notes. ani 21. How many sats willtur blue litmus to red Sol. GHANH,°Cr, FeCl, ARNO), 13, traction of zine frm zine blende ‘Sok Refer notes, *4. wn Fe{Co), the Fe-C bond possesses. ‘Sak Synerpic bonding exist batween Fe and C atom: So, bond between Fe and C contains both o and x character PitResonance Ns arsorveaa 7eee on Sol. CH,-CH,-CH=CH-CH, (cis trans) 22> crc Eefron, er Br (att CH,-CH,-CH,-cH=cH, 22> CHeeH en fi-eH (eb) br Br CHy—Br ig (COE), JOH? 14 2 —Statcocea sont by, ar 0 ae ov -eHco0e : ol 1 emtco0eryIO¥is, | of, sa ee oer nacres018 coos & [SOO He Doemouss [coon eT con PARTsIL(Physics) 24. A constant power Soi. Peo Prlaxe P o eee 220 3 oxo 25, Anice cube Sol AUsemg tem 0725 28, whatis tbe Nat 4 ol eee tat Sol ys ve : 27. A particle is > v= I6 ems, 28. Ahollow vertical sou net ne 5 oF 2a) = Vt Mo [> ""2aR Vo 28. A conductor of Sol. B¢a= my/2gh mg ‘SRB, 31. InYOSE with 2D, 2D age 1300 Sol qo noe tee 2 i 5x10" : ax =3xt08 10 = 06 « 10%= 6000 A 33. In alhydrogen 7 tags 2 So. aM: sot 6, 612( 5 os ot aaa) m+M 2 EQ) 41, The uniform sold =a sae= Sms See > o= ol Ex Ema See > om 48, ABi8 42, Sevenidentel large » sol 43. Aparale plate on: Sei. tev fo-rt e00 10%» 100 {Sex toaee ao 44, One fourth length Again tet WN y 2 > : oe _ 8? |—mg sind = mo? — mr aA m9 ‘ mgeoo-Nem ba =o eons Nem Soving 18 ano = 4 re 45. A pate of enarge Sol. Puty ax So, = v,c080 PN Resenence° 22, orcan-on 1.0% Bac, 1 Sol. CH,-CH,-CH=CH-CH, (cis trans) 225 onc conn, br or tea O04, cHH, 8 chcron- tHe a be be wa phe —Rnteooen sone CH —Br o eae! .,, grerexconena Sol. |" erCOOeRIOHPHA, Fa ik 2D Desi Poors ese PART-II (Physics) 24. A constant power Sol e020 oxo" 28. Anice cube Sol, AU ==mg = 1 em 26, Whatis the =-0725 sol ys te 27. A particle is f Tea = radius of mage = 2.6m oe 172 28, A hollow vertical Sol.m= 2 sol. n= 2 gt ol n= eR) = Vit Yo - "2a Vo 29. A conductor of Sol. Bra = my2gh Resonence 30. A.uniform current Sol, mgR=B,3RFi aos mg '= SRB, site 31. In YOSE with sot 40122 a saree 7 “ad ons 5x10 ax x10 10° 16 10 = 6000 A 33, In a hyo — a7. ta, wage 8 (2 __mM Sol. AM! er em, OM) ‘ 44, The unform soi = 8 Sol E= Smit She => @ 48, 181 2 42, Seven identical lage Aaa 5 Sol. 43. Aparatel plate on Soi. t= ov 3077x2900 10° 100 128% 10" sec. 44, One fourth length nam mge 4 Acai sot, PEE sino» Sto? Let HN mg-£coso a 2 «et ° 7 T a t iN -ma sin =o? aa t img cos0-N=m~a =e cost -N=m-5 Sobving 13 ano = 4, 45. A parle of charge sor % ee veoso46. A stationary observer 50, The valve of x f Sol. yx 20x—100 = VStyx-5 (¥ Ssxs10) Sol. ,= (y—v,0080)mn ” 0 vt = ober P20 =100 + Vi 20%= 100) ex 1800 (V-+V, C088) may é = ose \x=8)+(V5 - Jx—5)}ax= 105 3 51, {Nis aprime number. Sol. S=191 P50, #80, #70, #2. Cy )= 19! (°C, —1) E (41=19(41-2)(41~3)...(41=20)~ 20! 41k AMG 7 20 20 = efeatest pine numberis 41 a 4ap tu. 20 See a a 52 le between the roots ofthe quatatc equation 20 (13467) oMeace = 2018487) gs a ye Bak aa-3c0 229 28a Seo 8a, S40" Fae ba-8) 63. If 2 ie anarbirary 48, ABlea chord ofthe ere ca e sol t= fisecx)®""*(cosecx)?" ax > yh sLX Ss seo? x(1+ tan?) 4p tan x Sol, Let tane=t = sock ax=dt A4t?)dt_(_13 pres , 13 por ms 16 +t te Is (tam _ amr) = 9740 16 2 00+ F = conases ‘Again PA=4,P8=3 and AB=5 = ZBPA=90" Let = Bis [Number of one-one function is P, = 51 25 54 = P1825 4 Fy los F sino) : ‘Sle robabityle Ea* Gog Shee (8) Cleary fx) s discontinuous at x= t and X= 2 = fx) gfe) is continuous at x= t and X= 2 Hf g(t) = 0 ana =O a-b=t . © 49. fis real valued Sol Puty=1 3 fer nat eft) —x—t S feet =f) x Y 3 fin 1) t,neN but tis given that 1 = ()=n has only one solution Raaaoon6. So. sol 60, Sol 6 Sol, 63. Pi Besonence B WTSOL110312-4 (A) Order of differential 7 64. if = (A) Equation of aly of parabolae a (xa = 2 y-b) ke 2 ab tree aotzary constant. ke f\QHRE KSA dx (@) sum ot oots = 2 > 0 and product ==1 => rots are : 2 negative reciprocal of each other. a (-1,0) = tan-(cota) =~ cot tana) > cosltan"(cota) ~ cot (tana}] == 4 ! 8! _ ay cgyyre ayy ‘mlm! mal a Dare 82 = 82 = ey I 5 rial é (©) eae rere Dy 1 Nowiet 12 fVt=Det a = cootfcient of x at Putt sie => y= 2sino oso (©) Length of suonoral = (y m) x2 4-(2) can 2 fata amen i x 6x an 2 90° 30 44 ' Product of perpendcuars Xcoso+Lsino=1, Aia.0,A'-a, 0) ab 7 ___a*b?sin?@ Ane ra © b?c0870+8? sin? 6 65. Letx,y€ R. Ifthe maximum, Sol. Let X= rc088 and y= r sind wabe = 4 , ee eee = E* sin? 0+ sindcos0+cos? 6 ‘generate plane x, : 7 4, & generate plane x ee & in vector along ine of intersection of panes, and x. 5+ sin20-3e0s20 ( ‘There are two distinct black Now 5-10 < 5+ sinze—3c0s28 <5 +/10 eed 2 2 Prony FEA FCA” B OM Bo 550 or 1 root of quadratic a 266 AB) as me 26-1) acces Consider it 3ix+ 21=0, i= V=1 has real roots 1,2 ae be adacs-9-4(-2)=-1 20 = Sareme 2 Ze) itmagntude of a complex : ZMem= > 750092 = Reautiog umber is = 35 43) = 9-131 st Mf abceRand Tt SbiveaSebcs@ebroiesbed-66. If ange ofa for which Sol. Put 2=t>0 = Poat-ar3<0 P43 tet <* = fW=0 > t=1 as too 3 t= Tis point of minima Now graph of fe) 43 tH «R= zach) 67. If straight tines pit 2-3 Sol.}2 3 -5|20>Ktkt1 40 okeR Ke kt ‘This should be a right wiangle it CE) (4 3 ke-2or ke-32 6. HO) = 19-34 1, x _1¥ 353 sa.o-ver-(3 -3) +323 0, The vertces ot tangle Sol. Poon vector of orthocente is (i +bj-+ck) BALBC = 00-0 T+bj +08)- L2j+ak) =0 = -2b4200 BH LAT = Qi+(o-2)j+ck}Li+aK) 0 > -ar3er0 and CH LAB = (al+b]+(c~3)k)Li+2))=0 2-2 +2020 waz z=s0= 20h) a heh ane(atedi eRe) Hie onpareABc 36 vz Equoton ofplaneABC inxs 3+F #1 > a= 35 36) (5, 15,4 poaton vector of onhocente ( 3g | [i+ Zi+5| PAPER-2 PART (Chemistry) 41. Higher polarisation in case of Ag! compared Sol. Tye he [Agé having 48? 4p? 4d" = 18 electrons (pseudo inert gas. configuration) which having more polarization due to more effective nuclear charge, 2. Which ofthe folowing is incorrect statement Sol Refer notes. 3. During electrolysis of an aqueous S0lUtOR rn Sol. Copper electrodes are reactive electrodes. => At anode: Cu———> Cut + 20 ‘At cathode : Cu® + 26" ——>.cu ‘So, mass of Cu deposited on cathod ‘anode. 1288 of Cu decreased at A. Asaturated solution in AGA (Ky = 3#10-H) AGA SE Ag) + A AQB = Ag + o (ety) x oy) oy 3 y ye Seto; x= i8K10# segs tig, = AMADAD* Sion, AR(ADB) 2 fi = Fraction o edge covered by atoms = 1-75 = 0203 Resonance rene EL ae6. The method of zane cefining of metals is based. Sol. Refer notes. 7. Wich ofthe following compound on reaction. S01 O28 9) ~ OD let 8. Which ofthe fotwing test wil not Sol. Terminal alkyne and ~CH=O group gives ve test with tolens reagent oe Lo rem of ae HCH, i 10. Which of the folowing compound(s) is/are. Sol. f an t A 10 Dt amare fa ttle PN Mt 0108, ‘1. Forthe gven reaction. Sol (A) part (AC,) postive therefore AST; AH T (©)part AG= aH-TAS (©) part AGrio = [OHyep + (ACpl, (200 - 3000) 200 wn 802 12. Select the Incorrect option(s). Sol. (A) H, and He always show negative deviation at very low temperature (below thelr Boyle's temperature), (©) When atvactive forces dominate, Z< 1 and then V. < 2.4L 273 Kand 1 atm, 3 (O)Atcnticalpoint.2= 5. hence rel gas donot behave ike ick ons. 18, The conc statements) about biopolymer Sol. Its noneducing sugar because it lacks hemiactal linkage. its hydrolysis product is BD-Gucose. “)\ Resonance arsonist 6 0. 5 sesame 4D aint ha 800, 4 ster, FO.” BH PaBaso, @) NAH oH cook Be» Secsiime,. Sol. 2) oie ¢ 18. Calculate total pressure at equilbrium... Solis) === 8) + CW Ke, 02-02 o2-x 02 204 280) == 0a) + 280) Keo, 02 x 2 01 ot eos 2 X= 04, V=1LR= 0061 atm K- mo, T= 300K, agar 0-4+0.240:1421 Pye ET TE 10.08% 300 = 10.800 rene 416. Calculate the total pressure developed when SOLA) === BY)> 0) Ko, = 002 ome ant aeezroce x=02V2 arpa MRT , 22008720 «92 wapeg7oaen ‘Arrange the folowing compounds in order of Is the molar conductance. |. More isthe numberof ons and more is the charge on ions, more ” a2 Sd PARAL ame Rt Sol. He 2, Sol ln 720 u 25. He TN418. In which of the following pairs, both the Sol. (A)[NiCiJ?*——> tetrahedral (sp?) INVCN)J>——> ‘square planar (dsp) (©) (CoF, >> octahedral ep°) [C 0(NH)4]°* ——> octahedral (°sp") (©) (N(CO,) ——> tetrahedra (ep?) (NKCNI>——> ‘square planar (dsp?) (©) {Cu * ——> square pana (9%) IN(NH,) "> octahedral (sp*s®) 48. The compound (wis 20. The compound (is. So 21. Number of pais of enantiomers of [Ma,bede] Soi. (Ma,bode) Total GI. = 6 cis +3 trans ‘Ald are opteally actve & ans are opicaly inactive. No of enantiomers pair= 6 22. Boron exist in diferent allotopic forms, 28, Aisin ai. so x+1 on, n meryen, ahh 28, The cross section x dx 80h (A) Re Sea Gxt * Jap tA * BoA © sz (0) Joe 1.0 oe 29, The pressure inside 5200 « Ms tome $200 «5004s solver 3 [hee 23. Gaseous decomposition ofA otlows M oer 30. The fequeney ‘Sol. A(g) —> 2B(g) + Cig) eee om a nt wm + mgr be sits mat 1 ; Af arent oot et e sar5 7 a kK ae i 0.04 rite 1002 10 ‘31. When an object is. 24. The total umber ofsomere 444 & Fo FoF wut ree Oe ee «® ry) © u a Selina Ol 808 Ms 130m woot oe Xe0em 22. 1 cooticient of om. ee (ns0ce Sol. Velocity of separation = 0.5 xv e sea 7 _2aR 4a aoe ime morale BEE 4 AR sm LOS, LOT Bp me aa aD reg lA 1 . -WNResonance WTSOr 440849 -733. A converging lens os 40, Thepotental. — at. Thecharge Sol(40 to 41) “ Weex © 3-x _x-4 | x+10 x” qa te ty wy soe Sovving (9-8 7 “a 1=225.m 42, Thoums 43. Thebox 34. It work done by Sols to #3) 1 Vr ol. Ws Area = 5 nRAT=20J YR Sol. 2 cosh = 5 > Ve10v aU= 5 aRaT = 104 8-80 38. Auniform metal 37. Mass of plank ote Sol S=ute 3 a=02mist 38. A rectangular tank Feixteo Sol. QEt= (m,+mntv-0 et v= my +mnty 39. Anen-conducting 47. A 30d conducting sn 4ucx K(4u—x) , K(2) _ 9 a2 R 2R = {orRsineiese OR, aqeetno 7\|Resonsnce Edveating fo ber tomorow Sol 60. Th Sol. Co he48, Avotimeter and Sol VjeVyze ™, va 49, Ancarthsateite (om Sol. Yo= yga=mve Jnl y24¥8.)_SMm 4 GMm Jn v3 448 aoe 2 4a) a "2 re hs 2a Solving, Ans. ‘nin ~ 20/3 “* 50. The figure shows Sol. Consider the system gasscyinderepston From the conservation of energy, heat given to the system +work done by the atmospheric pres- ‘sure on the system = AU + AKE of the system 6 SORAT + aKE of the ays a-pAal= > 20 x4.2 ~ 10° 10x10 x4.2%107* $2 x 2x 4.8 x4,2 +KE of the system su, 12228 _ 43tand- tan? 0) 3rar6*~ 4=3tan?@ > SoS - aes Bard 1-0 1 2 wee easy ‘54. Let C, and C, be two cies. Sol. CACP=C0.0X (i) ‘and CPCB =Ca.cY by () & @) CX= CY a oma 99.98 a roe areca ace ete ectae +6, (99-99) 0, +0, M0; +,..) +0, 99" ("C,-20,+3.%C, =ororo+ +o-0 58. Number of real solutions, So. poml=3 a on ¥ Y 57, LetpN bethe perpen, sol OP = i2}+3k z 1P029 i + x i $1.20) y we 3 coves OBI KI ia OW-i+2] ONT 4 oP" TONITE -WN Resonance MTSOL110312- 958. Area ofthe region bounded Sol. O Q = (-at,0) ‘Normal at P intersects the parabola at Rat 2 sha 0 2 Slope of OP sm, = 5 Slope of OR ism, OP LOR = ti by tae v2 yet 22 Pa 2, ft? +1 =20V6 2a ava 4 2 Areaot aPORis= >|—2a 0 4] = 18/24 ba -4V2a 4 61. WA(i4 9) +56).0¢1+9) +26) ae [AB caval inclined to the positve direction of axes 3 an7,b=10 Let 0 be the fourth dare 100) £0) bi 1 lima Tt and ALE = tim os ana ee 20 = rye Now lt Me) Oe= 1) (ae + be +2) Co O)= 2) = Fle) = 20-1) (ae + bx-+ 2) + ax +b) x — 1 F1Q)=-6 = b=-2 user()=2 > atbe-t> 21) =~ f+ = 1) Point of intersection of curve y = £) with y-axis is (0, 2) y 2|_4 = Leth of subtangent at (0, 2)= [ar jap] = [6] = 3 ‘Area bounded by the curve y = f(x) and coordinate axis is Io 0" + 6-a7 ix 8 -6 2 Ae] 7 2-4 3 a ’ ce 8 -6 2)fa] fra -6 7 -4|/b].| ab 2 -4 3}le} [ac AkEX > = (@-Na-sb+2080 ta+(7-¥b-40%0 and 28-40 + (3-2) e=0 For non-zero solution (6-2 -6 2 -6 7-2 -4/20 as0.215 2-4 3- 4, Let £510, =) 510.0) Sol 09 + 7\ Resecencs ———nsouiiesa-70 - [2 aie 2 tes ere vero > x) Is nvertble function It FQ) = 96) = Mote) = x > Figbe). gt = 1 1 Now tat) = Tr oom) iy Sol, Let Now1 o > FO" Yrea%0o = GOP = 1+ 9°00 3 Bosse 65. Ascissas of point. 86. The valueot Sol(65, 68) 1 We have 90) = 90) + x90) + 3x9") 1 ne) = 900) a 3 Uxt= ay 8 be + x= 8 3 Uxt~ ay + be —cx+ B= 0 ss Which has 4 distinct real roots. Using Descartes rule of sgn ‘= Given biquadratic equation has 4 distinct postive roots. Let 9) 8nd 2 4 San per geet tant eT 67. PIE) =kil +). Sol. Let P(E)=Kil+ 4) aR Qiiey=1 cee, 3 . = Fae Hine) 8, I a coin selected at random o Sol, Let E be the event that the coin selected is a biased coin. Then S PEPE) & y i+) IC Zeninetin+2) *C, (ne h(n+2)" 4 3 ant an reared poatiy = —PCENPCE/E) DPE Pere) a2 4" a 24 nine tin+2)" an 68. 118 subtends an angle 70. if BC passes through. 01,89, 70) Let B(acosa, asina) and O(acosp, asin) Equation of chord BC is wale ‘(cosa + cos+1) a(sina +sinB) 3 as cro = (oJemty a +B ane een moa taped ana) (4) a2 Loais of he 8° + 2a a= 0 W cor 8 patos though pa thon va(B) oo Pom73. If the reflection of the Sol, Let (4c080 + 4, sind +3) be any point onthe el Image of (4co89 + 4, 3ein@ + 3) about the ne x=y~ i) then co, h-4cosd-4_ k-3sind-3 oa(2-}--(8)-(2-J J] = 2p(0h~a) + 69k = h?+ a Gan + 92 ioeus of 4) 8 = far 2 2. at+2pa rot ey Zt pe- Sat Seo aN ‘ane asp) (a) _(a%+2pa) [p?aq? a td 3 3, 9 9 3 7h. tf 2>0,b>0and Sol Let a= cos, b= snd x-5) y-2 ? toowsar unis (252) « (45?) o a = C208 and + soc + coset +4 9 1806 f= ito ony + a2 = 8 Tatecnso ney seme 2 eg te syemera “ += (tan"8 + CoO) +7...) ‘ ane. Now AM2GM = tant + cot’ 22Vtan? @cot?@ =2 74. If two points P and Q “Ans. Sol Let PO, ¥,) and Ot, 1) Be two points on y= 27 [ies 2 OBE a-1 > xe-tand y=2 (3) +63) OG-i=2 > x=2end y= 72. Wee (2, Tand.. Bec 7 2, oe 7a = OF =-i+2} ns OG = 2116] {09 8 con. and it, = (aso cont. and it. ee ‘By LMT = 00 ~ 40P =61 +8) ox LD=92) 5d 408) ato= 9 cean = /PG- 408 «10 - f=) 75. if number of quadrilateral... roa = mite” 5 Sol.x+y+z+w=n=4 where xyzwet No. = hehtheten-aunere (20 = PT) = PAR) = 15 ALC) FC) Number of solutions *C, ii : Na] nse, Hence numberof quadrilateral ‘rs. Punsz0 [owe KaSRTRIS=K a [Number of prime factors of kis 3. NResenens? —____ sonia2 bm ANSWER KEY PAPER-1 CODE-0 CHEMISTRY ano] +] 2 | 9 an. | a | 68 | co ano | a | @ yt an. | F | tT | Tt ano | 2 | 2 | 2 ‘Ans. | 03 | 08 | «2 PHYSICS 2 | 30 ° 8 o T o- r9;@)-pas as; (0)-ast a MATHS ano[ 7 | # |] © | o | 8 | 2] 8 | & [ie pi A-0,8-0.A)-@).@)-( wo {PP o PAT AT AT ©] Pe] 8 [ooo o-11.0-6 QNo| 57 58 59 60 6 62 6 64 «e FF as Ff | |e |e] +|]si|r iw. 02 aNo| 7 | @ | 0 ‘re. | 07 | 07 | LEM DaennaneoCODE - 0 /\ RESON ECS CHEMISTRY QNo. [of 2 3 4 5 é 7 3 2 0 ans. | € ° ° ° ® ° - 2 A an me | aco] Ac | aBcD. A 8 ano. | 2 2 2 25 : j ane | 6 3 « @ 2 | PHYSICS ‘ane: [26 a 2 28 » HE 2 3 us ‘ans. | __8 D 8 8 c 8 ° A c 8 @.No. | see | 97 38 39 “0 a aa | 4 “| a5 ‘Ane. | 80 | acd | aco | asc | 8 D 3 8 D 2 Taino mf 46 a a nH 50 = 7 ‘Ans. 1 3s | 3 3 1_ lt MATHS ‘ane [ #1 2] aes s 3 36 a 3 Ea a ‘ans. |__¢ c 3 c A c a A | Asc @.No, | 64 2 | 63 e4 65 36 o7 ee oa 70 ‘ane. | AB [ aco | Ad | AG A A c D A A @.Ne.|— 74 72 73 74 75 ‘ans. | 9 5 5 z 3 = MTSOL110312 - 14